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By Henry G. Dorsett

This report is a description of equipment and test procedures used by the Federal Bureau of Mines in laboratory studies on the explosibility of dusts. The principal tests concern ignition temperature, minimum explosive concentra¬tion, minimum electrical energy for ignition, limiting oxygen concentration, pressure, and rates of pressure rise. As new materials often present unique problems, variations in the general procedure and special tests performed are indicated, The general procedures for handling a dust sample from its receipt at the laboratory to the preparation of the report are described. The repro¬ducibility of the respective tests are shown. A brief history of laboratory studies on dust explosions by the Bureau of Mines and a description of current equipment and test procedures used are presented in this report. Its purpose is to facilitate interpretation of data previously published and those proposed to be published on the numerous mineral, agricultural and industrial dusts that have been studied. Through understanding and interpretation of the laboratory data obtained for the parameters of explosibility, preventive measures can be adopted for alleviat¬ing the hazard of dust explosions arising in manufacturing and processing industries.

Jan 1, 1960

By Bernard Porter

The rate of the heterogeneous reaction between high-purity uranium metal and uranium tetrafluoride in molten lithium fluoride was measured. The apparent heat of activation for the reaction is 16.91 kilocalories per mole of UF4. A surface-controlled mechanism is suggested in which UF4 is adsorbed on the uranium metal surface. Additional UF4 reacts with the adsorbed species and the metal site to form an activated complex that decomposes to the product UF3. The reaction is an important source of metal loss in the electrowinning of uranium metal.

Jan 1, 1966

By K. P. V. Lei

The Bureau of Mines investigated molten salt electrorefining 'n helium atmosphere cells as a means for the production of ductile vanadium. 'Electrolytes composed of NaCl-VCl2, LiCl-NaCl-VCl2, BaCl2-KCl-NaCl-VCl2 KCl-LiCl-VCl2, and CaCl2-NaCl-VCl2 were tested. Two electrolytes, KCl-LiCl-VCl2 and CaCl2-NaCl-VC12, were selected for laboratory-scale production tests. A molten salt electrorefining process was developed for the production of ductile 99.6 percent vanadium from a commercial 90-percent grade. Using the CaCl2-NaCl-VC12 electrolyte, an 87-percent recovery of ductile vanadium was made; an 85-percent recovery was made with the KCl-LiCl-VCl2 electrolyte.

Jan 1, 1967

By S. H. Ash

The United States Bureau of Mines has published relatively little on the flooding and unwatering of coal and metal mines. Bulletin 229, Fifty-Nine Coal-Mine Fires, published in 1927, contains several instances of the flooding of mines or sections thereof to extinguish fires but does not describe their unwatering. Report of Investigations 2649, Explosion Hazards Incidental to Unwatering Coal Mines, published in 1924, warned against the possibility of gas accumulations in flooded mines and indicated the precautions to be taken. Report of Investigations 2255, An Unusual Hazard in Reopening Long-Flooded Timbered Metal Mines, published in 1921, told of methane being pocketed and the danger thereof. The flooding of mines originates in many ways. At some mines flooding followed reopening after what was thought to be permanent abandonment; also, explosions have caused some mines to be flooded. Extinguishing fires, accidental encountering of underground streams or flooded old workings, and caves of strata admitting water from underground workings, water-bearing strata, or surface accumulations have also flooded all or parts of mines. Unfortunately, un watering often necessitates much study and causes apprehension largely because experiences in similar situations are not generally known, as few descriptions of successful or unsuccessful methods are available. The job has sometimes been contracted for outside the local management involved and has become a matter of record for the contractor only. As the cost-plus contract system often employed in the past is now known to be expensive, careful managements elect to handle the problem themselves, in line with the general policy of cutting expense where possible. This report describes specific in-stances of successful unwatering by operators.

Jan 1, 1933

By John R. Zelonka

Models made by encasing strain-gage networks in epoxy are described and evaluated. With this technique relatively complex models can be constructed in which any number of gages can be located and alined precisely. Although the gages are an integral part of the model matrix, they create no important mechanical or thermal stresses. Model construction techniques and experimental data proved reproducible and reliable. In addition, the sGlution obtained with these models to the problem of the state of stress around a circular hole in a plate subject to a plane stress condition was in agreement with theoretical, photoelastic, and finite-element solutions.

Jan 1, 1970

By Victor E. Kral

"SUMMARYA preliminary examination of the Buena Vista iron deposit was made in June 1942 by Paul E. Pesonen, mining engineer of the Bureau of Mines. Subsequent examinations were made by D. W. Butner, of the Bureau, in March 1943, and by the author in July 1944, who recommended exploration by diamond drilling, trenching, and sampling. Work on the project was done during the period March 28 to May 26, 1945.Property holdings, comprising 16 claims known as the Buena Vista group, are situated in sec. 4, T. 24 N., R. 34 E., Mount Diablo base and meridian, north Churchill County, about 37 miles east of Lovelock, Nev.Three diamond-drill holes totaling 575 feet were drilled; 45 small pits and ten trenches, totaling 435 linear feet, were excavated, and 84 channel samples totaling 862 feet were obtained under supervision of the Bureau.Purpose of the project was to determine the possible downward extension of the mineralized sections exposed in the outcrops and to determine grade of the ore.Bureau work was confined to one claim only - the Iron Mountain."

Jun 1, 1947

By M. M. Jones

A procedure for the spectrophotometric determination of uranium has been developed in support of minerals research being conducted by the Bureau of Mines. Uranium is separated from the sample by tributylphosphate extraction from acid solution containing added aluminum nitrate and (ethylene dinitrilo)-tetraacetic acid solutions. The colored uranium-dibenzoy1methane complex is developed in the organic phase by adding an ethanol solution of dibenzoylmethane buffered with triethanolamine. Absorbance is measured at 410 nanometers, and the response is linear up to at least 100 micrograms U30S in the aqueous aliquot taken for analysis. Aliquots containing as little as 8 micrograms U30S may be analyzed with relative errors no greater than ±5 percent. For aliquots containing at least 35 micrograms U308, relative standard deviation at the 95-percent confidence level is about ±2.2 percent. Appropriate procedures are given for analyzing a wide variety of samples.

Jan 1, 1980

By J. E. Matta

The Bureau of Mines made laboratory absorption measurements on oil shale samples, which showed that the amount of methane absorbed is proportional to pressure and oil yield, and can be much larger than would be predicted based solely on porosity. Oil shale cores collected in the field were also measured for their gas content using the Bureau of Mines direct method. Cores taken from deep locations and far from outcrops yielded more gas than cores from shallower locations or at outcrops, when taking into account variations in oil yield, and all data indicate that oil shale mines that are both deep and far from an out-crop will emit low levels of methane gas.

Jan 1, 1977

By Harry F. Weaver

Rivers in industrial and raining areas frequently are contaminated by material dumped into them causing the water to carry in suspension large amounts of silt, which subsequently is deposited alone; the banks and, ultimately on the agricultural lands if the water is used for irrigation purposes. Two common examples of this practice are the dumping of breaker refuse in the anthracite region of Pennsylvania and the dumping of tailings from the metallurgical mills in various metal-mining districts. Studies in stream pollution and its resultant problems are very important, and surveys are constantly being made by Federal and State agencies, as well as by private companies, to determine the quantity of solids actually being carried by these watercoarses. These studies require accurate sampling of the silt-carrying water to determine the amount of solids within reasonable limits. A device that will obtain reasonably accurate samples of material from silt-bearing streams is described in this circular.

Jan 1, 1943

By Hal D. Peterson

In research sponsored by the Bureau of Mines, a technique was developed for simulation of heap leaching on uranium ores. The equipment used for this simulation consisted of 2-ft-diam columns, constructed in sections, such that ores as coarse as minus 4-in could be treated in bed depths ranging from 8 to 18 ft with test condition variations. The technique consisted of the separate steps of ore preparation, column loading, charge wetting, leaching, washing, and residue recovery. For the ores studied, sulfuric acid was found to be generally superior to alkaline lixiviants. The rate of uranium extraction by acid leaching proved" to be primarily a function of percolation rate, alkalinity of the ores and oxidant requirements of the ores. Column leaching was closely comparable to field-scale heap leaching in terms of uranium extraction rate and recovery results. Acid and oxidant requirements were lower for the field-scale operation. All column tests, as well as the field-scaly heap, achieved in excess of 96-pct uranium extraction on a Bear Creek, Wyoming ore.

Jan 1, 1985

By R. W. Smith

The Bureau of Mines has been engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies were designed to provide basic thermodynamic information of high accuracy, facilitating the theoretical study of flame and combustion phenomena.4 This report is the fifth of a series5/ presenting results of the study for particular fuel-oxidant systems. These calculations have as their objective the constant pressure flame temperature of acetylene-air for a range of pressures.

Jan 1, 1954

By Harold P. Rue

The problem of removing hydrogen sulphide from natural gas has become within the last few years one of major importance to the natural gas and petroleum industry. Several gas fields in the United States produce natural gas containing hydrogen sulphide, and a number of oil fields produce gas which contains hydrogen sulphide. 3 The percentage of hydrogen sulphide in natural gas produced in these fields varies from a fraction of 1 per cent to as high as 20.5 per cent by volume. Hydrogen sulphide is probably the most toxic gas associated with natural gas, and from the standpoint of health and safety it is important that the hydrogen sulphide be removed if the gas is to be used for domestic purposes. Hydrogen sulphide, besides being toxic and therefore a hazard to animal life, is under certain conditions an active corrosive agent and very destructive to equipment. The annual loss caused by the corrosive action of hydrogen sulphide on equipment amounts to hundreds of thousands, perhaps millions, of dollars. The largest percentage of natural gas produced in the United States comes from wells which also produce oil. This associated gas invariably carries with it light fractions of petroleum, which when separated from the gas, condense to the liquid form at ordinary temperatures and pressure. Commercial application is made of this natural condition, and "wet gas" is processed to obtain so-called natural gasoline by employing the principles of absorption, adsorption, or compression and subsequent expansion accompanied by cooling. In the manufacture of natural gasoline from wet gas which contains hydrogen sulphj.de, if this contaminating gas is not first removed, some of the hydrogen sulphide may oxidize to form free sulphur and water. The free sulphur will dissolve in the gasoline produced by any of the aforementioned methods and cause the product to be positive to the corrosion test and there-fore unsuitable for commercial use in that condition. The objectionable sulphur compounds can be removed by washing the gasoline with a solution of caustic soda or other chemicals, but this treatment is expensive. It is advantageous therefore to remove the hydrogen sulphide from the gas before it is processed in a natural-gasoline plant.

Jan 1, 1932

By R. L. Montgomery

Heats of solution of cerium metal and cerium (III) chloride in hydrochloric acid were measured. The standard heat of formation of the aqueous cerium (III) ion at 25° C is -166.1 ± 0.3 kcal/mole. Heats of solution of cerium (III) chloride in hydrochloric acid are consistent with the existence of a complex CeC1++ having a stability constant of 1 and a heat of complexing of 5.4 kcal/mole.

Jan 1, 1962

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the Items is confidential. It present's analytical data for 4,608 samples, representing the products of 101 companies. The samples were collected during December 1956, January and February 1957. As in previous surveys, the gasolines covered by this survey include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation. A list of the Notional Motor Gasoline Survey reports published during the post 10 years is given on page 5.

Jan 1, 1957

By Leonard Obert, Wilbur Duvall

"INTRODUCTION 'The investigation reported herein is part of a comprehensive research program being conducted by the Metal Mining Research Section, Mining Division, Bureau of Mines, on pressure problems in underground mines. This program was initiated in 1937 and for the first 3 years was concerned primarily with measurement of the pressure on mine pillars and supports and their strength. 4/ 5/ During this period, investigations were conducted in both the laboratory and the field in the comparatively shallow load and zinc mines of Missouri and Oklahoma. As a result a seismic method of determining the pressure on mine pillars was developed.Before this research program was initiated, Chas. F. Jackson, chief of the Mining Division, suggested that rock under pressure might give rise to noises inaudible to the unaided ear - that is, subaudible noises. As a result of this suggestion, listening tests were made concurrently with the routine pressure measurements to see if any rock noises were present; with one exception, it was found there were no rock noises in any of these shallow mines. At the same time, pressure measurements disclosed that, with one exception, pillars were not under pressure amounting to more than 10 percent of the crushing strength of the rock. The one exception was a pillar in the Big John mine of the Eagle Picher Mining & Smelting Co. in the Tri-State district, which showed some physical evidence of failure, such as small cracks and spalling; it was reported that the pillar had been heard to crack or snap at intervals. Listening tests in this pillar disclosed that subaudible noises of comparatively small intensity were present and occurred at 1- to 2-minute intervals, on the average. Unfortunately, owing to the shortness of this pillar it was impossible to make any pressure measurements."

Jul 1, 1942

By William E. Dennis

"INTRODUCTION The San Antonio Canyon prospect was examined by engineers 3/ of the Bureau of Mines in March 1943 and again in October 1944. In July 1944, the United States Geological Survey mapped the prospect and submitted a report 4/ recommending core drilling by the Bureau of Mines. The drilling project, which was supervised by the author, was started on January 10 and completed on May 10, 1946.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work, and prepares the final report. The Metallurgical Branch, O. C. Ralston, chief, analyzes samples and performs beneficiation tests. Acknowledgment is made to W. D. McMillan, engineer in charge of the Austin field office, and to J. H. Hedges, chief of the Tucson Division, Mining Branch, for general direction and advice. The samples were analysed in the laboratory of the Metallurgical Branch at Rolla, Mo., C. Travis Anderson, chief."

May 1, 1947

By George S. Rice, J. W. Paul, E. H. Denny

Data assembled by the Bureau of Mines , coupled with requests from coal companies , have emphasized the desirability of establishing standardized specifications for brattice cloth with particular respect to durability and fireproofing . Brattice cloth is a canvas or other material , often covered with some fireproofing composition , which is used extensively in coal mining for temporarily deflecting air into pillar workings and maintaining ventilation at the working faces . These specifications will be established , it is planned , through a cooperative program in which the U. S. Bureau of Standards will make a series of tests of various brattice cloths treated with respect to fire- resisting qualities and the U. S. Bureau of Mines will continue to assemble field data on the use of brattice cloth . Plans now are being made for this cooperative work. Without attempting to make a complete survey , the Bureau of Mines has made preliminary studies and investigations , and verious representative coal - mining companies have furnished detailed information . The information thus gained will be used as the basis for the cooperative investigation , but the Bureau of Mines would welcome additional information from mine operators on the character and weight of brattice cloth , conditions of use , durability , quantity employed and price . Such information should be sent to the Director , Bureau of Mines , Washington , D. C. The mine operator is interested in procuring at reasonable cost a brattice cloth with lasting fireproofing quality and of as great durability and strength as possible . There has been a lack of assembled data and knowledge regarding the subject , but the Bureau of Mines feels that this lack of knowledge may be overcome if the coal -mining companies will lend their hearty support to the cooperative investigation and submit information relative to the use of brattice cloth in their own properties . Information contained in this report is based on data obtained from coal operators in bituminous districts of Pennsylvania , Alabama , Utah , Indiana , Illinois , Colorado and Nova Scotia .

Feb 1, 1923

By Launa Mallett, Charles Vaught, Michael J. Brnich

Purpose: This training material focuses on the content of emergency warning messages. Research has shown that when an emergency occurs, people often do not get the information they need for the purpose of taking appropriate action. This safety talk presents a procedure, using mental cues that can be used by senders and receivers of emergency warnings. Intended Use: This material has been developed for use in short safety-training sessions such as start-of-shift safety or Atoolbox@ talks. The information can be presented in approximately fifteen minutes and is appropriate for workers at all experience levels. While the examples and illustrations are taken from the underground coal mining industry, the training can be tailored to any work setting by substituting appropriate examples. Materials Needed: The instructor will need to prepare the figures provided in a form that can be seen by the entire class. Suggested methods include the use of: (1) overhead transparencies, (2) laminated pages that can be held up for small groups, and/or (3) handouts with copies of the figures for each trainee. As a supplement, stickers featuring the communication triangle can be placed on hard hats, telephones or other communication devices to remind workers about the key to effective emergency communication. The Talk: The accompanying script is a guide for presenting this safety talk. Training is enhanced if these materials are covered but not simply read by the trainer. Examples given in this guide are from real experiences. To make training more interesting and effective, the instructor can substitute examples from his/her workplace. Additional Resources: The following references will provide further information about communications during emergencies. Auf Der Heide, E. (1989). Disaster Response: Principles of Preparation and Coordination. The C.V. Mosby Company, St. Louis. Mallett, Launa, Charles Vaught, and Michael J. Brnich Jr. (1993). A Sociotechnical Communication in an Underground Mine Fire: A Study of Warning Messages During an Emergency Evacuation@, Safety Science, 16, pp. 709-728. Nigg, J.M. (1987). A Communication and Behavior: Organizational and Individual Response to Warnings@ in Sociology of Disasters: Contributions of Sociology to Disaster Research, R.R. Dynes, B. De Marchi, and C. Pelanda (eds.), Franco Angeli, Milan, Italy, pp. 103-116.

Jan 10, 1999

By H. R. Babitzke, H. Kato, R. E. Siemens, G. Asai

The purpose of this investigation was to develop a wide variety of columbium and tantalum alloys and to determine their suitability for use at elevated temperatures . Sixty - nine columbium and tantalum alloys were investigated . For this study , columbium was alloyed with two or more of the following : nium, tungsten , vanadium , titanium, and zirconium . Tantalum was alloyed with vanadium or hafnium, or hafnium and carbon . The fabricability was determined by an arbitrary procedure . Hardness measurements , elevated - temperature tensile properties , and oxidation- resistance studies were made . Of the alloys studied , Cb - 15 Hf - 5W, Cb - 15Hf - 5W- 10Ti , Cb - 15Hf - 10W- 10Ti , Cb - 10V - 5W, Ta - 30V , and Ta - 20 to 33Hf exhibited excellent high - temperature properties . These alloys were not only easy to fabricate , but they also had good oxidation resistance and excellent high- temperature strength .

Jan 1, 1964

Three complete connector assemblies and ten separate contacts were submitted to a series of tests to establish the connector permissibility and compliance with the Bureau of Mines' research Contract H 0110423. Test Procedure TPC-0100 was coordinated, and the test plan approved by the Bureau as fully complying with the intent of the contract for the low voltage, medium voltage and high voltage A.C. connectors. The components and connector assemblies have been demonstrated in testing that they meet or exceed all the requirements of the test procedure.

Jan 1, 1972