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By H. L. Bibbs, H. D. Snedden

"INTRODUCTION The use of beryllium and its alloys has increased rapidly during the last decade. Further expansion of its use is limited; in part, by lack of adequately developed ore reserves. The principal commercial beryllium mineral is beryl, which is found chiefly in pegmatites and produced for market as a byproduct of the mica and feldspar industries. The coarse beryl is mined selectively, sobbed and sorted by hand, and then sold without further beneficiation. The known reserves of coarse beryl are small. No method has been available for concentrating small disseminated beryl crystals, so ores of this type have not been mined or have been left on waste dumps. Disseminated ore in low-grade unmined areas and waste dumps on developed properties is a potential source of beryl, provided a method is developed for its beneficiation.Published literature on the concentration of beryl is lacking in detail or deals chiefly with tests on artificial mixtures of pure minerals, and procedures as given were not applicable to the beryl ores tested at the Salt Lake Station. The testing procedures described in this report are independent developments. By employing these procedures, beryl was satisfactorily con¬centrated from several run-of-mine and dump ores, although these ores wore low in grade and part of the contained beryl was finely crystalline and disseminated.Beryl, quartz, and feldspar, when ground to flotation sizes, are so alike in color and general appearance that they cannot he distinguished by visual observation. The progress of the work depended on rapid determination of the grade of test products by means of the petrographic microscope. Small samples of concentrates and tailings were often cut after each addition of reagents, dried, and examined under the microscope."

May 1, 1947

By Martin H. Rogoff

The presence of antibiotic materials extractable with polar organic solvents was demonstrated in coals of various ranks. Since these antibiotics occur in low concentrations, 200 pounds of a high-volatile C coal was extracted with acetone at room temperature to obtain sufficient material for detailed study. The biologically active materials in the extract were concentrated by extracting with aqueous sodium hydroxide. The fractions soluble in sodium hydroxide inhibited bacterial cultures when present in concentrations comparable to those at which other antibiotics are active (5 µg/ml). Steam distillation of the extracts did not yield highly active materials, contrary to the finds of other investigators. Mass spectrometry of the extract indicated, mainly, the presence of 6-ring compounds in the region of mass 324 to 392. The predominance of 3-ring aromatic systems found by ultraviolet analysis suggests compounds such as biphenanthryl or similar structures. The activity of the hydroxide- soluble material decreased markedly when the phenolic hydroxyl groups were transformed into trimethylsilyl ethers. Hydrolysis of the ethers yielded a product having the same activity as the original material, which indicates that phenolic compounds are largely responsible for the antibiotic activity observed.

Jan 1, 1963

By J. S. Dunning

The objective of this research by the U.S. Bureau of Mines was to determine the effects of AI additions on the sulfidation resistance of Fe-Cr-Ni alloys. A series of Fe-Cr-Ni alloys with and without -additions of 4 pet AI were tested in a wet S vapor atmosphere at 677 C. A study of the morphology and composition of corrosion scales indicated a different corrosion mechanism for AI-free alloys compared with AI-containing alloys. Aluminum-containing alloys formed a compact, tightly adherent layer at the metal-scale interface that reduced corrosion rates by a factor of 3 to 10 compared with that of AI-free alloys. The thin, adherent AI-containing scale limited inward diffusion of 0 and S to the base metal and outward diffusion of Ni from the base metal. Aluminum-containing alloys formed a three-layer scale in oxidizing-S environments, while AI-free alloys formed a less protective two-layer scale.

Jan 1, 1989

By Hon-Yim Ko

1972 constituted the second year of the projected five-year study on constitutive relations of coal. The schedule adhered closely to the five-year outline which is summarized in Table 1. This chapter is intended to serve as introduction and concise synopsis of the year's activities and results, which are presented in greater detail in the following chapters, which have been contributed by the individual researchers in charge of the various aspects of the project under study. Coal Sources, Material Procurement, and Sample Preparation Most of the studies performed during 1972 were done on coal from two sources: the Old Ben Mine #22 in Illinois, and the Bruceton Mine in the Pittsburgh seam of Pennsylvania, which may be considered typical of coal sources of economic importance in the Midwestern and Eastern part of the U.S. These two mines have proven to be reliable suppliers of coal material for our research. We have been able to establish good working relations with their personnel and feel that we can continue to count on their cooperation and help.

Jan 1, 1972

By William L. Crentz

Floyd County, KY., contains sizable deposits of high volatile bituminous coal. Some of the coals have been blended with higher-rank coals and used in the manufacture of high-quality metallurgical coke. The Upper Elkhorn No. 3, Upper Elkhorn No. 2, and Upper Elkhorn No. 1 beds produce the bulk of the present output in the county and contain the main known reserves of coal. Little information is available concerning the quality and extent of the deposits underlying the Upper Elkhorn No. 1 bed, although small operations in the past have worked a bed that is reported to be; the Lower Elkhorn. Undoubtedly, these lower beds occur in Floyd County, but depth Will preclude their development into a major source of fuel as long as large deposits of more-accessible coal are available. More is known of the occurrence of the beds above the Upper Elkhorn No. 3 owing to sporadic mining ventures in the upper measures. Many of the coal samples from beds above the Upper Elkhown No. 3. were collected in mines that had been abandoned. Almost all of the present production of Floyd County coal is taken from the Upper Elkhorn beds, and it is unlikely that their dominant position as coal producers will be challenged in the near future. Table 1 shows the coal production of the county by beds, during 1950.

Jan 1, 1952

Consumption and intensity of use trends for twelve metals, by industrial end use, were estimated for 1972 through 198Z. The trends were then forecast through 1993 using standard statistical methods. The intensity of use measure selected is the quantity of metal consumed per constant dollar output of a specific industrial sector. The metals studied were aluminum, chromium, cobalt, copper, lead, manganese, nickel, the platinum-group metals, tin, titanium, tungsten, and zinc. Average annual growth rates for the following four of the twelve metal increased from 1972-82 as follows: aluminum, 1.00 percent; platinum-group metals (consisting of platinum, palladium, and iridium), 8.83 percent; titanium, 7.82 percent; and tungsten, 6.09 percent. Consumption. for the remaining eight metals decreased at average annual rates ranging from 0.58 percent (copper) to 5.37 percent (manganese).

Jan 1, 1986

By George A. Bell

This paper reviewing the leaching practice of the New Cornelia mines of the Calumet & Arizona Mining Co. at Ajo, Ariz., is the first of a series being prepared by the Bureau of Mines on leaching methods and costs in the various mining districts. ACKNOWLEDGMENTS The author acknowledges the assistance of T. G. Chapman, consulting engineer, and E. D. Gardner, supervising engineer of the Southwest Experiment Station, Bureau of Mines, Tucson, Ariz.

Jan 1, 1930

By Hillary W. St. Clair

The purpose of this investigation was to determine the practicability of refining crude aluminum-silicon alloy or aluminum scrap containing silicon and iron by selective dissolution in zinc of the aluminum from the alloy followed by distillation of the zinc from the aluminum.

Jan 1, 1949

By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 1,070 Bcf as of January 1, 1985. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 280 Bcf, (2) helium in probable natural gas resources, estimated at 243 Bcf, (3) helium in possible natural gas resources, estimated to be 287 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 260 Bcf. These helium resources are further divided into depleting, non-depleting, and stored classifications. The depleting resources are those associated with natural gasfields that are, or will be, produced for the natural gas they contain. Almost all of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 900 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gasfields, are estimated to total 133 Bcf. There is 37 Bcf of helium in storage in the Federal Government-owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1987

By Charles Sabine

The 27,960-acre Newberry Mountains Wilderness Study Area (WSA) is located in the Mojave Desert, 17 miles east-southeast of Barstow. In 1983, the U.S. Bureau of Mines, in conjunction with the U.S. Geological Survey, investigated mineral resources of the area as part of the wilderness review process. The Newberry Mountains are underlain by Paleozoic metamorphic rocks, Mesozoic plutonic rocks, and Tertiary volcanic rocks. Eleven mines and prospects were examined. Of the seven sites within the WSA, only the Northrup Prospect is mineralized. Only a few tons of manganese-bearing rock, containing 49% manganese oxide (MnO), are exposed, but exploration may disclose larger deposits. The Azucar Mine, a past producer of gold, is the only site examined outside the area that appears mineralized. Sample data from quartz veins exposed at the surface do not indicate that resources are present; however, the occurrence could not be fully evaluated because underground workings were not accessible. Sand, gravel, and stone are plentiful in the WSA, but alternate sources outside the WSA are available.

Jan 1, 1985

By G. W. Grove

Coal-mine officials and those who are preparing to become officials should be familiar with the instruments and devices that are employed rather commonly in and around mines and should know how to use them with safety and efficiency. Among these axe instruments and devices used in determining the pressure, velocity, volume, and certain other conditions of ventilation and in detecting the more common mine gases, such as methane, carbon monoxide, and hydrogen sulphide, or a deficiency of that very important agent, oxygen. Water gages, anemometers, barometers, psychrometers, flame safety lamps, lamp-testing boxes, and methane, carbon monoxide, and hydrogen sulphide detectors are described and their use and operation discussed in this paper.

Jan 1, 1938

By T. F. Dumm, L. G. Austin

"INTRODUCTIONGomez and Austin (1,2) have recently described calibration procedures for quantitative chemical analysis of particles by energy dispersive spectroscopy using particles mounted and polished in a resin matrix and scanned by an SEM under computer control. Their software is specifically designed for the analysis of Si, Al, Ca, Na, K, Fe and S in coal particles, and in this case the resin is loaded with iodine (3) to enable the exposed cross-section of an embedded coal particle to be differentiated from the matrix. However, the basic ideas of their procedures could be extended to any system of particles where it is desired to measure inorganic species in particles containing light elements such 0, C, H and N which are not directly detected. In these circumstances it is necessary to perform a quantitative determination of the measured components, so that the equivalent volume of light elements in the excited sample volume can be estimated by difference using ZAF and other corrections applied to the raw count intensities.Part of their procedure involves a new technique (2) for estimating background spectrum intensities; the intensity for a particular energy window is then subtracted from the total measured intensity for that window to enable the concentration of the corresponding element to be calculated. In addition, corrections for overlap of peak spectrums are applied. For example, Figure 1 shows some typical spectrums for known materials for the system they used, demonstrating a wide Gaussian spread about the theoretical peak energy. Since background spectrum and peak overlap corrections require a knowledge of the composition of the material, as does the application of the ZAF corrections, it is necessary to have an iterative solution of the equation sets, starting with estimates of the composition based on initial count rate corrected solely for dead time and detector efficiency."

Jan 1, 1989

By J. K. Whyatt

Researchers at the U.S. Bureau of Mines have been exploring recent advances in the use of strain-softening constitutive laws that approximate shear fracturing. The purpose of these tests is to investigate shear-fracture-related rock bursts in hard-rock mines. The capabilities and remaining problems in the use of strain-softening laws in finite-element, distinct-element, and finite-difference methods are reviewed. Performance of the finite-difference implementation of strain softening is compared to classic experimental results and observations of rock mass behavior in the Coeur d'Alene Mining District of northern Idaho. The results show promise for developing methods to identify the general location and orientation of shear fractures and their sequence of occurrence, but such methods cannot be relied upon to quantify post-fracture loads or displacements accurately. Uncertainty over the amount of energy consumed by failing rock and the dependency of energy consumption on model mesh definition prevent direct application of the results to analyses of rock bursts.

Jan 1, 2010

By William L. Crentz

This study of the preparation characteristics of the coals in Indiana County, Pa., is the second in a series of Bureau publications appraising the Nation's coking-coal reserves by counties and the practicability of upgrading marginal deposits to metallurgical standards. The first publication dealt with the preparation characteristics of the principal coal beds in Cambria County, Pa. Over 95 percent of the coal remaining in Indiana County is in the Upper Freeport, Lower Freeport, and Lower Kittanning beds. Isolated patches of Pittsburgh-bed coal are present, and the Upper Kittanning bed is found in minable thickness at some locations, but production from these sources is not large. The greatest production is from the Freeport beds, which account for nearly 70 percent of the Indiana County coal output. These beds usually contain two or more shale or hone partings and in many places are high in sulfur. The large proportion of bony coal in the Freeport beds 'produces a relatively high-ash product. Mining practices vary from place to place, but it is frequently necessary to leave certain bony portions of the bed in place in order to load a satisfactory product. Table 1 shows the county's coal production, by beds, during 1948.

Jan 1, 1951

By David Oyler, Craig Compton

The The National Institute for Occupational Safety and Health (NIOSH) Pittsburgh Research Laboratory (PRL) is continuing to investigate the behavior of fully grouted roof bolts in the weak roof rock of the Safety Research Coal Mine (SRCM). This paper describes the results of three studies: • A series of 24 pull tests of bolts installed fully grouted and overcored to leave 12 inches of grouted bolt. The tests compared the pull-out performance of offset-head roof bolts with that of standard 5/8-inch bolts; • A second series of 24 tests that compared the pull-out loads obtained by bolts installed with 1 ft of resin (a Short Encapsulation Pull Test or SEPT) to that of fully grouted bolts overcored to leave only 12 inches of grouted bolt, and; • An investigation into the pressures generated during the installation of fully grouted resin bolts. All of the bolts installed and pulled were overcored and removed from the roof after the pull tests to allow inspection of the resin. The first study found that there was no significant difference in pullout load between the offset-head bolts and the standard bolts. The second study, comparing the SEPT bolts and the partially-overcored fully grouted bolts, indicated that SEPT can significantly underestimate bolt anchorage grip factor, suggesting that the SEPT is a conservative measure of actual bolt performance. Significant loss of resin to cracks in the roof was observed in the bolts overcored in the SRCM. The third study explored one possible explanation for the resin loss, high pressures generated during bolt installation. These tests employed bolts installed in strain gauged steel tubes. The results confirmed that significant pressures (greater than 4,000 psi) can be generated during bolt installation. The results of the pressure tests, combined with the observations of resin loss in bolts installed in the SRCM, suggest that under some circumstances resin loss and under-encapsulation could take place and lead to degraded bolt performance. Glove fingering was observed in all recovered bolts to various degrees. The limited comparative data suggested that the effect of glove fingering ranged from slight to moderate. Complete mixing of the resin was observed on all of the 40 bolts recovered (28 fully grouted and 12 SEPT). Australian and U.S. resins were compared and the Australian resins were observed to have much smaller catalyst compartment areas and lower resin viscosities. These differences are suggested as potential explanations for occasional resin mixing problems noted in Australian resin bolt installations.

By W. A. McKinney

Bureau of Mines Research has demonstrated that it is technically feasible to segregate oxidized copper ores by use of a direct-fired, refractory-lined rotary kiln. Previously, the segregation process had been effected only in much more complicated indirect-fired, stainless steel kilns, The method comprises heating crushed ore premixed with small quantities of salt and carbonaceous material, such as coke, to about 830° C to produce copper as fine flake and metallic films on the surface of the coke particles. After grinding of the cooled furnace calcines, the copper is recovered by conventional flotation. During direct-fired segregation it was necessary to closely control the air-gas mixture in the burner. Good copper recoveries were obtained only when adding air in the limited range of 1.15 to 1.2 times the theoretical amount required for combustion of the natural gas. Batch trials of the new technique on quartzite-, limestone-, sandstone-, and limonite-type oxidized copper ores containing from 1.4 to 6.2 percent copper yielded flotation concentrates containing from 3.7 to 45 percent copper, representing 84 to 95 percent recoveries. Analyses of the furnace gases showed that loss of copper by volatilization was negligible. The preliminary direct-firing segregation studies were complemented by continuous runs on the quartzite ore, containing 1.4 percent copper, in an integrated segregation-flotation pilot plant having a 60 pound-per-hour capacity. In a typical test, 84 percent of the copper was recovered in a cleaner flotation product containing 25 percent copper. The study will be continued to further delineate the conditions for good segregation as effective use of standard ceramic-lined kilns will render the process more attractive from a commercial standpoint.

Jan 1, 1963

By S. H. Ash

The Pennsylvania anthracite region is composed of four fields, namely, the Northern, Eastern Middle, Western Middle, and Southern. It is in the eastern part of Pennsylvania and is shown on figure 1. The anthracite industry is confronted with a crucial problem of inundation by water impounded in underground pools in many mines and by infiltration of water from streams and pools on the surface (3). The deposits of anthracite in the United States are limited virtually to Pennsylvania, and the difficulties of this industry have been commonly considered as a State problem rather than a national one (1, 4, 6, 7). Anthracite was discovered in Pennsylvania in 1762, and the first mining company was formed in 1793. It was not until 1812 that anthracite began to receive recognition in the Philadelphia market as a domestic fuel, and by 1838 the annual production was nearly 1 million net tons. Since anthracite mining began, mine water has become progressively more difficult and costly to handle because of the extraction of anthracite both underground and along the outcrops of the beds, until at the present time mine drainage is a major anthracite-mining problem. Mine water is handled at the anthracite mines as follows: (a) by pumping, (b) by drainage tunnels, (c) by combination of pumping and drainage tunnels, and (d) by water hoists (hoisting water by means of large buckets) (4, 5,6, 7). This paper covers removal of the water from mines by means of pumping plants. Pumping is indispensable in the production of anthracite (5). The cost of pumping mine water has increased progressively since anthracite mining began. Some collieries have been forced to discontinue mining because of the high cost of pumping.

Jan 1, 1950

By S. P. Holt

The Rush & Brown mine has been one of the most consistent small producers of copper ore in the history of Alaskan mining. Approximately 50,000 tons of ore have been shipped to smelters from the property. Production has been made from two distinct and separate ore bodies of dissimilar types. The Shear Vein deposit has been mined to a depth of 500 feet below the surface without a reduction in the size of the ore shoot or the grade of ore. The Magnetite ore body has been partly mined to a depth of 200 feet below the surface. Because of the favorable production record of the Rush & Brown mine, the present need for copper and the fact that the owners were attempting to place the mine in production, it was deemed advisable to investigate this property under the Strategic Minerals Act of 1939 as a possible source of copper.

Jan 1, 1948

By R. L. Rough, W. K. Overbey

The Bureau of Mines obtained samples of oil - reservoir rock from wells in Ohio , Pennsylvania , and West Virginia as part of an investigation of the susceptibility of petroleum reservoirs to secondary - recovery techniques . Illustrations and tables showing the geographic and stratigraphic sequence of the cored reservoirs and 40 tables of detailed lithologic descriptions of the reservoirs are presented . Information relevant to geologic surroundings , oilfield history , coring and well logging operations , and reservoir core analyses are referenced throughout the report .

Jun 1, 1970

By K. Thirumalai

The feasibility of breaking hard rock by thermal weakening and subsequent mechanical impacting was tested, Field tests at a basalt quarry in Dresser, Wis., demonstrated that large hard-rock blocks (5 by 5 by 5 ft) could be effectively reduced in size by this method. A series of secondary breakage tests, using air-propane heating, resulted in an average heating cost of $0.36 per ton. This combination energy approach provides an alternate means of size reduction of large hard-rock boulders for quarry and for underground are chute and grizzly operations where mechanical methods, used alone, are ineffective.

Jan 1, 1975