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By R. V. Ramani, R. Stefanko, G. W. Luxbacher

1 11 THIS IS A DIGITAL COMPUTER SIMULATION OF THE VENTILATION SYSTEM OF A MINE LOCATED IN WASHINGTON COUNTY, PENNSYLVANIA. THE VENTILATION SURVEY ON WHICH THIS SIMULATION IS BASED WAS RUN FROM OCT. 27-30 AND ON NOV. 2, 1976 IN THE ACTIVE PORTION OF THE MINE INBY COMBS SHAFT AND THE INACTIVE PORTION AFCUND AND INBY DONAHOO SHAFT. FOLLOW-UP SURVEYS WERE THEN RUN ON FEB. 18 AND FROM MARCH 7-11, 1977 TO INCLUDE THE MAIN HAULAGE SYSTEM OUTBY THE ACTIVE AREAS OF THE MINE. ALL SURVEY DATA WAS NORMALIZED TO A STANDARD DENSITY OF 0.075 POUNDS/CU.FT. PRIOR TO THE CALCULATION OF INPUT PARAMETERS FOR THIS SIMULATION.

Jan 1, 1977

By Harold M. Smith

Natural gas has been used as a fuel and source of energy almost from its discovery, but its use as a chemical raw material may be said to have begun in 1918, when Brooks and Humphrey3/ showed. presence of alcohols in the diluted acid oil obtained by the sulfuric acid-treatment of cracked petroleum distillates. However, development of the utilization of natural gas for chemical syntheses was slow, partly because erroneous ideas existed regarding the nonreactivity of tine hydrocarbons composing natural gas. Data accumulated by petroleum chemists throughout the world, particularly since about 1930, have shown that these hydrocarbons will react when activated by the effects of heat, pressure, chemical reagents, and light; also that the reactions can be made to proceed of practicable speeds and to provide good yields of useful products with moderate operating conditions, especially if catalysts are employed. As those results became known, the possibility of a synthetic organic chemical industry based upon these reactions became apparent, and today this industry is large and growing rapidly in importance. In this paper the story of the manufacture of chemical products from natural gas is told simply in graphic form. The industry is developing so rapidly that soma products may have been omitted, but every effort has been made to include all that are important or likely to become so. The difficulty of keeping information of this tape up to date is shown by reference to an information circular4/ or, the sore subject published by the Bureau of Mines in 1930, in which the important products are shown on a single chart, where as five charts are employed for the cane purpose at present.

Jan 1, 1940

By G. L. Oldright

"The various districts in the United States where complex lead-zinc ores occur are too well known to require description, there being hardly a mining State with any large amount of ores of either metal that is free from this problem. This paper briefly presents developments in the volatilization process, as applied to the treatment of such ores, since the data in Bureau of Mines Bulletin 211** were published. In that bulletin, among the many types of ore treated, examples are given of the treatment of lead-zinc ores by the chloride volatilization process for the separation of lead. An outline of the general process, with views of the rotary kiln, ore feeder, firing system (these three features resemble closely those of cement-kiln practice), dust chambers, and a Cottrell precipitator to remove the fume from the gas, are also shown in that bulletin, to which the reader is referred for the results obtained, and for practical details of operation. The small initial cost of a volatilization plant, and its adaptability for use in isolated districts were emphasized.In general, it was found that when an intensely oxidizing atmosphere was maintained in the furnace, a good lead-zinc separation could be made. Therefore, a heavy sulphide ore would have to be preroasted, and enough air would have to be admitted to obtain complete combustion of whatever fuel might be used.The work done by private companies and the bureau since the data for Bulletin 211 were obtained, indicates that the ores most immediately amenable to treatment by volatilization are of two types. The first is an oxidzed lead. silrer ore whose variable lime content makes it impractical to chloridize the ore for acidulated brine leaching, and whose base metal content makes treatment by cyanidattion unfeasible, The second type is the lead-zinc ore mentioned above, and is the one on which data are available for publication at present. This article Chows what ores of this latter type are amenable to treatment by volatilization, by giving briefly some of the more important physical and chemical properties an ore should preferably possess. Several examples are given from both laboratory experimental work, and from practice in the field, showing various phases of the volatilization process."

Nov 1, 1923

By Scott A. Stebbins

During 1981, the U.S. Bureau of Mines and U.S. Geological Survey conducted a mineral resource survey of the 6,400 acre (15,800 ha) Lincoln Creek RARE II area (No. 5983) in the Toiyabe National Forest (fig. 1). Samples of outcrops and stream channels contained no significant amounts of economic minerals. A radioactive deposit in a pegmatite dike occurs 1.25 mi (2.02 kin) southeast of the study area, hut similiar deposits have not been discovered within the area boundary. No coal or deposits were found.

Jan 1, 1982

By Zsuzsanna Zborovszky

[Certain chapters of the tentative document entitled, "Test Requirements for instruments & Apparatus to be Considered for MESA Intrinsically Safe Certification" are evaluated and supporting data are presented on certain key issues with the purpose of helping the regulatory agency in improving the above document. The subjects discussed in detail are: hot wire ignition with W and BeCu wires; the most sensitive methane-air :and propane air ratio; the ignition limits for inductive-resistive circuits in 8.3°; methane-air mixtures in the 24-OV, 100 mH-2 [ ]H range, the resistive ignition limit as a special case when L ? 0; the capacitive-resistive ignition limit representing a four ,dimensional problem is analyzed and discussed in general and the variation of the ignition limit using Vo and/or r2 as a parameter are determined experimentally. The ignition limit is also determined for the [r1 ,~ r2] = 0 case ("capacitor alone") and for the most dangerous capacitive resistive circuit combination. The ignition limits are below the limits proposed in the document. A survey of the different factors influencing the ignition is made as to their suitability to provide a constant safety factor. It is shown that a constant safety factor cannot be achieved. The best method for applying a safety factor appears to be the increase of initial pressure or use of other gas mixture. The revision of the safety factor concept and ignition limit curves is recommended.]

Jan 1, 1980

By Helen E. Edwards

The Bureau of Mines is engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies are designed to provide basic thermodynamic information of high accuracy facilitating the theoretical study of flame and combustion phenomena. This report is the third of a series3/ presenting results of the study for particular fuel-oxidant systems. The equilibrium composition of the products of combustion and the adiabatic flame temperatures of specified oxyacetylene systems have been computed.

Jan 1, 1953

By R. L. Lincoln

The effects of adding from 1 to 50 atomic percent (a/o) to vanadium were investigated by the Bureau of Mines. Properties studied included as-cast and annealed hardness, microstructure, fabricability at room temperature and elevated temperature, tensile strength, electrical resistivity, and oxidation resistance at 625° and 800° 2. Additions of small amounts of hafnium resulted in lessened as-cast hardness, decreased electrical resistivity, impaired roll- ability, increased oxidation resistance, and greater tensile strength. Larger amount of hafnium caused greater as-cast hardness, increased electrical resistivity, further impaired rollability, continued increase in oxidation resistance, and lessened tensile strength. INTRODUCTION The purpose of this study was to determine the effect of hafnium additions on the properties of vanadium and to learn if this binary alloy had any special or unusual properties. This investigation is a part of a larger research project in which new and expanded uses of vanadium are being sought. Domes tic vanadium is found frequently in combination with uranium, and because of the demand for uranium as a nuclear fuel, there now exists a surplus of vanadium-bearing minerals and vanadium pentoxide as a byproduct of uranium production. Primary principles of conservation demand that greater use be made of this readily available surplus; finding suitable metals to alloy with vanadium to enhance its properties is one way to increase its utilization. This report is the result of an investigation of the effects on the properties of vanadium when hafnium is added in amounts from 1 to 50 a/o.

Jan 1, 1962

By Robert D. Ewing

The computer program described in this user's guide provides for the static, three-dimensional, linear and nonlinear analysis of structural and geological systems by the finite element method. The guide describes the capabilities and general features of the program and shows how input is prepared. A number of recent advances in finite element theory and computer technology are incorporated in the program. Nonlinear material properties are provided for, including isotropic, anisotropic, and time-dependent material properties, gravity loading, simulation of a sequence of excavation or construction, and a slip or joint element. The finite elements include beam, rod, axisymmetric and plane quadrilateral, hexahedron, thick shell, and axisymmetric and plane joint. The program also has an automatic mesh generator to minimize user input preparation for continuum finite element meshes.

Jan 1, 1976

By Joseph D. Davis

Selection of a suitable coal or coals for the manufacture of coke of desired quality with due consideration of the purpose for which the coke is intended requires careful thought, and often it will pay to go to consider able expense in testing such coals as may be available. In general it will always be possible to obtain a satisfactory coal or blend of coals for the particular purpose in view, but in some places the cost of transportation would be prohibitive. It may then be necessary to consider a coal or coals inferior in grade, rank, or both. At times, in fact, only one inferior coal may be available, when the problem becomes mainly one of selecting equipment and operating conditions best adapted to that coal, keeping in mind that the end product of the plant must compete with the imported product in the market the plant will serve. This applies particularly to new projects for which it is necessary to build a plant and start with a clean slate, so to speak. However, it will pay every coke-plant manager to employ a force to continually test the coals used and the coke produced to make sure that the quality is not changing appreciably. Furthermore, if the supply of coals used becomes exhausted it will be necessary to use other coals. Continual testing is particularly necessary at plants using borderline coals or blends, where slight changes in the composition or in operation of the ovens may render them dangerously expanding. In this connection it should be stated that control in the newer coke plants is considerably easier than for those built a decade or so ago, consequently in the new ovens a given operating program can be maintained more precisely. This point is important, because one of the main requirements of the coke user is uniformity in both physical and chemical characteristics. For example, any appreciable changes in the quality of coke delivered to the blast?-furnace operator will involve changes in operation if the best results are to be obtained. Such changes are expensive usually they take considerable time and involve production of inferior iron.

Jan 1, 1942

By J. E. Schiller

The Bureau of Mines has investigated the surface charge of amphibole asbestos fibers and nonasbestiform cleavage fragments, as part of the Bureau's fundamental studies to provide new knowledge on the physical and chemical properties of the amphibole minerals. Microelectrophoresis was used to measure the electrophoretic mobilities, in water, of particles from six asbesti-from amphiboles and seven nonasbestiform amphiboles over the pH range of 5 through 9. The particles generally ranged in size from 2 to 5 µm wide by 10 to 30 µm long. The isoelectric point was determined for four of the minerals, and values were found to be between pH 3.5 and pH 5. The minerals studied had zeta potentials that generally ranged from -25 to -so mv in neutral solution. Attachment of colloidal positively charged AgI was also studied as a means of determining surface charge. Scanning electron microscopy of amphibole particles that had been in contact with aqueous AgI showed equal attachment of AgI to asbestos fibers and to cleavage fragments; the extent of AgI coating was the same for both. The electrophoretic mobilities of asbestos fibers were essentially the same as those of elongated cleavage fragments of the same aspect ratio (particle length divided by width). Blocky particles from both asbestiform and nonasbestiform specimens had lower mobilities.

Jan 1, 1980

By G. F. Kuncir

The time-cost-risk analysis described herein was performed as part of an evaluation of the Advancing Oil Shale Mining Technology Program performed by The Aerospace Corporation. The objectives of this analysis are to assess the feasibility of the program relative' to time and cost constraints, and to determine the probabilities of achieving various technological goals. A combination of standard program planning and analysis techniques were used to achieve these objectives. These included a critical path analysis, a resource allocation analysis, and a risk analysis.

Jan 1, 1977

By Gerrit V. R. Goodman, Charles D. Taylor, Edward D. Thimons

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 40 ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 40 ft.

Jan 1, 1992

By C. E. Coleman, Joseph D. Davis

During some distillation experiments conducted by the Bureau of Mines in cooperation with the Trent Process Corporation it was observed that amalgams of heavy petroleum oils and finely pulverized coal tended to produce a denser coke than that obtainable from the coal when retorted alone . Even anthracite coal when retorted with oil yielded a coke . This led the writers to believe that by mixing a lowrank coal ( sub-bituminous or even lignite ) - with asphaltic oil and retorting it, a coke suitable for domestic fuel could be made . Thus there was contemplated the production of domestic coke and the utilization of a low- grade oil in one operation . - In order to decide on the practicability of this process , it was necessary to know the value of products obtainable by such a method , as compared with those obtained by separate distillation . A laboratory method was therefore devised , and while it was realized that no small - scale testing apparatus for destructive distillation gives results that are directly applicable to commercial - scale operations , by keeping distillation conditions uniform for comparative tests , results were obtained valuable for purposes of comparison . The plan was to distill mixtures of coal and oil in a laboratory retort , and then distill the constituents separately under the same conditions . The comparative quantities of products yielded were thus directly obtained , and their quality was determined by analysis . The following are the main points investigated : ( 1 ) Quantity and quality of coke ; ( 2 ) Quantity of oils boiling below 221 °C . ( gasoline stock) and oils boiling at 221 to 300° C . ( kerosene stock) ; and ( 3) Quantity and quality of gases .

Jan 1, 1922

By Wilbur I. Duvall, S. L. Windes, Leonard Obert

"Previous investigations, too numerous to be listed in entirety, have been performed to determine the physical properties of rock. When considered according to their objectives, most of these investigations can be grouped as follows: First, the geologic group (1,2),4/ in which the purpose was to obtain information on the physical properties of the rocks that make up the earth's crust. Particular emphasis has been placed on the determination of the elastic constants--that is, Young's modulus, the modules of rigidity, and Poisson's ratio – as these quantities determine the propagation characteristics of seismic waves. Second, the structural properties group (3 - 11), in which the physical properties of architectural or monumental stone, concrete and aggregate rock, road blocks (cobblestone), and the like were desired. The tests have been quite general and include, besides the elastic properties; the compressive and tensile strength, and the toughness, hardness, and weathering properties of many types of rocks.To .a lesser degree, investigations have been carried out to determine the physical properties of mine rock. A few reports (12 - 14) present data on the crushability and grindability of mine rock, and a large number of papers discuss grinding and crushing procedures and methods of analyzing the data (for example, see references 15 - 17). Some of the latter group also have given the results of tests on mine rock; however, comparatively few include an adequate petrographic description or information on other physical properties of the rock. A few papers,(18 - 22) have reported studies of the strength of rock specimens in respect to the strength of parts of mine structures, such as pillars, roof, arches, etc. Other papers (23 - 26) have discussed investigations on such subjects as primary and secondary crushing, diamond and pneumatic rock drilling, explosive breaking and shattering of rock, rate of drifting and miring, and other allied problems. The majority of these reports have given no more than a cursory, description of the rocks and have included no statement regarding the physical properties. When statements have been given regarding the physical properties, they have usually referred only to isolated tests, making correlations between variations in the physical properties and variations in the .test under consideration difficult, if not impossible. Some reports have included handbook values on such characteristics as the crushing strength, hardness, and toughness. This practice is not satisfactory, because these values are usually given for col¬lective types of rocks, such as granites, limestones, and marbles, and it is known that the variations of the physical properties within these groups is often larger than the differences between the groups."

Aug 1, 1946

By T. T. Campbell

This report traces the development of techniques for the preparation of high-purity rare-earth metals. Rare-earth metals, excepting samarium, europium, and ytterbium, were prepared by converting their oxides to anhydrous chlorides or fluorides and reducing the rare-earth halides with active metals such as lithium or calcium. High-purity, anhydrous rare-earth chlorides were prepared by dissolving the rare-earth oxides in hydrochloric acid to form hydrated chlorides and by subsequently dehydrating the hydrated salts in the presence of ammonium chloride at temperatures ranging from 70° to 360° C. while under reduced pressure (50 microns to 1 inch Hg). The chlorides were also prepared by direct chlorination of rare-earth oxide-carbon mixtures. Reaction efficiencies in excess of 95 percent were obtained by either method; however, purer chlorides were prepared by the aqueous ammonium chloride conversion method. Purification of yttrium chloride by high-temperature vacuum distillation proved to be an effective method of separating, oxygen-bearing compounds from the chloride. Yttrium metal prepared from purified chloride contained significantly smaller amounts of oxygen (990 p.p.m. oxygen in yttrium metal prepared from raw chloride and 200 p.p.m. in that prepared from distilled chloride).

Jan 1, 1961

By G. H. West, R. L. Sebastian, W. A. Darror

"This bibliography was compiled in the course of research work by the Bureau of Mines on the utilization of magnesites in the West. The results of the research will appear as a bulletin of the Bureau.1. ANALYTICAL METHODS. 11 Knight, X. and Wheeler, W.H. Proc. Iowa Acad. Sci., 13, 1907, 167 (C.A.1, 1370). Describes experience in analysing calcite and dolomite. Reports great excess of oxalate unnecessary and separation of sulphates by alcohol is best.2 Meyerhofer, J. Zeit, Angew. Chem., 21, 1908, 592. Direct determination of Mg as phosphate after removal of SiC2, by keeping R203 in solution with ammonium citrate.3 Merckschen Guano Phosphat Werke. Chem. Ztg., 33, 1909, 545 (C.A. 3, 2281). volumetric analytical methods.4 Popel, M. Zeit. Angew. Chem., 21, 1908. 2082 (C.A, 6, 412). Determination of CaO in presence of CaC03.5 Blasdale, W.C. Jour. Am. Chem. Soc., 31, 1909, 91? (C.A. 3, 2658). Studies of separation of Ca from Mg.6 Hundeshrgen, F. Zeit. Offent. Chem., 15, 1909, 85 (C.A. 3, 1853). Valua¬tion of caustic magnesia by analysis. Volumetric methods.7 Frerichs, H. and Krosberg, W. Apoth. Zeit., 24, 1909. 679 (C.A. 3, 2996). Tecting magnesia alba for Fe.8 Schoorl, N. Zeit. Anal, Chem., 48, 1009, 593 (C.A. 4, 5E9). Microchemical tests for Mg, Li, K. and Na.9 Heyer. Chew. 2Ag., 33, 1009, 1157 (C.A. 4, 1588). Determination of CaO in presence of CaCO3. CaCO3 in soluble in cold neutral solution of NH3 salts. Solubility Is diminished by free NH4OH."

Oct 1, 1923

By L. J. E. Hofer, J. L. Snyder, J. N. Barn, J. E. Chilton, W. E. Thomas

Various silicone materials have been proposed for use in mining environments. The catalytic methane sensors now employed are poisoned by silicone vapors. Activated charcoal and carbon cloth adsorbents will increase the sensor lifetimes in an environment containing significant silicone vapor concentrations. The results of a study of catalytic methane sensor operation with adsorbent materials in hexamethyldisiloxane-air mixtures are reported. Sampling techniques developed for measuring silicone vapor content of mine atmospheres are described.

By R. L. Grant

[p(,ton~to'rs 'ar-IV uscG.. to explode 9crnli .... sible c}:plosivcs, dynamites, or other hiGh uxplosives. This ?,...!xplosion or detr)nation is brought about by th\.:J energy which i liberated as a cOl":"Lb' nation of concusBion and heat wl1en the ? detonator is fired. 'm Ot:18t? I'l(jrds~ liThe detonator is the key VI: ich unlocks the enerGY of a llgh? explosIve""? (8) :1/. Being sensitive nd latently dangerous, detonators ITl.ust lTIeet t\V0 primary requirerDentr: They must be ..;.afe to handle and IT. list? detonate' when (l,esired, the ... eby iIr.parting deton:l.tion to the explo8ivc cJ.1Cire-e.]

Jan 1, 1941

By Robert H. Essenhigh

A stirred reactor (SR) combustion system has been developed to gather information on the mechanisms of ignition and flame propagation of coal dust under conditions similar to those found in coal dust explosion flames. The prime scaling variable considered in this study is that of rapid particle heating (between 105 and 106°K/sec) which is accomplished by means of turbulent mixing during combustion. The SR combustors tested in this study have consisted basically of spheres hollowed in the centers of refractory housings. Coal and air mixtures have been injected into the spherical combustion chambers through a single jet, two opposed jets or four opposed jets. The diameters of the jets have ranged from 0.63 to 0.22 cm. The volumes of the combustion chambers have ranged from 1.0 to 0.2 liters. The reactors have been equipped with thermocouples embedded in the combustion chamber wall as well as a thermocouple located in the exhaust gas stream. In the latter versions of the SR, provisions were made for both solid sampling and gas sampling of the reactant stream exiting from the combustion chamber. Experiments have been carried out using pulverized bituminous coal. The coal has been reacted in an SR in mixtures of air and air/nitrogen. These experiments have provided information on the mode of ignition of the coal as well as yielding information on the kinetics of coal pyrolysis through the use of SR theory. Ash tests performed on the reacted samples collected from the SR indicated that the majority of the values of weight loss percentage were between 60 and 70 percent. The percentages of weight loss were relatively unaffected by changes in temperature which varied between 1100 and 1700°K and by changes in residence time which varied between 10 and 20 millisec. Volatile matter tests performed on the samples indicated that the volatile matter left in the char ranged from 3 to 20 percent of the original content. By assuming that all the mass loss was due solely to pyrolysis with no combustion occurring at the particle surface, Q-factors for each test have been calculated. The results of these calculations indicate an average value of Q equal to 1.88. This finding shows that the majority of mass loss can be attributed to pyrolysis. The fact that the extent of reaction varies only slightly over the range of test conditions has been examined in the context of the two component hypothesis of coal constitution. This approach leads to the conclusion that the reaction of the "easily evolved" component VMI is extremely rapid and that the majority of it is removed from the coal in times less than the residence time in the system. This means that the volatile residue remaining in the char can be considered to consist of component II, VMII. If the mass fraction of VMI = 0, then an activation energy of 18.0 kcal is obtained for the pyrolysis reaction. If the mass fraction is assumed to be 0.75, the activation energy increases to 31.2 kcal.

Jan 1, 1978

By F. P. Haver

The purpose of this investigation was to determine the effect of common impurities, that is, oxygen, nitrogen, carbon, and iron, on the Brinell hardness of electrolytic titanium. On a weight basis, nitrogen had the greatest hardening effect, followed by oxygen, carbon, and iron in order. The hardening effects of oxygen and carbon were almost identical up to a concentration of approximately 0.1 percent by weight. Above this concentration, the relative hardening effect of carbon decreased rapidly, possibly because of its limited solid solubility in a-titanium. Hardness vs. composition curves for both oxygen and nitrogen were essentially straight lines over the range of Brinell hardness numbers (B.h.n.) covered in the investigation. The hardness of titanium was also determined as a function of the percentage of impurity atoms. On this basis, iron in concentrations up to 0.17 atomic percent had a greater hardening effect than either oxygen or carbon. INTRODUCTION Determination of the as-cast hardness of arc-melted titanium is a method of quality control widely used in industry. Numerous studies4/ have been made of the effect of impurities on the hardness obtained by this method. However, most of them have been based on the use of either iodide titanium or commercially pure Kroll sponge (B.h.n. >90), as a starting material.

Jan 1, 1959