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By Frank A. Peters

This Bureau of Mines report is the second of a series of process evaluations planned to determine the relative processing costs of producing metallurgical-grade alumina from low-grade aluminous materials. Included in these evaluations are recommendations for additional research and development to improve the processes and to lower their costs. The design for each process is based on published work. The processes considered in this report are designed to extract alumina as aluminum chloride from calcined clay with 20 percent hydrochloric acid and to remove the silica residue by filtration. Iron is removed by one of the following processes: Isopropyl ether extraction, in which iron chloride is extracted before decomposing the aluminum chloride; gas precipitation, in which the aluminum chloride is precipitated with hydrogen chloride while leaving the iron chloride in solution; gas precipitation-isopropyl ether extraction, in which the aluminum chloride from precipitation is extracted with isopropyl ether, if necessary; caustic purification, in which a crude alumina is produced and then purified by a modified Bayer operation; or sinter purification, in which a crude alumina is produced and then purified by a lime-soda sinter operation. For plants producing 1,000 tons of alumina a day the estimated operating costs per ton of alumina are: [Isopropyl ether extraction process $ 65.09 Gas precipitation process 89.04 Gas precipitation-isopropyl ether extraction process 119.65 Caustic purification process 73.79 Sinter purification process 80.47] The estimated fixed capital costs per annual ton for these plants on a Marshall and Stevens chemical equipment basis of 240.0 are: [Isopropyl ether extraction process $229.03 Gas precipitation process 287.16 Gas precipitation-isopropyl ether extraction process 356.59 Caustic purification process 266.48 Sinter purification process 279.13]

Jan 1, 1962

By J. Litsenberger, T. E. Marshall, P. R. Coyle, L. J. Prosser, A. T. Iannacchione

For the first time in an underground stone mine, the relationship between roof movement and microseismic emissions was examined in conjunction with two distinct roof fall areas. As roof monitoring increases in acceptance and monitoring technology advances, the goal of providing reliable roof fall detection systems to enhance the safety of underground mine workers moves closer to reality. Instrumental to reaching that goal is the ability to interpret accurately and completely roof movement and microseismic emissions, which can serve as precursors to roof falls. This paper examines the capabilities of convergence and microseismic monitoring systems to better understand roof rock failure mechanics and to anticipate roof falls. An understanding of how these techniques are used and how they interact with each other is critical in developing the most effective ground control strategy for our nation’s mines.

By A. W. Hall

A neutron meter was developed for monitoring the sulfur content of coal streams. Neutrons from 80 micrograms of californium-252 penetrate the coal, producing thermal neutrons that are captured by atoms of elements present in the coal. The excited atoms emit prompt gamma rays with energies characteristic of the capturing element. These gamma rays are detected with a 6-by 7-inch sodium iodide detector and processed by electronic equipment to produce a gamma ray energy spectrum of the elements. Tests of the meter at a commercial coal preparation plant showed that sulfur in moving coal can be determined to a precision of 0.05 percent sulfur within 2 minutes. Based on this report by the Bureau of Mines, reliability of the coal-handling system proved inadequate for long-term operation, however, and improvements are planned.

Jan 1, 1975

By T. M. Klemetti, G. M. Molinda, D. M. Pappas

Some of the most difficult coal mine roof in the U.S. can be found in the Illinois Basin. Factors contributing to the high roof fall rate include: weak moisture-sensitive roof rock, high horizontal stress, and limited longwall mining. The depth of cover ranges from 90-1,000 ft and roof damage from horizontal stress can be severe. Moisture sensitive-roof rock is common above the Springfield-Harrisburg Herrin #5 and #6 seams in the Illinois Basin, and contributes to roof skin deterioration. The roof fall rate increases significantly in the humid summer months. The National Institute for Occupational Safety and Health (NIOSH) has shown, using lab and field studies, that highly moisture-sensitive roof rock can be directly correlated to poor roof conditions. Controlling the skin is the key to reducing rock fall injuries, and roof screening is, by far, the best remedy. Illinois Basin coal operators have been successful in reducing the number of rock fall injuries in recent years. NIOSH has documented best practices for screen installation which has resulted in safe, efficient operations. Other solutions to skin failure include: the use of denser five bolts per row patterns to reduce spans between bolts, systematic supplemental support in intersections, straps and large pans protecting operators, and air conditioning to remove moisture from the intake air.

By R. V. Higgins

As part of a study of application of the Buckley-Leverett method to an analysis of oil-reservoir performance covering a wide range of relative permeabilities and oil saturations, a method has been devised for quickly deter-mining average water saturation at breakthrough from relative permeability data. The base for the relative permeability used in the report is either the permeability to air or the effective permeability to oil at the irreducible water saturation. The permeability to air also was used because of the large backlog of air permeabilities available to reservoir engineers. The basic data were calculated by an electronic computer and are presented in a single graph from which the point of breakthrough may be obtained. In this study the water saturation at the beginning of the depletion is the connate or interstitial or irreducible water saturation. These water saturations are considered to be synonymous and to have a practical value.

Jan 1, 1960

By David W. Houseknecht

Probabilities of encountering coalbed discontinuities during vertical or horizontal drilling in a specific coalbed can be estimated based on analysis of mined-out areas of the coalbed where the size, shape, orientation, and distribution of discontinuities are known. The result- ant probability estimates can be applied to cost-risk evaluations of drilling programs proposed for exploratory, developmental, or methane drainage purposes in undeveloped areas of that coalbed. Data compiled from mine maps of the Beckley Coalbed in southern West Virginia were used to estimate the probabilities that discontinuities would be encountered in two illustrative hypothetical drilling programs--one for drilling vertical boreholes and the other for drilling horizontal boreholes. Analysis based on a mined-out area of the Beckley Coalbed indicated that vertical methane drainage boreholes spaced 1,000 feet apart in a square grid pattern would each have a 29 percent probability of encountering a discontinuity in a geologically unexplored area of the coalbed. It was also determined that exploratory vertical drilling could locate most of the discontinuities if a borehole spacing of 2,500 feet were used. For horizontal drainage boreholes in the Beck- ley Coalbed, the analysis indicated a linear relationship between hole length and the probability of encountering a discontinuity.

Jan 1, 1982

The strike of the Canadian asbestos miners entered its seventh month with increasing signs of early termination. Both unions are in the midst of heavy negotiations with management, and an optimistic industry source predicted that work would resume by October 1. Recession recovery in some segments of the asbestos manufacturing industry is being impeded by lack of fibers, CADMIUM - On September 9, St. Joe Minerals Corp. reduced the price of cadmium metal to $2.75 per pound. The producer price bad been uniformly quoted at $3.00 per pound since June 26, 1975. Subsequently, Amax, Inc. and National Zinc Co. reduced their prices to $2.50 per pound. By mid-September all five U.S. cadmium producers were marketing the metal at $2.50 per pound.

Jan 1, 1975

By W. P. Yang, L. B. Berger, G. W. Jones

"Any burning carbonaceous material, unless supplied with enough oxygen for complete combustion, will liberate carbon monoxide. Since tobacco in its many different forms consists largely of carbonaceous material, and duo to the conditions under which it is smoked (burned), carbon monoxide should be liberated. That this is true has been shown by Armstrong.***** who found that undiluted smoke from cigars contained in some tests more than 3.00 per cent carbon monoxide, the amount present depending upon the size and closeness of packing of the tobacco during manufacture and on the rate of burning.****** Cigarets gave much less CO, varying from 0.06 to 1.40 per cent. The rate of consumption and carbon content of the tobacco are not g.ven, so that a correlation of the values reported to conditions in closed spaces where people might be assembled are difficult, if not impossible.The Bureau of Mines is interested in the general question of carbon-monoxide hazards from tobacco smoke, mainly with regard to mine ventilation. In non-gaseous mines, especially metal mines, the question arises, whether, if groups of miners are permitted to smoke while working at unventilated faces or entries, would the accumulation of tobacco smoke in these places create an' additional hazards the to carbon-monoxide poisoning. The results should, in addition be of general interest in connection with ventilation of building and inclosed places where people may be assembled and smoking is permitted. The investigation described in this report was made with the above idea in view."

Oct 1, 1923

By T. Estelle Gardner

The Bureau of Mines made enthalpy measurements on sodium bromide and sodium iodide in the temperature range 400° to 1,200° K using an ice calorimeter. Equations representing enthalpy as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate smooth values of heat capacity, enthalpy, and entropy at 50° K intervals from the ice point to 1,200° K. The melting point determined for sodium bromide was 1,020° K; the melting point of sodium iodide was 934° K. The heats of fusion of sodium bromide and sodium iodide were calculated to be 6,270 and 5,680 cal/mole, respectively.

Jan 1, 1967

By M. H. Kline

The Scarlet mine, in Randolph County, N. C., was operated on a small scale at intervals from 1899 to 1915, but no records of the quantity of ore produced are available. J. I. Moore unwatered the mine in March 1948, and Bureau of Mines' engineers examined the underground workings. Several assays checked previous sampling of the mine and indicated a small but comparatively high-grade copper-zinc deposit. The high metal content of the veins and the possibility of developing additional reserves prompted the Bureau of-Mines to drill three holes, totaling 530 feet, at the deposit during March and April 1948. Drilling disclosed that the mineralized vein did not extend over 300 feet along the strike and is probably limited in depth to the contact with the granite mylonite.

Jan 1, 1949

By G. R. Hopkins

"Summary An apparent decline in fuel efficiency at refineries, which first became came evident in 1930 and continued through 1933, was checked in 1933 when the average amount of heat needed to refine a barrel of crude oil amounted to 660,000 B.t.u. This compares with an average requirement of 692,000 B.t.u. In 1932 and with a low of 639,000 B.t.u. in 1929. (See fig. 1.) The improvement in fuel economy in 1933 probably was closely related to the increase of 5 per cent in crude runs to stills. As much of the fuel burned at refineries is utilized for purposes other than under crude-oil stills and in relatively stable amounts, it is evident that a material increase in crude runs will usually reflected in a decrease in average fuel requirements. Another factor which has influences fuel economy at refineries in the past is the trend in cracking, a refining process requiring more than the average expenditure of heat. In 1933 production of gasoline by cracking increased slightly, but no appreciable rise in heat requirements resulted as an equivalent amount of fuel was saved in improved technique, particularly in the field of heat exchange.Since the beginning of the refining industry, the transition in fuels has been from solid to liquid to gaseous; in other words, the leadership was first held by coal, then passed to oil, and is now held by gas. In 1933, 54.7 percent of the total heat units generated came from gas, 39.0 percent from oil (including acid sludge), and 6.3 percent from coal and coke. The principal change in the relative importance of the various refinery fuels in recent years has been the rapid growth in consumption of refinery or still gas at the expense of all the other common fuels. Still gas owes its ascendency to its cheapness and availability, and probably it would have become the primary refinery fuel years ago if recovery methods had been perfected. The relative importance of coal showed a small increase in 1933, the first gain recorded since these surveys were inaugurated in 1925. The increase in use of coal was undoubtedly due to increased operations at plants using it,"

Feb 1, 1935

By Welby G. Courtney

The Bureau of Mines conducted a field test program in the Pittsburgh coal seam to investigate the effect of water sprays in the suppression of respirable dust being formed while cutting with a continuous-mining machine. Emphasis was given to the location of spray nozzles on the top and bottom of the cutting boom. Results showed that (1) sumping caused about 60 percent of the dust escaping the face area, and shearing and loading caused the other 40 percent; (2) during sumping, top and bottom sprays were equally effective in dust suppression and reduced dust ~13 percent; (3) during shearing and loading, bottom sprays reduced dust 61 percent and were about 50 percent more effective than top sprays; (4) the combination of top and bottom sprays was slightly more effective than the separate systems, but water consumption increased 60 percent; and (5) inclusion of throat sprays decreased dust reduction by removing some of the water from top and bottom sprays where it was more effective.

Jan 1, 1978

By J. H. Adkins

The goal of this program was to produce a set of baseline health and safety training materials that could be used by the metal/nonmetal mining industry to reduce injuries and to comply with federal training requirements. The materials developed are arranged in a two level outline format. The first level provides the title, course goals, background and topical outline while the second level provides a detailed outline of the course content. Visuals, designed to portray miners in a positive, attractive fashion, were done in simple line drawing so they would reproduce for handouts without loss of quality. Each of the required units in the Baseline Guides have one or more self-checks. These are designed to be suggestive of evaluation techniques the users can develop for themselves. An instructors guide and a mining terms glossary are included. In a second phase the program developed performance based training guides for Annual Retraining and Experienced New Hires in the Underground Salt Industry.

Jan 1, 1983

By L. K. Weaver

The purposes of this Bureau of Mines report are to review the history of the domestic offshore hydrocarbon production; to project offshore oil and lease condensate production from 1971 through 1985; and to show the impact of offshore development on the onshore segment of the petroleum industry. Since 1954, offshore production has provided an increasingly larger portion of the domestic oil production. Domestic offshore oil and lease condensate production has increased from about 2.0 pct of the U.S. total in 1954 to 16.7 pct in 1970. Likewise, marketed gas production has increased from 1.0 pct of the U.S. total in 1954 to 15.0 pct in 1970. The past performance of exploration, leasing, development, and production of the offshore petroleum industry was used to make projections of offshore oil production. A comparison between onshore and offshore operations was also made. Assuming a tentative Department of the Interior offshore leasing schedule is completed by 1980, the authors estimate that by 1985, about 30 pct of domestic crude oil and lease condensate production from the lower 48 States will come from offshore areas. Currently, leasing of Federal offshore areas has been delayed due to environmental considerations. The rate at which off-shore hydrocarbons will enter the energy market will depend, to a large extent, on how soon environmental considerations are resolved. Assuming that offshore leasing will resume in the near future, U.S. offshore production of crude oil and lease condensate should be about 934 million barrels in 1985.

Jan 1, 1973

"INTRODUCTION AND ACKNOWLEDGMENTSAt the request of the lessees, the Pearl tract was examined in February 1946, by Otto Ruhl, an engineer of the Bureau of Mines. From the evidence of old drill logs and from the few available records of mining operations on the Pearl and the adjoining Trussel (Big Tom) tract, it appeared that a relatively small churn-drilling program might develop enough lead-since ore to justify resumption of mining. In March 1946, funds were allotted for churn drilling, and the work was begun the following month. Ten holes totaling 1,933 feet were completed before the close of the project in August 1946. The work was under the general supervision of C. H. Johnson, chief, Rolla Division, Mining Branch, and under the direct supervision of the Bureau project engineers. 3/In its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to our national security and economy, It is the,of the Bureau to publish the facts development by each project as soon as possible after its conclusion. The Mining Branch, Lowell B. Moon, chief, makes preliminary examinations and conducts investigation of mineral deposits. The Metallurgical Branch, O. C. Ralston, chief, participates in this program by making beneficiation tests and analyses. In the present project, no metallurgical tests were made, and for the sake of speed the samples taken were analyzed by a local commercial assayer. 4/"

Jul 1, 1947

By T. J. Ballard

The Ore Knob mine, in Ashe County, N.C., was one of the largest producers of copper in the eastern states during the 1870's. The ore occurs in a fissure vein, which strikes N. 64° E. and dips nearly vertical. The country rock is granite gneiss. Drilling indicated that the vein structure is approximately 200 feet wide and 1,500 feet long. The vein material shows evidence of replacement of the original gneiss by sulfides. Solution cavities in the vein were noted in some places. The ore minerals and pyrrhotite, chalcopyrite, pyrite, and minor quantities of sphalerite. The gangue contains biotite, magnetite, albite, calcite, and many silicate minerals.

Jan 1, 1948

By R. C. Anderberg, F. J. Caervenyak, F. J. Frattali, H. J. Kandiner, R. A. Brown

"INTRODUCTION Considerable interest was shown .prior to and during World War II in the winning of metallurgical-grade alumina from anorthosite, kaolin, siliceous bauxites, diasporic clays, and other aluminum-bearing ores. Laboratory and pilot-plant investigations were made on many of these ores by the Bureau of Mines, and a series of reports on them is being prepared. This report covers the tests made on the application of the lime-soda-sinter process to anorthosite, which is a mixture of albite, NaAlS1308, and anorthite, CaAl2Si208. Extensive deposits of anorthosite occur in the Laramie Range in Wyoming and extend into Colorado; other deposits are found in New York, with outcroppings appearing in Vermont, Maine, and Labrador.Anorthosito can not be treated by the Bayer process for the production of metallurgical-grade alumina, because excessive losses of soda and alumina occur from the formation of sodium-aluminum silicate due to the large amount (50 percent) of silica in the ore.RESULTS OF INVESTIGATIONSSmall-scale laboratory tests supplemented by pilot-plant runs have demonstrated that the alunina and soda occurring in the Wyoming anorthosite from the Laramie Range can be extracted and recovered satisfactorily by the lime-soda process. It has been shown that liquors containing approximately 95 gram of A1203 per liter can be consistently produced at Na20:A1203 ratios from 1.75 to 2.27, and that these liquors can readily be desilicated and carbonated to yield high-grade alumina trihydrate of quality comparable to that essential for cell-grade alumina. The optimum results were obtained with Na20:A1203 mol ratio of 1.03 and Ca0:Si02 ratio of 2.14 in the sinter when calcined at an average temperature of 2,444ºF. for 25 minutes."

Nov 1, 1947

By Lulie H. Crump

U.S. supply and demand data for petroleum and natural gas liquids, by States and regions, were tabulated for the years 1960 and 1965. Estimates arcs provided of State-by-State quantitative data for the petroleum and natural gas liquids industry that can be integrated into State, regional, and national energy balances by source, form, and consumer sectors, and used for determination of interstate and interregional energy flows. Tables 1-4 show the estimated total supply of petroleum available for consumption and the supply's distribution among the major consumer demand sectors (household and commercial, industrial, transportation, and electricity generation). To obtain summary figures for the major proportion of refined products by States, individual tables were compiled for the six major products (tables 5-16). To enable comparison of petroleum data with those for other energy forms, conventional volumetric data in barrels were converted to their British thermal unit (Btu) equivalents. Interregional shipments of crude petroleum and theoretical flow patterns for petroleum products are shown in figures 1-4.

Jan 1, 1969

By Lucia Kuizon

The Antimony RARE II area is underlain principally by Mesozoic igneous rocks associated with the Sierra Nevada batholith. The San Andreas fault zone is near the southern boundary. Metallic mineral deposits are associated with the fault zone. These deposits were formed from magmatic solutions, and tend to be along shears and fractures within the country rock. Marble and dolomitic marble deposits occur in Paleozoic roof pendants or inclusions in the Mesozoic intrusive rocks in the area (Troxel and Morton, 1962, p. 52).

Jan 1, 1982

By Donald C. Strimbeck

The Bureau of Mines designed a down-fired refractory-lined combustor that efficiently burned pulverized coal to produce a gas suitable as working fluid for an open-cycle gas turbine. The gas contained relatively little carbon, so the load on the ash-separation equipment was significantly reduced. Moreover, reduction in carbon content of the gas increased the average density of the solid particles making them more amenable to removal by centrifugation. Centrifugal-type separators failed to remove sufficient ash; however, to limit blade wear enough to achieve operating periods generally deemed necessary for commercial practicability.

Jan 1, 1969