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By Steven J. Schatzel

Large-scale methane releases in dual salt mines have resulted in ignitions and mine fatalities as recently as 1979. Several past studies have implied that hazardous methane occurrences in U.S. salt domes are distributed neither uniformly nor randomly, but are geologically controlled and potentially predictable. A first step by the Bureau of Mines in addressing the problem of methane in deal salt mines required development of a new test to determine volumes of gases in solid salt samples. This report considers the results achieved when 80 deal salt samples were tested for gas content by dissolution in a controlled atmosphere chamber. Criteria were organized to delineate salt types based on geological occurrence. Outburst samples range from 0.014 to 7.4 cm3 CH4/100 g NaCl, anomalous salt samples from 0.0027 to 2.6 cm3 CH4/100 g NaCl, and normal salts from less than 0.0003 to 0.31 cm3 CH4/100 g NaCl. The presence of higher hydrocarbons was most common in samples containing larger quan¬tities of methane. The presence of higher hydrocarbons appears to be useful in detecting methane hazards where some methane may be lost before gas content testing. An exploratory rotary and/or core drilling program, dissolution testing for gas content, and up-to-date geologic mine napping could allow a mine operator to assess methane hazards in dual salt.

Jan 1, 1984

By K. J. Miller

A two-stage froth flotation technique was developed in the laboratory to separate fine-size pyrite from coal. The process consists of the initial flotation of a 15-percent solids coal slurry with a minimum of frother; the coarse, free pyrite and other refuse are removed in the tailings. The froth product from this first stage is then repulped and treated with a coal depressant, a pyrite promoter, and a frother to float the remaining fine-size pyrite or pyrite attached to coal particles. With the two-stage process, the pyritic sulfur content of a Lower Freeport bed coal sample was reduced from 1.78 percent to 0.75 percent in the first stage, and from 0.75 percent to 0.27 percent in the second stage with good clean coal recovery.

Jan 1, 1972

By Fei Chen, Lesley J. Gaydos, Laurence M. Demers, Douglas C. Kuhn

The fibrogenic effects of silica in experimental animals and humans has been extensively studied (I 7, 20). However, the pathogenesis and molecular mechanisms underlying lung injury and fibrosis resulting from silica exposure remain to be elucidated. It is well-documented that silica can stimulate monocyte-macrophage lineage cells to produce cytokines and growth factors, including interleukin-I (IL- I) (20), tumor necrosis factor-ex (TNF-cx) (I 7), insulin-like growth factor-I (IGF-1) (4), and transforming growth factor-P (TGF-P) (24). Consequently, it has been suggested that the fibrogenic effect of silica may be mediated by cytokines in the fater stages of silicosis. During the early phase of interaction between silica and the pulmonary alveolar macrophage, several direct and indirect lines of evidence suggest that reactive oxygen intermediates (ROI) may play a pivotal role in silica- induced tissue damage (2I, 22). One of the most important components of and contributors to ROI is nitric oxide (NO) produced from L-arginine and molecular oxygen under the catalytic influence of NO synthase (NOS) (I 9). At present, at least three NOS genes have been cloned: a constitutive neuron NOS, a constitutive endothelial cell NOS and an inducible NOS (iNOS) (16). A number of factors have been shown to differentially induce iNOS gene expression in different cell lines including bacterial cell products and foreign antigens. During inflammation, NO is a double-edged sword in terms of the host immune defense mechanisms and the physiologic response to an inflammatory insult. The macrophage is one of the major cellular sources of NO. During the early phase of acute inflammation, NO produced from the macrophage appears to facilitate the clearance of pathogens and promotes a local relaxation effect on the microcirculation of vascular smooth muscle. When the production of NO is left unattenuated, especially under oxidative stress, direct cytotoxic effects of NO can emerge through the formation of peroxynitrite as a result of a reaction between NO and superoxide (2).

Jan 1, 1998

By Thomas Varley

Data on the consumption of reagents used in .flotation during the year 1925, in metallurgical plants in the United States, are presented in this paper. Previous reports have covered the same subject for the years 1916, 1919, 1923 and 1924. The data contained herein show departures most radical from even the 1924 practice. Flotation has developed rapidly and on a more scientific basis than ever before. Perhaps more fundamental and useful data have been uncovered during the past two years than in all the years the art has been practiced.

Jan 1, 1926

By J. W. Jensen

This report was prepared as a background reference for future publica¬tions concerning the damping capacity of metals and alloys. It contains a broad description of the theory and methods of measuring damping capacity and correlates the developments of the past decade in terminology, units, and techniques. Damping-capacity instrumentation at the Mississippi Valley Experiment Station, Rolla, Mo., is described. The bibliography contains over 150 references to recent articles, each tabulated as to material investigated and test variables, such as frequency, stress, mode of vibration, and temperature. INTRODUCTION After it discovered high-damping manganese-copper alloys before World War II, the Bureau of Mines began research on the damping capacity of alloys and has continued to expand this activity to the present time. In physical metallurgy, damping capacity has become an important research tool in the Bureau. The physical measurement of the damping properties of alloys was begun at the College Park laboratories, and later conducted at Salt Lake City under the direction of Dr. E. V. Potter. Among the many articles resulting from this work, Damping Capacity of Metals (108)3/ has received frequent men¬tion in more recent literature and describes briefly the methods of measurement employed at that time.

Jan 1, 1959

By Lisa A. McDonald

The environmental compliance process affects all aspects of hardrock-mining operations, from exploration through post-closure. The primary components of the environmental compliance process are requirements under the National Environmental Protection Act of 1969 (NEPA) and the permitting requirements associated with various other federal, state and local laws. This study considers the Greens Creek Mine and the development of two other projects (Alaska-Juneau & Kensington). These mines were used as the foundation for a case study of the impacts of the environmental compliance process on hardrock-mining activity in Southeast Alaska. The case study presents the institutional and legal requirements, followed by a discussion of the impact of this process on the production and timing of the three mines. The results of this preliminary study reveal some interesting findings, some expected and others unexpected, regarding the impact of the permitting process on the exploration, development and (proposed) operation of the three mining projects in the Juneau area. Determining the cost of compliance with these requirements is an important step in evaluating the appropriate course of action to protecting the environment while providing the necessary raw materials needed for society. This preliminary study highlights the initial starting point for such an analysis.

Jan 1, 1992

By D. C. Fleck

Electrorefining yttrium from selected low-melting yttrium--base alloys is investigated, and various halide systems are studied as potential electrolytes for use in preparing low-oxygen yttrium by electrorefining unalloyed yttrium. Yttrium cathode products having significantly less metallic impurities than the anode materials were prepared from alloys containing nickel, iron, and manganese by electrorefining in LiCl-YC13 electrolytes at 900° to 1,000° C. Yttrium-copper and yttrium-magnesium alloys are not suitable as anode feed materials, An evaluation of chloride, fluoride, bromide, and mixed chloride-fluoride electrolytes showed that cathode products containing much less oxygen than the anode material can be obtained in the fluoride and mixed chloride-fluoride systems. Initial cathode current density has no apparent effect on the purity of the products obtained in both phases of the investigation.

Jan 1, 1973

By Sterling J. Anderson

Through the use of nondestructive testing techniques, the Bureau of Mines is pursuing a goal of improving the efficiency of the rock excava-tion process. Toward this end, 44 laboratory tests were conducted to identify a practical method of monitoring fracture development in rock, as caused by an excavation tool. An acoustic emission CAE) transducer was used to monitor the test samples as they were loaded. The signal from this instrument was recorded in real time along with the radial and axial loads generated by the fracturing device. Through the review of these signals on a common-time base, it was possible to see the relationship between the developing fracture and the loading conditions. As a part of the posttesting investigations, samples that were pletely fractured were sawn and ground to expose the fractures. examination of these samples allowed approximations to be made incom-Visual of the total surface created. Surface area approximations were also made for the completely fractured samples. Quantitative analyses· of the AE signals were conducted for comparisons with the calculated surface areas.

Jan 1, 1987

By J. H. Daniel

This report, summarizing the results of two studies sponsored by the Bureau of Mines, presents information on the types of mobile machines used in surface coal mines in the United States, and the amount of noise to which miners are exposed. Data consist of a calculated value of the probability of noise overexposure caused by specific equipment. These data are extrapolated to estimate the number of overexposed operators. Bulldozers were identified as the major contributors to noise overexposure, and the report presents results of a Bureau-funded program on the feasibility of providing retrofit noise control on bulldozers.

Jan 1, 1980

By Martin H. Rogoff

This publication combines a critical review of the literature on the microbiology of coal with an introduction to those areas of microbiology related to studies of coal as a biological material. The attack on coal by microorganisms as yet remains doubtful. Only the low-rank coals contain an indigenous microbial flora, and even these organisms are not peculiar to coal, but are common soil and water forms. No experimental data have as yet been presented, either in the literature or in the present work, which unequivocally demonstrate the oxidation of coal by microorganisms. Reasons for the resistance of coal to such attack, including insolubility, physicochemical structure, steric hindrance of enzyme action, and the presence of antibiotic materials in coal are discussed. Microorganisms do attack large aromatic molecules and the mode of oxidation of aromatic ring systems by bacteria is presented. Well-defined pathways are known for the oxidation of polycyclic compounds with one to three rings, and these paths with their key intermediates are described and related to the possible oxidation of coal.

Jan 1, 1962

Although early Spanish settlers used coal several centuries ago, significant commercial coal mining in New Mexico began in 1861, when the U.S. Army opened a mine to supply Fort Craig. Since then, coal from the state has been used to fuel railroads, lead and copper smelters, and other local industry. In recent years, lower-cost strip mining methods and an increased demand for coal by electric utilities in the Southwest have caused an increase in New Mexico coal production. The coal-bearing regions of New Mexico underlie about 25,000 square miles or20.6 percent of the total area of the state. However, the majority of coal-bearing regions lie under Indian lands that are regulated by the Office of Surface Mining (see Navajo and Hopi data on pages 72-75). Today, most of the coal produced in New Mexico comes from the San Juan Basin in the northwest part of the state and the Raton Area in the north central part. New Mexico's reserves are estimated to be 4.6 billion tons, about one percent of the national reserve. New Mexico's permanent regulatory program was conditionally approved December 3 1, 1980. Its Abandoned Mine Lands Program was approved July 17,198 1.

Jan 1, 1992

By Harvey L. Pastan

The purpose of the investigation and analysis described in this report is to assess the data flow requirements that are required for remote supervisory control of a continuous mining system. Since these control concepts as applied to continuous underground mining are still in a formative stage at the present time during the first half of 1975, assumptions had to be made based upon engineering judgment as to what embodiment of mining machinery and control methodology seemed most feasible for achieving such a system. Based upon these assumptions and estimates of the control system's accuracy and response requirements, it was then possible to estimate the communication requirements for the assumed system configuration. 2. Approach The team members responsible for this study visited numerous coal mines to observe room and pillar mining operations in both high and low coal. The objective was to observe the methods of operating a variety of continuous mining machinery and haulage equipment with a view toward defining the problems to be overcome in the application of automation to the coal extraction process. Descriptive information concerning the mining equipment was obtained through contacts with the manufacturers. Conferences with Bureau of Mines personnel, equipment manufacturers and developers, and mine operators were held to explore the current thinking and developments being pursued toward automation and increasing both production and productivity.

Jan 1, 1975

By B. R. Klahold

Each year hundreds of mineral specimens and numerous inquiries regarding tests and analyses of minerals and related inorganic substances are received by the Bureau of Mines. In response to this demand, in years past Information Circulars were published containing a list of laboratories. This paper is a revised version of Information Circular 7523, The listing has been changed from a regional basis to one of States arranged alphabetically and grouped by cities, again alphabetically, with Alaska and Canada listed at the end. All the services given at these laboratories are listed on one page for convenience and brevity. This list is compiled as a public service, and none of the laboratories listed herein are recommended over any other nor can the Bureau of Mines vouch for their results.

Jan 1, 1954

By Peter Krause

This report provides an overview of the worldwide photographic industry and of the applications of photography. It also covers important technological and market trends, with special emphasis on those factors which may affect the consumption of silver in the future. The text is divided into the following eight sections: 1. Principal manufacturers of silver-based photographic products 2. Major product sectors 3. Structure of the international market for silver-based photographic products 4. Silver-bearing raw materials for the manufacture of photographic products 5. Processing of photographic products: recovery of silver and recycling 6. Methods for estimating the use of silver in photographic products 7. Basic function of silver in photography and alternate image capture and recording systems 8. Brief history of photography Silver- based photographic materials are made for many applications that require different photochemical and physical response characteristics and a wide variety of formats and sizes. All of these products are laminates consisting of a surface-treated support and bonded gelatin layers. Two basic types predominate - films and papers. Films have transparent or translucent plastic supports (mostly cellulose tri-acetate and polyester), while papers have mostly a paper core coated with polyethylene resin layers on both sides (RC type). The front layer contains white titanium dioxide to provide high reflectivity and the back layer a matting agent. However, a few so-called fiber base papers are still supplied. These have a high quality paper base coated with a baryta layer ; i.e. a gelatin layer containing white barium sulfate. The manufacture of photographic film and paper supports requires special procedures and equipment, because of the severe requirements for chemical purity, optical integrity and uniformity (see Table 1 on page 10 for a list of the principal makers of film and paper supports).

Jan 1, 1992

By Philip Thompson

A part of the Bureau of Mines mission is to help improve the Nation's mineral posture by providing the technology for utilizing low-grade ores. In this regard, laboratory testing by the Bureau of Mines has shown that the removal of insoluble slimes using selective flocculation and flotation is a viable method for treating low-grade potash ores that have a high content of water-insoluble impurities. Results indicated that over 82 percent of the insoluble slimes could be removed from sylvinite ore containing 5 percent water insolubles and 13 percent K20 by using nonionic or cationic polyacrylamide flocculants and cationic, anionic, and/or nonionic collectors. Subsequent potash flotation recovered 87 percent of the potash in rougher concentrates containing 57 percent K2O. Sizing and cleaner flotation of the rougher concentrates upgraded the products to 60 percent K2O. Filtration of the water-leached insoluble-slimes flotation concentrates on a bed consisting of leached insoluble-slimes concentrate mixed with potash flotation tailings recovered 80 percent of the brine. Filtration rates using the mixed bed were nine times faster than filtration rates obtained when the insoluble-slimes flotation concentrates were filtered separately.

Jan 1, 1979

By E. Concha

The concept of an Automated Continuous Explosive Excavation system (ACEE) for the underground mining applications of development drifting and room and pillar mining has been evaluated in comparison with conventional drill, blast and muck operations. The role and possible extent of application as this method was identified. The evaluation examined each element of existing and of proposed ACEE design concepts in a defined mine environment. Step by step procedures were developed to quantify the evaluation process where this appeared feasible. One conclusion drawn was that a system approach to ACEE design is not only feasible but attainable within the state of the art. Several preliminary design concepts were formulated and examined in order to determine what further research or development might be needed to realize them.

Jan 1, 1982

By F. Garcia, J. Cervik

The cross-measure borehole technique has been shown by the Bureau of Mines to be an effective method of controlling methane liberated by fracturing the roof strata in longwall gobs where overburden is less than 750 ft (229 m). Boreholes are drilled into roof strata before mining operations affect the roof strata. Longwall mining fractures the roof strata and releases methane from source beds. Surface exhausters or vacuum pumps are used to draw the gas to the surface through an underground pipeline and vertical exhaust hole. The captured methane is thus prevented from entering the mine's ventilation system. About 71 pct of the methane produced by longwall mining in the Lower Kittanning Coalbed was captured by the cross-measure boreholes. Borehole spacing is an important factor affecting the performance of the technique. Interference tests and measurements of methane flows in return air indicate borehole spacing in the Lower Kittanning Coalbed should be limited to about 200 ft (61 m) except on the first 600 ft (183 m) of the longwall, where spacing should be reduced to about 100 ft (30 m) to capture the large quantities of methane released when the first large roof fall occurs. Comparisons between measured and calculated gas pressure differentials on boreholes indicate borehole length can be reduced from 280 to 140 ft (85 to 43 m), which reduces drilling costs significantly. Additional experimentation is necessary to verify the calculations.

Jan 1, 1985

This report includes a short history of uranium and its uses, mineralogy of common uranium minerals, and information on the use of electronic prospecting equipment and tests for detecting the presence of uranium. Details are given on geologically favorable areas and formations and practical methods of prospecting. Some information is given on the staking of claims, what lands are open to prospecting, and methods of securing mining rights. A forecast of the economic outlook for uranium is included. Appendixes give sources of additional information and a list of libraries where unclassified Atomic Energy Commission reports may be consulted. Because the increasing use of uranium by industry has revived interest in prospecting and exploration for this element, the Bureau of Mines has issued this report, which brings up to date and expands the subject matter of a hand- book on uranium exploration and production published in 1956.l

Jan 1, 1968

By Oliver W. Keener

The operation described herein differs from the usual practice in the Tri-State district in two important respects: (1) the ore is loaded into cars which are tramped to the shaft and hoisted on self-dumping cages, and (2) about 30 per cent of the ore is loaded by power shovels. The four-month period covered by the cost data appended at the end of the paper immediately followed a period of about one year during which the mine was shut down, and the expense incident to the resumption of operations is reflected in the costs. The author acknowledges the assistance of C. F. Jackson, mining engineer, U. S. Bureau of Mines, in the preparation of this paper and the compilation of the data.

Jan 1, 1929

By N. S. Dalal, Xianglin Shi

"The mechanism of vanadium(V) V ) toxicity is still not fully understood in spite of extensive current effort (1-3). The presence of a vanadium(V) V ) -dependent NAD ( P )H oxidase in cell membranes suggests that at least one of the pathways involves oxidation of NAD(P)H (1-3). Considerable effort has therefore been devoted to finding the mechanism of NAD ( P ) H-oxidation by va¬nadium( V ) (1-19). Recently Liochev and Fridovich (4, 16) provided a critical review of vanadium( V) -stimulated NAD (P )H oxidation by plasma membranes. They out¬lined a mechanism in which vanadium(V) V )-stimulated oxidation of NAD ( P )H by biomembranes involves an O2 - initiated free radical chain reaction (4 ). While the above may be the major pathway for the vanadium-me¬diated NAD (P )H oxidation in membrane-related sys¬tems, some recent results suggest that in the presence of NADPH the flavoenzyme glutathione reductase can function as a vanadium(V) V ) reductase (18). Because of the significance of this result in relationship to the mech¬anism of vanadium( V) metabolism and the novelty of the metal-reductase behavior of a flavoenzyme, we have car¬ried out additional studies on one-electron reduction of vanadium( V) by two other, related flavoenzymes: lipoyl dehydrogenase and ferredoxin-NADPH oxidoreductase. These two enzymes were selected because they are known to catalyze a one-electron reduction of Cr ( VI ) (19-21 ), which is isoelectronic with vanadium( V ).The present study also reports on the generation of hydroxyl ( • OH) radicals in the vanadium( V) -flavoen-zyme redox system without exogenous H2O2. The • OH study was undertaken because • OH radicals are known to be generated in reactions of vanadium( IV) with H2O2 (17,18,22-27). For example, Piette and co-workers (17, 22) have studied effects of vanadium(IV) IV ) on lipid per-oxidation and NADPH oxidation and suggested that va-nadium( IV) -induced • OH radical formation may play an important role in vanadium( V) toxicity. Carmichael (25, 26) investigated the reaction between a RNA /VO 2' complex and H2O2 with a view to probe the possible re-lationship between vanadium( IV) -mediated • OH radical generation and DNA damage. He has suggested that in this reaction the • OH radical adds to the C (5) carbon of uracil, causing nucleotide damage, similar to what occurs in the nucleotide /Fe2+ / H2O2 reaction (28) and in y-irradiated aqueous solutions of nucleic acids (29 ). To our knowledge, however, there is as yet no report on ·OH radical generation in any reaction involving the reduction of vanadium ( V) by a well-characterized enzyme, without exogenous H20 2 • The present study provides evidence that ·OH radicals can form in a flavoenzyme-mediated reduction of vanadium( V) to vanadium( IV) and that this process involves also the reduction of molecular oxygen ( 0 2 ) to H20 2 • The H20 2 thus generated reacts with vanadium( IV) to produce ·OH radical, in analogy with the Fenton reaction ( Fe2 + + H20 2 - Fe3 + + OH- + ·OH)."

Mar 1, 1992