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By Oren C. Baptist, Carlon S. Land, Eliot J. White

The water sensitivity of the oil - gas - producing sandstones in three fields in the Patrick Draw area of southwestern Wyoming was estimated by laboratory testing . The tests used to estimate sensitivity , which is a measure of the loss of well productivity if the producing formation is invaded by fresh water , are : Porosity ; permeability to gas , water , and brines ; saturation characteristics with air displacing water from the samples and by mercury injection ; and identification of clay minerals by X - ray diffraction . Laboratory results indicate that the degree of water sensitivity of the sands in the Patrick Draw, Table Rock , and Desert Springs fields vary , in that order , from moderately sensitive to highly sensitive . The main cause of the sensitivity appears to be the movement of fine particles in the pores , but the swelling of a small amount of an expandible clay mineral may also contribute to the permeability reduction observed in the samples . Laboratory results further indicate that the permeability of the sands to fresh water is seriously reduced if they are first flushed with sodium chloride brine ; calcium chloride brine is less harmful to the sands than sodium chloride brine . The low original permeability of the oil sand in the Patrick Draw field , together with its moderate sensitivity , indicate that the rate of water injection for the secondary recovery of oil will be low . Limited field experience in two pilot - injection wells confirms this prediction .

Jan 1, 1964

By E. G. King

Heat of formation values for mercuric sulfide appear in all the comprehensive listings of thermodynamic data, but experimentally determined entropy values have been lacking. Consequently, all free energy calculations involving mercuric sulfide have been based upon estimated entropy values. This paper reports Bureau of Mines measurements of the low-temperature heat capacity of red mercuric sulfide (cinnabar) and the entropy value at 298.15° K. derived therefrom. The entropy value was combined with heat data to obtain free energy values for the formation of red mercuric sulfide from liquid or gaseous mercury and from rhombic or gaseous diatomic sulfur.

Jan 1, 1962

By W. H. Ode

An investigation of standard methods for determining ash in low-rank* coals showed that generally 60 to 95 percent of the total sulfur in the coal is retained in the ash as SO3. This large sulfur retention causes a positive error in the determined mount of ash of as much as 6 percentage points for the coals examined, although it usually is 2 to 3 percentage points for lignites and about 1 for subbituminous coals. Unless the sulfur content is low or unless a correction is made for the SO3 retained, the fixed carbon and oxygen have an equivalent negative error when determined by difference; also other inaccurate analytical values occur when the data are calculated on an ash- free bas is. No simple modification of the ashing procedure was found that would reduce the sulfur retention to a point where its effect on the ash determination would not be significant, Therefore, for accurate analytical work on law-rank coals, the SO3 should be deducted from the determined ash to obtain a "corrected" ash value.

Jan 1, 1962

By R. N. Roby

In the course of the Bureau of Mines investigations for suitable sources of high-aluminum clay for the production of alumina, the Whiteware clay deposit was examined in August 1942 by G.N. Bennett, mining engineer, Bureau of Mines, Montana District Office. This report presents the factual data obtained by the investigation, which also includes data on trenching and drilling, and the results of some refractory tests and chemical analyses of representative samples of the clay later taken from some of the best trench exposures and from adit dumps.

Jan 1, 1949

By F. F. Aplan

Separation of the slightly soluble minerals (Ksp? 10-10), one from the other is one of the more difficult tasks confronting flotation engineers. This study has focused on means of separating such prominent members of this class as scheelite, fluorite and calcite from one another. Some experimental work has also been done on the minerals magnesite, dolomite and apatite. Carboxylic acid-type collectors are commonly used industrially to float all of these minerals. Thus, the problem at hand is to ascertain means of achieving selectivity between minerals known to respond rather similarly in flotation. Four techniques have been proposed for the separation of minerals of this class from each other: 1. Control of potential determining ions 2. Use of stereo-specific collectors 3. Use of flotation rate differences 4. Use of selective activating and depressing compounds. This study was directed toward a cursory evaluation of each of these techniques, and each was found to be a possible method of achieving selectivity. Stereo-specific collectors -- those whose parking area may closely match the available adsorption site on one mineral but not on another -- are a possible means of achieving selectivity between scheelite, fluorite and calcite. Stereo-hindered carboxylic acid salts and sulfonates all show selectivity between the three minerals tested. Separations also appear to be possible by the controlled use of the lattice ions (e.g., Ca and [W0=4] for scheelite, CaW04), H+, [OH-, C0-3 and HCO=3]; all of them ostensibly potential determining in the systems studied. Flotation rate differences of the minerals as a function of pH under conditions of starvation collector usage also showed promise. Scheelite and fluorite float most rapidly with sodium oleate in slightly acidic (pH 4-7) solutions whereas calcite floats most rapidly near pH 10. Use of Mn++, Pb++, or other heavy metal hydroxy complexes as activators was seen to effect each of the slightly soluble minerals differently. This is in sharp contrast to the oxygen containing, relatively insoluble minerals, where all minerals respond in a similar manner to such activation procedures. Results indicate that all four methods outlined above may potentially be used to achieve flotation separation of the slightly soluble minerals. More extensive research should be undertaken to detail the spcific applicability of each of the procedures and to make a more complete evaluation of the effect of collector type and concentration, mineral type, pH and size effects.

Jan 1, 1983

By Eric E. Cather

A mineral survey of a portion of the Lake Eleanor RARE II area (No. 5807), Trinity County, California, was done by the U.S. Bureau of Mines and U.S. Geological Survey (USGS). Approximately 8,650 acres (3,500 ha) of the Lake Eleanor RARE II area not examined for this report had been previously investigated by U.S. Bureau of Mines and U.S. Geological Survey personnel and published as part of USGS Bulletin 1371-B, (Hotz, 1972) Mineral Resources of the Salmon-Trinity Alps Primitive Area, California. The report showed that the section included in the rake Eleanor RARE II area contained no metallic mineral resources. Geochemical sampling indicated that the Lake Eleanor RARE II area contains no potentially important mineral resources. About 4,650 acres (1,880 ha) of the eastern part of Lake Eleanor RARE II area were examined for this report. The Bureau of Mines was responsible for detailed examination and sampling of mines, prospects, and mineralized zones; the Geological Survey conducted geological, geochemical, and geophysical studies of the area. This area is underlain mainly by granitic rock and serpentinite.

Jan 1, 1981

By Robert L. de Beauchamp

The Bureau of Mines reviewed aluminum chloride technology to determine the problems associated with its preparation from minerals, and to ascertain the best areas for research to solve these problems. Commercial AlC13 production processes are described and the ?state of the art? for the preparation of AlC13 from aluminous materials is evaluated. Areas for further research are indicated.

Jan 1, 1969

By B. H. Clemmons, B. G. Saunders, R. H. Stacy

"INTRODUCTION This investigation was undertaken to determine the response of Birmingham (Alabama) red-iron ore to heavy-medium concentration. Specifically, the work involved a study of the efficiency of the process in separating coarse gangue diluents from the ore and an endeavor to evaluate the potential economic results. The investigative work was not intended, nor is it to be construed, to be adequately exhaustive in scope to enable immediate plant construction. Rather, the primary objective was to determine the grade of ore that could be produced by heavy-medium treatment and the resulting indicative or tentative benefits to be derived from such treatment. The latter, in turn, would determine the merits of the more exhaustive study that would be required for an ultimate decision on the heavy-medium treatment of the ores.The problem of avoiding excessive contamination of red-iron ores by shale and/or ferruginous sandstone has been before the operators of the iron mining industry of the Birmingham, Alabama, district for many years. Within the last two decades, increased mechanization of mining methods has increased this contamination to a considerable degree. In fact, general utilization of scraper loading and other mechanical methods of mining, in conjunction with small increases in the natural insoluble content of the ores, in some cases has actually resulted in the production of ""acid"" or excessively insoluble ore, where ""basic"" or excessively lime ores were produced formerly.The contaminating materials are derived largely from roof spells and natural parting seams in the ore, a condition that to some extent has been aggravated by the irregularity of the ore beds. The latter have been subjected to both primary and secondary folding in many places. Considerable faulting has taken place, also. In many localities these conditions render virtually impossible complete avoidance of ore contamination from the over and underlying sandstones and shales. However, in a few localities, where the ore beds are less disturbed and shale partings are absent, mining can and is being accomplished with relatively little dilution."

May 1, 1948

By John C. Machisak

Employment and related injury experience of the coking industry in the United States for 1957 contained in this publication is summarized under three general sections: (A) General injury experience: Tables 1 to 9: Current and comparable statistics on operating data, number, frequency, and degree of severity of injuries and major accident agencies involved in the cause of Injuries. Data are presented for the industry as a whole, for each type of oven, and for the States in which coke was produced.

Jan 1, 1959

By Jay F. Colinet

Longwall mining in lower seam heights may necessitate the use of single-drum shearers to overcome size constraints associated with standard double-drum shearers. To avoid the operational problem of clearance in the tailgate entry with one single-drum shearer, two single-drum machines can be operated on the same face, with each shearer responsible for mining a predefined portion of the face. However, utilization of two shearers on the same face necessitates the positioning of one shearer operator and a jacksetter in the return air of the upwind shearer, thus complicating respirable dust control on the longwall. In an effort to evaluate the unique dust control problems associated with this type of mining, the U.S. Bureau of Mines conducted dust surveys on two multiple-machine longwall operations. Sampling was done to quantify major sources of respirable dust and to identify potential solutions to problem areas. Sampling results indicate that the cutting sequences utilized on multiple-machine faces may have to be designed to minimize dust exposure, as opposed to optimizing productivity or facilitating operational requirements. Also, state-of-the-art dust control techniques typically found on double-drum shearer longwalls must be employed to help minimize the exposure of all face personnel to traditional dust sources.

Jan 1, 2010

By Lotfollah Nahai

India is one of the fortunate countries that has substantial reserves of many raw materials for producing steel; however, for historical and economic reasons these resources have not been aggressively developed until recently. Production of steel on an industrial scale started in 1912, but annual output was below 1 million tons3 in 1938 and about 1,500,000 tons in 1951. Expansion of the steel industry became one of the objectives of India's economic planning after independence in 1947. The Planning Com¬mission's 1951 report emphasized the importance of steel production, but financial obstacles, emphasis on river valley projects, and priority for increased food production in the First 5-Year Plan (1951-56) did not permit large-scale expansion of steel capacity. The 1956 planned target for crude steel, only 1,650,000 tons, was actually exceeded by production of 1,737,900 tons. In the Second 5-Year Plan (1956-61), however, construction of steel plants received a high priority. Currently three new steel plants, each with an annual capacity of approximately 1 million tons of steel, are nearing completion in Rourkela, Dorgapur, and Bhilai. Simultaneously, the two privately owned steel plants and the small State-owned plant in Mysore have been enlarged and modernized. As a result, India's crude steel capacity will be about 6 million tons in 1961, almost evenly divided between Government-owned and privately owned plants. Actual production in 1960 totaled 3,254,000 tons compared with 2,434,000 tons in 1959. Assuming that the population will be 430 million and that capacity production will be achieved, the 1961 per capita steel output will be only 31 pounds compared with 200 pounds for Japan in 1959. Some Indian experts feel that development of steel-consuming industries merits greater emphasis in the Third 5-Year Plan (1961-66) than expanding existing steel-producing facilities. Nonetheless, the Third 5-Year Plan calls for a 10 million ton annual capacity by 1966 to be achieved by expanding the Government-owned plants in Bhilai, Durgapur, and Mysore, and by establishing a new integrated Government plant in Bokaro, in the State of Bihar.

Jan 1, 1961

By Otto L. Schumacher

The Overthrust Belt in portions of Montana, Idaho, Utah, and Wyoming, an area that has contributed generously to the Nation's mineral supply, is one of the few remaining oil and gas frontiers on the North American continent. Determination of the oil and gas potential and development of mineral resources of the area have been affected by a variety of land withdrawals and other restrictions, The purpose of this study is to determine the extent of these withdrawals and restrictions and to discuss the mineral resource potential within the study area. Statistics in this report refer to land status on January 1, 1979. At that time, of the 27.3 million acres of Federal mineral lands within the study area, applications tor Federal oil and gas leases for more than 4,4 million acres (about 16 percent) were pending; the average length of time was 2 years. Federal oil and gas leases covering 8.8 million acres were also on record. Although drilling has occurred on some of these leases, others are subject to restrictions that discourage or prevent development. Some in fact contain stipulations disallowing any development.

Jan 1, 1981

By John P. Powell, J. L. Eakin

"INTRODUCTION AND SUMMARYNowata County, in the northeast corner of Oklahoma, is one of the principal oil-producing counties of this stripper area. Many fields in the county were opened and much oil was produced before statehood. The location of the major fields, as defined by the Oklahoma Corporation Commission, 2/ the outline of the areas of water-flooding activity, and the location of the several projects described in detail in this report are shown in figure 1.There was some drilling in the county earlier; but it was not until after 1904, when the Secretary of the Interior confirmed as valid the leases granted by the Cherokee Nation, that the major drilling activity began. Initial development in this part of Oklahoma was in the Chelsea field in Rogers County, which adjoins Novata County on the south. The activity spread rapidly northward to the Alluwe and Coody's Bluff fields, and then to the Nowata-Claggett field. Continued exploration resulted in discovery of the Delaware-Childers field, where some wells having an initial production of 1,000 barrels daily were completed. Fields discovered and developed during the next few years included the Lenepah (Elliott), Adair, California Creek, Curl Creek, Woody, and South Coffeyville. The oil-production history of Nowata County is shown in figure 2. In assembling the data for a production curve, it was found that the combined production records for Nowata and Rogers Counties were available for 1914 to 1951, inclusive, and that records for the individual counties were available only from 1926 to 1951, inclusive. The early production figures for the counties from 1905 to 1914, inclusive, except for 1909, were calculated from the initial production statistics of the Federal Geological Survey mineral resources bulletins and production data assembled by C. H. Beal. 3/ The production values for 1905 to 1926 for Nowata County were obtained by dividing the total production for the two counties by a percentage factor derived from known facts regarding the oil industry in the area. Production figures for the individual counties from 1926 to 1933, inclusive, were obtained from the files of the Oil and Gas Journal, and the figures from 1933 through 1951 were obtained from monthly reports of the Oklahoma Corporation Commission."

Jun 1, 1952

By J. Hanslovan, R. H. King

An investigation of the feasibility of shielding low-voltage trailing cables in underground coal mines is described. Both laboratory and under¬ground installation results are presented. The main objective of shielding is to reduce the electrical shock hazard; however, several problems will be encountered by mine operators who install shielded cables. Parameters related to such items as purchasing, splicing, troubleshooting, safety, and reliability are discussed. Some of these problems can be minimized by changes in cable constructions and shuttle-car reeling-device components. Both SH-C and SH-D constructions are considered.

Jan 1, 1979

By R. D. Leitch

From time to time the Bureau of Mines has received requests from persons who wish to destroy unwanted explosives, and although the information that follows has been accumulated from sources considered reliable,4/ the. Bureau of Mines assumes no responsibility for accidents that may result from following the suggestions offered. Explosives to be destroyed may be fresh material from damaged packages, usable material for which there is no further need, or material that has deteriorated either from natural aging or from improper storage to the point where it is unfit for use.

Jan 1, 1945

Reduce the dust exposure of workers in large processing buildings at mineral processing operations, using a total mill ventilation system.

Jan 1, 1994

Large quantities of combustible materials are often found in underground metal and nonmetal mines, with support timber predominating. Wood lagging and timber, wires and cables, brattice cloth, hose, paper products, cardboard cartons, and wooden containers are additional combustible materials commonly found in underground storage areas. Shorted or overloaded electrical cables, worn sockets and plugs, spontaneous combustion, careless smoking, and welding and cutting are common fire ignition sources. Inexpensive, reliable fire detection and suppression systems are available to provide early warning and to extinguish fires that originate in underground storage areas.

Jan 1, 2011

By V. E. Homme

Low- and high-temperature reduction techniques were employed by the Bureau of Mines in study of conditions favorable to the formation of massive titanium crystals. '1,1,2 low-temperature method, feeding molten sodium to solidified titanium lower chloride-sodium chloride, produced higher quality and high quantity crystalline metal. The percentage of crystalline titanium was increased with increasing reactor diameter, melt depth, and titanium dichloride concentration. The high-temperature technique, feed molten sodium to melts above 8000 C, producing needle-type crystals of lower quality and with less consistent results than the low-temperature method. Layers of titanium foil, sponge, fine needles, wool, and crusts of sin-tered granules were formed during the earl, -art of the low-temperature reduction, and massive crystals were produced beneath this barrier in the latter part of the reduction. Crystalline titanium having an average hardness of Bhn 76 and representing 58 percent of the total titanium was obtained. Lamellar crystals up to 1 1/2 inches long with a hardness as low as Bhn 54 were also produced. A second-stage reduction for reclaiming titanium from offgrade sponge is described. Titanium produced by this method was comparable in quality to that from sodium reduction of titanium tetrachloride.

Jan 1, 1966

By Vernon Helm, John S. Ball, Welton J. Wenger, William E. Haines

"INTRODUCTION Although the presence of sulfur causes many petroleum’s to be classified as ""low-grade"" because of the difficulties encountered in manufacturing products to meet rigid specifications, the petroleum industry is finding it necessary to use such crude oils to satisfy present needs. As the demand for petroleum products increases, and available reserves diminish, this utilization of high-sulfur crude oils will be accentuated. Programs designed to supplement the supplies of fuel available from petroleum by the manufacture of synthetic fuel from natural gas, shale oil, and coal are in progress. Such fuels, especially shale oil and, less so, oil from the hydrogenation of coal, also contain sulfur compounds which must be effectively removed. Thus, the need for fundamental research on the sulfur compounds that may be expected in petroleum and allied products is becoming greater as the industry is forced to call upon all available resources to meet the demand for petroleum products. In recognition of this need, the Bureau of Mines has inaugurated a long-range program assigned to furnish fundamental data concerning the presence, characteristics, and effects of sulfur compounds in petroleum and its products."

Dec 1, 1946

By R. Karl Zipf

A fatal explosion in a sealed area at the Sago Mine in 2006 prompted researchers and regulators in the United States to re-examine the requirements for explosion-resistant mine seals. Seals are used in underground coal mines to isolate abandoned mining areas from active workings. Prior to the Sago disaster, mining regulations required seals to withstand a 140 kPa explosion pressure. Recent research at the National Institute for Occupational Safety and Health (NIOSH)Pittsburgh Research Laboratory showed that pressures from explosions can far exceed this pressure. U.S. mining regulations now require much stronger seals. Current research focuses on understanding the science, engineering and management of sealed areas of coal mines. Scientific efforts seek understanding of how explosive methane-air mixtures accumulate using measurements and models of the sealed area atmosphere. Additional scientific efforts aim to understand the explosion pressures that can develop using a combination of numerical modeling and experiments. Engineering efforts aim to produce design guidelines for seals that can resist the new higher pressure design criteria. NIOSH researchers are also developing guidance for monitoring of sealed area atmospheres and inertization of potentially explosive gas mixtures within sealed areas. This paper seeks to encourage scientific discussion among international peers since preventing explosions within sealed areas is of interest to underground coal operators and regulators.

Jan 1, 2009