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By Raymond M. Stateham

Calculations based on data obtained from measurements of smoke from coal-fired powerplants predict that infrared imagers will be useful tools for smoke vision. Infrared imagers operating in the 3-to 5-um spectral region have been evaluated for this purpose. A mine opening 110 meters long was filled with smoke from burning coal, and two men, wearing breathing apparatuses, moved through the smoke to serve as targets. The men were detected and identified at 80 meters.

Jan 1, 1976

By Kenneth G. Broadhead

The objective of this rare-earth oxalate study by the Bureau of Mines was to determine systematically by radiochemical techniques what effects, if any, could be attributed to the several variables--temperature, digestion time, acid concentration, rare-earth concentration, oxalic acid concentration, stirring, and the presence of other rare-earth ions. A Latin Square experimental design was used to evaluate statistically some of the variables. Precipitation losses ranged from near zero to about 7 percent, and mineral acid and rare-earth concentration were the predominant factors affecting completeness of precipitation. Quantitative oxalate precipitation of the rare-earth elements was achieved by controlling the experimental conditions as follows: (1) Maintaining rare-earth concentrations above 0.01M; (2) stirring the mixture several minutes after precipitation; (3) using an adequate (two to five-fold) excess of oxalic acid; (4) precipitating at room or iced temperature and digesting for at least 1 hour; (5) avoiding an excess of mineral acid and, if possible, maintaining the pH above 2.0; and (6) avoiding excess complexing agents such as EDTA (ethylenediaminetetraacetic acid). In the past 20 years research aimed at developing more efficient separation and purification techniques applicable to the rare-earth elements and yttrium has been extensive. Common to most of these procedures has been the use of oxalic acid to precipitate this group of elements selectively. However, this particular use of oxalic acid has a much earlier origin; its application in precipitating yttrium was first reported by Mosander (8)4 in 1843. Despite long and popular employment of this technique, only limited and somewhat conflicting data are available regarding the many factors affecting the degree of rare-earth oxalate precipitations.

Jan 1, 1961

By P. M. Ambrose, C. Travis Anderson, Cresap Moss, R. S. Dean

"MANGANESE METALMethods of PreparationMethods of preparing the manganese metal that has been used in chemical and metallurgical investigations have passed through a cycle. Most of the investigations made before the turn of the century used Moissan's pyrophoric manganese. 5/ This material was made by electrolysis into a mercury cathode and distillation in vacuo. It was essentially a pure material, and investigations in which it was employed (with proper precautions against oxida¬tion) led to accurate results concerning the intrinsic behavior of metallic manganese.An early investigation of the properties of ""Manganese-by-Mercury"" was made by M. Guntz. 6/ He prepared manganese by electrolysis of a concentrated MnCl2 solution with a mercury cathode. The manganese amalgam was pressed through chamois and distilled in vacuo (2 to 3 cm. of mercury) at 200°0., slowly rising to 250°0. Guntz recognized especially the decreased reactivity of manganese with increased temperature of mercury distillation. The most careful and com¬prehensive study of manganese made by this method is that of Kuh 7/ whose work unfortunately was never published in an accessible journal.Royce and Kahlenberg 8/ studied the electrode potential of manganese made by this method."

Nov 1, 1939

By D. Harrington

The coal-mining industry of the United States finds difficulty not only in making ends meet financially but also in operating with anything like reasonable safety. The record to date has not been particularly good as to either finance or safety, but at least in some phases or safety there are indications of better times to come. During the fiscal year ending June 30, 1929, only 139 lives were lost in explosions in our mines as against 342 lost during the fiscal year ended June 30, 1928; this decrease in such fatalities is definitely a matter for satisfaction. During the fiscal year July 1, 1928, to June 30, 1929, the attention of the safety division of the U. S. Bureau of Mines was directed to 38 mine explosions in the United States. Two explosions were in non-coal mines, one in a semianthracite mine, two in anthracite mines, and 33 in bituminous mines. These were not all major explosions - that is, explosions in which five or more lives were lost; in some of the explosions no lives were lost, while in others fewer than five fatalities resulted. Table 1 gives data on the explosions, showing the number of mines using open or closed lights and the number of explosions with resulting deaths, by causes, for each State.

Jan 1, 1929

By Fun-Den Wang

Rock bolting has become a major method of coal mine roof support because of its effectiveness, economy, and convenience. The polymeric-resin-bonded bolt has generally proved to be more effective than the mechanically anchored bolt, but the higher cost of the resin bolt limits it to applications where the increased support is essential. The low-cost high-early-strength cement grout developed during this project will encourage more widespread use of fully grouted roof bolts provided practical installation techniques can be developed. Laboratory tests of four types were performed on various rapid-set and accelerated cement products to find a material with properties suitable for replacing resins. A proprietary gypsum cement was ultimately used with good success. A field test of the cement grout was made in an operating coal mine. An intersection was bolted in the standard pattern with cement-grouted bolts and instrumented. A nearby resin-grouted intersection was also instrumented and observations were carried out in both intersections for 2 months. No substantial difference was found between the support provided by the cement and the resin.

Jan 1, 1976

By Frank E. Cash, John A. Johnson

"INTRODUCTION The operators of the Lake Superior district iron-ore mines have made tremendous progress in the past 25 years in the transportation of broken ore from the working places to the surface. This progress has paid divi¬dends in increased production and in lower accident-frequency rates. The trend has been toward more efficient use of mechanical and electrical power and abolishment of many of the backbraking tasks formerly required of min¬ers and trammers.ScopeTransportation of iron ore as described in this paper covers (1) movement from the working place to ore raises by scrapers, shaker,conveyors, and belt conveyors, and, loading underground cars from chutes or-by scraping from loading drifts; (2) underground haulage, which includes underground cars trains, locomotives, and tracks; (3) shaft station's and hoisting shafts, which. Includes dumping cars, storage-pockets; auxiliary storage trenches, and shafts; (4) hoisting, which consists of skips, cages and hoists; and (5) head frames, loading into railroad cars, and stock-pile haulage.The 19 underground iron-ore mines discussed in this paper, situated in the Menominee, Marquette, Gogebic, Guyana, Mesabi, and Vermilion iron ranges of Michigan, Wisconsin, and Minnesota., shipped about 9,000,000 tons of iron ore in 1945, which constituted 56 percent of the underground iron ore taken from the Lake Superior district."

Nov 1, 1947

By Terry J. Close

The Gates of the Mountains Wilderness study area is underlain by intrusive and sedimentary rocks, mainly limestone. No limestone has been produced from the study area; suitable material is more readily available elsewhere. Small amounts of gold, sapphires, and corundum were produced from a placer deposit along the banks of the Missouri River. The remaining gravel contains low mineral values. Other alluvial deposits along the Missouri River and Beaver Creek contain no identified economic resources other than sand and gravel. Some deposits could provide suitable construction material for local use.

Jan 1, 1984

By John R. Hoskins

Uniaxial compressive strength of rock is usually determined in the laboratory from cylindrical samples that vary in diameter from 5/8 to 8 inches, using a spherically seated compression head of unspecified size. The Bureau of Mines conducted a series of tests on limestone, marble, sand-stone, granite, and plaster of paris to determine the influence of the spherical head sizes and the specimen diameters themselves on the uniaxial compressive strength. Cylindrical samples of several different diameters of each rock type, all having a length of twice their diameter, were prepared and broken using at least three different diameter spherical heads. Analysis of the data shows that spherical head size does not significantly affect the uniaxial compressive strength of cylindrical rock samples. However, the diameter of the rock specimens does significantly affect the uniaxial compressive strength. Within the range of specimen diameters tested, a coefficient of variation of 6.4 percent for plaster of paris can be attributed to the selection of specimen diameter alone. Similarly, a maximum coefficient of variation of 4.7 percent for the rock types tested can be attributed to the specimen diameter alone.

Jan 1, 1969

By Harry Freund

Gallic acid is a sensitive, stable, colorimetric reagent for the determination of tantalum in the range of 2 to 40 µg.Ta/ml. The method consists of the fusion of tantalum oxide with potassium pyrosulfate and solution of the cooled melt in satu-rated ammonium oxalate, followed by development of a yellow complex with an ethanolic solution of gallic acid. The tantalum-gallic acid complex absorbs over a broad region in the blue and near ultraviolet. Adverse effects due to interfering ions and solution conditions, such as oxalate concentration and pH, can be minimized by a suitable choice of wave length. A new and sensitive colorimetric method is provided that has been used successfully at the Northwest Electrodevelopment Laboratory of the Federal Bureau of Mines for determining minor amounts of tantalum.

Jan 1, 1956

By Alla D. Mah

Energies of combustion of vanadium nitride (VN) and vanadium carbide (VC) were measured. Correcting to vanadium tetroxide (V204) as the final state, the heats of combustion were ?H298.15=-118,700±100 cal/mole of vanadium nitride and ?H298.15=-240,270±360 cal/mole of vanadium carbide. With vanadium pentoxide (V205) as the final state, the heats of combustion were ?H298.15= -133.440±100 cal/mole of vanadium nitride and ?H298.15=-255,020±360 cal/mole of vanadium carbide. Combining these results with vanadium oxide data, the heats of formation obtained were ?298.15=-51,880±200 cal/mole of vanadium nitride and ?H298.15=-24,350±400 cal/mole of vanadium carbide. Heats and free energies of formation of vanadium nitride and carbide were calculated to 2,000° K.

Jan 1, 1963

By Florence L. Feicht, Carlton E. Brown

"INTRODUCTION This report contains information on the approximate size of the smallest dust Particles revealed by or the limit of visibility of various microscopic systems. The information was obtained mainly for use in interpreting and evaluating results of number-contentration and particle-size, determinations on, samples of unhygienic particulate matter collected from industrial atmospheres and in developing better methods for determinations nations.Some speculation and even controversy have been published on the limit of visibility of the widely used microscopic system (16-mm., 0.25-or 0.3-N.A. objective, and axial light-field illumination) used in counting the dust in the liquid medium from impinger, 4/ 5/ filter-paper, 6/ and other samples, but little or no quantitative data have been published on the limits of visibility of this or other microscopic' system.ACKNOWLEDGMENTSThe interest, encouragement, and assistance received from H. H. Schrenk, chief of the Health Division are gratefully acknowledged, as is all other assistance received in this study."

Aug 1, 1945

By Bruce Cantrell, K. L. Rubow

"INTRODOCTIONMeasurement of the contribution of diesel exhaust to respirable aerosol in mine environments has become increasingly important because of current concerns over the occupational health effects resulting from exposure to diesel emissions. In response to this, the U.S. Bureau of Mines is developing and evaluating new sampling methods for measuring diesel aerosol in underground mines. Two such techniques are being studied by the Bureau, size selective sampling and Chemical Mass Balance (CMB) modeling. These techniques use measurable physical or chemical characteristics of a mine aerosol sample to infer the amount of diesel particulate material contained in the sample.Size selective sampling is being adapted for measurement of diesel aerosol by the Particle Technology Laboratory (PTL) of the University of Minnesota under sponsorship by the Bureau. 1 It is based on the premise that diesel and mineral dust aerosol can be physically separated by size and collected during sampling using inertial impaction. An independent effort by the National Institute for Occupational Safety and Health to develop a size selective sampling technique was also sponsored by the Bureau.The second technique, CMB modeling, is being developed by the Bureau as an alternative measurement technique to referee the results obtained using size selective sampling.3 It compares measured trace element ""finger prints"" of aerosol sources with similar profiles of mine aerosol samples. From these, the portions of the sample contributed by each source can be determined. Results of these investigations in underground coal mines have confirmed that diesel and coal dust aerosol are of different size and can be measured separately using size selective sampling techniques.A major difference in diesel usage among underground mines is the requirement for exhaust gas cooling systems in coal and gassy noncoal mines. Nongassy mines usually employ limited exhaust conditioning in the form of catalytic converters, which have limited effect on primary exhaust particulate. The cooling system in most general use in gassy mines is the water scrubber. This device has little effect on most of the gases but removes particulate material from the exhaust. 5 Because of this, exhaust aerosol characteristics in nongassy mines are expected to be different. To see if size selective sampling techniques can be used in such mines, the Bureau and the University of Minnesota conducted a second study in three metal and nonmetal mines, two nongassy and one rated as gassy."

Jan 1, 1990

By Raymond B. Ladoo

Silica , or silicon dioxide , ( Si0, ) , occurs in a free state chiefly as quartz , but hydrous silica ( amorphous silica carrying a variable amount of combined water , 2 to 13 per cent ) , occurs as opal , flint , diatomaceous earth , tripoli and so on . Quartz is found in many forms , the most important of which are ; As vein quartz; quartzite ; sandstone ; silica sand and gravel ; as crystals or crystalline grains , masses or aggregates in igneous rocks such as granites , dicrites and pegmatites . Commercially silica is used in many ways , but ordinary uses of sand and gravel are so well known that they will not be considered here .

Jan 1, 1922

By Ralph H. Espach

The value of careful fractionation in the manufacture of petroleum products is recognized more and more by petroleum refiners. Recent studies have shown that the quality of the products depends largely on the type of fractionating equipment and on the care used in operating the equipment. For example Rue3 has shown that careful fractionation of pressure distillate will greatly reduce the amount of chemical treatment necessary to produce finished gasoline. The advantages of the combination of pipe still and bubble tower in obtaining good fractionation are well recognized in the petroleum industry. However, the equipment designed in the past has in general been much too large for convenient laboratory use. The present paper describes a continuous-distillation apparatus for the laboratory study of fractionation. This apparatus has given very satisfactory results in the study of different crude oils and petroleum products. A discussion of the theory and action of bubble towers has not been given, as this subject has been discussed previously by Cooke and Rue4. It is believed that the distillation curves of the products obtained from this apparatus show clearly its capabilities.

Jan 1, 1928

By L. C. IlsLey

The cool drills that have received the approved of the Bureau of Mines may be divided into three general classes: (1) Hand drills, small drills that are held in the hands or supported against the body while in use; (2) post drills, drills that are too heavy or powerful for hand operation and therefore require some mechanical mounting when in use; and (3) drilling machines. Besides these three classes, drilling equipment has been incorporated in the design n of a number of permissible coal-cutting machines, but such drills are considered an integral part of the cutting machine and are not given separate approval. The hand drills have been described in Report of Investigations 3363, which is cite of several papers that have been published dealing with miscellaneous types of permissible motor-driven mind equipment not covered in bulletins. The present paper describes post drills and drilling machines approved by the Bureau of Mines up to July 1, 1937.

Jan 1, 1938

By C. E. Armantrout, H. Kato, M. I. Copeland

The data collected during this investigation indicate that the chromiumgadolinium system has extensive liquid immiscibility and one eutectic point . Liquid immiscibility occurred at temperatures above the monotectic isotherm , 1,830 ° C , which extended from less than 0.25 to about 85 weight - percent gadolinium . The eutectic was at 96 percent gadolinium and 1,170 ° C. Gadolinium and chromium were the only phases in this system . There was a solid solubility of less than 0.25 percent gadolinium in chromium at 1,730 ° C and less than 0.10 percent chromium in gadolinium at 1,160 ° C. The alloys were prepared by nonconsumable - electrode arc - melting , and the alloy system was investigated by heat treatment , metallography , thermal analysis , and X- ray diffraction . All the melting , heat treatments , and thermal analyses were conducted in a vacuum or in helium because of the reactivity of chromium and gadolinium with the components present in the atmosphere at elevated temperatures .

Jan 1, 1964

By Jr. Holmes

The Bureau of Mines drilled and sampled the more important magnesite deposits in the Currant Creek Mining District, White Pine County, Nev. The properties of the Ala-Mar Magnesium Co., Inc., and the Nevada Magnesite Co. were examined in August 1942 by D. W. Butner, engineer of the Bureau of Mines, to determine the advisability of investigating the deposits under the strategic minerals program. Development involving diamond drilling, trenching, and sampling was started September 1, 1942, and was completed in the latter part of November 1942. The deposits are on unsurveyed public land in T. 12N., B. 59 E., M.D.B.&M., in an area of high relief ranging from 7,300 to 8,100 feet in altitude. Both properties are situated northwest of the Tonopah-Ely Highway, U.S. Highway 6, from which a dirt road extends about 4.6 miles northwesterly, about 35 miles southwest of Ely, to the Ala-Mar property, and another dirt road extends about 10 miles westerly, about 26 miles southwest of Ely, to the Nevada Magnesite property. The magnesite occurs as irregular nodules, veins, and lenses in a bedded calcareous tuff formation, which overlies a group of volcanic rocks, and which is capped by remnants of rhyolite flows.

Jan 1, 1950

By George T. Motock

In Germany the extraction of lithium and its salts has been handled mainly by units of the two major concerns - Metallgesellschaft A, G. and Deutsche Gold und Silber Scheide Anstalt, both with headquarters in Frankfurt. Zinnwaldite, which belongs to the mica group, is the major source of the lithium-containing raw material in Germany. Lepidolite and amblygonite also are used when available, but they are imported, as there are no major deposits of these two minerals in Germany.

Jan 1, 1946

By W. W. Adams, T. D. Lawrence

"A. larger enrollment and a greater number of man-hours of employment by the enrolled companies were the outstanding features of the National Safety Competition of 1942, an annual safety contest conducted by the Bureau of Mines, United States Department of the Interior, for the promotion of safety among workers in the mines and quarries of the United States. The accident-frequency and accident-severity rates were somewhat higher than in 1941, but the frequency of accidents in relation to the number of man-hours worked was strikingly lower than in the earlier years of the 18-year period during which the contests have been conducted.Companies that enroll in the National Safety Competition compete for a bronze trophy known as the ""Sentinels of Safety."" Six of these trophies are provided by THE EXPLOSIVES ENGINEER annually for award by the Bureau of Mines. The trophies for 1942 wore won by an anthracite mine in Pennsylvania, a lignite mine in North Dakota, an underground metal mine in Tennessee, a limestone mine in Ohio, an open-cut metal mine in Minnesota, and a lime-:tone quarry in Pennsylvania. The trophies are presented to the companies for 1 year and are then transferred to the winners of the succeeding year's contest.The contest rules state that a mine or quarry must have at least 25 men employed underground or in the pit for at least 100 days, and the plant must be in operation 30,000 or more man-hours to be eligible for a trophy. The rank of mines and quarries is determined by accident-severity rates, or, in the case of accident-free records, by the number of man-hours worked."

Oct 1, 1943

By James M. Spear

The U.S. Bureau of Mines conducted a mineral survey of the Domeland Addition (5207) and Woodpecker (5206) RARE II areas during the summer of 1979. These study areas were examined to determine the presence or absence of mineral resources and reserves and where possible, to estimate values. The study areas are 9 air mi northeast of Kernville, California, and encompass 47,400 acres of primarily granitic rocks of the Sierra Nevada batholith with some scattered exposures of older metasedimentary, volcanic, and metavolcanic rocks. These other rock units partially surround the exposed batholith in the Domeland Wilderness and consist mostly of late Paleozoic quartzites, mica schists, marbles, and meta-volcanics, Mesozoic quartz diorite and gabbro intrusives, and local Tertiary basalt and andesite flows.

Jan 1, 1981