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By R. E. Meaker

Electrical conductivities and densities of molten fluoride systems were measured as functions of the melt temperature and composition. For any given mixture, the two properties change linearly with temperature. Three alkali metal fluorides were selected as solvents for melts of the type LiF-, NaF-, and KF-MFx, where M is a metal selected from the alkali metal or alkaline earth groups, or from the lanthanide or actinide series of elements, and x = 1-4. Heats of activation for conductance were calculated from the experimental data and varied from 2.3 to 9.2 kcal/mole at 1,000° C. Some relation between position in the phase diagram and the conductivity changes was suggested.

Jan 1, 1971

By C. I. Pierce

This report describes and presents results of a phase of a laboratory study conducted at the Morgantown Petroleum Research Laboratory, Federal Bureau of Mines, Morgantown, W. Va., to determine the response of shielded electrodes of different dimensions in thin, noninvaded beds and to stimulate interest in the use of focused-type logging devices in the Appalachian oilfields. A blotter model was used to obtain plots of the potential field in the vicinity of a model shielded electrode. Three plots are presented. The difference in curvature of equipotential lines and the variation in measured resistance values for different blotter-model conditions suggest that the shielded electrode will give resistivities higher than normal when measurements are taken in a thin conductive bed located between resistive beds, and resistivities lower than normal when measurements are taken in a thin resistive bed located between conductive beds.

Jan 1, 1961

By Frank D. Lamb

Pyrophyllite, a hydrous aluminum silicate (Al2 Si4O10 (OH)2 ) has been mined in North Carolina and marketed without beneficiation for the past 100 years, but recent demands for higher-grade material indicate that an economical concentration method is needed for at least a part of the pyrophyllite production. Past production has depended upon selective mining and hand sorting, which is often unsatisfactory because of the finely disseminated character of the ores. The major impurity in North Carolina pyrophyllite ores is quartz, which accounts for the abrasiveness of the commercial product. Since pyrophyllite is only slightly heavier than quartz, those ores cannot be beneficiated by simple gravity-concentration methods. Some separation can be attained by differential grinding and air classification because of the difference in hardness of the two minerals) but the separation is not sharp. Froth flotation of pyrophyllite from Quartz has never been attempted commercially, but if the demand for high-grade material is sufficient, it would seem that this process offers the most premise of being economically feasible.

Jan 1, 1950

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By H. S. Kalman

A table of factors for rapid, accurate calculation of the volume of pure helium in cylindrical steel containers, at base conditions of 14.7 psia and 70° F, is presented. The table covers a pressure range from 10 to 10,000 psin in 10-psi increments and a temperature range of 0° to 120° F in 2° increments. The volume of helium is calculated from the observed pressure and temperature of the helium, expressed as a factor from the table, and the known internal volume of the container. The calculation requires a single multiplication. A discussion and evaluation of the accuracy obtainable and a derivation of the formula used (which takes into account compressibility of helium, thermal expansion of steel containers, and the stretch of steel due to internal pressure) are presented. An example showing how the table can be used is given also.

Jan 1, 1968

By C. W. Davis, M. W. Von Bernewitz, S. C. Lind

During the past few years our possible domestic resources of platinum have attracted much attention . On account of the extensive use of platinum during the World War , and the practical elimination of the Russian supply , the price of this metal rose to new high levels , as shown in Table 1 ; and though it since receded to some extent , the price is now nearly six times that of gold .

Jun 1, 1923

By C. W. Davis

There are four parts to this circular and, respectively, they list firms in the Eastern (pp. 5-8), Southern (pp. 9-10), Central (pp. 11-15) and Western (pp. 16-22) United States and Provinces of Canada. Before listing the laboratories and the work performed there, it is proper to make clear what is done and what is not done by Federal bureaus, States, and Territories, as well as by Canada and Mexico. FEDERAL Bureau of Mines. - The Bureau of Mines does not make assays, analyses, or tests for individuals or firms unless they be incidental to investiga¬tions that are of possible benefit to the entire mineral industry. All significant results obtained in this way are made public through published reports. Any mineral sample sent to this Bureau for simple identification will be subjected to a cursory examination.

Jan 1, 1938

By A. W. Deurbrouck

This Bureau of Mines report describes the washability characteristics of 14 coalbed samples collected in Wyoming. Such data is needed to evaluate the quality of the coals of the West where most of our low-sulfur-content coal reserves are found. Of the 14 samples included in this report 13 had a total sulfur content of 1.1 percent or less. All of the samples contained low per¬centages of ash or could be readily washed to a desirable ash level with minimal loss of yield. The coals ranged in rank from high-volatile B bituminous to subbituminous C, although 10 of the samples were high-volatile C bituminous. The coalbeds varied in thickness from 4.5 to an unknown thickness greater than 67.5 feet.

Jan 1, 1971

By John C. Edwards

Chapman-Jouguet detonation calculations were carried out for pentaerythri-tol tetranitrate (PETN), TNT, and ammonium nitrate-fuel oil (AN-FO) explosives using the compressibility form of an equation of state of hard spheres based upon Percus-Yevick (PY) theory, and a chemical equilibrium detonation code called TIGER. Similar calculations were also carried out with the Becker-Kistiakowsky-Wilson (BKW) equation of state. For PETN, the BKW equation gives somewhat better agreement with experimental values of detonation velocity and pressure. However, in terms of experimental temperatures and concentrations of the minor product species (NO), the predictions of the PY equation are shown to be more satisfactory. Similar comparisons of experimental and theoretical results for TNT and AN-FO indicate that the PY equation has general utility in predicting the detonation properties of condensed explosives at moderate loading densities (Po < 1.3 g/cm3).

Jan 1, 1974

By J. M. Harrington, C. W. Owings

"The transportation of explosives, and especially their distribution from the supply magazines of the manufacturers or dealers to the mines, quarries, or other points where they are to be used, by means of horse-drawn vehicles is an old-time practice, and the records of accidents of the past show this to have been a hazardous undertaking requiring for safety the taking of many precautions not required in the transportation of other merchandise.Displacement of the horse-drawn vehicle by the motor vehicle for the transportation of explosives is increasing rapidly. A consideration of the facts that the vehicle is operated by an explosion engine, using easily vaporized liquid fuel; that the charges in the engine are fired and the vehicle lighted by electricity; and that the vehicle, being operated insulated from the ground, may accumulate static charges led to the conclusion that new hazards are being introduced into the transportation of explosives through the use of motor-operate& vehicles, and that therefore additional special precautions must be taken against these additional hazards.That accidents have already occurred in this use of motor-vehicle transportation is evidenced from the following examples:Recently in California a driver loaded a box of granular powder in the rear of an automobile truck and a box of electric detonators in the front. Suddenly, while traveling along a highway, the explosives detonated, demolished the truck, and blew the body of the driver into small pieces. No evidence was left to show the cause of the explosion, but it is assumed that a jar or other means caused the detonators to fire, and that they in turn detonated the explosive. It should be recognized that it is unsafe to transport detonators and explosives in the same compartment, and this rule should be strictly enforced. At present this rule appears to be either unknown or, at least, frequently ignored.There are usually so many possible causes of ignition or detonation of a truck load of explosives that it is often impossible to state definitely the exact cause in a given case. This is well illustrated in the following account of an accident: A trucking company was hired to haul a truck load of explosives about 200 miles. The driver had had experience in driving trucks of explosives, and it was stated that he inspected the truck carefully before leaving the garage. Eighty 50-pound boxes of explosive were placed in tiers on each side of the truck and 265 25-pound kegs of black blasting powder were placed in the center of the truck. The boxes were placed flat and the kegs were placed on end, arranged in tiers. While the truck was being driven along the highway there was a muffled explosion. When some men, who were about a quarter of a mile away, arrived at the scene the truck was in flames and they could get no nearer than 100 feet. The driver was sitting in his seat and had apparently been killed instantly either by shock or fumes. When the flames were finally quenched, the driver's body was recovered, badly charred. It was, found that several boxes of explosives had been thrown about 40 feet by the initial explosion but were uninjured. A total of half a ton of dynamite was recovered. The cover to the gasoline tank could not be found."

Aug 1, 1930

By D. B. Taliaferro

Information regarding the pores or voids in reservoir rocks is vitally important in the scientific extraction of petroleum from natural underground reservoirs, and petroleum technologists concerned, with subsurface, conditions have devised various methods that give reasonably accurate information as to the porosities of oil and gas-bearing sands.5/ In this, work, several investigators have made use of the experience of the ceramic and other industries. The method of determining the effective porosity of oil sands described in this report falls within the general classification of gas-expansion methods. It was devised and developed at the United States Bureau of Mines Petroleum Experiment Station, Bartlesville, Okla., as a part of the research dealing with fluid and energy relations in reservoirs and improved oil-recovery methods. The apparatus and procedure are well adapted to the requirements of the Bureau, and the following detailed description has been prepared so that others may make use of the information. A tabulation at the end of the report gives the results of several hundred porosity determinations for oil sands in fields of 11 States.

Jan 1, 1937

By D. B. Taliaferro

Information regarding the pores or voids in reservoir rocks is vitally important in the scientific extraction of petroleum from natural underground reservoirs, and petroleum technologists concerned. with subsurface conditions have devised various methods that give reasonably accurate information as to the porosities of oil and gas-bearing sands.5/ In this work, several investigators have made use of the experience of the ceramic and other industries. The method of determining the effective porosity of oil sands described in this report falls within the general classification of gas-expansion methods. It was devised and developed at the United States Bureau of Mines Petroleum Experiment Station, Bartlesville, Okla., as a part of the research dealing with fluid and energy relations in reservoirs and improved oil-recovery methods. The apparatus and procedure are well adapted to the requirements of the Bureau, and the following detailed description has been prepared so that others may make use of the information. A tabulation at the end of the report gives the results of several hundred porosity determinations for oil sands in fields of 11 States.

Jan 1, 1937

By John P. Walsted

Because of the absence of an iron-producing industry, the Pacific Northwest is working under an economic handicap. This is particularly apparent in the gray-iron-foundry industry because of the high price of pig iron imported from foreign sources or shipped in from producing ?areas within the United States. The high prices and sometimes short supply of ferrous metal products has put a brake on industrialization, which has been only partly compensated by the availability of cheap electric power. The economic condition of the gray-iron-foundry industry could be improved by establishing a small iron-producing industry based on the locally available ores. Moreover, establishing a local iron smelter would create a market for resources now dormant. Low-grade ores of manganese, chromium, and nickel would become usable in industry when combined with the iron ore from Scappoose. Pig iron produced in even limited quantities would level out the fluctuation in supply. The ore deposits, being small, would not supply enough pig iron to satisfy the entire demand. This condition necessitates designing special pig irons that will carry abnormally high proportions of scrap in the cupola charge.

Jan 1, 1955

By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By John A. Johnson

The first report of investigations5/ in this series pertaining to the investigation of stemming at the Mount Weather testing adit dealt with dust produced from blasting. The present report discusses the effect of stemming on eases generated by blasting, describes the test procedure, and analyzes the results from, blasting 61 standard rounds. Following care the types of stemming that -,re being investigated: 1, No stemming. 2. Sand in 2 paper cartridges. 3. Clay in 2 paper cartridges. 4. Commercial hydrated lime in 2 paper cartridges. 5. Combustible blasting plugs. 6. Ceramic is blasting plugs with clay in 2 paper cartridges.

Jan 1, 1940

By John A. Johnson

The first report of investigations5/ in this series pertaining to the investigation of stemming at the Mount Weather testing adit dealt with dust produced from blasting. The present report discussed the effect of stemming on eases generated by blasting, describes the test procedure, and analyzes the results from, blasting 61 standard rounds. Following care the types of stemming that are being investigated: 1, No stemming. 2. Sand in 2 paper cartridges. Clay in 2 paper cartridges. Commercial hydrated lira in 2 paper cartridges. 5. Combustible blasting plugs. 6. Ceramic is blasting plugs with clay in 2 paper cartridges.

Jan 1, 1940

By J. A. Woolf, E. S. Leaver, A. P. Towne

"INTRODUCTION A report giving experiments dealing with factors affecting the floatation of the most commonly occurring silver minerals was published years ago. At that time we could not obtain suitable samples of many of the so-called sulfo-salts of the base metals, which are generally silver--bearing and which comprise an appreciable percentage of the natural silver ores. Since Leaver and Woolf's work was published, samples of impure tennantite and enargite have been obtained, and considerable experimental flotation work has been done with synthetic mixtures prepared from these samples. During the present national emergency, research dealing solely with the recovery of gold and silver must necessarily be curtailed. However, many deposits of strategic minerals and critical base metals contain an appreciable amount of gold and silver, the recovery of which would aid greatly in recovering the strategies by taking care of a considerable part of the cost of treatment. Because of this, the recovery of precious metals should not be overlooked entirely. As the Bureau of Mines is now utilizing all of its facilities for the development of increased domestic productions of strategic and critical minerals, this is the last report not concerned primarily with such minerals that will be published until the war ends."

Sep 1, 1942

By Raymond W. Hiteshue

Experiments were conducted al temperatures of 480° to 800° C. and hydrogen pressure of 6,000 p.s.i.g. to determine the effect of coal residence time on the conversion of a high-volatile bituminous C coal to liquid and gaseous products when using a semicontinuous apparatus designed fur rapid heating and cooling of reactants. The objective of the studies at high temperatures was to determine if appreciable quantities of coal could be converted to gaseous hydrocarbons and low-boiling liquid hydrocarbons. Experiments at lower temperatures were designed to indicate shifts in product distribution with respect to temperature and to learn more about the general mechanism of the reaction when using close control of coal residence time. One percent molybdenum, based on m.a.f. (moisture-and ash-free) coal, was used throughout this investigation. At 800° C., 6,000 p.s.i.g., and "zero" residence time) the yield of gaseous hydrocarbons was about 38 percent and the yield of oil about 4.5 percent, based on m.a.f. coal. With IS minutes residence time, under the same conditions, the yield of gaseous hydrocarbons was approximately 80 percent with no increase in yield of oil. Apparently at 800° C., and hydrogen pressure of 6,000 p.s.i.g. coal was rapidly carbonized to char with expulsion of volatiles. Char was then slowly hydrogenated to gaseous hydrocarbons without production of oil.

Jan 1, 1962

By John W. Cole

The Bureau of Mines conducted a trenching and sampling project during 1947 on the tungsten-rich granodiorite that outcrops in Henderson Gulch, Montana. During the course of this investigation, interest was attracted to the Sunrise copper-gold mine in metamorphosed limestone in the north slope of the gulch. The mine was examined by S. H. Lorain, Chief, Mining Division, Albany Branch, in May 1948. A trenching and drilling program was recommended to develop a parallel vein indicated by outcrops to lie below the principal productive Queen vein. In the meantime, the Queen Mining Syndicate initiated a trenching program that exposed high-grade lead-copper-silver-gold ore in a nearly vertical vein that strikes N. 600 E. to east. A core-drilling program to develop this vein was initiated in September 1948. This report presents the factual data obtained from the trenching and drilling operations. The Sunrise mine was discovered about 1890. Production has been estimated to be $120,000 in gold from 40,000 tons of ore mined during the period 1892-1903. The tailing from this operation was treated by cyanidation in 1912, with a reported recovery of $3.50 to $4.00 a ton from 15,000 tons of material. Subsequent production of sulfide ore was 7,396 tons treated by smelting, with recovery of 1,569.42 ounces of gold, 10,003 ounces of silver, 352,899 pounds of copper, and 354 pounds of lead.

Jan 1, 1950

By Alan G. Mayton

Exposure to whole-body vibration (WBV) and the postural requirements of the job have been identified as important risk factors in the development of musculoskeletal disorders of the back among workers exposed to a vibratory environment. This paper focuses on preliminary results of WBV data collected for two groups of haulage trucks ? four older trucks from manufacturer A (MFR-A) and two newer trucks from manufacturer B (MFR-B). All of the trucks and their respective seats were considered to be in good working order during the study. Measurement periods for the truck groups had similarities, but varied from 2 to 58 minutes. Sampling times for the older trucks included a mean of 19.5 minutes and a standard deviation (STD) of 6.5 minutes compared to a mean of 40.8 minutes and a STD of 12.1 minutes for the newer trucks. Data collection coincided with the approximate delivery and first operation of the new trucks, and occurred approximately 12 months apart under similar weather and road conditions, and with the same drivers except an additional driver was included with the older trucks. Truck routes were somewhat different in that quarry production had changed location in the time between data collection activities. Overall, the results suggest that the newer trucks may provide better overall isolation to drivers/operators from WBV exposure compared to the older trucks operating at the quarry; although, this will need to be confirmed with additional measurements. Considering the higher variability and shorter sampling times for the older trucks, the results should be viewed with caution. For two of seven trials, the older trucks showed that seats amplified vibration, i.e., a transmissibility (T) >1.0. Seat T for the older trucks ranged from 0.31 to 1.17 with a mean of 0.77 and STD of 0.32. This contrasted with the newer haulage trucks where seats amplified vibration in 3 of 8 trials. In this case, T did not vary greatly and ranged from 0.87 to 1.05 with a mean of 0.97 and STD of 0.07. Regarding older trucks, in five of seven trials, the seat (output) data of weighted root-mean square (RMS) acceleration (wRMSZ) for the dominant z-axis exceeded the action level of 0.5 m/s2 action level recommended by the European Union Good Practice Guide for WBV (EUGPG) and levels exceeded the recommended exposure limit of 1.15 m/s2 in two of the seven trials. The wRMSZ values for the older trucks varied from 0.41 to 1.83 m/s2 with a mean of 0.99 and STD of 0.57. Similarly, newer trucks indicated a narrower range of wRMSZ from 0.38 to 0.95 m/s2. The mean wRMSZ was lower for the newer trucks at 0.58 m/s2 with a STD of 0.23 m/s2. Similarly, newer trucks indicated wRMSZ reached or exceeded the action level in four of eight trials. None of the trials with the new trucks showed wRMSZ levels that reached or exceeded the recommended 1.15 m/s2 exposure limit. As an indicator of driver/operator discomfort, overall weighted total RMS acceleration (vector sum) values seem to show a ?rougher? ride for the older trucks. The vector sum values for these trucks ranged widely from 0.70 to 2.59 m/s2 and, in four of seven trials, showed levels greater than 1.40 m/s2. The mean vector sum was 1.44 m/s2 with a STD of 0.75 m/s2. Comparatively, the newer trucks exhibited less variation with a range from 0.69 to 1.59 m/s2. The mean vector sum was 1.02 m/s2 with a STD of 0.35 m/s2. Vibration dose values for the dominant z-axis (VDVZ), gave a sense of vehicle jarring/jolting conditions. All trials with the older trucks were within the recommended EUGPG action level of 9.1 m/s1.75. On the other hand, in three of eight trials, both newer trucks exceeded this action level with values of 9.18, 12.58, and 13.21 m/s1.75. Neither truck group showed VDVZ that exceeded the exposure limit of 21 m/s1.75. A statistical analysis was not conducted, since the differences reported between truck groups may not be statistically significant owing to the relatively small sample size. Road conditions, changes in the truck routes, and driver/operator differences (e.g., stopping and turning) are possible factors in the higher VDV for the newer trucks.

Jan 1, 2008