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By Edmund S. Leaver, Charles E. Van Barneveld

In response to numerous requests from metallurgists and operators for information regarding the status of the sulphur dioxide leaching process , developed at the Southwest experiment station of the U. S. Bureau of Mines , Tucson , Ariz . , the following statement has been prepared . A more complete report is now in course of publication and will appear as Technical Paper 312. This process was devised to provide a cheap and efficient method for treating the so- called "porphyry " copper ores of the Southwest which generally contain both " sulphide " and "nonsulphide " copper minerals , mixed in such proportions that they can only be satisfactorily treated by a method which will concurrently recover both the sulphide copper and the nonsulphide copper . The latter term has been adopted to include all the minerals commonly referred to in operating phraseology in the mills of the Southwest as " oxidized" , " oxide " , or " soluble " copper . confident that the sulphide dioxide leaching process , as developed by us with the cooperation of the Miami Copper Co. and the Arizona Copper Co. , is suitable and commercially available for a wide range of ores .

May 1, 1922

By Floyd G. Anderson

Owing to the rapid growth of the perlite industry in recent years, the Bureau of Mines has received numerous requests for information relative to the possible harmful effects of breathing dust resulting from the processing and use of perlite. As published information on the composition of perlite is rather meager, consisting chiefly of conventional chemical analyses, samples of crude and expanded perlite from 9 deposits in 6 Western States were studied. Crude perlite ores were examined petrographically and analyzed by chemical, spectrographic, and X-ray-diffraction methods. Sized crude and expanded perlites were analyzed chemically for total free and combined silica content.

Jan 1, 1956

By K. E. Stanfield

One of the initial projects under the oil-shale research and development phase of the Synthetic Liquid Fuels Act, Public- Law 290, 78th Congress, approved April 5, 1944, was a survey of oil shales of the United States for the selection of a site for an oil-shale demonstration plant. The oil shales were assayed by the conventional Bureau of Mines retort method proposed by Karrick and described by Guthrie in a more recent publication. From previous experience and that had in making these assays, it became evident that the assay method should be modified or replaced by a more satisfactory one. There are several outstanding objections to the Bureau of Mines oil-shale assay method: (1) the oil yields are frequently smaller than those obtained by other types of assay equipment and by commercial retorts; (2) the assayed oil yield represents only a portion of the organic matter in the shale, which under more favorable conditions, may, Jae converted, more completely into oil; (3) the retorting procedure is controlled mainly by trial-and-error methods; and (4) the assay requires approximately 6 hours for completion.

Jan 1, 1949

By G. T. Fisher

The U.S. Bureau of Mines conducted research on calcium ferrite slags to determine the distribution of Pb and minor elements (Ag, Cd, Zn, and Co) between Pb bullion and slag. These fundamental data are required to evaluate nonferrous smelting with calcium ferrite slags as a substitute for conventional iron silicate slags. Determinations were made in 25-cm3-capacity MgO crucibles at 1,250° C for 2 h in a CO-CO2 atmosphere with an O2 potential that would retard the formation of magnetite. Calcium ferrite slag composition variables studied were from 16 to 32 wt pct CaO in 2-pct increments and Si02 ranging from 1 to 5 wt pct in 1-pct increments with equal additions of MgO. For all compositions studied, the retention of Pb in the calcium ferrite slag was less than 1 wt pct, which compares favorably to about 6 wt pct Pb in conventional iron silicate slags used in smelting of Pb concentrates. Minor element distribution was insensitive to changes in slag composition in the range studied. However, slag composition had significant impact on the melting and fluidity of the slag.

Jan 1, 2010

By G. W. Birge

Carbonizing properties of the principal coal beds of Perry County, Ky., are described in this Bureau of Mines report. Seven samples, representing the Hindman, Flag, Haddix, and Fire Clay beds, were carbonized by the Bureau of Mines-American Gas Association (BM-AGA) method, and yields of products and physical properties of cokes were determined. Carbonizing properties of blends of Flag and Fire Clay coals, with 20 and 30 percent Pocahontas No. 3 low-volatile coal from McDowell County, W. Va., also were determined. Expanding properties of the Flag and Fire Clay coals and their blends were determined in the Bureau of Mines sole-heated oven. The Perry County coals tested are high-volatile A bituminous in rank and, with the exception of the Hindman-bed sample, which contained excessive sulfur, were chemically suitable for metallurgical use. The three coals tested in the sole-heated oven contracted less than normal for Appalachian coals of similar rank, Blending the Fire Clay and Flag coals with 20 or 30 percent low-volatile coal increased coke strength appreciably but increased the expansion beyond normal limits for industrial blends.

Jan 1, 1962

By R. L. Handy

The goal of this research was to adapt the highly successful rock borehole shear test for use in deep, small-diameter boreholes. Operating somewhat on the principle of a rock bolt, the borehole shear test measures both the expansion pressure and pulling force to give discrete measures of rock shearing strength as a function of the applied normal pressure. A new instrument was designed and built to fit into a 2-3/8 inch diameter hole. Unfortunately the design became so complicated, the operation is nut reliable. This is attributed to constraints of the small hole, and added requirements of an in-hole anchor to push against, and a rotating shear plate cleaner for repeated tests down-hole. A clue to the d: vice complexity is its length, which is over 10 feet. Furthermore it employs concentric cylinders and one hydraulic cylinder bored into the piston of another, or it would be even longer. Meanwhile drilling technology has advanced to greatly reduce costs of drilling 5- or 6-inch diameter holes. The downhole tester therefore should be redesigned and simplified for use in a larger diameter drill hole.

Jan 1, 1982

By R. S. Fowkes

The degree and manner of packing of bulk materials influences all phases of their loading, such as by a front end loader or a dragline, and their mechanics of flow, such as through a binhopper or an ore pass. The most important quantity in analyzing the handling of a bulk material is its shear strength which depends primarily on the same parameters as those that determine the packing state. Some of these are size, size distribution, moisture content, particle shape, particle orientation, and cohesion. The variables that affect the packing state arc vibration, pressure, intensity of deposition, velocity of deposition, and, when the material is confined, container used. The analysis of packing by a number of investigators has been done almost entirely with spherical particles. Most of these studies have dealt with monosized spheres. There is scant information on particles with angular shapes. Since most of the investigations by far have been concerned with ceramics and powder metallurgy, the particle sizes and ranges of size distribution have been small compared to those generally found in mining after fragmentation.

Jan 1, 1974

By James H. Jolly

Although zinc in the environment is generally considered to be beneficial or benign, excessive amounts can cause deterioration of environmental quality and toxicity problems for some plants and animals. High amounts of zinc in the environment are often associated with anthropogenic activities, mainly those involving zinc production and consumption and those related to the use and disposal of zinc-containing products. To obtain some upper limit parameters on the historical quantities of zinc chat may have entered the U.S. environment from anthropogenic sources, the Bureau of Mines conducted a materials flow study of zinc from the earliest beginning of the domestic industry through 1990 and for the year 1989. For comparative purposes a generalized historical materials flow of zinc for the world was also prepared. The United States was the world's leading producer and consumer of zinc in the 1850-1990 period. In that period, U.S. mines and smelters produced 15% and 20%, respectively, of world output, and U.S. zinc consumption accounted for about one-fourth of the world total. Maximum zinc losses into the environment related to the above production, consumption, and disposal of end use products total about 63 million tons. Dissipative uses and landfill disposal have accounted for about 73% of the potential zinc losses to the environment, followed by mining and smelting 22%, and manufacturing, 5%. At the end of 1990, contained zinc in useful end-products in the United States was estimated to be about 23 million tons. In 1989 slightly more than 1 million metric tons of zinc in new zinc-containing products were added to the domestic pool of zinc in use but in the same year, an estimated 0.9 million tons was dissipated and discarded, indicating only small net gains to the zinc pool of use annually.

Jan 1, 1992

By J. P. Morris

"INTRODUCTION In the investigation being conducted by the Bureau of Mines concerning the production and utilization of sponge iron, it soon became evident that more information was needed regarding methods for determining the degree of reduction attained in the manufacturing process. Sponge irons made by different processes vary in physical characteristics and chemical composition, and a method of analysis that is suitable for one type is not necessarily applicable to all others. For example, the hydrogen-evolution method, which measures the volume of hydrogen evolved upon treating the sample with acid, accurately determines the oxygen content of some types of sponge iron. However, when the sponge iron contains combined carbon, hydrocarbon gases are also-evolved and large errors may result. Probably no single method will give accurate results in all instances, and for this reason it is desirable to have several reliable procedures available and to know the limitations of each.For measuring the degree of reduction, determination of either metallic iron or oxygen should suffice, although for practical application of sponge iron to the production of steel the oxygen content is more significant. After consideration of proposed methods of analysis in regard to their suitability for routine use and the probable influence of other substances, four procedures were chosen for investigation:(1) Mercuric chloride method.(2) Copper sulfate method.(3) Hydrogen-reduction method.(4) Hydrogen-evolution methods."

Sep 1, 1945

By D. A. Reynolds

THIS REPORT gives results of an investigation of the carbonizing properties of two Tennessee coals, one from the Jellico bed in Campbell County and the other from the Sewanee bed in Marion County. Jellico coal and blends with 20 and 30 percent Pocahontas No. 3 coal were carbonized at 800° and 900° C. by the BM-AGA method. Sewanee coal was carbonized by the same method at 800°, 900°, and 1,000° C.; blends with coals of similar and different ranks were carbonized at 800° and 900° C. The coals were subjected to various physical and chemical tests, including complete chemical analyses, low-temperature assays, and agglutinating, free-swelling, friability, plasticity, and expansion tests. The Tennessee coal field is a part of the Appalachian field, which extends from northern Pennsylvania to central Alabama. The Jelico bed, one of the most important in the State, is part of the Jellico formation, which is above the Lee formation of the Lower Pottsville. Sewanee coal bed belongs to the Sewanee conglomerate and is stratigraphically lower than the Jellico bed.

Jan 1, 1953

By H. E. Hilliard

A method was investigated for detecting and counting filamentous iron bacteria in open recirculating cooling systems. It is simple and fast and does not require trained microbiologists. Samples from 26 systems were examined. Cells were cultivated on commercially prepared ready-to-use media. Cultures grew well on this medium and were identified as filamentous iron bacteria by microscopic examination and by their ability to deposit iron using the prussian blue reaction.

Jan 1, 1976

By Richard A. Dick

In this report commercial blasting compounds are classified according to their nitroglycerin (or equivalent explosive oil) and ammonium nitrate content as dynamites, gelatins, blasting agents, military explosives, and blasting , accessories. The ingredients and more significant properties of each explosive are tabulated and briefly discussed. Data are summarized from various handbooks, textbooks, and manufacturers' technical data sheets, together with the author's personal experience; however, this report is not intended to be a technical handbook, since it does not deal with blasting techniques. Instead, it seeks to acquaint the reader with the great variety of explosives, available, their advantages and disadvantages, and their general areas of application. Properties discussed are weight strength, cartridge strength, detonation velocity, density, detonation pressure, water resistance, and fume class. The weakness of the strength rating system and the importance of detonation pres- , sure, density, and detonation velocity in rating explosives are discussed. The terms "blasting agent" and "slurry," which are often misused, are defined. Trends indicate that blasting agents (that is, blasting mixtures with none of of the ingredients singly classified as an explosive), particularly high-density slurry blasting agents, will dominate the explosives field in the future.

Jan 1, 1968

By John K. Alley, Robert C. Johnson

The primary objective of the research was to grow aluminum borate whiskers or fibers and to determine their properties . Molten salt bath and vapor deposition methods were used for synthesis . Whiskers exceeding 25 mm in length were grown . The best results were obtained by vapor deposition and most of the data presented were determined on whiskers produced by this method of synthesis . Three different aluminum borate compositions ( 4.8A1203 B₂03 , 3.8A1203 B203 , and 2.5A120, B203 ) were identified by X- ray and chemical analyses . The aluminum borates 4.8A1203 B20, X- ray diffraction pattern was indexed . Optical data were obtained on the three aluminum borates . In addition the following whisker properties and growth factors were determined : ideal atmospheric dewpoint for vapor deposition method , near 65 ° F ; temperature range of whisker formation , 1,000 ° to 1,400 ° C for the molten bath method of synthesis , > 1,000 ° to < 1,400 ° C for the vapor deposition method ; whisker growth rates by the vapor deposition method , maximum 12 mm per hour ; raw material vaporization , 50 to 60 percent of the fluoride lost in 1 hour ; tensile strength , maximum obtained 174,162 psi ; melting points , ranged from 1,675 ° to 1,795 ° C.

Jan 1, 1965

By Earl R. McMillan

"Coal washing commands the thoughtful attention of a steadily incre in number of people. Clean coal is not merely a luxury but is rapidly becoming a necessity in some industrial operations.Coal seams in the Northeast are rarely free from ""bone"" and shale or clay partings which vary from a fraction of an inch to several feet in thickness. Nearly all of the coal measures are folded and faulted, the coal seams dip at various angles, and in some cases are badly broken. In mining these seams fragments of the roof and floor, as well as partings of impur-ities within the seams, unavoidably become mixed with the coal, so that the raw coal as it comes to the surface often contains as much as 50 per cent, by weight of waste.At the Bureau of Mines experiment station at Seattle, the washing of this coal in order to improve it for commercial use has been studied. Since the process of coal-washing depends upon differences in specific gravity between the clean coal and, its associated impurities, the first problem undertaken was that of determining the specific gravity of the clean coal and of each parting of impurity contained in a large number of representative seams.It was found that the freshly-mined coal is practically saturated with water, this being observed in determining the effect of moisture content upon the specific gravity of the coal particles, selected from samples of coal varying from low-grade subbituminous up to semianthracite, all of which are found in the State of Washington. The specific gravity values determined for the cleanest particles varied from 1.28 to 1.35; in general, the higher the rank of the coal the hither the specific gravity."

Nov 1, 1920

By Mildred Nadler, Alvin Kaufman

To aid industry and Government in planning water developments the Bureau of Mines in 1963 canvassed mineral producers to determine water use in 1962. Water use by the mineral industry comprises only 2 percent of the water withdrawn by industry as a whole. The major water-using mineral industries are natural gas processing, phosphate rock, sand and gravel, and iron ore. Analysis indicated the following conclusions: 1. Total water use and new water intake is dependent on the quantity of material processed and the process water requirements of the particular indus- try or commodity. 2. Recirculation is dependent on the processing requirements of a par- ticular commodity, the manner in which the water is used, cooling and condens- ing requirements in certain large industries, the quality of new water intake, and the need to treat new and discharged water. 3. Consumed water is dependent on the quantity of water recirculated, the temperature and humidity in the area, and the proportion of water used for cooling and condensing. 4. A threefold increase in water use by the mineral industry by 1985 is forecast.

May 1, 1965

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines-developed induction slag melting process is of concern to the titanium industry. The objective of the research was to determine the effect of removing the nonconductive molten calcium fluoride (CaF2) slag used as an insulator between the titanium and the segmented copper crucible. The data were obtained from single-induction-melted ingots prepared with no CaF2 insulating slag and an ingot prepared with the normal addition of 4 pct CaP2 slag. The results showed that the mechanical properties of single-induction-slag-melted and annealed Ti-6AI-4V alloy exceed the minimum values specified in "Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H." High-cycle, tension-tension fatigue testing yielded similar results. The data from 44 of the 45 specimens were contained within the typical scatter band for fatigue data on wrought Ti-6AI-4V alloy. Although the removal of the insulating slag is a desirable change, the data from the specimens with the previously standard 4 pct slag addition showed no detrimental effect from the slag inclusions.

Jan 1, 1988

By J. R. Ross

The extraction and recovery of nitrate from waste solutions generated in the production of titanium were investigated using solvent extraction techniques. Laboratory studies and continuous tests in a small solvent-extraction system showed that up to 98 percent of the nitrate can be selectively extracted by a solution of tributyl phosphate in kerosine. The extracted nitrate can be recovered as nitric acid, at concentrations suitable for reuse, by stripping the loaded organic with water.

Jan 1, 1973

By L. E. Green

For shortwall mining to be profitable, the additional capital investment of about $1 million for shortwall roof supports must be offset by decreased total operating costs and/or increased coal production. The Bureau of Mines therefore conducted a demonstration project to compare shortwall and room-and-pillar mining. Daily two-shift production from the bureau of Mines-Beth-Elkhorn Corp. shortwall demonstration n project averaged 975 tons of raw coal, compared with 905 tons from a room-and-pillar unit operating undo r similar conditions. The estimated direct operating costs for the shortwall and room-and-pillar unite were $4.21 and $4.03 pier ton, respectively. The profitability of the shortwall system was found to depend not only on the increased depreciation cost of the powered roof supports and the decreased cost of supplies and materials but also on such factors as the fixed and variable indirect costs and the selling price of the coal. Shortwall mining was demonstrated to be a viable alternative to room-and-pillar mining.

Jan 1, 1977

By D. E. Wolfson

Twenty-two samples of West Virginia coals were carbonized at 9000 C by the Bureau of Mines-American Gas Association (BM-AGA) method, and yields of products and physical properties of cokes were determined. Eighteen samples represented the Coa1burg, No. 2 Gas, No. 2 Gas and Peerless, Powellton, Eagle, Big Eagle, Lower Eagle, Sewell, Fire Creek, and Pocahontas No.6 beds in Fayette County, and four samples represented the Sewell and Fire Creek beds in Greenbrier County. Expansion characteristics of the majority of samples were determined in the Bureau of Mines sole-heated oven. Chemical analyses were determined for all coals. The coals in Fayette County are high-volatile A, medium-volatile, and low-volatile in rank, and the Greenbrier coals are medium-volatile in rank. Most of the coals are chemically suitable for metallurgical coking. All coke strength indices are within acceptable limits for metallurgical coking coals. All the high-volatile A coals contracted and the medium-and low-volatile coals expanded in the sole-heated oven expansion test.

Jan 1, 1966

By Jr. Driscoll

The thermoelectric properties of yttrium monoarsenide, yttrium monoanti-monide) and ternary materials from the Y-As-Se and Y-Sb-Te systems were investigated by the Bureau of Mines from room temperature to 1,000° C. The maximum calculated figure of merit for yttrium monoarsenide and yttrium monoantimonide was 2 x 10-5 ° C-1. YAs and YSb were semimetallic conductors with low Seebeck coefficients and electrical resistivities. The values of the Seebeck coefficient and electrical resistivity of the Y-As-Se and Y-Sb-Te materials were between those of the yttrium selenides and tellurides and of YAs and YSb, respectively. The maximum power factor calculated for the Y-As-Se materials was 2 X 10-5 watt/cm ° C2 which yielded an estimated figure of merit of 6 X 10-4 0 C-1. Most of the Y-As-Se compounds had high Seebeck coefficients and moderately low electrical resistivities. The Y-Sb-Te materials were degenerate semiconductors with power factors of 6 X 10-8 watt/cm ° C2.

Jan 1, 1967