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By R. Barany

This report contains the results of experimental work conducted by the Bureau of Mines to obtain the heats of formation at 298.15° K. of analcite, dehydrated analcite, lawsonite, anorthite, hexagonal anorthite, and leonhardite. Thermodynamic data for these minerals have applications in ceramics, extractive metallurgy, and particularly in geochemistry. Except for data on anorthite, no previous similar data existed. The present results will be a substantial aid in deriving the temperature-pressure-equilibrium relationships among these minerals. The heats of formation were determined by solution calorimetry, with hydrofluoric acid as the reaction medium. The results were expressed both in terms of the constituent oxides and in terms of the constituent elements. The heat of formation data were combined with related entropy values to obtain the free energies of formation at 298.15° K.

Jan 1, 1962

By Carl Sunderman, Steve Signer

Researchers at the National Institute for Occupational Safety and Health (NIOSH) have developed several new tools for evaluating roof support performance. A miniature data acquisition system (MIDAS) was developed that can collect readings from up to 16 strain gauges at regular time intervals and store the readings for later retrieval. Three LED lights change from green to yellow, then red, based on the reading levels and/or rates of change of rock movement. This feature can be used to warn miners of rock instabilities. The system can be used with any strain-gauged support (resin bolt, friction bolt, cable bolt) or with a newly developed rock strain strip (ROSS) developed by NIOSH to measure rock strain. A ROSS is grouted in a hole drilled adjacent to the rock support to be evaluated; the deformed shape of the ROSS provides anchorage on either side of the strain gauges. Data from both laboratory tests and field evaluations are presented that describe the capabilities of both the MIDAS and ROSS instruments.

By N. F. Le] [Jaune

[ ]

Jan 1, 1923

By George J. Conroy

Types and causes of short-circuit and open-circuit faults in mine portable trailing cables are discussed, and techniques for locating these faults are described. Time domain reflectometers (TDR) , tone generator, infrared sensing, and high voltage methods are covered. The paper summarizes Bureau of Mines research, including development of a ~DR/tone generator sender with auxiliary probe.

Jan 1, 1975

By Martin H. Rogoff

This publication combines a critical review of the literature on the microbiology of coal with an introduction to those areas of microbiology related to studies of coal as a biological material. The attack on coal by microorganisms as yet remains doubtful. Only the low-rank coals contain an indigenous microbial flora, and even these organisms are not peculiar to coal, but are common soil and water forms. No experimental data have as yet been presented, either in the literature or in the present work, which unequivocally demonstrate the oxidation of coal by microorganisms. Reasons for the resistance of coal to such attack, including insolubility, physicochemical structure, steric hindrance of enzyme action, and the presence of antibiotic materials in coal are discussed. Microorganisms do attack large aromatic molecules and the mode of oxidation of aromatic ring systems by bacteria is presented. Well-defined pathways are known for the oxidation of polycyclic compounds with one to three rings, and these paths with their key intermediates are described and related to the possible oxidation of coal.

Jan 1, 1962

By Andrew B. Cecala

The Bureau of Mines conducted laboratory and in-mine tests on the Racal airstream helmet (Model #AR21) to evaluate its protection efficiency. Laboratory tests indicated that as ambient air velocity increased, the protection offered by the helmet decreased. In tests conducted at several coal mine long-wall sections with face velocities under 400 fpm, the helmet was 84 pct effective at reducing respirable dust in the miner's breathing zone. However, at a high-velocity section, 1,200 fpm, the efficiency of the helmet was significantly reduced, confirming our laboratory results.

Jan 1, 1981

By K. J. Liles

Research was undertaken by the Bureau of Mines to determine the technical feasibility of producing lightweight aggregate from the waste glass fraction of municipal incinerator residues. Tests were conducted to determine the amount and optimum size of glass, the amount of sodium silicate, and the method used to form the material to be expanded. The most suitable mixture, 78 percent glass, 20 percent clay, and 2 percent sodium silicate, was pelletized and then expanded by exposure to a temperature of 1,550° F for 15 minutes The resulting lightweight material had a bulk density of 38 lb/cu ft and exhibited excellent pore structure. Concrete test cylinders made from the light weight aggregate had a unit weight of 104 lb/cu ft and a compressive strength of 2,550 lb/sq in after a 28-day steam cure.

Jan 1, 1976

By C. W. Owings, J. J. Forbes

"INTRODUCTION The recent coal-dust explosions in Illinois and Indiana have again brought forcibly to the attention of mining men the fact that mines which liberate little or no methane can have widespread explosions, if dry and dusty conditions exist and if adequate measures are not taken to control the dust hazard by rock dust¬ing or use of water.Even though rock dust has been used more or less extensively for more than 20 years as a means of limiting or preventing coal-mine explosions, many mine operators have requested information on rock dusting and means of allaying coal dust at its source. The purpose of this circular is to summarize available information on these two methods.COAL MINES TO BE ROCK-DUSTEDAll nonanthracite coal mines must be rock-dusted, except those mines or locations in a mine that are too wet or too high in incombustible content to propagate an explosion.Coal dust that contains 20 percent or more moisture may prevent ignition or propagation of an explosion. Such dust can be molded in the hands, and under such condition the roadway would be considered muddy. Mine dust that is only damp is not wet enough to prevent propagation of an explosion. Beads of water standing on accumulations of dust are not indications that the dust is wet. Only those mines or locations in a mine in which the coal dust can be molded in the hand need not be rock-dusted."

Jun 1, 1947

By Fred N. Kissell

In This Chapter [Instruments available to measure methane in mines and tunnels Using a portable detector in both accessible and restricted spaces Machine-mounted monitors: placement and response time Calibration of catalytic detectors for different gases and Misinterpreting warning signs This chapter gives guidelines for methane measurement in mines and tunnels. The emphasis is on the measurement procedure and the interpretation of the measurement rather than on the instrument itself.] The failure to properly sample for methane is a major contributing factor to methane explosion risk. Sampling errors are most likely to occur at mines or tunnels where the presence of methane is not suspected or during nonroutine tasks at mines or tunnels known to have gas. More specific information on methane sampling at continuous miner sections is in Chapter 3. Chapters 4 and 5 discuss sampling at longwall sections, and Chapter 14 discusses sampling at tunnels. METHANE DETECTORS FOR MINING Many models of gas detectors are available to measure methane concentrations, as well as most of the other contaminant gases found in mines and tunnels. An example is the iTX Multi-Gas Monitor, a portable gas detector available from Industrial Scientific Corp., Oakdale, PA. This handheld instrument measures several gases simultaneously. The cost (2004) ranges from $1,300 to $2,200, depending on the number of gases measured. Similar instruments are available from other manufacturers. Most methane detectors used in mining use a catalytic heat of combustion sensor to detect methane and other combustible gases. These have been proven through many years of reliable operation. For detection of methane, proper operation of catalytic heat of combustion sensors

Jan 6, 2006

By T. F. Anstett

The Bureau of Mines estimated the potential availability of tungsten from 57 mines and deposits in 19 market economy countries. The tungsten resources of China and the U.S.S.R. were also estimated. This resulted from an evaluation of tonnage-cost relationships indicating the quantity of tungsten available as ammonium paratungstate (APT), artificial and natural scheelite, and ferrotungsten at various average total costs of production including 0- and 15-pct rates of return on invested capital. The evaluated deposits contain 1.2 million metric tons (t) of recoverable WO3, of which approximately 52,000 t of AEYT can be produced at the January 1983 market price of $5.37/lb, 89,000 t of natural and artificial scheelite at a market price of $3.63/lb, and 1,700 t of ferrotungsten at $5.61/lb of tungsten. An annual availability analysis indicates that by the early 1990's new deposit discoveries, development of known prospects, or expansions of producing mines will be necessary to meet projected tungsten demand.

Jan 1, 1985

By Ernest J. Conway

This report presents engineering drawings for six material handling devices for underground coal mines. The devices were designed under a U.S. Bureau of Mines program to reduce injuries from material handling during mine and equipment maintenance. The six devices are (1) scoop-mounted 1411: boom, (2) swing-arm boom, (3) heavy-component lift-transport, (4) mine mud cart, (5) container-workstation vehicle, and (6) timber car. Each device is described briefly, and recommendations are made concerning the design of new devices.

Jan 1, 1989

By Henry Kreisinger, F. K. Ovrız

Some of the investigations conducted by the Bureau of Mines have for their object the collecting and disseminating of information regard- ing methods by which the fuels of the country may be most effi- ciently used. As the analysis of flue gases tends to develop better methods of firing, which in turn reduces waste of fuel, the Bureau of Mines in this bulletin presents for the benefit of those in charge of boiler plants and all other persons interested detailed information on methods of sampling and analyzing flue gases, and on the utilization of the analyses in promoting boiler-room economy. This bulletin is intended to be a companion to Technical Paper 80," and is written in plain and nontechnical language, as far as pos- sible, so that it may be readily understood by persons who have not had the advantage of a technical education. Whenever possible, illustrations of apparatus and methods of handling have been used rather than elaborate descriptions. The material presented in this report is arranged in two parts. The first part contains the description of the apparatus and the methods used in sampling and analyzing flue gases. The second part gives experimental results obtained with the different methods of sampling and collecting flue gas that are recommended in the first part of the report. Only simple apparatus and methods are considered, as they are accurate enough to show the large heat losses due to the use of too much air, and are also accurate enough to indicate any incomplete combustion losses of economic importance. Without doubt the loss due to large excess of air is the greatest one in the boiler room, and can usually be greatly reduced by making proper use of gas analysis. Before engineers in the isolated industrial plants can be induced to analyze for small traces of combustible gases, they must be first taught how to analyze for carbon dioxide (CO), and they must learn to appre- ciate the great possibilities of reducing loss from large excess of air. Furthermore, in the face of the great difficulty of obtaining a fair

Jan 1, 1915

By R. S. Norman

The objective of this program was to select approximately 100 acoustic materials for flammability evaluation. Noise control programs have been initiated on several types of mining equipment and vehicles which can be used in underground coal mines. Often, the materials which are used in these noise reduction programs have not been tested for flammability properties according to the same reference standard. During this program a variety of materials were selected for measurement according to ASTM E-162 procedures. A radiant heat energy source was used to measure flammability properties of 15.2 x 45.7 cm. samples. In the absorptive materials category, 45 percent of the materials tested had a flame spread index of less than 25. For barrier, damping, and isolation materials the corresponding values were 40, 43, and 9 percent.

Jan 1, 1979

By Paul E. Loustaunau

This report describes a project in which three structured underground coal mine equipment operator training programs were developed. The project was carried out in two parts. In the first part, a research study was conducted to determine how on-the-job training is currently conducted in industry, and to determine the overall effectiveness of current on-the-job training. In addition, the possible application of the principles of social learning theory to on-the-job training was investigated. In the second part three prototypes on-the-job training programs were developed for shuttle car operation, roof bolter operation, and continuous miner operation. These programs were carefully structured to eliminate the shortcomings of current industrial on-the-job training identified in the research study and incorporated the application of relevant principles of social learning theory. The programs are prototypes which underground coal mine training personnel can use as models to develop their own customized equipment operator training programs.

Jan 1, 1983

By Joan T. May

Federal Bureau of Mines studies showed that some organic amine hydrochlorides can be used as dehydrating agents for producing anhydrous magnesium chloride from hydrates and brines. Laboratory-scale tests showed that double salts are formed by reacting 35 percent magnesium chloride brine or spray-dried magnesium chloride with pyridine hydrochloride. Heating decomposed these double salts to anhydrous magnesium chloride and recycle pyridine hydrochloride. Pyridine hydrochloride also chlorinated any magnesium oxide in the spray-dried magnesium chloride. The anhydrous magnesium chloride obtained by the method described contained less than 0.8 percent oxygen. More than 98 percent of the organic amine hydrochloride was recovered.

Jan 1, 1978

By James D. Eklund

Towards the goal of improving safety, economy and efficiency of scaling in underground metal/nonmetal mines, Battelle developed a combination prying/hammering scaling tool. A prototype was subjected to limited testing 1) to verify its operational functions and 2) to assess its potential capability in future underground testing.

Jan 1, 1983

By Laird Crocker

A goal of the Federal Bureau of Mines is to minimize the undersirable environmental conflicts and impacts associated with mineral processing operations. To help reach this goal the Bureau operated a citrate-process pilot plant for the removal of sulfur dioxide from lead smelter sintering machine waste gases to test the process. The process uses a carboxylate solution such as citric acid to absorb sulfur dioxide from waste gases. The absorbed sulfur dioxide is subsequently reacted with hydrogen sulfide to precipitate sulfur and regenerate the solution for recycle. Nominal capacity of the pilot plant was 1,000 scfm of 0.5 vol-pct sulfur dioxide gas. The pilot plant was operated for over 5,400 hr and produced about 55 net tons of sulfur. The operation demonstrated that (1) 99 pct of the sulfur dioxide could be removed from lead smelter sintering machining waste gases containing from 0.1 to 0.6 vol-pct sulfur dioxide, (2) sulfur precipitation and solution regeneration with hydrogen sulfide in conventional stirred vessels was readily controlled, (3) precipitated sulfur could be continuously recovered as a 99.S-pct-pure product by flotation and melting, and (4) 78 dry-vol-pct hydrogen sulfide gas could be produced from pilot-plant product sulfur, natural gas, and steam.

Jan 1, 1979

By I. Liebman

The Bureau of Mines conducted experiments on coal dust explosion suppression. The investigation took place on a beltway in the double-entry of the Bureau's Experimental Mine. Using conditions that simulate those in a working mine, the investigation showed that a coal dust explosion can be readily initiated in a conveyor belt entry. Also, the explosion can spread into adjacent entries through opened crosscuts (stopping destroyed by explosion) to propagate for long distances even though the adjacent entries are rock dusted in compliance with regulations. Passive water barriers (water-filled tubs) were found to be effective in suppressing explosions on a beltway; however, barrier efficiency was reduced by opened crosscuts. The study indicated that the beltway barrier should be the distributed type consisting of continuous rows of water-filled tubs covering long distances along the entry. A plan is outlined for the installation of a water barrier system in a working coal mine for the protection of a beltway.

Jan 1, 1981

By G. L. Oldright, J. D. Sullivan, W. E. Keck

"An apparatus and procedure developed in the laboratory of the South-west Experiment Station of the Bureau of Mines are capable not only of determining the rate and volume of penetration of solutions into porous materials but also of determining the total volume of voids within particles of porous material, and the density. The method is applicable to ores, bricks, concretes, tiles, filter bottoms, or other porous materials of this nature. As will be made clear in the descriptive matter to follow, the method measures (a) the volume of voids within the porous materials and is not concerned with the interstitial space between the particles.Porous materials usually contain some large voids and also pores that are capillary in nature. To measure the total volume of voids in a sample it is necessary to replace the gas or gases within the voids with some liquid of known density. The large cavities can be filled quite readily, but under ordinary conditions a long time may be required to fill capillary pores. As many porous materials are of a decomposable nature it is necessary to evacuate the porous materials and then submerge them in a liquid of known density to bring about saturation in a short time. Then by the use of a hydrostatic balance the volume of porous material (solid itself) can be determined. To determine the volume of porous material plus voids it is necessary to coat the sample with some material, such s paraffin, which will prevent solution from entering the voids; then, by means of a hydrostatic balance, the volume of porous material plus voids is determined and by subtracting that of the porous material from this the volume of voids is ascertained. The rate of penetration of solutions can be determined either (a) by measuring the change in weight as the sample becomes saturated when immersed ni a liquid of know density, or (b) by measuring the volume of liquid penetrating with a dilatometer. In either instance, due to the fact that some penetration takes place as soon as the sample comes in contact with solution and before a reading can be taken, the sample must be paraffined to determine the total volume of penetration. Since many porous materials partly decompose and disintegrate in liquids the rate and volume of penetration can better be measured by dilatometer than by the change in weight, as saturation takes place when immersed in a liquid. The details of procedure for determining (a) total volume of voids, and (b) rate and volume of penetration are given in this paper."

Oct 1, 1930

By John C. Cook

This was a study to identify and evaluate known technologies employing electromagnetic resonance phenomena in solid minerals for their identification and assaying, particularly assay logging of exploratory boreholes. A comprehensive literature search and study revealed some little known NMR (nuclear magnetic resonance) techniques developed by Professor G. J. Béné's group at the University of Geneva, Switzerland. These are suitable for use in weak, inhomogeneous magnetic fields. Laboratory NMR tests of numerous U.S. ore minerals showed good identifying signals from phosphates, fluorspar, bauxite, oil shale, and spodumene (lithium) ores, but not from the copper, lead, antimony or manganese ores tested. Use of EPR "signatures" for such ores is suggested. A conceptual design for an NMR assay logging system is proposed.

Jan 1, 1978