Search Documents

By E. J. Kloos

The Bureau of Mines devised a new machine-test method for measuring carbon dioxide inspired by a wearer of self-contained breathing apparatus. The new method compares favorably in speed and precision with standard man-tests in which the apparatus is tested while actually worn, and is scheduled for use in future approval tests for facepiece carbon dioxide 'measurements. However, man-tests will still be used to measure the efficiency of the carbon dioxide sorbent materials in closed-circuit breathing apparatus.

Jan 1, 1966

By Oliver Bowles

Wire saws have been used for many years in European travertine, marble, and slate quarries. This method of sawing found very limited use in America until 1927 when it was accepted as standard equipment in elate quarries in Pennsylvania where it has been remarkably successful. Details of its operation in slate have been published in a recent bureau report.3 The very limited extent to which the wire saw has been employed in limestone and marble quarries in the United States and the seeming lack of interest even in experimental work to determine its advantages are difficult to explain in vied of its wide use in cutting similar rocks in Europe and its unquestionable advantages in sewing slate in America. In order to encourage improvement in quarry practice the United States Bureau of Mines has endeavored to obtain information as to the extent to which wire saws are used in Europe together with data on the rate and cost of sawing. The information at hand is by no means complete either in territory covered or in details of operation; it nevertheless brings out certain significant features that may be of interest and advantage to quarrymen in the United States.

Jan 1, 1931

To reduce operator exposure to noise from vibrating screens at coal preparation plants. Background Hearing loss is one of the most common occupational illnesses in the United States. In the U.S. mining industry, hearing loss is 2.5 to 3 times greater than what is expected for the average population that is not exposed to occupational noise. Furthermore, studies by the National Institute for Occupational Safety and Health (NIOSH) showed that by age 50, 90% of coal miners have a hearing impairment versus only 10% of the population that is not exposed to occupational noise. A NIOSH cross-sectional survey of coal preparation plants showed that 43.5% of employees were overexposed to noise. The study also found that vibrating screens were one of the top five loudest types of equipment at these plants?as well as the most numerous?making them a key noise source to address.

Nov 1, 2009

By Allen S. Smith

Analysis of the helium content of a natural gas presents more than the usual difficulties encountered in applying the thermal-conductivity method because of the relatively small amounts of this inert as present and the wide variation in the other constituents. However, the numerous advantages of this method and its adaptability to Continuously recording and control instruments make it worthy of consideration. A specific application of the method described yields quantitative results only when used with gas mixtures of known qualitative compositions which Vary within predetermined limits. Periodic analyses for the helium content of a producing gas well may be conveniently made by an absorption method, and a continuums analytical method is not necessary for this purpose. Natural gas containing 1.75 to 1.90 percent of helium produced from Government-owned wells is processed in the Amarillo (Texas) Helium Plant of the Bureau of lanes. The helium extracted in the plant is supplied to the Army and Navy, and the processed natural gas is sold to a commercial gas company. As complete recovery of the helium in the raw material is not economically practicable, the processed gas contains 0.1 to 0.3 percent of helium, depending upon conditions of operation. Production is checked against the helium removed from the gas, which before the installation of the thermal-conductivity apparatus was calculated from the analysis of a cumulative sample of the processed gas. As conditions of operation affect the residual helium content to a large extent, a composite sample was an uncertain index of the efficiency of the process.

Jan 1, 1934

By Sabri Ergun

NEW theoretical data are presented for the intensity of X-rays diffracted from randomly oriented aromatic and alicyclic molecules and diamondlike structures such as are found in coals, cokes, and carbonaceous materials. Data have been computed using the Debye interference function. Computations for the smaller molecules have been made with the Univac 1204 computer: those for large structures, with either the IBM 704 or Bendix G-20 computer. A brief theoretical introduction of the Dobye interference function is given, and an outline is made of the treatment of experimental data so that the experimental interference function can be obtained.

Jan 1, 1965

By B. J. Scheiner

Extraction of silver from silver mill tailings by an electrolytic oxidation procedure was investigated by the Bureau of Mines. Various parameters affecting silver extraction, such as electrolysis time, particle size, and dissolution of the silver as the tetrachloro or cyanide complex, were studied at 30° C with an electrolyte concentration of 20 weight-percent sodium chloride. Resulting silver extractions ranged from 77 to 90 percent, depending on the tailings being treated. Concomitant extraction of mercury ranged between 90 and 95 percent. Power consumption was 52 to 90 kilowatt-hours per ton for the tailings investigated. Comparative experiments using direct cyanidation resulted in extraction of 46 to 82 percent of the silver and 20 percent of the mercury. Cyanide consumption ranged from 3.3 to 9.4 pounds per ton of tailings, depending on the tailings being treated. Silver and mercury were recovered from leach solutions by precipitation on iron powder, followed by conventional distillation and fire refining steps.

Jan 1, 1972

By John T. Aydelotte, Martin J. Gavin

" Oil shale contains little or no oil as such , but it contains an organic material from which oil may be produced by destructive distillation" . This statement , or others conveying the same meaning, appears in many popular and techni cal articles on oil shale . It is based on the belief that the ordinary solvents of petroleum have but little action on the organic substances contained in oil- yielding shales , although on distillation these same shales may yield upwards of 50 gallons of crude shale oil per ton . A 50 - gallon shale thus yields by distillation 18.73 per cent of its weight as oil ( assuming the specific gravity of the oil to be 0.900 ) , although only a relatively small part of this can be recovered by extraction with such solvents as chloroform , carbon tetrachloride , and the like . In the course of certain experiments designed to determine the solubilities of different shales after they had begun to yield oil by distillation , it was found desirable to determine the quantity dissolved from certain unheated shales by various solvents , at or near the boiling points of these solvents . The method used and results obtained are presented below. These experiments were made in connection with the oil - shale investigations being conducted by the U. S. Bureau of Mines , in cooperation with the States of Colorado and Utah .

Jan 1, 1922

By Ellis S. Hertzog

The data published in this report cover only one phase of a special study of the physical and chemical properties of Alabama coals made by the Bureau of Mines. In addition to determinations of friability, the survey included determinations of grindability, B.t.u. value, end ash-fusion temperature. Assay distillation tests, both for high- and low-temperature carbonization, and proximate and ultimate analyses were made also. However, this preliminary paper is concerned only with the results of friability tests and is issued to expedite the release of this information to the public. The friability test measures the liability of a coal to break into smaller pieces when subjected to repeated handling, as occurs in the mining, preparation, and transportation operations. Friability depends on many physical characteristics of the coal that vary not only between different seams but also in the same seam. The laboratory methods of determining friability have been developed to give a practical means of estimating degradation of size. So far as is known to the authors, no data on the friability of Alabama coals have ever been published. This paper makes available for the first tine fairly comprehensive information on this subject. Because the procedure for the tumbler test for determining the friability of coal is relatively new to the coal operators, the authors have included a complete description of it in this report.

Jan 1, 1938

By M. M. Myers

"Importance pf the small stone problem.Profitable disposal of limestone too small for making lime in the shaft kiln, is one of the most urgent problems in the lime industry. Reports received by the Bureau of Mines from 31 quarries show that the proportion of small stone varies from 2 to 40 per cent, averaging 18 per cent of gross pro¬duction, Modern methods of heavy blasting, and the use of crushers in large quarries tend to increase the proportion of small stone above that produced in early days when light blasting and hand sledging were almost universally used. There is also a growing movement toward underground operation of lime deposits, a method which in general produces a greater proportion of fines than is encountered in open-pit work. Thus the small stone problem is of growing importance, and demands the attention of every progressive lime producer. As the problem is of almost universal interest, it is urgently desired that every operator who reads this report will contribute from his knowledge or experience, answers to the questions on the final sheet.There are several markets in which small stone may be sold but in these markets the competition is generally keen and the prices low. The lime producer's chief product is lime, he understands its manufacture and marketing, and brings him a greater return than can be obtained from most limestone by-products. For these reasons it is evident that the conversion of small into lime is the nest desirable means of disposal."

Apr 1, 1924

The problem of separating the constituents of a mixed gas has assumed increasing importance to chemical technology during the last several decades. Metallurgical practice, dealing mostly with the application of gases as fuel, such as for the oxidation or reduction of ores, has not often confronted an important need for such separations. If theory occasionally has indicated advantages in the use of purified or separated gases, as for example the "dry" blast for the iron furnace or oxygen-enriched blast for a variety of smelting operations, the economics of the proposals has not often been satisfactory. It has seemed evident that the practice of the chemical plant was too expensive with regard to installation or material costs, or both, for the needs of the basic smelting industries and indeed was applicable commercially to metallurgical purposes only when the metals in question were especially valuable or pure. This bulletin deals with a new mechanical means of attacking the problem of separation. Although it is improbable that any one type of separation could hope to find universal application, the method described is to be regarded as an alternative to conventional means that has attractive possibilities in certain instances. It extends the number of methods previously available by one that has not before been applied commercially and that utilizes a well-known property of gases that never has received effective technologic attention.

Jan 1, 1940

By F. P. Haver

Primary lead is produced in the United States by the pyrometallurgical smelting of lead sulfide (galena, PbS) concentrates, which poses sulfur dioxide and lead air pollution control problems. The Federal Bureau of Mines has investigated an alternative hydrometallurgy procedure that does not generate gaseous sulfur oxides and diminishes the potential for the escape of lead into the atmosphere. The procedure involves leaching galena flotation concentrates with ferric chloride (FeC13) solution to obtain lead chloride (PbC12) and elemental sulfur as expressed by the following chemical reaction: PbS + 2FeC13 ? PbC12 + 2FeCl2 + S°. At 100° C, over 99 pct of the PbS in the concentrate is converted to PbCl2 in less than 15 min. The leach solution, composed of brine (NaCl) containing slightly more than the theoretical required amount of FeC13, dissolves the PbC12 as it is formed, leaving a residue of elemental sulfur plus gangue. High-purity PbC12 (>99.9 pct) crystallizes from the leach filtrate on cooling and is electrolyzed in a low-temperature, fused-salt cell to obtain corroding-grade metal (>99.94 pct Pb). Spent leach solution (FeC12) is regenerated for further use by reaction with the chlorine obtained in the electrolysis of lead chloride. Other values, such as Ag, Cu, Zn, and S°, are recovered by additional treatment of either the leach solution or leach residue.

Jan 1, 1976

By George H. Holmes

This report describes the results of a reconnaissance survey of areas in California and Nevada considered favorable to beryllium mineralization. Pegmatite dikes, veins, intrusive sills, contact metamorphic, and disseminated deposits as well as tactite deposits in the former major tungsten-producing districts were investigated. A general geographic pattern of beryllium mineralization was found to be concentrated along a wide belt in eastern Nevada extending from the Ruby Mountains, Elko County, south through the Fish Creek Range, Eureka County, the Snake Range, White Pine County to the Virgin Mountains in Clark County, Nev., and Mohave County, Ariz. Sporadic occurrences of beryllium are in central and southern Nevada, and in the pegmatite dikes of San Bernardino, Riverside, and San Diego Counties, Calif., and the granite masses of the southern Inyo Mountains, Inyo County, Calif. Principal company activities are centered in the Snake Range, Fish Creek Range, and the Virgin Mountains, Nev., and the Inyo Mountains, Calif. Other areas in California and Nevada have been superficially explored with results indicating either limited or widespread, but submarginal, mineralization. Although beryllium was found to occur, to some extent, in many of the deposits, mining has been hindered by the lack of a market for beryllium ores and concentrates other than standard-grade beryl and also by the erratic pattern of mineralization and the high exploration and beneficiation costs required to produce a marketable product.

Jan 1, 1963

By George H. Holmes

This report describes the results of a reconnaissance survey of areas in California and Nevada considered favorable to beryllium mineralization. Pegmatite dikes, veins, intrusive sills, contact. metamorphic, and disseminated deposits as well as tactite deposits in the former major tungsten-producing districts were investigated. A general geographic pattern of beryllium mineralization was found to be concentrated along a wide belt in eastern Nevada extending from the Ruby Mountains, Elko County, south through the Fish Creek Range, Eureka County, the Snake Range, White Pine County to the Virgin Mountains in Clark County, Nev., and Mohave County, Ariz. Sporadic occurrences of beryllium are in central and southern Nevada, and in the pegmatite dikes of San Bernardino, Riverside, and San Diego Counties, Calif., and the granite masses of the southern Inyo Mountains, Inyo County, Calif. Principal company activities are centered in the Snake Range, Fish Creek Range, and the Virgin Mountains, Nev., and the Inyo Mountains, Calif. Other areas in California and Nevada have been superficially explored with results indicating either limited or widespread, but submarginal, mineralization. Although beryllium was found to occur, to some extent, in many of the deposits, mining has been hindered by the lack of a market for beryllium ores and concentrates other than standard-grade beryl and also by the erratic pattern of mineralization and the high exploration and beneficiation costs required to produce a marketable product.

Jan 1, 1963

By M. A. Trevits

During the time period from 1990-2007, 1601 reportable fires occurred in the U.S. mining industry (an average of 89 fires per year). The leading causes of U.S. mine fires were flame cutting and welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions, and spontaneous combustion. The fact that mine fires continue to occur with an alarming regularity reinforces the importance of recognizing and eliminating the potential hazards and the overall need for improved fire control and suppression technology to ensure the best possible outcome during a mine fire. The National Institute for Occupational Safety and Health (NIOSH) is conducting an evolving comprehensive program of research that is addressing mine fire prevention, detection, management and suppression. This paper presents a summary of recent research accomplishments and provides an overview of the next phase of the NIOSH mine fire research program.

Jan 1, 2008

By W. E. Wallace, V. Castranova, P. Hathaway, F. H. Y. Green, E. D. Recad, V. Vallyathan, M. J. Keane

Inhaled particle contact with pulmonary surfactant in the hypophase lining pulmonary alveoli was modeled in vitro by exposing two respirable sized dusts, kaolin and silica quartz, to lecithin, a major component of pulmonary surfactant, emulsified in physiologic saline. Lecithin adsorbs to the dusts upon incubation at 37º C and suppresses their cytotoxicity as measured by pulmonary macrophage and erythrocyte assays, suggesting that pulmonary surfactant provides a defense system against prompt cell membrane lysis by inhaled dusts. Subsequent pulmonary macrophage phagocytosis and lysosomal enzyme digestion of the coated dusts was modeled in vitro by incubation with phospholipase A2 for one hour. With increasing lipase activity, silica hemolytic potential was restored to native silica levels. Kaolin was retoxified to levels far in excess of native kaolin hemolytic potential. Elution, thin layer chromatography and phosphate assay of treated dusts indicate most lecithin on silica is digested to lysolecithin and desorbed, silica retoxification being due to surface and adherent lysolecithin effects. Most lecithin on kaolin is not digested in this same time; that which is results in adherent lysolecithin which is responsible for the kaolin retoxification. Digestion with phospholipases A2 and C together produces only weakly retoxified kaolin. Results suggest that surface adsorption properties which control the adherence of prophylactic surfactant distinguish the pathogenic potentials of quartz, kaolin and mixed dust.

Jun 1, 1988

By Albert E. Long

Preliminary experiments conducted in 1949 with a few diamond bits in which the diamonds in the bit crowns were set in hard-vector directions indicated that a substantial saving could be effected when a high percentage of the diamonds were oriented in this-manner. It was realized, however, that many additional tests would have to be performed before a positive trend could be established and the possibility of coincidence eliminated. Therefore, a long-range series of experiments was planned to investigate various phases of the problems related to the orienting of diamonds in diamond bits. This report (the third in a series) 2/3 presents the information obtained from tests conducted to investigate more fully the effects of orienting high-grade drill bort in diamond bit crowns. In these tests, the drill bort were oriented in both hard-vector and soft-vector directions in the crowns of AX-size bits. Test drilling was done in a dike of saussuritized dacite porphyry similar to a fine-grained granite in hardness e drillability.

Jan 1, 1954

By K. J. Maggs

The U.S. Bureau of Mines has investigated the chemical vapor deposition of diamond films on tungsten substrates. The effects of deposition parameters on the adhesion of the films was determined. The films were produced using a hot filament chemical vapor deposition system. Parameters investigated were substrate temperature and methane concentration in the feed gas. Film quality, morphology, and composition were characterized by scanning electron microscopy and Raman spectroscopy. Adhesion testing was performed using an indentation technique, and the results were quantified by relating adhesion to interface fracture toughness. Diamond films with well-faceted crystalline morphology with grain size greater than 1 µm had poor adhesion properties regardless of substrate temperature or methane concentration. Diamond films with smooth morphologies consisting of rounded clusters of small (<0.2 µm) diamond crystallites and amorphous carbon phases displayed much higher adhesion, although the conditions that led to the growth of these films are not understood.

Jan 1, 2010

By Neal M. Muir

The increasing demand for iron ores prompted the Bureau of Mines to investigate the sources of past production in Kentucky to determine whether reserves of usable ore still exist. Preliminary investigation showed that the holdings of the Rose Run Co. were the most promising, inasmuch as the deposit had not been exhausted by past mining and the property was near railroad facilities and but 80 miles from the blast furnaces at Ashland, Ky. The Bureau conducted a churn-drilling and sampling program to investigate the depth, thickness, and iron content of the ore beds so that they might be evaluated as a possible reserve of low-grade iron ores. The Rose Run area in Bath County, Ky., was explored by 74 churn-drill holes totaling 2,059.4 feet of drilling and 4 cuts and test pits. Fifty-seven drill holes and the four test pits penetrated the ore bed at an average depth of 22 feet. The bed had an average thickness of 2.54 feet. Analyses show that the calcium and magnesium carbonate content is more than sufficient to flux the silica and provides an excess that needs an admixture with other siliceous iron ores.

Jan 1, 1950

By Xinquan Zhou, Rudolf E. Greuer

MFIRE, written in Fortran 77, is a computer program for ventilation state simulation in the steady state or transient state condition. It can be applied for the calculation of normal ventilation system planning or the analysis of the dynamic state variation in a ventilation system under thermal or mechanical disturbance. The state simulator MFIRE is a useful tool for mine fire fighting. In the case of a mine fire, mine ventilation engineers want to get some help to obtain more information, such as what is happening in the underground mine and how to control the mine fire, for correct decision making. By use of program MF&apos;IRE, forecasts can be made on the variation of airflow, temperature, and contaminant distribution in a ventilation system during a mine fire. The paths which the contaminant takes at each time interval can be traced. The program MFIRE can be of assistance in the preplanning of escape routes. It can also be helpful during a mine fire emergency and mine recovery operation. Besides of offering the information of state simulation during a mine fire, MFIRE can be applied for state control by pretesting the suitability of the selected state control measures. It is to simulate the effects of the state control measures on the airflow distribution of a dynamic ventilation system. The testing result can be used for fire fighting in a similar real case of a mine fire. By employing empirical methods or a qualitative analysis like Budryk approach, ventilation engineers can choose different combinations of locations and sizes of control devices as samples of state control for an underground mine fire. Program MFIRE can simulate the different combination samples, that consist of a certain mine fue, the corresponding different control measures, and obtain the control effects. After the different control results are compared, the state control measure, which creates the best effect among the different state control measures, will be chosen for that fire case. When a mine fire, which is similar to one of the pretested cases, breaks out, the corresponding choice of the state control measure is applied to the ventilation system. It means that the simulator MFIRE has the function of indirect state control [10]. To achieve the above two functions, state simulation and state control, the mine ventilation system condition, sometimes, should be changed in a wide range to meet the requirement of the fire fighting. These wide system condition changes, such as adding operating fans, stopping or reversing fans, changing fan characteristics, adding regulators and making airflow shortcuts are represented in the time table of the input data set When the data files are changed in a wide range, however, an iteration divergence and some other computing errors in the distribution of airflow, temperature, and contaminant may occur. More serious logical programming and flexible selection on the algorithms are wanted to meet the request of the different data sets, to achieve correct state distribution simulation and improve the iteration convergence. To enhance the reliability and common suitability of program MFIRE, it is necessary to make investigation, analysis, and modification for the formal versions of MFIRE. The version 1.29, permitting dry .calculation, and versions 2.01/v2.0, permitting dry and humidity calculation, are widely applied

Develop a technology for producing high-quality hake graphite from the steelmaking waste known as kish. Approach Treat the waste kish as an ore and apply mineral processing techniques of physical beneficiation and chemical purification to produce a range of graphite products com¬petitive with the natural mineral. Background Graphite is a naturally occurring form of carbon with a unique combination of properties that make it indispensable in a very wide range of industrial and consumer applications. It has high electrical and thermal conductivity and remains stable to extremely high temperatures It has a low coefficient of friction and is nearly impervious to corrosion. The steel industry is dependent on graphite in clay-, magnesia-, and alumina-bonded refractories for crucibles, bricks, facings, and coatings. Electrical uses include graphite brushes in motors and generators, and electrodes in batteries. The transportation industry needs graphite for clutch and brake linings, and all industries depend on graphite in seals, gaskets, lubricants, and coatings. The consumer sees graphite in composite plastics and in the common pencil. As with all natural minerals, the availability of graphite is diminishing and costs are rising as quality decreases.

Jan 1, 1993