Search Documents

By A. C. Rice

Aminopolyacetic acid chelating agents were added to separatory-funnel-scale solvent-extraction systems to determine the effect on separating rare-earth elements. Average values for separation factors between adjacent elements obtained with Primene JM-T2 increase 36 percent when EDTA is added to the aqueous phase. Adding HEDTA or DCTA also improves separation factors for certain rare-earth elements. Percentage of extraction and the separation factors exhibit marked sensitivity to concentrations of amine, chelating agent, and hydrogen ion. The chelating agents improved separation in Primene JM-T, BHDA, and Primene 81-R extraction systems.

Jan 1, 1963

By T. Estelle Gardner

The Bureau of Mines made enthalpy measurements on sodium bromide and sodium iodide in the temperature range 400° to 1,200° K using an ice calorimeter. Equations representing enthalpy as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate smooth values of heat capacity, enthalpy, and entropy at 50° K intervals from the ice point to 1,200° K. The melting point determined for sodium bromide was 1,020° K; the melting point of sodium iodide was 934° K. The heats of fusion of sodium bromide and sodium iodide were calculated to be 6,270 and 5,680 cal/mole, respectively.

Jan 1, 1967

By L. A. Haas

The Bureau of Mines conducted bench-scale leaching tests with recycled spent copper electrolytes and copper-nickel mattes produced from the Minnesota Duluth Complex concentrates. This report describes the first stage of an overall two-stage leach operation. The objective of this research was to determine the matte-leach technology required to convert spent copper electrolyte into an enriched nickel liquor suitable for a nickel refinery and there-fore essentially free of copper, iron, and sulfuric acid. The experimental variables investigated were matte composition, particle size, spent electrolyte content, pulp concentration, oxygenation, temperature, and time. The time required to produce an enriched purified nickel liquor decreased with increasing pulp concentration, temperature, and oxygenation, but increased with increasing particle size and electrolyte copper and acid content. Nickel-rich (about 50 g/l) liquors at a pH of about 4 and containing less than 1 g/l of copper and iron were produced at 70° C by leaching minus 325-mesh low-iron (less than 5 pct) matte for 8 hours with spent electrolyte containing 22.4 g/l Cu, 28.9 g/l Ni, less than 0.1 g/l Fe, and 50 g/l H2S04 at a pulp concentration of 1 kg of matte per liter of spent electrolyteo Varying the nickel content of the spent electrolyte from 11 to 101 g/l appeared to have no appreciable influence on the matte leaching characteristics.

Jan 1, 1981

By B. H. Clemmons, B. G. Saunders, R. H. Stacy

"INTRODUCTION This investigation was undertaken to determine the response of Birmingham (Alabama) red-iron ore to heavy-medium concentration. Specifically, the work involved a study of the efficiency of the process in separating coarse gangue diluents from the ore and an endeavor to evaluate the potential economic results. The investigative work was not intended, nor is it to be construed, to be adequately exhaustive in scope to enable immediate plant construction. Rather, the primary objective was to determine the grade of ore that could be produced by heavy-medium treatment and the resulting indicative or tentative benefits to be derived from such treatment. The latter, in turn, would determine the merits of the more exhaustive study that would be required for an ultimate decision on the heavy-medium treatment of the ores.The problem of avoiding excessive contamination of red-iron ores by shale and/or ferruginous sandstone has been before the operators of the iron mining industry of the Birmingham, Alabama, district for many years. Within the last two decades, increased mechanization of mining methods has increased this contamination to a considerable degree. In fact, general utilization of scraper loading and other mechanical methods of mining, in conjunction with small increases in the natural insoluble content of the ores, in some cases has actually resulted in the production of ""acid"" or excessively insoluble ore, where ""basic"" or excessively lime ores were produced formerly.The contaminating materials are derived largely from roof spells and natural parting seams in the ore, a condition that to some extent has been aggravated by the irregularity of the ore beds. The latter have been subjected to both primary and secondary folding in many places. Considerable faulting has taken place, also. In many localities these conditions render virtually impossible complete avoidance of ore contamination from the over and underlying sandstones and shales. However, in a few localities, where the ore beds are less disturbed and shale partings are absent, mining can and is being accomplished with relatively little dilution."

May 1, 1948

By A. T. Coumbe

During 1953-55, 31,105 miles of pipe for transporting crude petroleum and refined products was laid in the United States, a total slightly below that of the prior 3-year period, according to data compiled by the Bureau of Mines, United States Department of the Interior. The added mileage consisted of 22,571 miles of new pipe, representing about 2,163,807 tons of steel, plus 8,534 miles of secondhand pipe, equivalent to about 419,849 additional tons of steel. During the 3-year period, 13,069 miles of pipe was taken up. By January 1, 1956, the Nation had 188,540 miles of pipeline, an 11-percent gain over the 1952 total of 170,504 miles. The greater use of larger diameter pipelines indicated in recent surveys has continued, as the mileage for sizes 12 inches and over increased from 13 percent of the total mileage at the close of 1952 to 16 percent 3 years later. Crude-oil trunklines 12 inches and over in diameter gained 24 percent during 1953-55, and these larger lines represented 30 percent of the total mileage compared with 25 percent at the close of 1952. Furthermore, the mileage for crude-oil lines less than 12 inches in diameter declined 2 percent and made up only 70 percent of the 1955 total against 75 percent n the previous survey. Product Lines 8 inches and over increased 43 percent from 1952 through 1955 and composed 70 percent of the total mileage compared with 66 percent in 1952.

Jan 1, 1956

By V. F. Parry

[Approximatel~r 7-1/2 illion tOlls of subb1tnminous coals are mined an-nuall in Colorado, Wyo~ing, and Montana, of which 50 percent probably reaches dome ,-tic conswno:os. r:L'he moi s t'_re of the se subbi t1.Uninous coal sis high, averae;:t.:ug about 25 :!,)ercent \-Then they are :nined. T'ne coals are non-caking d ~~ack to a vari ble degree when exposed to nornal atmospheric conditions. ~hey a~e gpod domestic fuels, are considered to be smokeless in most furn~ces, and have been used. f, r f!1an: y ars in hand-fired domestic furnaces in hich tnc practice i~ to e~ploy large lureps for efficient com-]

Jan 1, 1941

By Claude A. Tongish

This Federal Bureau of Mines report presents information on the accumulation and distribution of helium in U.S. natural gas reservoirs. The investigation concerns the relationship or association of helium with geographic location, geologic age, reservoir depth, nitrogen, carbon dioxide, and argon. Although helium is a minor constituent in natural gas, these data show that certain conditions make some reservoirs statistically more favorable than others for the accumulation of helium. The report is based on gas analysis information collected-by the Bureau from 1917 to 1974 from 10,086 gas samples, representing 6,455 reservoirs in 35 States. The occurrence of helium in the reservoirs was 11.5 percent with less than 0.005 percent of helium, 70.9 percent with 0.005 through 0.29 per-cent of helium, and 17.6 percent with 0.30 percent or more of helium in the gas. Results of the various correlations are presented in tables and charts. Relationships have also been determined quantitatively by measures of correlation. The statistical data can be used to determine the environment under which reservoirs with high-helium contents are most likely to occur. These data can be used with other information for predicting the future helium resources of the United States.

Jan 1, 1980

By R. K. Franklin, S. T. Reese, J. J. Forbes

"INTRODUCTION It is a recognized fact that in the coal-mining industry coal dust must be allayed to promote the safety and health of underground workers. The Bureau of Mines has been cognizant of the hazards of coal dust for many years, and the necessity of controlling such dust was acknowledged when the Federal Mine Safety Code was formulated. Accumulations of coal dust increase the explosion hazard in a bituminous-coal mine and facilitate the propagation of an explosion. Some of the coal dust produced in mining is inhaled by the workers and contributes to respiratory infection. Impairment of vision and personal discomfort resulting from working in dense clouds of coal dust reflect unfavorably on the efficiency of workmen. Considerable coal dust, originating at the working face, is carried in the ventilating current and deposited elsewhere in the mine, thereby increasing the explosion hazard. It is apparent, therefore, that if coal dust could be allayed effectively at its points of origin, the dust-explosion hazard in bituminous-coal mines would be reduced greatly.Although dust control is practiced in many bituminous-coal and lignite mines, the extent and effectiveness of control for the, entire industry-is not generally known. The purpose of this circular is to present such information clearly, and to encourage coal-mine operators to install dust- allaying equipment.Factual data on dust-allaying practices at working faces in a large number of the bituminous-coal and lignite mines in the United States were .compiled from reports on recent Federal inspections of these mines, The information is presented in tabular form to permit review of the dust-allaying practices of a substantial part of the industry, by States, and also according to employment, and loading practice."

May 1, 1950

By James R. Kerr

This study reviews the sulfur and suliuric acid industries in Eastern United States with emphasis on patterns of consumption and marketing. Output of sulfur in the East is relatively small, and most of the area's sulfur requirements are met by gulf coast Frasch sulfur. Over the long ten recovered elemental sulfur from sour natural gas and petroleum may become the East's major source of sulfur. In 1958 sulfuric acid manufacture consumed over 80 percent of the area's sulfur requirements. The leading uses for sulfuric acid were the manufacture of superphosphates and chemicals. Over the years, unit requirements for sulfur and acid in many major markets have been reduced through improved technology, but new markets always have been developed to keep the industry vital and growing.

Jan 1, 1965

By Wilbur I. Duvall

A linear array of shot and gage holes 30 feet deep in a granite outcrop was used to compare the size and shape of radial strain pulses produced in the rock when short cylindrical charges of cast composition B were detonated axially or at one end. The axially detonated charges produced radial strain pulses that had shorter rise times and larger peak strain than the strain pulses produced by end detonated charges.

Jan 1, 1965

By Chas. F. Jackson

The mining literature is replete with descriptions of methods and costs of operation at producing mines. To day the mine manager can find published information bearing upon almost any problem with which he may be faced. From this literature he can familiarize himself with methods employed by otter operators for coping with problems similar to his own, under more or less parallel conditions. Transaction of mining societies, publications of the U. S. Bureau of Mines, technical journals, and handbooks all afford valuable information dealing with operating methods and costs, Very little has been published, however, regarding methods and costs of equipping and developing new properties and bringing them to tae productive stage. There may be some question in the minds of many as to the value of papers on this subject, due to the great variety of conditions encountered. No two prospects are alike. Obviously, it is impossible to forecast what expenditure will be required to develop a mine from a raw prospect or even to predict whether the prospect can be developed into a productive mine.

Jan 1, 1933

By Arnold B. Hubbard

Automatic control instruments were utilized by the Bureau of Mines for routine assays of large numbers of oil shale samples and other bituminous materials. The standard Fischer assay method was automated by automatically controlling the heating cycles of a battery of 12 electric heaters with electronic controllers and programmers. The condensers were cooled with a modified automatically controlled refrigeration bath. The complete assembly consisted of 12 retort units, necessary control instruments, and the refrigeration bath. This equipment was capable of producing more consistent results than those previously obtained with the gas-heated retorts and of increasing the output of assays substantially with no increase in operating personnel.

Jan 1, 1965

By W. P. Diamond

Coalbeds exhibit a directional permeability, with the maximum permeability oriented parallel to the face cleat. Thus, the most efficient pattern of vertical degasification holes for a coalbed is dependent upon cleat orientation. Surface joints, infrared photolinears, and Ronchi grating photolinears were investigated as potential estimators of subsurface cleat orientation. Cleat orientations were measured in 18 mines, in the Pittsburgh coalbed in southwestern Pennsylvania and northern West Virginia to be used as a standard against which prediction techniques would be evaluated. Two cleat systems with a strong geographic segregation were measured in the study area: N 670 W -N 280 E (950 separation) for the north, and N 76° W -N 17° E (930 separation) for the south. Directional data obtained from the three techniques investigated yielded satisfactory regional predictions of cleat orientation. Analysis of surface joints was the only technique considered sufficiently reliable on a local basis. Prediction of cleat orientation is based on the pairing of the principal directional sets into all reasonable combinations of fundamental systems. The system or systems composed of the most dominant sets nearest to 90° separation are likely to be a reliable prediction of cleat orientation. The most dominant set of the system selected is likely to be the face cleat.

Jan 1, 1976

By Warren E. Morrison

This study was prepared in response to the need for a series of data that reflect the basic flow pattern of energy resources in the United States. To effectively measure and analyze energy,2 it is necessary to prepare balances that reflect both production and consumption, and the various forms energy resources take at different stages of utilization. Before energy can be measured it must also be put into a common unit. In this study the common unit used is the British Thermal Unit (Btu). The ideal point to survey energy is at the stage of final ultimate use, representing the useful work derived from the interaction of energy inputs and the prime mover. Unfortunately this concept of efficient or useful work from energy output cannot readily be measured in the aggregate. With the present available official data, energy measurement can be carried to the point of calculation of net inputs of energy3 into the economy at various stages of utilization. However, preparation of energy balances, on a net basis is hampered by the fact that this can only be done for years when the censuses of Mineral Industries and Manufactures are taken, usually at 5-year interval.

Jan 1, 1964

By R. V. Ramani

One area of study in the Coal Mine Injury Analysis project was to illustrate and enhance the ability of mine safety management personnel to apply analytical techniques to injury experience data and to justify requests for funds for safety enhancement actions on a cost/benefit and other quantitative basis. Four volumes of this final project report detail (1) the objectives and scope of the mine safety management research, (2) the results of literature review, and case studies, and (3) models developed for mine safety management. The four volumes are titled as Volume III: Mine Safety Management, Volume IV: Analytical Techniques for Mine Safety Management; Volume V: Mine Safety Management Case Studies and Volume IX: Training Cost Model. This volume deals with the development of a microcomputer based training cost model (TCM) which can be used to analyze training cost implications of various types of training. The model has been developed using Aston Tate's dBASE III plus language. The computer program and a test run of the model are presented in this report.

Jan 1, 1993

Underground coal mining continues to evolve in the U.S., and more reserves are being mined under deeper cover, with worse roof, or with interactions from previous workings. At the same time, the mining community is responding to higher safety standards and intense competitive pressures. The need for effective ground control design has never been greater. Ground control safety issues that have been addressed by recent the National Institute for Occupational Safety and Health (NIOSH) research include: Improving roof support performance; Maintaining safe tailgate escapeways from longwalls; Optimizing pillar design for retreat mining; Controlling multiple seam interactions; Predicting roof conditions during extended cuts, and; Preventing massive pillar collapses. As funding from both government and the private sector has diminished, the emphasis in research has focused on providing the mining community with practical techniques for improved ground control design. Many projects have successfully employed empirical methods that emphasize the statistical analysis of case histories from underground mines. Other projects have employed numerical models and large-scale laboratory testing of roof support elements. Using these data, NIOSH has developed an entire toolbox of computer programs that have been effectively transferred to the mining community.

By Brian P. Stapleton, Bill M. Stewart, Joel R. Warneke, Curtis C. Clark

Of the 28 accident/injury classifications listed by the Mine Safety and Health Administration, handling materials is second only to roof falls in terms of generating the highest number of reportable accidents in active underground coal mines. Two materials-handling activities that cause numerous injuries each year are the categories of “handling supplies or material, load and unload” and “moving power cables.” Mechanization and mine worker activity training are two methods that can aid in preventing these injuries. This paper describes three mechanical methods—the mobile manipulator, the in-mine hoist, and a cable-handling system—being developed and tested at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health. Two of the devices are specifically designed for loading, unloading, and moving supplies and materials, and the third device is for handling trailing cables in the confined spaces of coal mines. Also described are safety solutions developed for underground coal mines geared to showing miners safe and unsafe ways of performing various materials-handling tasks.

By Thomas M. Barczak, Joe Bower, Jinsheng Chen

Pumpable roof supports provide an alternative longwall tailgate roof support and have grown in usage during the past few years. Heintzmann Corporation has been installing pumpable roof supports at the RAG Resources Emerald Mine in western PA since 1998, where they have provided effective roof control in their longwall tailgates. Despite the success of these supports in this application, questions remain regarding critical design issues for optimizing the use of this support technology. The support loading profile is characterized by a high initial stiffness with peak loading occurring at less than one inch of convergence, followed by significant load shedding with a post failure capacity comparable to that of wood cribbing. Therefore, the key to optimizing the support utilization is to provide sufficient load density to prevent convergence from occurring beyond the peak loading capacity. This requires an understanding of how the supports interact with the ground conditions, hence measurement of the ground reaction curve. In order to obtain this information, pumpable roof supports were instrumented to measure support loading. Roof deformation and roof-to-floor convergence measurements in the vicinity of the instrumented supports were also made. The experimental parameters for the installation were the support spacing and water-to-solids ratio of the grout, which controls the grout strength and ultimately the maximum capacity of the support. The study clearly shows that at this mine a 24-inch diameter support is fully capable of providing adequate ground control under depths of cover of 750 ft as only 50 pct of the available support capacity was utilized outby the longwall face. It was also shown that the 2.00 to 1 water-solids ratio, despite providing a slightly softer support response, is sufficient for maintaining the same degree of roof control provided by the traditional 1.75 to 1 grout mix. The 10-ft spacing of the supports did not cause any ground control problems outby the face. However, inby the face the performance of the support is degraded once the peak capacity of the supports is exceeded. It appears that the large load shedding behavior, which is characteristic of this support following peak loading, allows the immediate roof to separate. When this happens, the support is unable to regain control of the roof in time to prevent failure of the immediate roof beam.

By H. H. Heady

This Bureau of Mines report provides specific information regarding the analysis of ores, concentrates, and bullion. It describes analytical services provided by some Federal agencies, and discusses analytical techniques applicable to the precious metals. The appendixes list Bureau of Mines State Liaison Offices and commercial assay laboratories.

Jan 1, 1976

By E. J. Murphy, John C. Holtz

"INTRODUCTION Toxic gases in the products from the detonation of explosives are one of the hazards in blasting underground. Investigations by the Bureau of Mines 4/5/ have shown that the oxygen balance of the explosive is an important factor in the control of toxic gases. This balance is considered in determining the composition of modern metal-mining explosives for blasting underground, and application of the concept has reduced the volume of toxic gases generated.The chemical nature of the material being blasted also influences the composition of the toxic gases produced. Under some conditions of blasting in massive pryrite, unsafe concentrations of sulfur dioxide and hydrogen sulfide have been found.Experiments with the O-J apparatus 8/ have shown that there is an increase in the volume of carbon monoxide in the gaseous products when permissible explosives are detonated in contact with coal dust. Thus, reactive materials of a reducing nature adjacent to explosives loaded in drill holes may decrease the effective oxygen balance of the explosive and cause the volume of toxic gases to increase.Several blasting accessories of reducing nature have been introduced recently for use in coal or metal mines or tunnels. In practice these are loaded adjacent to the explosive where conditions favor reaction with the products of detonation. The effects of this loading on the gaseous products obtained from the shot are indicated in this report. Broad consideration was not given the efficiency, usefulness, or over-all safety of these devices, but the practical significance of the hazard resulting from increased volume of carbon monoxide is discussed."

May 1, 1942