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By T. M. Garland

This report presents a more extensive perspective of the calculated profitability of developing and producing crude oil and associated natural gas by primary methods from selected onshore areas of the United States. Estimates were made for cost of drilling, completing, equipping, and producing oil wells at four depths in seven onshore producing areas. A computer program was developed for calculating the discounted cash flow rate of return for the 64 different models in each area resulting from varying the oil-producing rate and production decline rate. The results of these calculations provide data that vividly illustrate the change in rate of return to changes in well depth, initial producing rate, and production decline rate, as well as to variations in development cost and operating expense. Cost per barrel of oil produced in terms of annual cost and total cost is also discussed. Included in the report are explanations of the method of determining costs and the procedure used for profitability analysis. Summaries of all cost estimates and results of profitability analyses are presented in the appendix in tabular form for each of the seven producing areas.

Jan 1, 1972

By George S. Koch

A mathematical simulation model has been devised to guide the layout of underground mine workings, drill stations, and drill holes that are established in order to search for tabular ore bodies. Developed and tested for elliptical ore shoots in fissure veins in the Galena mine, Coeur d'Alene district, Idaho, the model can also be applied to ore bodies contained within sedimentary beds (for instance, many types of uranium, copper, and gold ore bodies) or other tabular structures. Programed for a time-shared digital computer, the model contains both stochastic and deterministic variables. Stochastic or natural variables include the number of ore shoots and their sizes, orientations, locations, and values. Deterministic or controllable variables include (1) locations and costs of workings; (2) drill-station locations and costs; and (3) drill hole azimuths, inclinations, lengths, and deflections, if any. For various assumptions about the stochastic variables, the model is run while the controllable variables are changed deliberately. Thus, layouts are devised to determine the percentages of the total number of assumed ore shoots found at different costs. In order to choose among the various layouts, cost-effectiveness measures are calculated.

Jan 1, 1974

By K. H. Johnston

This guide was written to furnish the coal industry with a description of techniques, instruments, and clues on how to find abandoned oil and gas wells that have penetrated coal seams. The report includes specific information on searching techniques currently in use by several coal mining companies, gas-transmission companies, and waterflood operators, as well as information on State agencies responsible for the enforcement of laws and the preservation and distribution of data pertaining to the drilling, development, and abandonment of oil and gas wells. Comparative tests were performed with several commercial electronic metal detectors to determine the feasibility of using them to aid in the search for abandoned wells and to determine the instrument most suited for that particular use. The role of methane detectors to locate abandoned wells is described, including a case history. Tests were made to develop an efficient procedure to follow in systematically searching an area for metallic clues or hydrocarbon evidence to abandoned wells. The guide describes, in detail, a search sequence, including the collection of basic data, preparation of the selected area, and the physical search. Methods are given for evaluating the results.

Jan 1, 1973

By Robert W. Van Dolah

The prevention of fires and explosions involving the combustibles and oxidants likely to be found in flight vehicles requires a knowledge of the flammability and related characteristics of these materials. This circular is a compilation of the available charactersilics data for a series of combustibles and oxidants of current interest. Vapor pressure data are presented for fluorine, oxygen, chlorine trifluoride, nitrogen tetroxide, nitric acid, hydrogen peroxide, ethylene oxide, hydrogen, ammonia, pentaborane, unsymmetrical dimethylhydrazine, monomethylhydrazine, hydrazine, and a series of hydro-carbons including decalin, tetralin, bicyclohexyl and other high-density fuels. In addition, flammability characteristics diagrams are included for each of the fuels in contact with air and, where available, other oxidants (for example, oxygen and nitrogen tetroxide). To assist in understanding these data, sections on definitions and theory and applications have been included. Each section is complete in itself and can be used separately. For example, a reader who is familiar with the general theory of combustion and detonation may find the data sections more useful than the definitions and theory and the application sections. However, since pertinent data are included in these sections, they should also prove useful to the experienced engineer interested in preventing fires and explosions.

Jan 1, 1963

By W. D. Dietzman

This Bureau of Mines report presents a continuation of statistics pertaining to distribution of petroleum reservoirs (or fields), wells, and production by depth and producing rate classification in the United States. These statistics show the change that has occurred since results of a similar study were published by the Bureau of Mines in 1967. Data are presented in tabular form by State for the 18 principal oil-producing States and by subdivision for the two largest oil-producing States, Texas and Louisiana. Tabular summations and graphical illustrations are presented for the Nation. The data are classified by 4-barrel-of-oil-per-day rate increments up to 36 barrels and one increment of greater than 36 barrels of oil per day and by 2,000-foot depth increments up to 8,000 feet and one depth increment of greater than 8,000 feet. The overall average producing rates for States and the Nation have been published for many years, and although such rates are useful, they are very general descriptions of producibility. A breakdown of production, wells, and reservoirs by various depths and rates and by State or by State subdivision provides a more detailed description of producibility.

Jan 1, 1975

By Deborah A. Spotts

Researchers at the Bureau of Mines have developed a technique for re- generating chromic acid-sulfuric acid etching solutions used in metal surface treatment operations. The technique utilizes a diaphragm cell equipped with a cation-selective membrane to oxidize cr3+ to cr6+ at the anode and to remove copper, the major metallic contaminant, at the cathode. Normally, spent etchant is discarded after approximately 3 days of use. Using the electrolytic cell, the etchant can be used for a year without replacement, From data obtained from industrial-scale cells, the installation of a regeneration cell with a 1,000-gal catholyte- holding tank has been estimated to save at least $240 per day, The payback period for the investment is estimated to be about 10 mo or less. Because the magnitude of these cost savings will vary at different locations, several graphs are presented to aid in calculating payback for a specific site. Using these graphs and the capital costs presented in this study, the payback period can be determined for installing a regeneration cell with a 500- or a 1,000-gal catholyte-holding tank in an existing surface treatment plant.

Jan 1, 1983

By Alan R. Buehler

The Bureau of Mines conducted a mineral investigation of the 10,500-hectare Cache Peak study area in 1992; the area had been proposed as wilderness. Bureau personnel examined and sampled prospect workings; 14 rock and 20 placer samples were taken during the investigation. The study area is centered about 40 km south-southeast of Burley. Idaho, in the Sawtooth National Forest. There were seven mining claims located inside the study area, and one additional historical mining claim location. Gold, silver, copper, lead, zinc: Possible resource, poor exposure precludes estimate. Marble: Several million tonnes may be suitable for a variety of uses; markets too distant to favor mining. Sand and Gravel: Several million m3, but markets and transportation costs do not favor mining. Quartzite: Several million tonnes may be suitable for metallurgical purposes; however, markets are too limited to mine. Slabs have been quarried at three localities adjacent to the study area, for decorative stone. Production: In 1979, two tonnes of ore were produced and a plan of operations was submitted calling for approximately 5 km of access road for the Last Chance mine. Decorative stone production was not recorded.

Jan 1, 1993

By E. P. Youngman

This paper is one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to can and ore rate mines in various foreign countries. This interpretation of the mining laws of the Irish Free State has been prepared from the best available material in Washington and is released subject to amplification and correction, if necessary, by American foreign-service officials. INTRODUCTION This paper is based upon the mines and minerals act, 1931, enacted by the Legislature (Oireachtas) of the Irish Free State (Saorstát Eireann), December 22, 1931, the lull title of which is "An act to establish a board to perform functions in relation to mines and minerals, to authorize the making of lenses of mines and minerals belonging to or vested in Saorstát Eireann, to name provider for facilitating the working of other mines and minerals and, for imposing restrictions on the working of minerals required for the support of buildings and works, to amend the law with respect to mines, and for other purposes incidental to the matters aforesaid.'

Jan 1, 1933

By Earl L. Hastings

Although the principal market for diatomite in the United States is in the East,4 production of the material is presently restricted to the West, because the deposits are larger, mining costs are cheaper, and the quality of product is better than that obtained from other domestic deposits. However, Tallahatta diatomite, occurring in Choctaw and Clarke Counties, Ala., has a freight rate advantage, which should encourage competition for those market that are now being supplied with the purer diatomites from the western deposits. For this reason, diatomite occurrences in the Tallahatta formation were examined by the Bureau of Mines and physical properties of samples from the deposit were determined to obtain additional data for use by any potential producer who wished to evaluate the material for its commercial possibilities. In 1894 K. M. Cunningham5 found that the buhrstone formation (now known as the Tallahatta formation) contained "siliceous shells of marine diatoms, radiolaria and foraminifera, thus being rather of the nature of tripoli or diatomaceous earth than of a true clay." Cooke6 and Semmes7 also reported the Tallahatta formation to be composed principally of diatomaceous earth with accompanying beds of sand, clay, and sandstone.

Jan 1, 1963

By M. J. Spendlove, P. P. Zapponi

"INTRODUCTION In carbothermic processes for the production of magnesium, magnesium oxide is reduced by carbon according to the following equation:(1) MgO + C = Mg(g) + CO.The reaction is virtually complete at temperatures above 2,000° C. but reverses rapidly at somewhat lower temperatures. To produce magnesium by this reaction, therefore, it is necessary to cool the gas very rapidly to a temperature at which the rate of the reverse reaction becomes negligible. Several media for quenching the gas have been proposed, among which are hydrogen, natural gas, liquid hydrocarbons, and molten metals of low melting point.The results of a preliminary investigation on the use of molten lead as the quenching medium are summarized in this report. The work was done in 1941, when the threat of war made it imperative to investigate every process that offered possibilities for rapid expansion of domestic production of magnesium. Although the results were encouraging, other processes appeared to offer better prospects for immediate wartime development, so the work was not continued. Shortly before the investigation was completed, several patents on the use of low-melting metals for absorption of magnesium vapors appeared, 4/"

Jun 1, 1947

By O. C. Blade, E. L. Garton

Louisiana is one of the major oil-producing States of the country. Commercial production of crude oil in the State began in 1902 and has increased to an estimated output of 157,409,000 barrels in 1945, which is the maximum production up to this time and places the State fourth in the nation. The cumulative production for Louisiana through 1944 is 1,544,481,000 barrels, and, adding the output for 1945, the total to January 1, 1946, is 1,681,890,000 barrels. Data on annual production of crude oil in Louisiana and tentative statistics for 1945 are given in table 1. The large production of crude oil in Louisiana and the present trend to utilize petroleum in accordance with its general characteristics make it increasingly important to present analytical data for crude oils. This report is the fifth of a series presenting such data obtained on crude oils from Louisiana according to the procedure used by the Bureau of Mines. Individual analyses are given for 82 samples from 64 fields; many of the samples are from recently discovered fields, and some are from new producing formations.

Dec 1, 1946

By Donald P. Tuchman

The U.S. Bureau of Mimes is investigating Fourier transform infrared (FTIR) spectroscopy for on- filter quartz analysis of respirable dust. A custom accessory is described for full-face examination of filters utilizing a large-diameter infrared (IR) beam. The accessory positions samples to match diameters with that of the diverging analytical beam. Sample absorbance is then measured. With nonuniform deposition of dust on collection filters being a major issue for such analyses, this approach is the most direct way to accomplish sample area averaging. The approach is unconventional since it utilizes large-beam geometries instead of the usually desired minimized beam dimensions. The issues and problems involved in the analysis of quartz on a filter matrix are discussed. Absorption bands chosen, light-scattering effects, curved baselines, random noise, interference fringes, and possible solutions to technical difficulties are the topics covered. The more significant findings include a 20-pg detection limit for quartz when the custom accessory is used and minimal occurrence of light-scattering effects at low wavenumbers. The custom accessory performance was satisfactory and merits further work. With continued research, an on-filter method for quartz analysis of respirable dusts seems achievable.

Jan 1, 1992

By Edward A. Barrett, Roberta A. Calhoun

Introduction This Instructor’s Copy contains most of the materials trainers will need in order to use Drill Rig Incident (DRI). It includes suggestions for using the exercise, performance objectives for the training, master answer sheets, a scoring key, and a set of discussion notes that provides additional subject information. Four appendices are also included. Appendix A is the complete exercise problem booklet. It may be reproduced so that every person in the training class has one. Appendix B contains answer sheet blanks. The blanks are furnished if you choose to have the invisible ink answers that appear in appendix C printed on them at your location.3 Answer sheets are consumable. One is needed for each group of three to five persons who work the exercise together. An alternative is for each individual trainee to have his/her own answer sheet. Appendix D contains the 24-question pretest / posttest that was used in the field evaluation of the DRI exercise. Acknowledgment The authors thank Linda J. McWilliams, Statistician, NIOSH Pittsburgh Research Laboratory, for her assistance in analyzing the experimental data in this document.

Jan 2, 2005

By H. O. Poppleton

This Bureau of Mines study was made to investigate a possible method for selectively removing the Si02 component of silicate minerals and ores. Of specific interest were aluminum ores and zircon. Methods are described for removing Si02 from these ores as volatile silicon sulfides by treating the ore with sulfur and carbon; with sulfur, carbon, and a reducing gas; or with sulfur compounds and carbon. Comparative results are also given for the desilication of some of the ores with carbon alone to form volatile silicon monoxide. The silica component can be removed partially from bauxites at temperatures above the sublimation temperature of SiS (940° C) by treatment with carbon, sulfur, and methane; however, it is more difficult to remove the silicon from kyanite, manganese silicate, red muds from aluminum processing, kaolinite, lateritic nickel ores, and zircon. Complete desilication requires temperatures ranging from 1,100° C for bauxite to 1,450° C for zircon. Although the high temperatures required and the undesirable metal sulfides produced eliminate practical application of this method using present technology, the Bureau is reporting this data so that they will be available to future investigators.

Jan 1, 1974

By G. B. Atkinson

To develop technology to help assure an ample domestic supply of zinc, the Bureau of Mines is investigating an aqueous chlorine-oxygen leaching process for treating complex sulfide concentrates. This report discusses the purification of aqueous C12-02 leaching solutions by utilizing zinc cementation to remove Cd, Co, Cu, Ni, and Pb. Additional processing of the purified solution is necessary to produce ZnC12 crystals suitable for molten-salt zinc electrowinning cells. The effects of solution temperature, reaction time, zinc dust concentration, ZnCl2 concentration, and degree of agitation on the removal of impurities were investigated for both simulated and actual leaching solutions. Zinc dust addition to a leaching solution at 30° C decreased the Cd, Cu, Ni, and Pb concentrations to acceptable levels of less than 3 mg/1 each. By increasing the solution temperature to 75° C, the cobalt content was decreased to less than 5 mg/l, an acceptable level for producing electrolytic cell-grade ZnC12. Impurity removal rates from ZnCl2 solutions are Pb>Cu=Cd>Ni>>Co. An increase in the solution temperature increases the rate of removal for these metal impurities.

Jan 1, 1982

Provide a coalbed methane data source for industry use in mine planning. Approach Coalbed methane data have keen collected and formatted into a computer implemented data base with software developed for storage, retrieval, and generating files of selected data in response to information requests and for statistical analysis of relationships among various coal parameters. How It Works Coalbed methane data is obtained by the Bureau's direct method test on exploration coal cores. The test involves sealing fresh coal cores in desorption canisters and periodically bleeding the gas into a water-filled, graduated cylinder to measure the volume of gas released. Coalbed methane data collected over the past 9 years have been entered into a computer-implemented data base for efficient retrieval and statistical analysis. Data base processing is accomplished with a commercially available storage, sorting, retrieval, and report writing software package (Datatrieve 11). Information requests from the coal industry are processed with the system, and the data in the desired output format am printed and forwarded to the requestor. Information such as coalbed name, location (state and county), depth of sample, gas content, and coal rank are available from the system. The data can be used for

Jan 1, 1982

By J. W. Walkiewicz

One of the objectives of the Bureau of Mines is to develop substitution technology for scarce materials. In accordance with this goal, alloys containing lanthanum, cobalt, copper, and magnesium were investigated for fabrication of rare-earth-cobalt (RE-Co) permanent magnets. A complete substitution of lanthanum for samarium and a partial substitution of copper for cobalt was accomplished. Magnets of La-Co and La-Co-Cu-Mg alloys were fabricated by powder metallurgy techniques and evaluated. A maximum intrinsic coercivity of 23.2 kOe was obtained with a La-Co-Cu-Mg alloy. In comparison, maximum values of 9.3 kOe and 11.6 kOe were obtained with La-Co and La-Co-Cu alloys, respectively. The substitution of copper and magnesium for part of the cobalt resulted in a large increase of intrinsic coercivity, similar to the results of Bureau research with mischmetal-Co-Cu-Mg alloys. Unlike the mischmetal-Co-Cu-Mg magnets, the La-Co-Cu-Mg magnets showed signs of physical deterioration on exposure to air. The effects of fabrication parameters on the magnetic properties of the La-Co-Cu-Mg alloys were also determined.

Jan 1, 1982

By R. K. Koch

The vapor pressures of liquid columbium and liquid hafnium were deter-mined by the Langmuir free evaporation method as a part of the Bureau of Mines program on the study of transition metals. An electron-beam furnace with a water-cooled copper crucible was used for melting. Temperature was measured with a two-color ratio pyrometer. Least-squares analyses of the vapor pres-sure data gave the following equations: [Logp (atm) = 5 .429 -31,310 T] for liquid columbium in the range 2,740° - 3,140° K, and [Log p (atm) = 5,690 28 T] for liquid zirconium in the range 2,500° -2,810° K. Third-law evaluations of each data set gave mean heats of sublimation (298.15° K) of 175.1±3.2 kcal/mole and 148.3±1.2 kcal/mole for columbium and hafnium, respectively. Second-law standard heats of sublimation determined from sigma plots and from sigma-prime plots agreed fairly well with the third-law values. The sigma-prime plots gave standard entropies of sublimation of 30.96±0.84 eu and 33.S6±0.44 eu for columbium and hafnium, respectively.

Jan 1, 1968

By Stephen D. Cramer

The solubility of methane, carbon dioxide, and oxygen was measured in brines at temperatures from 0° to 300° as part of Federal Bureau of Mines research on the corrosion of metals in high-temperature geothermal and mineral processing environments. Solubilities were measured by the technique of extracting pure gas, dissolved at pressures where Henry's law was applicable, from known volumes of brine. The results were smoothed with respect to temperature. The solubility, expressed in terms of the Henry's law constant, reaches a maximum at temperatures ranging from 60° to 100° C for methane and oxygen, and from 160° to 170° C for carbon dioxide. The Henry's law constant increases, that is, gases are salted out of the brines, in the presence of dissolved salts. Salting-out coefficients are strongly dependent upon temperature. The temperature dependence of the Henry's law constant for geothermal brines is different from that for sodium chloride brines owing to the more complex chemistry of the geothermal brines. The solubility of oxygen and carbon dioxide in brines exposed to air saturated with water vapor and at a total pressure of 760 mm Hg is reported for temperatures from 0° C to the normal boiling point.

Jan 1, 1982

By F. P. Miknis

Previous studies at the Bureau of Mines have shown that broad-line nuclear magnetic resonance (NMR) techniques have potential applications for rapid evaluation of oil-shale deposits. In a continuation of this study the techniques of pulsed NMR have been applied in a similar manner. The basis for the pulsed NMR oil-shale assay method lies in the assumption that the free induction decay (FID) amplitude following a 90° pulse is proportional to the potential oil yield. This assumption was tested on two groups of oil-shale samples, numbering 141 and 263 samples, from two different oil-shale cores. For both groups of samples a small number were selected as calibration samples. Free induction decay amplitude measurements were made on the 141 and 263 samples. The best least-squares regression line was obtained for the calibration samples, and the oil yields of the remaining samples were calculated using the slopes and intercepts obtained in the regression analyses. The agreement between measured and calculated oil yields was good, the indexes of determination being 0.93 and 0.89 for the groups of 141 and 263 samples, respectively.

Jan 1, 1974