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By Harold P. Rue

The problem of removing hydrogen sulphide from natural gas has become within the last few years one of major importance to the natural gas and petroleum industry. Several gas fields in the United States produce natural gas containing hydrogen sulphide, and a number of oil fields produce gas which contains hydrogen sulphide. 3 The percentage of hydrogen sulphide in natural gas produced in these fields varies from a fraction of 1 per cent t6 as high as 20.5 per cent by volume. 4 Hydrogen sulphide is probably the most toxic gas associated with natural gas,5 and from the standpoint of health and safety it is important that the hydrogen sulphide be removed if the gas is to be used for domestic purposes. Hydrogen sulphide, besides being toxic and therefore a hazard to animal life, is under certain conditions an active corrosive agent and very destructive to equipment. 6 The annual loss caused by the corrosive action of hydrogen sulphide on equipment amounts to hundreds of thousands, perhaps millions, of dollars. 7 The largest percentage of natural gas produced in the United States comes from wells which also produce oil. This associated gas invariably carries with it light fractions of petroleum, which when separated from the gas, condense to the liquid form at ordinary temperatures and pressure. Commercial application is made of this natural condition, and "wet gas" is processed to obtain so-called natural gasoline by employing the principles of absorption, adsorption, or compression and subsequent expansion accompanied by cooling. In the manufacture of natural gasoline from wet gas which contains hydrogen sulphide, if this contaminating gas is not first removed, some of the hydrogen sulphide may oxidize to form free

Jan 1, 1932

Since roof falls in the vicinity of the working face in underground coal mines are a major source of fatalities and injuries in this country's coal mines, it is evident that the present systems of temporary support for use in this working area are ineffective. This seems to be chiefly due to the inconvenience of setting up heavy and awkward devices such as jacks, posts and the like, which also interfere with the movement of men and machines in this critical working area. This program was concerned with defining and testing commercially available materials that could be used as support elements in a more convenient flexible personnel shield. The objectives of this program were to: 1. survey the materials that might provide the support elements of a flexible-material personnel shield for use in underground coal mines and prepare a list of those materials which appear most suitable for use in coal mines. 2. prepare a proposed testing plan for the materials to be selected from the aforementioned list by the Bureau of Mines for further evaluation. The test plan was designed to provide the following information: a. Tensile strength. b. Proportional limit. c. Creep characteristics at room temperature. d. Elastic properties depicted by stress-strain curves. Properties were tested in two directions for woven fabrics. e. Density. f. Resistance to abrasion. g. Resistance to attack by mine atomsphere. h. Resistance to humidity. i. Impact characteristics.

Jan 1, 1972

By Francis J. Fratttali, Verda McLendon, Stanley J. Green

"INTRODUCTION During the first phases of the war emergency the shortage of aluminum prompoted the Bureau of Mines to investigate methods for using low-grade bauxites of high silica content and also clays as raw-material sources of this strategic metal. The Bayer process treats low-silica bauxites to provide the industry with a major portion of the purified alumina, which contains very low percentages of silica and other impurities. One of the methods investigated in the laboratories of the Bureau of Mines for low-grade materials is the lime-soda sinter process, which was studied on a pilot-plant scale. In this process, the alumina content of the alumina-bearing minerals Bs made water-soluble by sintering the raw material with limestone and soda. Simultaneously, the siliceous material is rendered insoluble. The sinter is extracted with an alkaline liquor, and the resulting extract liquor is treated as follows to recover the alumina: (1) Autoclaving with lime to remove silica as a zeolitic complex and (2) treatment with CO2 to precipitate alumina as the trihydrate (A1203.3H20). Figure 1 is schematic flow sheet of this process.As the process is cyclic, it is necessary that nearly all of the soda and alumina remaining in the plant liquors after carbonation be recovered. Upon passing through one cycle, these liquors contain 14 to 15 percent NaCO3 2 to 5 percent NaOH, 1 to 3 percent A1203, minor amounts of silica, and, with certain materials such as Pennsylvania diasporic clays, 0.5 to 1.0 percent Na2S04. Approximately 50 percent of the Na20 in these liquors must be returned, as soda ash, to the dry-grinding and raw-materials blending operations. Previous work (6)5/ on sulfate-free solutions demonstrated that two methods for recovering Na20 were feasible, namely: (1) Salting out Na2C03.H20 by evaporation of the carbonated solutions and (2) crystallizing Na2C03.10H20 by cooling the concentrated carbonated solutions."

Sep 1, 1947

By S. H. Ash

California leads the Nation in the number of operating metal mines and the small number of persons employed at individual mines, which reached a minimum irk 1932 with an average of seven men. The mines are scattered over the entire State, which is the second largest in area (155,562 square miles) in the United States. The mines are situated at various altitudes, with portals ranging from approximately 300 feet below sea level to almost 12,000 feet above. Many of the mines can be reached only during the summer, while at others the heat of the regions adds so the difficulties during the summer months Supplied of explosives the use (or, probably more correctly, the misuse) of which constitutes one of California's gravest mining problems; are handled and stored under condition that contribute many hazards. The problem of providing medical care is serious and complicated, especially at small mines and more particularly in the almost inaccessible mountainous regions; instances in which a knowledge of first aid would have been beneficial but was lacking, or when first aid was instrumental in saving life or limb because it was available are too numerous to be mentioned.

Jan 1, 1936

By Walter W. Fisher

Cement copper was flash roasted in a vertical tube furnace to convert the copper to acid-soluble oxides as part of a postulated process for refining cement copper by oxidation roasting, acid leaching, and electrowinning. The results of the study showed that the oxidation was a linear function of oxygen concentration between 0 and 20 percent, but above 20 percent oxygen there was no further increase in oxidation. Therefore, air was the optimum oxidizing atmosphere in this flash roasting system. The oxidation followed a parabolic rate law as the roasting temperature was increased from 400° to 800° C. Extrapolation of the data, based on the parabolic law, indicated that at 400°, 500°,600°,700°, and 800° C, the roasting times required for complete conversion to soluble oxides were 75, 37, 21, 7.7, and 4.6 seconds, respectively. Cyclic-roasting test results did not substantiate the predictions obtained through data extrapolation.

Jan 1, 1973

By Manuel Gomez

A general prediction model for the Hardgrove grindability index was constructed from 735 coal samples using the proximate analysis, heating value, and sulfur content. The coals used to develop the general model ranged in volatile matter from 12.8 to 49.2 percent, dry basis, and had grindability indexes ranging from 35 to 121. A restricted model applicable to bituminous coals having grindabilities in the 40 to 110 range was developed from the proximate analysis and the petrographic composition of the coal. The prediction of coal grindability within a single seam was also investigated. The results reported support the belief that mechanical properties of the coal are related to both chemical and petrographic factors of the coal. The mechanical properties of coal may be forecast in advance of mining because the variables used as input to the prediction models can be measured from drill core samples collected during exploration.

Jan 1, 1970

By Thomas J. Fisher, Thomas Novak

Strong circumstantial evidence suggests that lightning has initiated methane explosions in abandoned and sealed areas of underground coal mines. The Mine Safety and Health Administration (MSHA) investigated several of these occurrences within recent years. The investigated explosions occurred at significant depths, ranging from 500 ft to 1200 ft. Data from the National Lightning Detection Network indicate a definite correlation between the times and locations of the explosions with those of specific lightning strikes. This paper addresses the question, "Can lightning cause potential differences capable of igniting methane-and-air mixtures at overburden depths at which underground coal mining occurs?" A mine depth of 600 ft was selected for this initial study. Computer simulations were performed, with and without the presence of a metal- cased borehole extending from the surface to the mine level. CDEGSTU software from Safe Engineering Services & Technologies, Ltd (SES) was used for the simulation.

By L. J. Douglas, A. G. Kim

Methane and other hydrocarbon gases, byproducts of coalification, are emitted from coal at widely varying rates and often present ventilation problems during mining. The air in some coal mines apparently contains no methane. To determine if coals from mines which had no history of detectable gas emission contained adsorbed methane, samples of coal at the shaft bottom and at an active face were obtained and placed in sealed metal cylinders. The atmosphere around the coal was sampled and analysed by gas chromatography. Methane, ethane, ethylene, propane, propylene, and butane were found to have been desorbed from these coals. Hydrogen and helium were also detected. An estimate of the amount of residual gas per ton of coal indicated that coal samples from the active face generally contained more adsorbed gas than coal samples obtained from the shaft bottom, although in both instances the total amount of gas was relatively small.

Jan 1, 1973

Lower the respirable dust expo? sure of longwall shearer operators Approach Use improved water sprays on the shearer machine to direct the dusty air toward the face. In laboratory tests and actual mining conditions, the shearer-clearer has proved to be an effective dust control technique. Recent field experience however, has indicated that not enough technical information is available on proper installation of the improved shearer-clearer. This Technology News will provide details of the Improvements made to the shearer-clearer and provide guidelines for installing the system. How It Works The shearer-clearer system consists of several strategically-mounted water sprays and one or more passive barriers. The sprays redirect the airflow around the shearer into both a clean and a contaminated split. The sprays confine the contaminated split or dust cloud to the coal face, allowing the shearer operators to remain in the clean split on the walkway

Jan 1, 1986

Enable mine personnel to determine the effectiveness of and to optimize the mine fire stench warning system without resorting to costly trial and error fire drills. Approach The mine fire stench warning system is used by underground metal/nonmetal mines to warn mine workers of a fire or other emergency. Stench is released directly into the mine ventilation and/or compressed air lines, and its repulsive odor warns miners to evacuate the mine or to follow other established emergency procedures. Unfortunately, since most deep metal mines have complex ventilation systems, some areas of the mine may receive nauseatingly high concentrations of stench while other areas, in more remote locations, may receive no warning or greatly delayed warring at best. The Bureau of Mines, through research, endeavored to solve this problem with a computer modeling system designed to calculate the distribution of odorant by the stench warning system.

Jan 1, 1986

By B. Dimitriades

The Bureau of Mines measured the reactivities of 19 hydrocarbons known to be prominently present in automotive exhaust and ambient air in a smog chamber. Results agreed well with those obtained using two other smog chambers. Reactivity scales were developed for hydrocarbons and aldehydes using the results of this work and those of a previous study. Application of the reactivity scales to automotive exhaust samples gave fair agreement between predicted and observed rate-of-N02-formation values; however, predicted and observed ozone yields were neither in agreement nor did they correlate well. This lack of correlation for ozone yield was attributed to the inappropriateness of (1) the individual component reactivity data, (2) the reactivity classification scheme used, and (3) the linear summation method. In seeking to understand this problem and to develop more appropriate reactivity scales, the data were examined from a reaction mechanism standpoint, and further studies were suggested.

Jan 1, 1975

By John C. Edwards

A two-dimensional, time-dependent, mathematical model has been developed that describes fire spread along the walls of a ventilated duct. The model is based on the assumption that the leading edge of the fire zone propagating along the wall surface coincides with the isotherm for the fuel ignition temperature. The model includes gas-phase energy transport via radiation and forced convection inside the duct and solid-phase energy transport by conduction into the fuel lining. Product gases emitted from the fire zone are assumed to mix uniformly with the ventilation gas to produce an optically dense gas mixture at the combustion temperature that enters the preheat region. Numerical solutions of the model equations for a coal-lined duct (simulated coal mine entry) have been used to investigate the effects of tube radius, air velocity, combustion temperature, and optical density of the soot-laden gas upon the terminal fire spread rate.

Jan 1, 1977

A computer system for calculating the illumination on coal mine surfaces due to machine-mounted lights is described. Utilizing numerical models of mining machinery and measured data on luminaire output characteristics, the program computes the ft-candle levels incident on the mine entry surfaces for any desired machine/luminaire/ entry configuration. Shadowing effects of the machine are taken into account. Results are provided at 2 ft. intervals on the face, left and right walls, floor and roof. The system operates, interactively from a Tektronix 4014 graphics terminal which handles all input/output functions. The software is installed on a Cyber 74 computer that communicates with the terminal via telephone line.

Jan 1, 1978

By J. R. Allsup

In cooperation with the Division of Advanced Automotive Power Systems Development, Environmental Protection Agency, the Bureau of Mines studied a conventional spark-ignition engine as a prime mover for use in a hybrid system. The study involved both steady-state and transient engine operation with ignition timing, air-fuel ratio, exhaust gas recirculation, oxidizing type catalytic converters, engine speed, and power output as variables. Data were obtained from two 1971 model 350-cubic-inch-displacement engines mounted on engine dynamometer stands. When the hybrid engine was operated with an oxidizing catalyst at power output levels required for a 4,000-lb curb weight hybrid vehicle, carbon monoxide and hydrocarbon emissions could be reduced to approximately 2.0 grams and 0.3 gram per brake horsepower-hour, respectively. With exhaust gas recirculation, oxides of nitrogen emission levels could be reduced to approximately 1.2 grams per brake horsepower-hour.

Jan 1, 1974

By S. P. Howell

The Bureau of lines as repeatedly called attention to dangerous practices in the transportation and opening of kogs of black blasting powder. In 1914 Diwin Higgins (Prevention of Accidents from Explosives in Metal inos, Miners' Circular 19, Bureau of Mines, p. 15) stated "canisters should always be opened by removing the bung. To use a pick or other sharp tool for cutting a hole in the canister is dangerous. After the necessary amount of powder has boon taken out, the canister should be kept closed. The powdor should always be handled at a safe distance from an open light." In 1919, Geo. S. Rice (onthly Statement of Coal line Fatalities for June, 1919, Bureau of Mines, pp. 16 to 18) calls attention to the dangers that arise in underground transportation and handling of explosives, and calls special attmtion to the danger of hauling explosives in motor trips; the unnecessary risk involved in hauling men on the trip at the same time, and the necessity of keeping open lights away from black blasting powder. In 1919 the writer (Sensitiveness of Explosives to Frictional Impact, Tech. Paper 234, Bureau of Mines, pp. 13, 15) called attention to the fact that black blasting powder is not as sensitive to frictional impact as the nitro-glycerin dynamites and the gelatin dynamites. Black powder may be ignited by direct impact and the writer believes that this may occur without presupposing a preliminary spark. It is well known, however, that black blasting powder is very sensitive to ignition by spark flame, or heated materials, and these may be produced by an electric current, by an open light, by incandescent particles from a pipe, cigar, or cigarette, by the tearing of metal sheets or scraping of metal against metal, and possibly, by other means. -- The above discussion will serve to introduce a newly recognized hazard the ignition of black blasting powder by the forcible opening of kegs with wodden tools. The details of three accidents in which kegs of black blasting powder ex- ploded instantly when a wooden tool was driven forcibly through the top of the kegs are as follows: 1. In 1915, a powder man employed by a coal mining company stated that he was opening a 25-pound log of black blasting powder by driving a hole in the top with a wooden sprag when the powder in the leg ho was opening ignitod. This caused the ignition of fifty-two additional 25-pound logs of the powder, and the fatal burning of this and another powder man. The ono making this statement lived five hours after the explosion.

Sep 1, 1920

By R. R. Sayers

Mine operators and managers for a number of years have known that the maintenance of health among the workers has an appreciable financial value, In order to maintain the health, it has been found ne cessery to imow; 1. The health hazards existing in the industry as a whole and the specific hazard in the individual mine. 2. The physical condition of applicants for employment as well as that of the old employees. This can be determined only by systematic physical examination of all applicants and of regular employees at intervals of at least once a year thereafter. 3. All cases of sickness that occur among the workers. No operator or manager, or personnel, medical, or safety organization can control or prevent sickness without knowing where, when, and under what conditions the sickness actually occurs. In order to obtain information as to the hazards of industry, investigations have been and are being made of the effects of the condi- tions both in the field under usual working practices and in the laboratory. In the field several factors are generally present which affect the health. The effect of these factors may be determined by studying each of them separately in the laboratory. However, both the field and the laboratory studies are limited in value in that such studies usually have been made over a comparatively short period. While we have some information as to their immediate effect, we do not know to what extent extreme heat, humidity, the presence of dust or other health hazards are the cause of disability. Mortality statistics are probably the most easily available indices as to the hazards of industry. As an example, a study of such statistics among coal miners of Indiana shows a marked increase in the death rate in 1918.

Mar 1, 1923

By NIOSH Publication

In 2004, a total of 7,074 sand and gravel mining operations reported employment to the Mine Safety and Health Administration (MSHA).

Sep 1, 2007

In 2004, a total of 4,401 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). Stone mines comprised 30.4% of all mining operations.

Sep 1, 2007

By CDC CDC

In 2004, a total of 251 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Metal mines were the smallest mining commodity sector, comprising 1.7% of all mining operations. • Gold mines

Sep 1, 2007

By Linda L. Chasko, Ronald S. Conti, John D. Cool

Mine operators often rely on mine rescue teams to save lives during an underground emergency such as an underground fire, explosion, roof fall or water innundation. It is extremely important that team members are provided with adequate exploration equipment and that training simulations are conducted in a realistic manner. A series of mine rescue training exercises was developed, conducted, and evaluated by the National Institute for Occupational Safety and Health (NIOSH) in cooperation with the Pennsylvania Department of Environmental Protection, Bureau of Deep Mine Safety and several mining companies. The exercises were conducted at NIOSH’s Lake Lynn Laboratory and operating mines during 1995 to 1999 and resulted in improved technology and training for mine rescue teams. For example, existing technologies were identified to help rescue teams during exploration. These included various chemical light shapes and laser pointers to identify team members and mark crosscuts and mine materials, strobe lights for mapping out escapeways and marking crosscuts, and thermal imaging systems to see through smoke. A hands-free communication system showed potential for enhanced communications between team members and the fresh air base. Anew team lifeline that allows for flexibility of movement between team members was developed. A positive-pressure inflatable escape device (IED) was used to isolate the “hazardous” environment from fresh air and allow rescue team members to traverse through. An inflatable feed-tube partition that can rapidly block large openings such as underground passageways and simultaneously provide a feed-tube for high-expansion foam generators was also deployed for several simulations. During the simulations, mine rescue team members donned self-contained breathing apparatuses (SCBA) and traversed more than 400-m of mine passageways filled with nontoxic smoke. Visibility ranged from 0.3 to 0.9-m. In one area of the mine, a kerosene heater was used to simulate a fire and reduce the oxygen concentration. In another area, a 1.5 pct methane zone was established. The team members searched for "victims,” administered first aid, mapped the passageways, built temporary stoppings, and ventilated the smoke-filled entries. Advanced training included the extinguishment of a conveyor belt fire in a surface fire gallery. Two teams, each carrying charged waterlines, were escorted into the fire gallery through both doors. These teams controlled the rollback smoke and extinguished 7 to 9-m of burning conveyor belt. Team members indicated that the exercises were extremely beneficial due to the realism of thetraining simulations.