Search Documents

By Maurice Deul

A special short-term research project was initiated to develop plant design parameters for treating mine waters to yield an effluent acceptable for discharge into streams and a sludge amenable to effective and economic disposal. Neutralization was investigated to provide simple and direct treatment of ferruginous acid waters using lime; coarse limestone, and limestone followed by lime. Limestone treatment was accomplished using a small cement mixer as a simple reactor to provide abrasive agitation of limestone and mine water. Results from tests with nine mine waters encompassing a wide range of iron and acid concentrations showed that coarse limestone, one of the cheapest neutralizing agents known, is potentially useful for treating mine water discharges. However, process variables must be defined more completely before the practical applications and limitations of the process can be fully established. In all the tests a pH of >7.2 was obtained ultimately with limestone. Reaction time to reduce the iron content below 7 ppm in the water was dependent on the original ferrous iron concentration. For waters with high ferrous iron content, treatment with limestone followed by lime rapidly produced an acceptable treated water, Sludges with good settling and handling characteristics resulted when limestone was used for neutralization either alone or with subsequent treatment. Reaction rates are expressed graphically as pH change and iron depletion curves; characteristic solids settling curves are shown. The temperature dependency of ferrous iron oxidation was verified.

Jan 1, 1967

By J. E. Conley

Available statistics show that the demands of the American chemical industry for sodium sulphate have been increasing slightly in recent years. The supply from domestic sources, particularly In the form of byproduct salt cake from the acid manufacturers, has been tending to decrease due to the growing manufacture of synthetic acid. Both hydrochloric and nitric acids are being synthesized from their elements. The natural result has been that a smaller amount of salt cake is available. Simultaneously, the expansion of the Kraft paper industry, especially in the South, has brought about greater demand for sodium sulphate in that section. This dean is being met by domestic byproduct salt cake, by imported German sodium sulphate made from potash waste liquors, and by favorable situated domestic deposits of Glauber salts and tile anhydrous salt, thenardite. No shortage of natural sodium sulphate exists in the United States, but usually such deposits occur in semiarid regions far removed from transportation facilities and from markets. Moreover, the major portion of the natural deposits is Glauber salt or mirabilite (Na2SO4 ? 10H20), which must be dried or dehydrated in order to meet consumer requirements. The water of hydration represents, roughly, 55 percent of tae total weight of the crude salts and therefore has a very important influence on transportation costs. In marry instances the cost of getting, even the dehydrated product to market is the deciding economic factor. Therefore, the recovery oil production of anhydrous sodium sulphate from plant-.waste liquors or from natural brines of suitable composition might be economically feasible. The U.S. Bureau of Mines, at its nonmetallic Minerals Experiment Station, New Brunswick, N. J., has, for a number of rears, been investigating the commercial possibilities of treating the complex saline mineral polyhalite (K2SO4?NgSO4?2CaSO4?2H20) for the recovery of potash and magnesia. Certain proposed processes (1, 2, 3, 4)4/ yield waste liquors that contain the bulk of the magnesium and sulphate originally combined as magnesium sulphate in the polyhalite molecule. Sodium chloride In limited concentrations is also present, as extensive beds of salt occur in strata overlying the polyhalite deposits. A typical waste liquor would contain:

Jan 1, 1936

By N. A. C. Smith

The Bureau of Mines motor gasoline surveys have been conducted in January and July, during 1920 and 1921. The Bureau has obtained and analyzed samples of gasoline representative of that marketed in the larger cities. These surveys have indicated that the gasoline on the market during the winter months is more volatile than that sold during the summer months. Naturally, the motorist desires a more volatile gasoline in the cold winter months, as it affords greater ease in starting. The fourth semi-annual motor gasoline survey, conducted during the month of July, shows an interesting relation between the market price and the quality of motor gasoline. This is particularly evident if figures obtained today are compared with those of a year ago. At the time the Bureau of Mines conducted its summer survey of motor gasoline last year, the average tank wagon price of gasoline was 28.2 cents per gallon. This year it was 21.2 cents, a drop of practically 25%.

Jan 1, 1921

By R. Lincoln

A surplus of vanadium has resulted from the tremendous output of uranium, of which vanadium is a byproduct. More knowledge of the properties and characteristics of vanadium as a pure metal has been needed so that industry can take advantage of its availability and use it according to the best principles of conservation. Besides the problem of utilization, there is the ever present need of finding new materials which will satisfy specific and demanding requirements of science and engineering; vanadium or one of its alloys may possess the latent potential for filling some of these needs. Thus this? research project was undertaken by the Bureau of Mines to determine and examine some of the physical and mechanical properties of pure vanadium. A corallary investigation was the determination of the effect of the interstitial contaminants, oxygen, nitrogen, and carbon, on unalloyed vanadium. The vanadium used for these determinations was principally the product of experimental production of the Bureau. The evaluation of this material, as small quantities became available, provided most of the data that have been obtained.

Jan 1, 1962

By L. B. Pankratzt

The heat capacity of dimo1ybdenum carbide (Mo2C) was measured from 51° to 298° K, and the entropy at 298.15° K was evaluated. Heat content measurements above 298.15° It were conducted for dimolybdenum carbide (M0caY) and monotantalum carbide (TaC). The results were combined with known heats of formation and the 298.15° K entropy for TaC to obtain values of the heat and free energy of formation from 298.15° K to 1,400° K for MoaC and from 298.15°K to 1,800° K for TaC.

Jan 1, 1966

By E. R. Palowitch

Two samples of the Lower Hartshorne (Spadra) bed were collected: A sample of the raw coal with the machine cuttings excluded, and a sample of the machine cuttings exclusively. Analysis of the 5-inch by 200-mesh size fraction of the raw coal, excluding machine cuttings, showed that a product meeting minimum quality specifications could be produced by washing at 1.60 specific gravity, yielding a theoretical 93.7 percent of clean coal. A negligible amount of near-gravity material at the separation gravity indicated an easy washing problem. The sample of machine cuttings had a maximum size of 2 inches and contained about 50 percent ash. Washability tests of the 2-inch by 200-mesh size fraction indicated that a theoretical yield of 30.0 percent of specification-grade coal could be achieved by washing at 1.49 specific gravity. As the machine cuttings represent an estimated 10 percent of the total coal mined, their inclusion in the mine output would increase the theoretical net yield of salable coal by only 3.7 percent. Because the machine cuttings contained a high percentage of sink 1.80 specific-gravity material, they had neither an effect on the separating gravity required to clean the raw coal nor on the difficulty of separation. Gabbing underground versus transporting the cut-tings to the surface for disposal or washing either separately or combined with the raw coal involves a number of practical, economic; and intangible factors; hence, no specific recommendations could be made. A discussion of some of the factors involved in dealing with a similar problem is given by Gandrud and Riley.4

Jan 1, 1962

Reduce dust on long wall faces by using a gob curtain to lower air leakage Into the gob and raise the airflow along the face. Approach A brattice curtain (gob curtain) Is hung between shield #1 and the rib in the headgate entry forcing the ventilating air stream to make the 90° turn and stay on the face side of the shields rather than leaking into the gob. How It Works Air leakage is greatest in the headgate area because the gob behind the first few shields remains open due to the roof bolts in the headgate entry. In addition to the open gob, there is a large gap between shield #1 and the rib. Prevention of air leakage behind the shields is accomplished by the Installation of a curtain between the first shield and the rib extending from the roof to the bottom. The curtain Is advanced with the shield line each pass and is helpful In maintaining a sufficient air quantity along the face. The biggest Improvement due to this curtain is seen in the first 25-30 shields where the Increased air volume lowers dust concentrations through dilution.

Jan 1, 1981

By W. S. Sanner

Anthracite was used extensively as a fuel in iron metallurgy from 1840 to 1880. In 1874, 226 of the 680 blast furnaces in the United States were operating on anthracite and producing almost one-half of the Nation's pig iron. However, by 1890, railroad expansion, the development of western iron-ore reserves, and the growing use of coke decreased the importance of anthracite as a metallurgical fuel. As a result, the last blast furnace designed exclusively for anthracite use was built in 1891. Because of the increased energy requirements of our expanding national economy, the abnormally high demands during national emergencies, and the proximity of anthracite deposits to eastern steel-producing areas, interest has grown in again using anthracite in iron metallurgy. Estimates of anthracite reserves indicate a 300-yr. supply at a production rate of 30 million tons per year. These large reserves dictate the development of an adequate technology for the use of anthracite by the metallurgical industry.

Jan 1, 1961

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By J. C. Judd

The Bureau of Mines investigated the recovery of vanadium, uranium, and phosphorus from low-grade phosphorite ores and concentrate by leach-ing with H2S04. Samples containing 0.12 to 0.23 pct V20S, 0.009 to 0.012 pct U30S and 18 to 30 pct P20S were treated by batch-agitation leaching, roasting followed by acid leaching, salt-roasting followed by acid leaching, and leaching under pressure. Maximum recoveries using leaching alone ranged from 78 to 98 pct of the V20S and 74 to 88 pct of the U30S-Leaching under pressure resulted in extractions of 88 to 95 pct of the V20S and 84 to 89 pct of the U30S. Leaching following roasting--with or without NaCI--produced extractions of 97 to 99 pct of the V20S and 86 to 91 pct of the U30a. Depending on the technique(s) employed, phosphate extractions ranged from 89 to 99 pct. Solvent extraction laboratory tests were conducted to selectively re-cover vanadium and uranium values from acid leach solutions. An average of 95 pct -of the U30a was recovered using di(2-ethylhexyl) phosphoric acid, plus trioctylphosphinic oxide. Essentially all of the V20S was recovered with octylphenyl acid phosphate plus isodecanol. The phosphate remained in the raffinate.

Jan 1, 1986

By Steven E. Mischler, Jon C. Volkwein

A diesel particulate matter analyzer capable of direct, real-time measurement of engine exhaust particulate is necessary to effectively institute source control technology currently being used on diesel equipment and to ensure that the control measures are working. To investigate the potential of a differential pressure monitor to measure diesel particulate matter in undiluted exhaust, samples were collected from three different diesel engines-Kubota, Isuzu, and Deutz-running under 12 different RPM and load scenarios. These measurements were compared to elemental carbon concentrations in the sampled exhaust as determined by using the NIOSH 5040 analytical method. Elemental carbon is used as a surrogate measurement for diesel particulate matter. The results of the two data sets were then compared using a linear regression analysis. The coefficient of determination (or R2) was calculated to be 0.98, 0.94, and 0.74 for the Kubota, Deutz, and Isuzu engines, respectively. R2 values of this magnitude indicate that this method can be successful in estimating elemental carbon emissions in the engines tested. In addition, for replicate samples, the coefficient of variation ranged from 7.1% to 10.2% with an average of 8.5%. These data indicate that this method could prove useful to mechanics as they work to maintain engines and DPM control technologies.

This chapter summarizes data on crude mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are tables that show the principal mineral commodities exported from and imported into the United States, and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at 'any of several stages of extraction and processing, the stage of measurement used In this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the product of auxiliary processing at or near the mines.

Jan 1, 1977

By Keith A. Heasley, John L. Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has continued the research role of the former U. S. Bureau of Mines to develop techniques that will reduce the hazards in the mining work place associated with coal bumps. Current research focuses on both analyzing historical seismic data from bump-prone operations and utilizing a mine-wide seismic network to investigate the exact strata failure mechanics associated with bump-prone geology. The anticipated outcome of this research will be reduced bump incidences through advanced engineering concepts and designs which implement the new understanding of strata behavior. The analysis of the historic seismic data consists of correlating observed mining seismicity with the geologic and geometric parameters at the sites. The primary seismic parameters are the timing, location and magnitude of are corded seismic event. These parameters are correlated with such mining parameters as: the overburden, the size of the immediate gob, the size of the district gob area, etc. This detailed analysis of historical seismic data has provided an informative quantifiable relationship between many of the specific mining parameters and the induced seismicity. The second aspect of the coal bump research is the instrumentation of an appropriate field site to determine the main roof, floor, and gob behavior associated with bump behavior. The chosen field site is a deep-cover longwall mine with competent geology in a historically bump-prone area. The primary field instrumentation is a three-dimensional, full-waveform, seismic array with both surface and underground sensors surrounding an active multi-panel district. The purpose of this seismic array is to determine the timing, the exact location, and the mechanism (tensile fracture, bedding plane slip, etc.) of the failure of the strata surrounding the active and multi-panel gobs. The preliminary results presented in this paper help to define the strata failure areas around the longwall panel.

By Welby G. Courtney

The Bureau of Mines conducted a field test program in the Pittsburgh coal seam to investigate the effect of water sprays in the suppression of respirable dust being formed while cutting with a continuous-mining machine. Emphasis was given to the location of spray nozzles on the top and bottom of the cutting boom. Results showed that (1) sumping caused about 60 percent of the dust escaping the face area, and shearing and loading caused the other 40 percent; (2) during sumping, top and bottom sprays were equally effective in dust suppression and reduced dust ~13 percent; (3) during shearing and loading, bottom sprays reduced dust 61 percent and were about 50 percent more effective than top sprays; (4) the combination of top and bottom sprays was slightly more effective than the separate systems, but water consumption increased 60 percent; and (5) inclusion of throat sprays decreased dust reduction by removing some of the water from top and bottom sprays where it was more effective.

Jan 1, 1978

By M. O. Serbousek

The load-transfer mechanics of fully grouted roof bolts in coal mines have been investigated in laboratory and analytical studies. The purpose of this Bureau of Mines research is to increase understanding and better interpret data from routine field pull tests and to develop a numerical model of a grouted bolt that can be used in a global computer model of a mine roof. Analytical studies using closed-form solutions and finite-element techniques were compared to experimental results. Laboratory work includes variation of bolt length, hole diameter, and grouL type. Pull tests were pel'fol·med on 4-, 2-, and I-ft bolts in holes of 1-and I-3IB-in diameters. Both polyester resin and inorganic grouts were used as the anchorage medium. Strain gauges were installed on the bolts at several locations to observe the rate of load transfer from the bolt through the grout to the rock mass when a force was applied at the bolt end using standard jack pull testing procedures and equipment. The average anchorage length of 4-and 2-ft bolts was 22 in. Grout type and hole size variations did not produce a significant effect on the rate of load transfer from the bolt to the rock.

Jan 1, 1987

By D. W. Bridges

Solvent extraction has become important in recent years as a unit process in extractive metallurgy. The flexibility and simplicity of the technique have attracted widespread attention, and numerous papers describing actual and projected metallurgical applications have been published. However, differences in terminology, procedure, objectives, and standards, as reflected in reports by different operators and investigators, have sometimes made appraisals and comparisons difficult. Consequently, a need appeared for n series of basic reports on the subject. This Bureau of Mines Information Circular is the first of such a series. It deals with the status of solvent extraction in metallurgy, as well as with the rudiments and terminology of the unit operation. In analytical chemistry, extraction of molecular species from aqueous media by immiscible organic solvents has been used for many years to separate and determine chemical elements (61).4 Complex chlorides of iron and other metals are readily soluble in ethers and ketones, as are the nitrates of uranium and thorium. Most metals are extractable as complex salts of some organic reagent, such as dithizone, 8-hydroxyquinoline, or cupferron.

Jan 1, 1962

To investigate mine ventilation problems which do not lend themselves to conventional anemometer and smoke study techniques by use of SF6 (sulfur hexafluoride) tracer gas. Approach SF6 tracer gas is released in-to the air at a given mine location. By collecting air samples at various other locations and analyzing these samples for SF6, the amount of air traveling from the release location to each sampling location can be quantitatively determined. Travel time between these locations can also be deter-mined. How It Works SF6 is ideal as a mine tracer gas. It is safe, odorless, chemically and thermally stable, and it generally has no background concentration. Furthermore, it is instrument detectable at concentrations as low as 10 parts per trillion. The SF6 is generally released from a pressurized lecture bottle, and air samples are taken in syringes or evacuated bottles. During the past several years, SF6 tracer gas has been employed to study a wide variety of mine ventilation problems such as: recirculation of return air into In-take airways, air leakage from adjacent mines and gob areas, air transit times through stoped areas, airflow patterns during a mine fire, leakage of gases from an underground oil shale retort into mine workings, face area ventilation patterns, methane flows in metal/nonmetal mines following a methane out-burst, and many other problem areas. Examples of some recent uses of SF6 follow.

Jan 1, 1982

By Lloyd A. Morley, Robert Stefanko

This report was prepared by The Pennsylvania State University, College of Earth and Mineral Sciences, ' Department of Mineral Engineering, University Park, Pennsylvania, under USBM Grant No. GO-133077. The grant was initiated under the Coal Mine Health and Safety Research Program. It was administered under the technical direction of the Pittsburgh Mining and Safety Research Center with Mr. G. J. Conroy acting as the technical project officer. Mr. J. A. Herickes was the grant administrator for the Bureau of Mines. This report is a summary of the work recently completed as part of this grant during the period 19 June, 1973 to 17 June, 1975. This report was submitted by the authors on 18 July, 1974. This technical report has been reviewed and approved.

Jan 1, 1974

By George T. Faust

The petrographer engaged in examining the products resulting from the beneficiation of ores, and rock minerals is constantly required to develop new means acid methods of assaying microscopically the results of such operations. From time to time investigators have published descriptions of apparatus that have aided in solving problems in processes of physical separation. Thus, in 1919, Coghill and Bonardi 3/ published a paper covering the application of the binocular microscope and camera lucida to the microscopic analysis of pulverized ores. Similar work has been published by Schneiderhohn 4/ Schwartz 5/, and Head and his associates 6/, 7/, 8/. The present paper goes further and considers application of the polarizing comparison-microscope to problems directly concerned with mineral dressing where it is desirable to compare analogous products, and in addition it suggests new uses in various related fields. This work was conducted under the cooperative agreements of the Southern Experiment Station of the Federal Bureau of Mines and the University of Alabama.

Jan 1, 1940

By T. A. Hendrickson

The Bohemia district, situated about 30 miles southeast of Cottage Grove, Oreg., in the Calapooia Range, has been the major producer of lead and zinc in Oregon. Sporadic production has been Maintained from the district since its early discovery about 1858. In 1942, a selective-flotation mill was built at the Champien mine, which operated for only a short time and was forced to close because of the war and lack of labor. The Champion mill reportedly has been operated as a custom mill for the treatment of ore from the Musick and Helena mines, located in the district sometime in the past. This report summarizes the results of laboratory ore-dressing studies made on ore samples from the Musick and Helena Mines.

Jan 1, 1951