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By J. L. Wiley

[NOTE. - P before the number indicates that the ab tract appears in patent section. Abstract numbers without. P appear in literature section. A Abietic acid, hydrogenolysis - 404 Acetone, recovery - P-4024 Acetylacetonate catalyst - P-3352, P-3664, P-6067 Acetylene, production - P-2556, P-3169, P-4064, P-4221, P-4222, P-5002 Acid catalyst - P-4584 Salts - P-4555 See also Specific acid. Acid treatment. See Procedure. Adsorption. See Hydrogen, adsorption. Agitation. See Equipment, agitators; Procedure. Alcohols: Decomposition -1128 Hydrogenation - P-3288, P-4743 In motor fuel - 1486]

Jan 1, 1952

By J. B. Littlefield

[Ata. meeting of the Subcommi ttce on Chemical _ et.lOds of Air Ant:..1ysis of-the American Public Health Ascociation in October 1937, the llse of the impinger for collectinG lcs.d fu.l1e wa:., discussed. The Bureau of Mnes de-cided to obtain infornw.tion on the efficiency of the lerge and midget im-pingers for this purpose y using the electric recipitator as a reference method. 'I'ests ~ ere made aJ,so to aScer ain the effici ency of the recently developed midget i;npi gerS..! for collac ing lead dust. For comparative pur-poses, samples collected by tte large impinger wore included.]

Jan 1, 1938

By HOWARD I. OSHRY, James W. Ballard, H. H. Schrenk

Photometric instruments were designed and built for use with X- ray and spectrographic apparatus for the investigation and analysis of a variety of materials of hygienic interest . The instruments are simple in design , may be constructed economically , and have a number of features that make them stable and easy to operate . They are readily adaptable for measurement of either X - ray diffraction patterns or spectrographic films or plates . Because of these features and the interest shown in the instruments , they are described in detail , and reference is made to their application in the laboratory .

Apr 1, 1942

By T. Kessler

As part of a respirable mine-dust research program at the U.S. Bureau of Mines, spark-source mass spectrometry has been used for the semiquantitative determination of trace elements (200 ppm weight or less) in raw coals. In addition, several minor and major elements have been determined using this technique. Sixty-four elements ranging in concentration from 0.01 to 41,000 ppm weight were determined in one anthracite, two mvb, four lvb, and six hvab raw coal samples. The samples represented 10 coal seams located in Pennsylvania, West Virginia, Virginia, Utah, and Colorado.

Jan 1, 1973

By Howard C. Pettibone

Mine safety personnel reported occurrences of excessive "glove-fingering" and other problems with resin-grouted roof bolt installa tions. To study these problems, the Bureau of Mines designed a test plan to (1) obtain baseline information on several resin cartridges and (2) investigate the variables involved in the installation of a resin bolt. Three brands of resin representative of the industry in January 1983 were selected for cartridge evaluation. The installation variables selected for study were the method of installation, the hole depth, and the hole annulus. These variables were studied by installing a series of bolts in concrete blocks using different values for each variable. Results of the research show overspinning the resin may cause problems, but they can be avoided by using the spin times recommended by manufac-turers. Excessive glove-fingering is not a problem if the manufacturer-recommended installation procedures are followed.

Jan 1, 1987

By Forest H. Majors

"INTRODUCTION The Brutch sulfur deposits were explored by the Bureau of Mines during the spring and summer of 1944. Old workings were rehabilitated and sampled, test pits and shafts were sunk, and trenches were cut through the surface alluvium.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts prelimi¬nary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.Special acknowledgment is due S. R. Zimmerley, regional engineer, and Paul T. Allman, principal engineer, Bureau of Mines, Salt Lake City, for their supervisory aid, and to the metallurgical staff, Salt Lake City, for beneficiation of samples."

Oct 1, 1946

By Oliver C. Ralston

The growing popularity of perlite (sometimes spelled pearlite) as a raw material for thermal expansion into pumicelike products in the Western States has prompted a preliminary investigation of the properties of such material and the problems that want solution to put a perlite industry on a firm foundation. The Bureau of Mines is undertaking the gathering of data and the solution of these problems, and the following paper records some of the available information. and the promise of the material, with some comparisons of advantages of the various competing lightweight aggregates that can be made from siliceous volcanic glasses and rocks containing entrapped or dissolved water that causes their expansion on' quick heating to their softening points. This new industrial rock has caught the fancy of the mineral industry in the western States because it has Fume advantages over natural pumice. Chemically, it is typified as rhyolitic in composition, and one may find obsidian, rhyolite, pumice, pumicite, and perlite from the same vant and contemporaneous in origin. The material need not be rhyolite but should be a siliceous or acid lava and contain 2 to 5 percent water still in "solution" in the rock. On quick heating to the softening temperature the material puffs, due to conversion of the contained eater into bubbles of steam. Slow heating causes gradual release of the imprisoned water by decrepitation and. cracking and-results in, very little puffing. Perlite is often in the form of ovoid volcanic bombs formed by explosive eruption of large masses of lava into the air, where they, quickly cool, with escape of little of the contained water, exceptt perhaps for a hollow interior. Since they cool in layers they have an onion-type structure and a pearly luster from interference of light between the. layers, which is' the origin of the name "perlite." Perlite may occur in intruded flows that have been quickly cooled and partly expanded but retained most of their magmatic water content. Obsidian may be the same lava cooled quickly under conditions that prevented crystallization of feldspars and other minerals, leaving the volcanic glass that may or may not retain all of the original contained water.

Jan 1, 1946

By G. W. Birge, D. E. Wolfson, J. G. Walters

An investigation was conducted to determine the relationship between ASTM and Micum tumbler data and to develop equations that would enable the conversion of data from one test method for comparison with those determined by the other , and thereby facilitate the international exchange of data . Relative strengths of 18 commercially produced cokes were determined by ASTM and Micum tumblers and ASTM shatter test . Two of the samples were coke produced for foundry use , and two were produced in beehive ovens . The remaining 14 samples were produced for blast furnace consumption and had ASTM tumbler stabilities of 36 to 58. Statistical procedures were used to relate the three test methods and also to evaluate the effect of charge weights , top sizes of coke , and types of screens specified by the two standard tumbler procedures , square - hole wire mesh for the ASTM tumbler and punched round - hole for the Micum . A significant result was that the data obtained with like screens have a higher degree of correlation with a smaller standard deviation than data from the screens specified for each tumbler .

Jan 1, 1964

By J. L. Holman

The Bureau of Mines is conducting research to recover strategic and critical metals such as Ni, Co, and Cr from mixed contaminated super-alloy scrap. One approach being studied involves melt refining of superalloy scrap to produce anodes for electrolytic deposition of Ni-Co alloy. This melt refining of superalloy turnings is described based on melt-oxidation and oxidation-carburization experiments, using roasted superalloy grinding sludge to supply the 0 needed to oxidize Cr and other readily oxidized elements to the slag. Controlled melt-carburization subsequent to oxidation improved the metal phase recovery of Ni and Co to well over 90 pct and decreased electrolytic solubility of Cr, Mo, and W by carbide formation. Electrolytic refining experiments were conducted using a controlled-potential mode (preset cathode potential). Data show effects of Fe and Cr impurities, cation concentration, electrolyte pH, S04-Cl electrolyte ratio, temperature, cathode potential, and cation-selective membrane use on current efficiency, current density, and deposit composition. Disposition of Ni, Co, Cr, MO, W, and Fe is compared for melt-oxidized versus oxidized-plus-carburized anodes. Deposits containing >97 pct Ni + Co (major impurity Fe) have been routinely obtained from scrap anodes. Research is continuing to improve deposit quality in sustained deposition and to recover Cr and other metals from refining slags and anode sludges.

Jan 1, 1986

By J. W. Town

Studies were made by the Bureau of Mines to determine the influence of textural features on the beneficiation of phosphate minerals (pellets) from selected bed and composite samples representing different rock types of the Western Phosphoria Formation. The particle size of the samples was reduced by attrition grinding to minus 20-, 28-, or 48-mesh depending on ore grade and gangue matrix. Sizing of the ground material showed that the phosphate pellets would concentrate in the plus 200-, 270-, or 325-mesh size fractions sufficiently so that the phosphate content was above the 31.5 :cent P2O5 required for acidulation. The phosphate content of essentially pure phosphate pellets was shown to range from 33 to 39 percent P2O5. Microscopic identification of the particles in each size fraction showed that the phosphate was either in the pellet form and readily liberated or so intimately associated with the gangue matrix that size reduction necessary Co obtain liberation was impractical.

Jan 1, 1967

By Vernon C. Davis

In initial attempts to mine taconite by conventional open-pit methods, the material tended to break into tabular blocks that were too large to be handled by conventional shovel dippers and were unsatisfactory in an ordinary crusher feed. A great amount of secondary blasting was necessary, which added considerably to the cost of mining. The Bureau of Mines and others are engaged in studies designed to contribute to the solution of taconite-mining problems. These studies concern problems related to drilling techniques and patterns, types and methods of use of explosives, and other factors relative to effecting maximum fragmentation at minimum cost. This report, is concerned with study of the application of shaped charges in drill holes, the effectiveness of shaped charges as compared to capped charges in secondary blasting, and the merits of different drilling patterns and methods of detonation of conventional-explosive charges. Fragmentation of taconite at or near the surface is controlled or strongly influenced by joint and bedding planes. Since all tests in this study were made in a jointed and bedded area, a definite conclusion as to the relative effect of a shaped charge in a drill hole, as compared to a conventional charge at greater depths and tighter ground, is precluded. However, application of shaped charges in primary blasting of taconite appears to be of no advantage. In secondary blasting of taconite, conventional, capped charges produced better breakage than shaped charges of the designs tested. Based on the results of conventional blasting practice in horizontal-, inclined-, and vertical-hole tests, no better fragmentation is obtained from blasting either horizontal or inclined holes, compared to vertical holes. Holes drilled in staggered parallel rows that intersect both series of joint planes at the greatest possible angle, give maximum breakage compared to rows paral-lel to one of the series of joint planes. Methods of detonation made little difference in breakage; but the milli-delay caps produced the best conditions for moving the broken rocks.

Jan 1, 1953

By F. B. Tough

"INTRODUCTION Organizations formed for the purpose of conducting conservation work in oil fields, in order to conserve and prolong the supply of crude petroleum are rare and novel. Such an organization is the Rocky Mountain Petroleum Association, Denver, Colo, As our production of petroleum can no longer keep with the consumption, the plan of organization, character of work, and results obtained by this association are well worth considering. It is hoped that the results achieved in the Wyoming fields will serve to stimulate similar organizations among operators in the state or other oil fields of the United States, The Rocky Mountain Petroleum Association, Danvers Colo., was formed in May, 1919. It comprises the Midwest Refining Co,. The Ohio Oil Co., and the Continental Oil Co. These three companies entered into a cooperative agree¬ment with the Federal Bureau of Mines whereby $30,000 would be spent under the direction of the bureau, which agreed to furnish competent men, and to furnish the work and expenditure of funds. Although the financial burden for the first year's work, now drawing o a close, was carried by only three companies, they stipulated their desire that the benefit of the work should accrue to the industry, and that the personnel employed should be as zealous to assist one operator as another, without regard to whether ha was contributing to the support of the work or not."

Apr 1, 1920

By John P. Capp

The feasibility of simultaneously burning several paths through a coalbed to develop a multiple path underground gasification system was investigated by the Bureau of Mines during two experiments, Boreholes were drilled through the overburden and into the coal and arranged in a circle approximately 50 feet from a central borehole. In the first experiment, in an area which had previously been hydraulically fractured,5 air was injected at the center borehole. The coal was ignited at the other boreholes and the fire fronts traveled toward the center, counter to the flow of air, to backward burn paths through the coalbed. Two paths were linked during the first 5 days of operation. The outlets of these two paths were throttled and air pressure was increased to maintain the flow of air, but no other linkages were made. Fourteen days after the two linkages these two paths were opened and gasification was carried on for 10 days, but with only moderate success. In an effort to overcome operating difficulties air was injected at the peripheral boreholes, and the gases were drawn off at the center borehole. Reversed flow operations continued for 12 days and two more paths linked. The heating value of the gas generally was higher than 100 British thermal units per standard cubic foot (B.t.u. per std. c.f.). Because only four of seven paths linked, however, the entire system could not be evaluated with respect to product-gas output and recovery of energy.

Jan 1, 1961

By Welby Courtney

Because of the inherent safety problem associated with the deposition of airborne respirable dust onto the floor and other airway surfaces, the Bureau of Mines investigated the rate of reduction of airborne respirable dust in an airway due to deposition of the particles onto the surfaces of the airway. The effects of relative humidity and air velocity on the deposition rate were examined. It was found that the deposition rate was comparable in magnitude with the Stokes sedimentation rate and that it was independent of relative humidity. However, near the dust source the deposition rate depended significantly upon the air velocity, with such dependence decreasing with increasing distance from the dust source. In addition, the size distribution of the airborne particles was approximately constant along the first 300 ft of the airway, indicating that it was not merely the larger (heavier) particles that were being deposited. These results suggest that deposition, though comparable with the Stokes sedimentation rate in magnitude, does not follow a simple Stokes-type process, and that the process of deposition remains to be explained.

Jan 1, 1986

By E. B. Kester

A study of the composition of the corresponding fractions of a primary and a high- temperature tar was undertaken to throw light on the net results of the pyrolysis of the primary products of coal decomposition in high-temperature coking practice, with reference both to total quantities of the chemically similar constituents and to their distribution throughout the boiling range. No exactly parallel investigations are on record. The distribution of substances in high-temperature tars, however, is fairly well understood. Such tars are more or less similar, for they consist of the more stable phenols, aromatic and olefinic compounds resulting from the pyrolytic decomposition of a wide variety of primary tar constituents. For example, from a typical distillation curve for high-temperature tar phenols4 it may be seen that the greatest portion of the phenols distills between 180° and 220° C., a fairly narrow range.

Jan 1, 1932

By John Nagy

Dust explosion data obtained in laboratory tests by the Bureau of Mines are presented for 181 miscellaneous materials that present an explosion hazard. Data are given also for 50 dusts that present primarily a fire hazard and for 88 dusts that did not present an explosion hazard.

Jan 1, 1968

By Everett A. Sondreal

Material and energy balances for stockpiled lignite were calculated by computer simulation techniques to determine the occurrence of spontaneous heating. Data on properties of lignite which affect spontaneous heating were required. In some cases, best values from reported data were utilized; in other cases, new data were developed. These include specific studies on the rate and conditions that influence oxidation, heat of oxidation, heat of wetting, specific heat, thermal conductivity, and permeability of stockpiles to air. These data are presented and discussed in detail for possible application to other studies. Results of computer simulations confirm past field experience on the storage of lignite containing as-mined moisture, and predict a greater risk of heat occurrence in stockpiles of dried lignite where experience is lacking. Successful storage was predicted for dried lignite of 20 pct moisture content, if it were cooled after drying and compacted to an interparticle void fraction of 9 pct (bulk density of 67 lb/cu ft) compared to 10 pet void fraction (72 lb/cu ft) for as-mined lignite.

Jan 1, 1974

By D. Harrington

Although for many years considerable attention has been given to devising safe and efficient methods of using explosives, with some success, relatively little has been done to provide satisfactory storage facilities for them. This was known long before the present war began, but it was emphasized during the past 30 months? inspections of explosive magazines by employees of the Bureau of Mines in administration of the Federal Explosives Act of December 26, 1941. These inspections have revealed woeful in adequacy as well as definite hazards and the urgent need for obtaining better storage facilities either by remodeling old magazines or constructing ink new ones that would afford suitable protection for the contents against theft, fire, deterioration, and detonation. The purpose of this paper is to offer suggestions and to show by sketches and drawings some of the fundamental features of suitable magazines. Type of construction and available materials differ with different; localities, but the information herein contained can be applied to most magazines, whether already constructed or the construct: on of which is planned. It is hoped that this information will be helpful and will aid persons who are trying to provide suitable storage for explosives end detonators. It is also hoped that States and cities will be made aware of the unbelievable laxity practiced in storing explosives in the United States and will take some remedial action.

Jan 1, 1945

By Hylton R. Brown

Advertisements and articles in technical and trade journals announce the approach of a new age, in which plastics, light metals, laminated wood, and numerous other products or byproducts will be used in the construction of automobiles, airplanes, and furniture and equipment used in our factories, offices, and homes. Undoubtedly, after the war there will be many such developments which will introduce new manufacturing methods and new hazards to challenge the safety engineer. Already we know, from experience in laboratories and pilot plants where these new products are being tested, that there will be many fire and explosion hazards to be overcome. The danger of dust explosions may be one of the principal hazards, because thetic resins and other materials used in the plastics industry, as well as metal powders, wood dust, and other finely divided substances, are capable of forming explosive mixtures in air. Heavy losses of life and property have been caused by dust explosions in flour and feed mills, starch factories, and grain elevators, and it will be well to consider the possibilities that such losses may occur in any new industry and to provide all possible safeguards against hazards. Fortunately, we have learned something about the behavior of dust explosions and know something about the ease of ignition, limits of Explosive concentration, end pressure developed. Our efforts should now be directed toward the application of this knowledge in the development of safe operating practices.

Jan 1, 1945

By J. A. Eisele

The Bureau of Mines conducted bench-scale cyclic tests to determine the composition of recycled leach liquor in the Bureau?s proposed clay/HCl leach/ HCl sparge process for producing Al203 from clay. The data developed from these tests make it possible to synthesize leach liquors for predetermined steady-state operating conditions when conducting large-scale crystallization tests. The results of two sparge tests were compared. One was a 20-cycle test with a 36-pct-HCl concentration in the mother liquor; the other was a 10-cycle test with a 26-pct-HCl concentration in the mother liquor. The effect of impurity concentrations in the leach liquor on the purity of aluminum chloride (AlCl30?6H20) crystals was determined, but there was poor correlation between this data and results that have been obtained from miniplant-scale work.

Jan 1, 1980