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By S. L. May

The Bureau of Mines has developed several methods for extracting tantalum and columbium (niobium) and the rare-earth compounds from ores and concentrates. A cooperative agreement was made by the Bureau with Porter Bros. Corporation of Idaho to process 200 pounds of its euxenite concentrate by methods that had been developed at the Albany, Oreg., Metallurgy Research Center. The euxenite concentrate was processed to extract and purify the valuable metals by chlorination, solvent extraction, and hydrometallurgical techniques. Chlorination was used to convert the valuable constituents into chlorides and to partly separate them. Solvent extraction techniques were used to separate the tantalum from the columbium. The rare-earth and uranium compounds were purified by hydrometallurgical methods.

Jan 1, 1959

By R. L. Crosby

Microscopical and X-ray diffraction techniques were used to identify two intermediate phases in that part of the solid region of the magnesium-cerium system between and Mg3Ce. Previous literature had reported only one intermediate phase for this region, 1)12t chemical analysis determined the approximate composition of the two compounds to be Mg23Ce2 and Mg17Ce2. The range in composition of the two intermediate phases was found to be limited to less than 0.3 atomic percent cerium. The study did not determine the crystal structure of Mg17Ce2, but that of Mg23Ce2 is tetragonal with a = 10.33 A and c = 19.51 A.

Jan 1, 1966

By H. Kenworthy

The objective of this investigation was to evaluate the technical feasibility of smelting certain low-grade domestic iron ores in an electric furnace. Laboratory-scale experiments showed that a high recovery of iron in the form of pig iron can be obtained from east Texas ores containing less than 25 percent iron. The pig iron was amenable to standard-or electric-furnace-refining methods for producing steel. Car-bon, silicon, and phosphorus were the primary impurities removed in refining. Overall recoveries of iron as pig iron exceeded 95 percent, in contrast with commercial mineral-dressing recoveries on these particular ores of 50 percent of the iron as a 45-to 50-percent iron concentrate.

Jan 1, 1958

By J. R. Nettle

The electrodeposition characteristics of seven binary alloys of titanium have been investigated. The object of the electrorefining experiments with an alloy was to determine the efficiency of titanium separation from individual alloying elements under established conditions. Reported results are only indicative. It is conceivable that numerous duplications of tests might give average maximums that would vary from those noted in this report; however, in the few tests that were repeated, the magnitude of transfer of the alloying elements was of the same order. The results detailed herein are for a given set of conditions. Many combinations of operating variables are possible, and the results achieved under different conditions probably would differ from those reported.

Jan 1, 1958

By W. S. Sanner

Seven samples were analyzed from the major reserves of the Bottom Red Ash bed, Northern anthracite field. The data show variations in thickness and geo-logic structure and in the amount of coal that can be recovered. Recovery of market-grade (less than 17 percent ash) coal is high for all samples, ranging from 76 tp 95 percent in the 3-1/4-by 9/16-inch sizes. The occurrence of coal containing less than 5 percent ash varies from 19.5 to as much as 57.5 percent. Crushing the coarse sizes to minus 9/16 inch increased recovery of market-grade coal in six of seven bed samples. Crushing released sufficient impurities to cause substantial increases in yield of coal containing less than 5 percent ash for all samples. Analyses of the float coal indicate that the quality of coal is comparable for all samples.

Jan 1, 1967

By J. E. Matta

The methane gas emitted from coal samples collected from the conveyor belts dumping into silos was measured by the Bureau of Mines. Approximately 50 pct of the total gas desorbed into a sealed can within 1 week was released during the first 24 hours. No simple correlation between the gassiness of the coal stored and the methane concentration in the silo open space above the coal was found. This was probably because the gassier coals were stored in open-top Silos, which were better ventilated. Although the methane concentration in the open space above the coal pile was less than 1 pct for all 34 silos investigated, a methane measurement in the coal pile showed that high methane concentrations can exist. The methane released in the pile appears to accumulate and not liberate freely into the open space above the coal pile. Probably this gas is released during reclaiming operations, but further research is required to substantiate this claim.

Jan 1, 1978

By James W. Myers

The Bureau of Mines studied factors affecting ignition of coal mine refuse and on methods for control of burning. Laboratory experiments showed that air permeates more readily through segregated than through nonsegregated refuse and that air permeability is greater through coarse than through fine particle refuse. Minus 3-1/4-inch refuse ignites spontaneously more readily than minus 1/4-inch refuse. The burning of a 1,000-pound conical coal pile was con-trolled by capping with an 18-inch-thick layer of minus 1/4-inch refuse containing 37 percent combustible. In field trials, the burning of refuse at operating mines was controlled by capping with a layer of fine refuse. Water, applied as a spray or by injection, quenched surface flames and cooled the burning waste. Inspection of refuse piles at operating mines showed that the spontaneous ignition tendency is affected by the exposed surface relative to the total volume and the segregation of particles during dumping.

Jan 1, 1966

By C. H. Fisher

Coal carbonization, the basis of a major industry, consists in heating coal in the absence of air at various temperatures (ranging from 500° to 1,000° C.) that are selected according to the kind of products desired. During this treatment, the complex organic substances that comprise the major part of the coal are converted into several useful products that are quite different from the original material. The principal products of coal carbonization or distillation are coke and gas. These products, as well as others of which lower yields are obtained (light oil, tar, and ammonia), occupy an important place in present-day commerce and civilization. This paper is concerned with the composition of the tar and light oil, which, as complex mixtures of organic compounds, are the source of many important dyes, inter-mediates, medicinals, resins, etc. The volatile products obtained when bituminous coals are destructively distilled or carbonized are tar, aqueous liquor, and gas. These products vary in composition and properties, depending on the nature of the coal and the temperature and conditions of carbonization. The tar is a dark, rather thick and viscous liquid at ordinary temperatures, becoming semisolid when cooled to the freezing point of water. The aqueous liquor (chiefly water) contains several inorganic substances and certain organic compounds, which, because of their solubility characteristics, have been extracted from the tar. The carbonization gases consist chiefly of carbon dioxide, carbon monoxide, hydrogen, hydrogen sulphide, ammonia, methane, ethane, ethylene, and several hydrocarbons of higher molecular weight. The hydrocarbons of higher molecular weight (benzene, toluene, xylene, etc.) may be re-moved as liquids from the gas by suitable means. This liquid and the first fractions obtained on distilling the tar are known as light oil.

Jan 1, 1938

By D. R. Wilburn

The Bureau of Mines investigated the potential availability of magnesium from 45 properties in market economy countries (MEC's). The 38 significant deposits evaluated have demonstrated resources of approximately 29 billion short tons (st) magnesium-bearing material containing 416 million short tons (MMst) magnesium oxide (MgO). Using data it gathered, the Bureau determined the magnesium production potential for each property including a 15-pct rate of return on invested capital. Total and annual availability assessments for the next 30 yr were completed for magnesium (Mg) metal, deadburned MgO, and caustic calcined MgO. At a January 1984 market price of $1.34/Ib Mg metal, the properties evaluated could economically produce an estimated 13 MMst Mg metal. At a market price of $400/st nonmetal magnesium product, these properties could economically produce 109 MMst deadburned MgO and 43 MMst caustic MgO. These properties could produce approximately 301,000 st Mg metal, 3.0 MMst deadburned MgO, and 430,000 st caustic MgO annually at current full production levels and 1984 market prices until at least the year 2000. Total 1984 MEC production assessed in this study was 153,000 st Mg metal and 4.3 MMst nonmetallic MgO products.

Jan 1, 1986

By Earl T. Hayes, W. M. Sternberg, F. P. Williams

"INTRODUCTION The limited domestic demands for lithium salts and metal before the war were met readily by the use of minerals particularly lepidolite (lithium mica) and amblygonite (a lithium phosphate), from which lithium can be recovered relatively easily. New wartime uses, however, created such a demand that it became necessary to turn to spodumene (a lithium feldspar) as the principal source of supply. Although very large deposits of spodumene occur in South Dakota and in North Carolina, it much more difficult to extract lithium from spodumene than from lepidolite or amblygonite.During the spring and summer of 1942 a study was made in Salt Lake City laboratory of the Bureau of Mines on the recovery of lithium from spodumede. Preliminary tests were made on two processes - roasting with potassium sulfate 4/ 5/ and roasting with calcium chloride and calcium carbonate 6/ -,which appeared to be the most promising of the various processes that had been proposed. By roasting spodumene with approximately its own weight of potassium sulfate at 1,050º C. and leaching the product with water, about 70 percent of the lithium could be extracted. Consumption of the relatively expensive potassium sulfate, however, was high; much of the potassium was found in the insoluble leach residue, end large amounts were lost by volatilization and dusting. By roasting the spodumene with calcium chloride and calcium carbonate, nearly 90 percent of the lithium was chloridized temperatures of 850° to 1,050° C. Much of the lithium could be extracted from the calcine by leaching with water after roasting at the lower temperatures, but volatilization of lithium chloride was appreciable, amounting to 20 to 25 percent in a direct gas-fired furnace at temperatures of 800° to 850° C. At 1,000° to 1,050° C., volatilization was far from complete. Thus, it would be necessary to use both fume collection and leaching of the calcine, unless the roasting temperatures were sufficiently high to volatilize all the lithium chloride. Because of the well-known difficulties of collecting chloride fumes, it was decided to search for a better process."

Mar 1, 1946

By George D. Dub, FREDERICK G. MOSES

The Bureau of Mines, in connection with the investigations of war minerals it conducted, examined the graphite deposits of this country, studied the methods of mining and preparation used, and sought to devise more efficient methods for the preparation of do- mestic graphite, and to standardize the quality of the product. The graphite investigations covered three general phases, as follows: 1. An examination of the deposits in Alabama and other States, and a survey of the methods of mining and preparation used. In this connection methods of sampling and analysis were noted and ex- periments made to determine a standard method of sampling and a rapid but accurate method of analysis. 2. Experimental work on the concentration and refining of domes- tic crucible graphite to improve the quality of the product and to lessen waste. 3. Experimental work in crucible manufacture to determine the properties of domestic flake and the maximum proportions that might be used without impairing the quality of the crucibles. This work was accompanied by photomicrographic study of crucible structure. In this bulletin are presented the results obtained in the first two phases of the work outlined above. The bulletin is in two parts. The first part describes the methods of mining and milling used, suggests a standard method of sampling finished graphite, and de- scribes a rapid and convenient method of analysis developed at the Pittsburgh station of the Bureau of Mines, to which had been as- signed the analytical and microscopic work. The second part describes experiments on the concentration and milling of graphite, which were made at the Salt Lake City, Utah, station. As soon as the reports incorporated in this bulletin were ready, mimeograph copies were distributed to those persons most interested in order to make the results immediately available. The experimental work on crucible manufacture, assigned to the Columbus, Ohio, station, yielded results which were made known to the industry. Á report on this work will be published later as a separate bulletin.

Jan 1, 1920

By D. Harrington

The record of fatalities from mine explosions in the United States during the past 44 years has been the best in the history of the mining industry, despite the fact that the number of fatalities from this cause during the past fiscal year now is nearly double that of the previous year. During there 4 fiscal years, mine explosions have resulted in an average of 45.5 deaths per year, compared with an average of 153 deaths per year for the preceding 5 years; an average of 542 deaths per year for the 3 years 1907-1909, inclusive, and a yearly average of 265 deaths per year for the 20 years prior to 1929. Other types of mine accidents also have been reduced during this period, but not to the same degree or by as large a percentage as mine explosions. The fact that in this fiscal year ended June 30, 1937, electricity was responsible for 60 percent of the explosions and 85.5 percent of the fatalities resulting therefrom (see tables 3 and 4) is evidence that either mine operators are lax in providing proper electrical equipment or there is laxity in the upkeep and use of electricity in our mines and more particularly in our coal mines. Several large coal-producing States that in the Fast have had numerous disastrous explosions have been free from such disasters for continuous periods of as long as 8 years. The bituminous mines of Pennsylvania, one of the largest coal-producing States, give a good example of what can be done to prevent explosions. 'his State, with its large number of operating mines, many with very definite hazards from gas or dust or both, has had only two major explosions (resulting in 16 fatalities) during the past 7 years; this is a decidedly good record compared with any similar period in the past and when it is considered that during this period about 750,000,000 tons of coal have been produced. Other good records are: Tennessee, without a single fatality from explosions during the past 9 years; Alabama, with 6 fatalities during the past 7 years; Illinois, with no explosions during the past 4 years; and

Jan 1, 1938

By John C. Machisak

Injury data and experience, with related employment statistics, at coal mines in the United States for 1959 are presented in this publication under the following general sections: (A) General injury experience: Tables 1 to 6: Current data on number of injuries degree of injury, frequency and severity rates, average severity, and related employment and production data by work location. (B) Selected injury experience: Tables 7 to 38: Current data on principal agencies of injuries, distribution of injuries by part of body injured, days of disability, extent of hand and machine loading, experience by employment and production groups, and various other operating factors and physical conditions related to the occurrence of injuries at the Nation's coal mines.

Jan 1, 1961

By C. W. DeLong, L. L. Farnham, L. A. Stewart

This paper is one of a series covering mineral resources of the Nation . It describes briefly most of the known manganese deposits of eastern Arizona , which for the purpose of this report includes the counties of Navajo , Apache , Gila, Graham, Greenlee , Pinal , Pima , Santa Cruz , and Cochise . With few exceptions , these descriptions are the result of field examinations by the writers . Work on this paper was begun in May 1956 , and in the following 18 months 151 deposits were examined . The distribution of the deposits by counties is as follows : 1 in Navajo , and 1 in Apache , 37 in Gila , 4 in Graham, 13 in Greenlee , 25 in Pinal , 13 in Pima , 12 in Santa Cruz , and 45 in Cochise . In surveyed areas the locations of the deposits are described by section , township , and range and in unsurveyed areas , by approximate projections of these subdivisions . The township and range numbers refer to the Gila and Salt River base and meridian . The history, production, ownership , geologic setting , and mining methods used are discussed for most of the deposits that were visited . Probably , some occurrences have been overlooked , but all of the principal ones have been examined . Ore dressing studies were made of typical ores from several of the larger districts . The work was performed in the laboratory of the Bureau of Mines Tucson Metallurgy Research Laboratory . The results of these studies are given with the descriptions of the deposits from which the samples were taken .

Jan 1, 1961

By Scott W. Hazen

METHODS of determining the grade and tonnage in a mineral deposit have not kept pace with scientific developments in certain other fields. The most commonly used methods of computing ore reserves and grade based on diamond-core-drill sampling are the cross section, the polygon, and the triangle. Tonnage and grade may be determined by these methods with acceptable accuracy, providing a sufficient number of samples is obtained; however, there is no means of determining when an adequate number has been taken or conversely if the deposit has been sampled excessively. It is demonstrated that, by using the techniques of statistical analysis, a mining engineer will be able to determine when a sufficient number of samples has been taken to determine the grade of a mineral deposit within a specified degree of confidence. Using statistical analysis to compute the estimated average grade of the ore makes it possible to compute a fiducial interval, when a distribution of the sample means is normally distributed, so that there is 95-percent confidence in the statement that the true average grade of the deposit is covered by the interval. This report utilizes data obtained from the Maggie Canyon manganese deposit, Artillery Mountains region, Mohave County, Ariz. Four separate exploration projects were conducted at Maggie Canyon between 1936 and 1950. Present economic conditions have made it desirable to determine the amount of 5-percent manganese ore developed by these projects.

Jan 1, 1957

By Paul M. Price

The Mouat mine, Nye, Mont., was reopened in 1953 by the American Chrome Co. under a Defense Minerals Production Administration contract. Operations were terminated in 1961 after completion of the contract. Mining methods employed during this period are described in detail, and cost data are presented by years for 1953 through 1959. Ultramafic rocks of the Stillwater complex in Montana contain the largest domestic resource of chromite, and the Mouat mine has been the largest producer. Mine reserves were estimated in 1960 to be about 4.4 million tons containing 22.5 percent Cr2O3. The chromite deposits occur as a series of overlapping bands or lenses roughly paralleling the steeply dipping layers of the complex. Only two of the chromite layers have proven to be of economic importance. One layer is 2 to 16 feet wide; the other is 3 to 8 feet wide. Shrinkage stoping was generally used throughout the mine, but various methods of ore breaking, stope drawing, chute construction, etc., were tested to improve output and lower costs. Long-hole stoping proved to have limited use. Breasting down benches, developed outward from the center of the stope with air-leg drills, was satisfactory only in wider stopes. At the close of operations, the company had standardized the use of lightweight stopers to advance a flat back by breaking from a centrally located face. Mining costs were reduced 47 percent during 7 years of operation.

Jan 1, 1963

By G. W. Weems

The Bureau of Mines combined preconcentrating techniques and mass spectrometry to develop a parts-per-billion general analysis of impurities in helium. The impurities are preconcentrated using a Bureau trace-impurity analyzer; 35-mm Hg pressure of helium is left in the concentration trap to sweep the impurities into the mass spectrometry and provide a 10-mm Hg sample pressure.

Jan 1, 1966

By R. N. Roby

"INTRODUCTION A preliminary examination of the Green Monster and Benich copper prospects was made by engineers E. W. Newnan and George N. Bennett, of the Bureau of Mines, on December 13, 1943. In an unpublished report, it was stated that certain geologic features appeared to be similar to those associated with the copper deposits of the nearby Butte district. On these premises, a preliminary diamond-drilling program was recommended to explore 300 to 400 feet below the mineralized outcrops for the possible presence of a sulfide enrichment zone. In accordance with that recommendation, three holes were drilled. This report presents the data provided by that preliminary drilling exploration.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell D. Moon, chief, conducts preliminary exminations, perform the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyses samples and performs beneficiation tests.The field work on the Bull Run exploration project was supervised byE. W. Newman engineer in charge of the Helena field office. The chemical analyses and assays included in this report were performed under the direction of A. C. Rice, acting engineer in charge, Bureau of Minos Rare and Precious Metals Experiment Station at Reno, Nev. The diamond-drill cores were logged by geologists of the Federal Geological Survey."

Mar 1, 1947

By Paul M. Price

The Mouat mine, Nye, Mont., was reopened in 1953 by the American Chrome Co. under a Defense Minerals Production Administration contract. Operations were terminated in 1961 after completion of the contract. Mining methods employed during this period are described in detail, and cost data are presented by years for 1953 through 1959. Ultramafic rocks of the Stillwater complex in Montana contain the largest domestic resource of chromite, and the Mouat mine has been the largest producer. Mine reserves were estimated in 1960 to be about 4.4 million tons containing 22.5 percent Cr203. The chromite deposits occur as a series of overlapping bands or lenses roughly paralleling the steeply dipping layers of the complex. Only two of the chromite layers have proven to be of economic importance. One layer is 2 to 1.6 feet wide; the other is 3 to 8 feet wide. Shrinkage stoping was generally used throughout the mine, but various methods of ore breaking, scope drawing, chute construction, etc., were tested to improve output and lower costs. Long-hole stoping proved to have limited use. Breasting down benches, developed outward from the center of the stope with air-leg drills, was satisfactory only in wider scopes. At the close of operations, the company had standardized the use of lightweight stopers to advance a flat back by breaking from a centrally located face. Mining costs were reduced 47 percent during 7 years of operation.

Jan 1, 1963

By Robert M. Becker

Part 5, the last of this series, deals with the theoretical confirmation and application of results developed in parts 1 and 2. The bulk-sampling variances of Hassialis and Kassel and Guy are compared with those in part 2, both as to formulation and as applied to ores and coal. The results provide confirmation for much of the development in part 2. Examples are presented for determining the reliability of bulk samples with respect to various measurable characteristics. These characteristics include, for example, assays for elements or compounds and particle surface area. The bulk samples considered consist either of a given weight, a given volume, or a given number of particles. In addition to problems of sample reliability, some of these examples may also be applicable to quality control. Several possible applications of results developed in parts 1 and 2 are outlined. These include tests for random data, degree-of-mixing indices, and particle-fineness indices.

Jan 1, 1966