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By Will H. Coghill, G. Dale Cole

"INTRODUCTION This paper describes a method for the rational sorting of particles by means of a laboratory batch jig. Its purpose is to show that a material can be reliably appraised for gravity concentration without the drudgery of sink-float fractionations.Development of the batch- jig method of testing was incidental to a study of the Birmingham, Ala., red-iron ores now being conducted by the Bureau of Mines in cooperation with the University of Alabama and the ore-producing companies.APPLICATIONOres and coal are commonly tested for their gravity-concentration characteristics by specific-gravity dissections in heavy liquids. The heavy liquid most commonly used for coal is zinc chloride and for ores they are benzene, carbon tetrachloride, acetylene tetrabromide, methylene iodide, and thallium malonate formate. The last is poisonous and corrosive to the skin but is essential for separations in the 3.3 to 4.4 specific gravity range. The last two of these liquids are expensive, and several of them are hard to obtain now.Although it is not suggested that heavy-liquid dissections be eliminated entirely, sometimes a more reliable evaluation of coal and ore can be obtained by other and more simple means. For example, sink-float data were unsatisfactory as a guide to commercial gravity concentration of a red-iron ore because they did not take into account the difference in particle shape of the hematite and gangue and the differences in true and apparent specific gravity of the hematite grains, some of which were porous. For this ore, the batch-jig method of testing herein discussed proved advantageous. Not Only did the batch-jig data give a truer picture of the concentration problem, but only about one-tenth the time of the conventional sink-float tests was required."

Jul 1, 1944

By Thomas H. Dubaniewicz

Thirteen miners died as a result of 2 explosions in the Jim Walter Resources No. 5 mine near Brookwood AL in September 2001. Both explosions were ignited in intake air entries, and both were probably ignited by electrical equipment. With few exceptions, permissible equipment is not required in intake air entries of US underground coal mines Researchers with the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory. studied the electrical equipment ignition sources for the Brookwood and other w disasters to develop recommendations for preventing similar disasters Adherence to National Electrical code® requirements for flexible cords installed in hazardous (classified) locations may have prevented the second massive Brookwood explosion. The 30 CFR Part 7 requirements for battery assemblies should be reevaluated, taking into consideration United Mine Workers of America recommendations and the Zone 1"increased safety" standard requirements for battery assemblies, Class 1 Division 2 or Zone 2 explosion protection techniques are recommended for intake air equipment so that they do not present a methane air ignition source under normal operation before mine power is shut down during emergencies Battery powered circuits intake air that are likely to remain energized during emergencies should be protected by more stringent protection techniques, to protect rescue/recovery personnel. Index Terms -Class 1 hazardous location, mine explosion, flexible cord, battery assembly, permissible equipment

By E. C. Pattee

A mobile spectroscopic laboratory was completed by the Bureau of Mines in 195 to provide a rapid, inexpensive means of field testing samples for beryl¬lium and other associated metals of possible commercial importance. Spectro-copes have been used in laboratories for many years in various types of research and routine analyses, but this spectroscope is probably the first mobile unit. The laboratory provides for spectroscopic, radioactivity, fluorescent, and limited chemical tests of samples. The unit has been a valuable reconnaissance tool. It has been used to search for beryllium, cesium, columbium, tantalum, rubidium, and lithium in Idaho, Washington, and Montana. Several very low grade deposits of these elements were found, and occurrences of other important elements were identified; however, none are of economic importance. The spectroscope permits the detection of elements by analysis of visible light produced when elements in a small powdered sample are volatilized in an electric arc., A total of 70 elements can be detected; 29 can be detected at or below 0.01 percent, Electric power for the arc is supplied by a gasoline motor-driven generator, Equipment is housed in an aluminum van, mounted on a 4-wheel-drive vehicle for easy maneuverability on mountain roads, A trailer with crushing, pulverizing, and splitting equipment permits the reduction of samples to a small representative pulp.

Jan 1, 1963

By Richard J. Mainiero

Traditional techniques for the experimental determination of toxic fumes produced by the detonation of high explosives are not applicable to blasting agents. To detonate properly, blasting agents require confinement, a significant booster, charge diameters of 3 inches (7.5 cm) or greater, and charge lengths greater than two-times the charge diameter. Without these conditions, blasting agents will not detonate at full order, leading to a misrepresentation of the gaseous products. A facility for detonating large, confined charges in a controlled volume has been constructed at the Pittsburgh Research Center’s Experimental Mine. The facility consists of a portion of mine entry (once used for full-scale mine explosion research and demonstrations) enclosed between two explosion proof bulkheads. Total volume of the chamber is 9,666 ft (274 m). The chamber is equipped with an air circulating system and is3 3vented using the mine's airflow. Up to 10-pound (4.5-kg) charges can be detonated in the chamber using a variety of confinements. For a typical test, the blasting agent is confined in a 4-inch (10-cm) schedule 80 steel pipe and initiated by a 3-inch (7.5-cm) diameter, 1-inch (2.5-cm) thick Pentolite booster. This combination of confinement and initiation yields a detonation velocity of about 4,000 m/sec for ANFO. This velocity is in line with that measured for blasting in the field. Twenty four 2-inch thick steel plates are suspended around the pipe bomb to stop shrapnel that would otherwise seriously damage the chamber. Following detonation of an explosive in the chamber, a circulating fan is run for about 10 minutes to uniformly mix the chamber atmosphere. Fumes samples are taken out of the chamber through 1/4-inch (0.6-cm) Teflon or polyethylene2tubes for analysis. The fumes are analyzed using bubblers or Vacutainers to collect samples for analysis by the analytical chemistry lab. The technique described here has been employed to determine the fumes produced by the detonation of a variety of ANFO formulations and commercial explosives. This technique may be developed as a standard test to measure fumes produced by blasting agents or may be used to provide data with which to develop a computer model that will reliably predict the expected fumes production based on chemical composition.

By E. J. Gleim

[THE ORGANIC act under which Federal Bureau of Mines was established provided for the investigation of the safe use of electricity in mines. Each Congress appropriates funds for conducting this investigation. As part of this investigation, electrical apparatus used in mines is studied to determine if its operation and use might introduce a hazard. From this study, certain safety standards have been developed. These standards, established with the aid of both the manufacturer and user of such apparatus, are published in schedules, and apparatus that complies with the requirements set forth these schedules is classified as "permissible." This term is defined to designate apparatus as "completely assembled and conforming in every respect with the design formally approved by the Bureau of Mines." In the judgment of the Bureau, the manufacturers of such apparatus have adhered to certain minimum standards of safety in supplying a product that when properly used and maintained is safe for operation in mines where flammable gas or coal dust may accumulate. This work of the Bureau of Mines for increasing safety does not make it obligatory for manufacturers of mine equipment to produce only that of permissible classification. Before the effective date of the Federal Mine Safety Code,5 the Bureau sought to promote safety by recommending that mine operators install permissible equipment in gassy mines as a preventive measure against gas and dust explosions initiated by electrical equipment. For some years, the mining laws of several States have prescribed the conditions under which permissible equipment must be used. The Federal Mine Safety Code requires that ?all new electric face equipment and replacements of equipment purchased for mines where nonpermissible equipment is now being used shall be of a permissible type approved by the United States Bureau of Mines,]

Jan 1, 1955

By Jeffery L. Kohler, Harvinder Singh, Jon G. Bredeson

A survey of electromagnetic noise reports was performed and a summary of the results are given. Industrial concerns were surveyed for techniques to minimize the effects of electromagnetic noise and are presented. The common types of communication links used in mines today are presented. A mathematical development was presented which determines the probability of bit errors versus distance for various types of communication links designed for in mine use. The probability of undetected errors for the protocols of the communication links is given together with burst error detection.

Jan 2, 1981

By Michael S. Wieland

The work-principle from thermodynamics was used to formulate a model for predicting toxic fumes from mining explosives in underground chamber tests, where rapid turbulent combustion within the surrounding air noticeably changes the resulting concentrations. Two model constants were required to help characterize the reaction zone undergoing rapid chemical transformations in conjunction with heat transfer and work output: a stoichiometry mixing fraction and a reaction-quenching temperature. Rudimentary theory with an unsteady uniform concentration gradient was taken to characterize the combustion zone, yielding 75% for the mixing fraction. Four quenching temperature trends were resolved and compared to test results of ammonium nitrate compositions with different fuel-oil percentages (ANFO). The quenching temperature 2345 K was the optimum choice for fitting the two major components of fume toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). The resulting two-constant model was used to generate comparisons for test results of ANFO compositions with additives. Though respectable fits were usually found, charge formulations which reacted weakly could not be resolved numerically. The work-principle model yields toxic concentrations for a range of charge formulations, making it a useful tool for investigating the potential hazard of released fumes and reducing the risk of unwanted incidents. Keywords: Toxicity; Fumes; Explosives

By James R. Aggson

The theoretical relationships that are used to calculate in situ rock stress magnitudes and directions from borehole deformation data obtained during overcoring are based on the assumption that the rock is a linearly elastic material. Strictly speaking, this assumption is not valid in any rock. Thus, investigators using overcoring techniques must either accept various degrees of nonlinearity and the associated inaccuracies or use core testing techniques that address the problem and compensate for elastic nonlinearity. Previously developed test procedures for stress-relief overcores partially correct for nonlinearity. This Bureau of Mines paper describes a test procedure that completely corrects for elastic nonlinearity in stress-relief overcores.

Jan 1, 1977

By B. R. Eichbaum

To develop technology to assure an ample supply of zinc and to reduce environmental pollution, the U.S. Bureau of Mines investigated alternatives to the roast-leach process for treating complex sulfide concentrates. Previous studies proved that low-grade zinc sulfide (ZnS) concentrates could be leached using chlorine-oxygen to produce zinc chloride (ZnCI2). The process involves high energy requirements for evaporating the pregnant solution to produce anhydrous ZnCl2 needed for electrolytic cell feed. An efficient hydrometallurgical process would facilitate treatment of lower grade ores than can be used in conventional processing and would render roasting unnecessary. An alternative method was devised for recovering ZnCl2 from solution. Zinc diammine chloride [Zn(NH3)2CI2] was precipitated from solution by adding ammonium chloride (NH4CI) and sparging with ammonia (NH3) to a pH of 6 to 7.5. The spent solution was treated with calcium hydroxide [Ca(OH)21 at 60° to 80° C for 1 to 4 h to remove remaining zinc and NH3. The Zn(NH3)2CI2 was heated to 300° to 400° C to remove NH3 and produce anhydrous ZnCI2. A possible flowsheet was devised and is included.

Jan 1, 1991

"When a metal-mining company takes out a workmen's compensation insurance policy, it does so to relieve itself of its uncertain and variable financial liability under laps requiring payment to employees for lost-time accidents, there-by passing the liability or to the insuring agency. For this service, or rather for the assumption of the risk, the insuring agency charges the mining company a price, or in insurance parlance, ""a premium"".The insuring agency depends upon a volume and variety of business to average the losses incurred by its individual policy holders, and determines its price to cover losses that are suffered and its cost of doing business.It is generally known that all types of insurance are founded on the theory of probability applied to large groups of risks, Workmen's compensation insurance is no exception, and the average price paid therefor must be based on the frequency and severity of accidents in the particular industry or branch of industry under consideration. The frequency and severity rates are determined by statistics, which, of course, unless standardized, kept carefully and consistently, and analyzed properly, are liable to be inaccurate and misleadingThe importance of large groups in arriving at an average price for insurance service can not be overestimated, For example the writer knows of one small group of some twenty metal-mining companies whose losses during the past two years exceeded their premium charge by 54%. Not a single individual company during the two years kept its losses below the premium rate. For several years the group as a whole has persistently exceeded its premium rate, Such risks are not profitable to the insuring agencies and can only be carried where a large volume of good risks will balance the poor risks, but in order to conform to good insurance ethics the premium rate must be based on averages for the industry as a whole, and kept sufficiently low to induce operators to sell their risks."

May 1, 1924

By L. C. IlsLey

"This paper is intended for State mining inspectors, safety engineers of mining companies, and others interested in electrical safety inspection in mines, It presents the important points that should be watched by inspectors, and briefly reviews the work of the Bureau of Mines in the testing of electrical apparatus or equipment to determine their permissibility for use in gaseous coal mines.Important Points in Inspecting Mine Electrical Installations or Equipment.The following questions are intended as suggestions to a safety inspector who may not have been specially trained in looking for defects in installations or in the maintenance of electrical equipment:1.,Is there someone in charge of electrical equipment who is fitted for this position by ability, training and experience?2.,Is a systematic recorded inspection of electrical equipment made at least once each month?3.,Is a plan map of the mine kept showing all permanently installed electrical machinery and apparatus, including cables, conductors light etc.?4.,Are there instructions for resuscitation from electric shock posted in each surface and underground electrical station, also at the entrance of the mine and in the first aid station and are employees working on electrical equipment trained to apply these instructions in case of accident?"

Nov 1, 1923

By Wilbert J. Huff

For the past 9 years , the technical studies conducted by the Explosives Division of this Bureau have been summarized in a series of reports issued annually . The following account presents investigations undertaken from July 1 , 1943 , to June 30 , 1944. The work is detailed under a number of main headings corresponding to the organizational structure of the Division , the various activities being under the immediate direction of unit chiefs , who report directly to the author . Specific credit , however , is due to the individual unit leader and his assistants .

Jan 1, 1945

By George S. Rice, J. W. Paull, R. R. Sayers

"Standard rock dust for use in the rock dusting of coal mines might be defined tentatively as powdered mineral, light colored and free of carbonaceous matter and free silica, all of which will pass a 20-mesh screen while 50% of it will pass-through a 200-mesh screen.Such dust may be prepared from limestone, gypsum, anhydrite, or shale free of sand and flint. For the initial rock dusting of the average nongaseous bituminous mines enough standard rock dust should be applied so that the combustible content of the resulting mixture of rook dust with mine dust shall not exceed 45%, a range somewhere between 35% end 45% being the practical objective sought.All entries, slopes or passageways and room necks should be rock dusted.Additional safeguards are:a.,Rockdusting roomsb.,Scattering of dust in vicinity of shots before firing.c.,Placing of barriers in the mouths of panels, cross-entries and other key positions.Redusting becomes necessary whenever the combustible content of the mine dust exceeds the permissible maximum. This should be determined by regular, systematic sampling, followed by a simple analysis of the samples for combustible content. A Bureau of Mines volumeter for measuring the density can be used for the determination of combustible content."

May 1, 1924

By L. B. Pankratz

Enthalpies above 298° K were determined for AgCl to 1,400° K and for AgBr to 1,200° K by copper-block calorimetry. Before melting, both compounds showed an anomalous increase in enthalpy, an effect associated with lattice defect formation. Melting points and heats of fusion were determined to be AgCl, 730° K and 2,945 cal/mole; AgBr, 700° K and 2,030 cal/mole. The heat capacity of both melted substances decreased with increasing temperature over the entire liquid ranges investigated. Enthalpies above 298° K were tabulated at even temperatures along with derived entropy increments and heat capacity values. The results were combined with the known heats of formation and entropies at 29.8.15° K to obtain values of the heats and free energies of formation over the range 298.15° to 1,400° K for AgC1 and 298.15° to 1,200° K for AgBr.

Jan 1, 1970

By S. H. Katz, J. J. Bloomfield

In studies of mine and tunnel ventilation conducted by engineers of the Bureau of Mines , various smokes are used to determine flow of air , direction of the currents , and the rate of mixing . The instrument for generating streams of sulphur trioxide (SO ) smoke , shown in the drawing herewith, has been found helpful , convenient and practicable for such purposes ; it is also especially useful in some places where fire for generating smokes is not permissible . The apparatus consists simply of a glass tube containing fuming sulphuric acid on granular pumice stone , attached to a rubber syringe bulb . When a squeeze of the bulb blows air through the tube , a stream of dense white smoke evolves, which follows and makes visible the air currents . The tubes after preparation are hermetically sealed to prevent deterioration . When ready for use , they are easily broken open at a file scratch for the purpose on both tips , and inserted into a rubber nipple at the bulb . Sometimes it is of advantage to attach them to a longer rubber tube leading to the bulb . Tubes of the size shown (about 1/2 inch outside diameter by 5 inches long) are usually sufficient for the needs of a day . Thereafter they cease to fume because the acid absorbs moisture from the air and looses its effectiveness . Smaller sizes of tubes and larger have been made , but the size shown has proved most practicable . Immediately after a person has finished using a tube it should be buried or disposed of in a place where it will not be touched by shoes or clothing, or come in contact with wooden floors , furniture , or metals , because the acid , which will eventually leak from the tubes , is highly corrosive . -- Reports of Investigations , Department of the Interior , Bureau of Mines .

Jul 1, 1923

"Introduction.The Bureau of Mines has taken up the problem of determining a method or methods whereby underground compensation insurance rates for metal-mining companies can be equalized in proportion to the underground hazards involved. This study has been started by the writer with the assistance of Mr. I. M. Wolfin* as consultant.The present paper briefly reviews the origin of accident compensation, gives a digest of State compensation laws, and describes types of insurance carriers. This will be followed by study of the basis of premium rate, risk differentials, and cost of compensation insurance to mine operators. These data will be supplemented by an analysis of the accident hazards in different mining methods and practices, and the severity and frequency of accidents classified by time lost and period of exposure to hazard, for different States, mining methods, occupations and nationalities. Attention will be given to standardized preventives for underground accidents in metal mines, and, finally, the classification of underground metal-mining hazard for workmen's compensation insurance premium rating."

Mar 1, 1924

By L. B. Pankratz

The Bureau of Mines determined low-and high-temperature thermodynamic properties for anhydrous ferric sulfate and anhydrous indium sulfate. Low-temperature heat capacities were measured between 50° and 298° K, and enthalpy increments above 298° K were determined. The high-temperature measurements of Fe2(S04)3 extended to 900° K and those of In2(S04)3 to about 1,000° K. A minor transition was found for Fe2(S04)3 at 800° K, with a heat of transition of 540 cal/mole. Tabulations were made of the low-temperature heat capacities and the high-temperature enthalpy and entropy increments. The 298° K entropies derived from the low-temperature measurements were 67.6±0.S ca1/deg mole for ferric sulfate and 72.2±O.5 cal/deg mole for indium sulfate. High-temperature enthalpy increments were also given in equation form.

Jan 1, 1969

By E. D. Calvert

As part of its goal to minimize the requirements for critical and strategic minerals, the Bureau of Mines is conducting research to foster the use of domestically abundant materials such as molybdenum. This report describes the development of an investment shell molding technique that can be used to make castings of molybdenum and its alloys. The mold material is cubic Zr02 with a monoclinic Zr02 binder. The shell, formed by standard investment molding techniques described in the text, is prepared for molybdenum casting by firing for 6 hours at 1,550° C (2,822° F) or for 4 hours at 1,650° C (3,002° F). The resulting castings have predictable and reproducible dimensions with good detail. As-cast strength is poorer than the strength of wrought materials below 1,600° F. At and above this temperature, tensile strengths of cast and wrought materials are nearly equal. Aqueous corrosion of the castings in most media is insignificant.

Jan 1, 1982

By C. E. Saxon, F. E. Cash

"Adequate lighting for all mining operations would unquestionably tend to promote both safety and efficiency; this would be true not only for men but also for the animals that man impresses into service in mines. The Markeeta Coal Co. and the Alabama Fuel & Iron Co. both operating mines in Alabama, have found that equipping mine mules with portable electric lights is more efficient, much more humane, and far more safe for both men and animals then the more or less usual method of forcing the animal to do its work essentially in darkness.This report is intended to give the mining industry data, that will aid in trying to bring about safe and efficient operation of mines.The authors desire to thank Charles F. DeBardeleben, president, Fred R. Bell, general manager, Hewett Smith, C. H. Shepherd, and R. A. Sensing, superintendents for the Alabama Fuel & Iron Co.; and Charles F. DeBardeleben, Jr., president, and H. M. House, superintendent for the Markeeta Coal Co., for their cooperation in furnishing the data for this paper.The eight mines operated by the Alabama Fuel & Iron Co. and one operated by the Markeeta Coal Co. in Jefferson and St. Clair Counties, Ala., are the only mines in Alabama where mules are provided with portable electric lights, and there are few if any mines in other States in which this system is in use.These two companies are convinced that equipping all mine mules with good lights decreases underground haulage cost by animals by prolonging the useful life of the animals, increasing their efficiency, lessening haulage wrecks and delays on haulage, and increasing production. Last but not least of the advantages would be the more humane treatment of the animals.The nine mines are developed by slopes along the dip of the coal bed, with double-room entries on 200- to 300-foot centers turned right and left off the slopes and with approximately 1 per cent grade in favor of the loads. Rooms are driven up or diagonally up the pitch from these entries.A surface hoist delivers the empties from the surface to the entry sidetracks at the slope and pulls the loads to the surface. From these sidetracks, mules pull one to four wooden cars, each of which holds 1-1/2 to 2-1/2 tons of coal, deliver the empties to the rooms and entry faces, and pull the loads to the slope sidetracks. The mule haul varies from 100 to 3,000 feet; there are no locomotives or trolley wires in any of these nine mines, seven of which are rated as gassy and two as nongassy by the Alabama state Mining Department."

May 1, 1933

By F. Garacia, J. Cervik

Gob holes are routinely used by the mining industry to vent methane from gobs and to prevent it from entering the mine ventilation system. In some cases, flows from gob holes are measured by centering an anemometer on the end of a discharge pipe. These measurements are erroneous and tend to be high by as much as 30 pct. The Bureau of Mines deter- mined method factors (correction factors) for anemometer measurements taken in this manner. Method factors for 4-, 6-, and 8-in (10.2-, 15.2-, and 20.3-cm) ID pipe are 0.68, 0.71, and 0.78, respectively. Comparisons between horizontal and vertical flows indicated no significant change in method factors. Consequently, the method factors for horizontal pipe flows can be applied to vertical upward flows.

Jan 1, 1987