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By Martin Hertzberg

This Bureau of Mines report analyzes diverse observations of the rates and mechanisms for the pyrolysis and devolatilization of coal and polymethylmethacrylate (PMMA). New data are presented for PMMA, together with new morphological evidence for the microscopic structure of the pyrolysis and devolatilization wave front in coals. It is concluded that there is no substantive evidence to support the traditional viewpoint that the pyrolysis and devolatilization rate process occurs isothermally, under chemical rate control; or is described realistically by a classical, unimolecular Arrhenius function of temperature. Instead, the reaction process occurs as a highly nonisothermal, heat-flux-driven, pyrolysis and devolatilization wave front, whose speed of propagation is predictable by internal heat transport constraints. Except for the complication of its charlayer residue, whose increasing thickness insulates the pyrolysis wave front from the heat source flux that drives it, both coal and PMMA behave similarly during pyrolysis and devolatilization. For PMMA, decomposition occurs at a temperature of 3500 to 5500 C; for coal it occurs at 4500 to 6000 C. There is no evidence that the reactant temperature ever exceeds those values regardless of the source temperature to which the samples are exposed.

Jan 1, 1988

The Particulate Mineralogy Unit has been established at the College Park, Maryland, Metallurgy Research Center. The Particulate Mineralogy Unit will have the responsibility within the Bureau of Mines for the characterization of particulate minerals which have potential for adverse environmental effects. The Unit will provide a focal point for identifying particulates in connection with environmental problems related to the activities of agencies such as OSHA, HEW, EPA, and MESA. The Particulate Mineralogy Unit is seeking to clarify the ambiguities surrounding the mineralogy of and terminology used for asbestiform minerals and other mineral particles. The Unit?s investigations of the morphology, composition, and structure of asbestiform minerals and their nonasbestos analogs have made its members recognized experts in this field. The information which it develops on the characterization of asbestos and other particulate mineral forms such as silica should provide a technically rational basis for decisions by regulatory agencies. Those desiring further information, contact Dr. W. J. Campbell, Program Coordinator, College Park Metallurgy Research Center, College Park, MD 20740, telephone: 301-344-4014. ALUMINUM: For over a month, domestic producers have priced 99.5 percent grade primary aluminum ingot at 48¢ per pound. In the same period, merchants raised ingot quotes by 1.5¢-2.5¢ to a range approaching 44¢-47¢ per pound.

Jan 1, 1976

By R. G. O'MEARA, Alexander M. Gow, W. T. SCHRENK

Lime is used extensively in the various industries. The National Lime Association in an excellent and recent bulletin lists 23 important in- dustries in which lime plays a vital role; and it thereby justifies the statement that "Lime is one of the most versatile and widely used reagents in the chemical and industrial world." There is, however, one application of this "universal" reagent which has not been mentioned. It is the use of lime in the flotation of ores. An appreciable percentage of the lime produc- tion is consumed by ore-dressing plants. The uses of lime throughout all the industries are more or less re- lated, but "lime" is a broad term; the varieties of lime are more mumerous than the limestones from which it is made, and its use involves a complicated technique. The interrelated application and growing importance of lime in flotation warrant this additional publication on the various "limes," with emphasis on those uses related to the function of lime in flotation. ཁྐྲ་ Lime in water treatment, cyaniding, and amalgamating will be men- tioned, after which its use in flotation will be taken up. This compendium was prepared by the Mississippi Valley Experiment Station of the United States Bureau of Mines and the Missouri School of Mines and Metallurgy, Rolla, Mo.

Apr 1, 1931

By W. W. Adams

With greater production of coal per man-hour of work than ever before achieved, the coal-mining industry of the United States established a better safety record in 1941 than in any year since 1930, the earliest for which complete reports of nonfatal as well as fatal injuries were collected by the Bureau of Mines, United States Department of the Interior. In only one year (1933) of the 12-year period 1930-41 was the fatal-accident rate better than in 1941, whereas the rate for nonfatal accidents was better in 1941 than in any previous year. Accident and employment reports received from mine operators, together with fatal-accident reports received monthly from State mining departments and inspectors, showed that 546,692 men were employed in and about the coal mines of the United States during the calendar year 1941. This number does not include office employees or coke-oven workers. The increase of 1.3,426 over the number of employees in 1940 was accompanied by a gain in man-hours of work performed at the mines and an increase in average number of hours worked per man during the year.

Jan 1, 1944

By C. H. Herty

Intensive work on the deoxidation of steel with manganese-silicon alloys by the U. S. Bureau of Mines has shown that the use of those alloys, which may be produced from our domestic manganese ores, would decrease the ferromanganese requirements of a very large tone of our steel by from 60 to 30 per cent and in some cases by 100 per cent. The open-hearth heats made with these alloys have been of excellent quality. The tonnage of our ferro-grade ores which has been made available by the bureau's ore-dressing studies, combined with the ,products resulting from such processes as those developed by the bureau and by Bradley for Cuyuna ores, should easily fill our reduced ferromanganese requirements Then manganese-silicon alloys and ordinary spiegel are used in the way described in this report. There are no technical difficulties in the application of this practice, and any difficulties involved in its wide and immediate application would only be those arising from habituated ideas of the necessity of ferromangenese. General acceptance of this practice and development of the available sources of domestic ferro-grade material by already proven processes should make this country independent of foreign ores.

Jan 1, 1931

By John Durkin

This report discusses the configuration and system deployment for the postdisaster surface seismic system for detecting and locating trapped miners. It analyzes the results of 15 field tests to define a signal model, background noise levels, and subarray performance. A waveform modeling procedure is described and compared with observed waveforms. The resulting similarity indicates that the major factors affecting the signal amplitude, waveform, and spectral character are understood. A model is presented which gives the sig-nal amplitude as a function of source type, source depth, and horizontal off-set between source and receiver. Using this model a curve is presented which gives the range at which a signal will be detected for different signal and noise levels. Finally, and most important relative to the mission of the system, the ability of the system to detect signals on one or more subarrays is put into a probabilistic framework. For a strong source it is almost certain that a subarray directly over the source will detect the signal. After signal processing, it is highly likely that signals will be detected on sufficient subarrays to locate the trapped miner. Location errors have been found to be less than 100 ft in the majority of cases. Techniques have been used that can reduce the location errors to this level even when soil layer variation between subarrays is severe.

Jan 1, 1981

By Charles Vaught, Jeff Duncan, Michael J. Brnich, Lisa J. Steiner

This document contains most of the materials needed to use the exercise. The main part of the document is the instructor's copy. It tells how to use the exercise, presents the objectives, the master answer sheet, the scoring key, and discussion notes to be used following the exercise. The next section summarizes results from field tests of the exercise, and reports the miners' evaluation of the activity. The last part of this document is three appendices. Appendix A is the exercise problem booklet. This booklet can be duplicated locally. The booklets are reusable. One is needed for every person in the classroom. Appendix B is the answer sheet. Copies of this answer sheet must have the latent image (invisible) ink answers that appear in Appendix C printed on them.3 Answer sheets are consumable. One is needed for each person or each small group of persons who work the exercise. Exercise Summary Read this section first. It determines if the exercise is appropriate for your classes. If you choose to use the exercise, examine the table of contents and review the remainder of this document. Type: Latent image Audience: Remote control and extended cut miner operators and face crews Length: Eight questions (30 minutes for administration plus 30 for discussion) Skills: Remote control mining procedures including remote control mining, taking extended cuts, resetting breaker on mining machine, and setting timbers. Communicating mine conditions, influencing safe behaviors when mine conditions are less than stable Location: Underground coal mine, four section continuous mining operation Average seam height is 48 inches Problem: Your regular job is on the general labor crew at Cripple Creek #9 mine, a four section continuous mining operation. The mains are 9 entries wide and panels are 5 entries across. You and the rest of the crew had annual refresher training about 3 months ago. For the past few days you have been sent to 2 South panel to fill in as the third shuttle car operator. This morning, however, your buggy is down. The face boss asks you to get the scoop and take seven or eight timbers to the number 5 entry because the last shift got off sight line. The miner will be working in entry 5 while the bolter crew pins entry 4. When you get up to the face you see that Mo, the remote control continuous miner operator, has rounded off the left inby corner in order to make his first cuts in the right hand rib. Now, he has squared around enough so that you and Red, the miner helper, can set some posts on the corner. The two of you set posts along the left inby rib of #5 entry while the shuttle car operator waits. You are in a tight spot when Mo decides to start mining. You must decide where the best place is to stand for safety and to be out of the way.

Jan 10, 1999

By Oliver Bowles

Chalk is defined as a noncrystalline, soft, friable, fine-grained, light-colored type of limestone. It consists essentially of calcareous shells of minute organisms known as "foraminifera," although skeletal remains of molluscs, corals, and sponges are also present. Flint balls which are found so commonly in the chalk cliffs of Europe are regarded as segregations of the remains of certain organisms, such as radiolarians and sponges, that secrete siliceous shells or spicules. The famous chalk beds of northwestern Europe are of Upper Cretaceous age, a geological period that was particularly favorable for the develop- ment and multiplication of foraminifera. The distinguishing physical characteristics of true chalk never have been fully defined; probably its noncrystalline and colloidal properties are most important. The properties of chalk, whiting, and whiting substitutes are not well understood, and much re- search is necessary before definite reasons may be ascribed for the behavior of these materials under various conditions of use. The Bureau of Mines has undertaken a detailed study of chalk and similar materials to determine their exact properties and to establish a basis for classifying formations loosely designated as chalk occurring in various parts of the United States, but the results of this study will not be available for some months. Whiting is a pulverized, purified, and carefully sized chalk. Whiting substitutes consist of finely ground limestone or dolomite, ground marble (marble flour), white marl, and chemically precipitated calcium carbonate.

Jul 1, 1931

By Roy J. Greenfield

The overall purpose of this research was to improve the understanding of how the post disaster seismic location system works, what determines the signal size, what is the character of the seismic noise, how well the system can detect blows from a trapped miner, and how well the source of the blows can be located. Based on an improved understanding of the system, improvements were suggested in the seismic subarray configuration, and in the system deployment procedures. An important part of this research was to become familiar with the seismic system operation and to work with the Westinghouse Electric Corporation and MSHA personnel to modify and improve the system. To accomplish this we participated in the planning, execution, and data analysis for a number of seismic field tests. Several in-mine field tests were conducted. From these tests the capabilities of an in-mine seismic system were analyzed and specifications were made for designing an operational in-mine system. Several portions of the work done on this grant were covered in previous reports. In particular the capabilities or the presently operational surface based seismic location system has been thoroughly documented by Durkin and Greenfield (1981). Portions of the location procedures and effects of mine openings on seismic signals have also previously been published. These portions or the work will only be summarized in this final report.

Jan 1, 1982

By A. J. Forney

The hot-gas-recycle process, for the hydrogenation of carbon monoxide, was investigated in a 12-inch-diameter reactor. Initially because the distribution of gas was poor, hotspots developed in the catalyst bed. After the velocity profile of the gas flowing through the bed was studied, the method of packing the catalyst was altered. Because this change improved the distribution of gas, temperature control was excellent. The l2-inch-diameter reactor was operated successfully in the synthesis of gaseous and liquid fuels. When high-Btu gas was synthesized in two stages, parallel-plate assemblies of Raney nickel were almost as active as granular Raney nickel in the second reactor. The pressure drop through the second reactor, however, was reduced 90 percent by the use of these assemblies.

Jan 1, 1962

By Oliver Bowles

The National Granite Commission at its annual meeting in Norfolk, Va., in January, 1930, passed a resolution requesting the Bureau of Mines to conduct an economic study of the granite industry. In with this request a preliminary review has been made of trends in the production and uses of block granite.. Some unfavorable conditions were thus brought to light, and certain suggestions regarding a more orderly and consistent growth in the industry are herein discussed. The results of the study are, presented in this report for the earnest consideration of. the industry, and comments are invited, not only on this report but as to future work that might be accomplished by the Bureau of Mines. The authors desire to acknowledge many helpful suggestions and comments from Paul M. Tyler of the Bureau of Mines and from Harris F. Sherman, secretary of the National Building Granite Quarries Association. Miss A. T. Coons of the Bureau of Mines rendered valuable assistance through her wide knowledge of granite statistics. The block granite industry has shown little expansion during recent years. While the value of the annual production has grown from about $14,000,000 in 1904 to nearly $25,000,000 in 1928, the increment in value is caused mainly by mounting prices rather than by increased production. Even granite for memorials shows a very small advance in production volume, although the value has increased from about $3,500,060 in 1904 to more than $11,000,000 in 1928, which is the most consistent growth of any branch of the industry. The value of building granite has fallen for a number of years much below the figure for 1904, and in 1928 was very little in advance of the value attained 24 years previously. The use of granite paving blocks and rubble has shown a gradual decline.

Jan 1, 1931

7133. Clewell, D. H. The Gravimeter. Prec. and Trans. Texas Acad. Science 1941, Austin, Tex., vol. 25, 1942, pp. 86-88. Static gravimeters, unastatized and. astatized, are considered to be the most practical for oil exploration. One gravimeter is described using a beam whose moment about a pivotal axis is elastically balanced. Magnetic or electric fields are deemed unsatisfactory for balancing gravitational force because they cannot easily be kept constant. The gravimeter described is capable of detecting a change in altitude of 3 inches and a change in latitude of about 150 feet. V. S.

Jan 1, 1944

By G. Schuman

Variations in pyrite reactivity are known to exist within samples collected from different areas. Using samples collected from acid and non-acid sites, the relationship between the factors affecting pyrite oxidation and observed variations in pyrite reactivity was studied. Heavy liquid separations were used to extract the pyrite from nine pulverized rock, coal, and coal refuse samples. Simulated weathering tests were used to determine the degree of reactivity of the extracted pyritic material. Representative portions of each pyritic sample were analyzed for whole rock composition (including pyritic sulfur and neutralization potential), for elemental composition, and by x-ray diffractometry. The samples were also examined with reflected light microscopy to ascertain pyrite morphology distributions. Tests for the presence of iron-oxidizing bacteria were all negative indicating the leaching tests were conducted under abiotic conditions. The results of the simulated weathering tests permitted the partitioning of the samples into two groups based on positive or negative neutralization potential (NP) values. Determinations were then made to evaluate the degree to which a variety of factors, including temperature, partial pressure of oxygen and water, and crystallography affected pyrite reactivity. Multiple regression analyses showed no statistically significant relationship between degree of reactivity and elemental composition. However, for samples with negative NPs, a simple regression analysis showed a strong linear relationship to exist between the reactivity of the pyrite and the proportion of "unstable" pyrite (framboidal + mossy pitted) found in each extracted pyrite sample. Samples of pyrite with positive NPs, although producing acidity, did so in at least one order of magnitude less than the NP deficient samples, indicating the important role that NP plays in controlling pyrite reactivity. A simple linear regression between cumulative sulfate production and NP for the three samples with positive NPs had a correlation coefficient of 0.99. For the nine samples grouped together, a linear regression model between cumulative sulfate production and NP (both negative and positive) was established between log of sulfate and NP.

Jan 1, 1991

By M. M. Ayoub

With a return to coal as a major energy source for many companies, more emphasis is being placed on recovery of coal from areas that were formally considered uneconomical to mine. Increasing emphasis is being placed on production from low coal (seam height 48 inches or less) as high coal seams are depleated. Mining in restrictive spaces requires unusual work postures that can turn easy jobs into demanding ones. The objectives of this research were: (1) to evaluate the job demands associated with low coal mining, (2) to survey the anthropometry, strength, and aerobic capacity of low coal miners to determine if they differ from the U. S. population, and (3) to recommend, on the basis of available information, optimal job and work station design for low coal mining. This research effort was supported by the U. S. Bureau of Mines. The male and female anthropometry with the exception of weight and circumferential dimension, was quite similar to the comparison population. Back strength for male and female miners was significantly lower than the industrial worker population. This can be one of the contributing factors of low back problems in mining. Shoveling, timbering, and helpers tasks were physiologically demanding activities. However, due to the frequent stoppage of work, adequate rest was usually available. If work stoppage is corrected, then better work/rest schedules are essential.

Jan 1, 1981

By Albert L. Toenges

This report is the second of a series describing methods and systems of mechanical mining; where operations are conducted on more than one shift. The first report, Information Circular 7014,4/ describes mining operations at 14 mines and the present paper describes operations at 11 additional mines. The purpose of this study is to analyze the advantages and disadvantages of the various types of equipment and mining systems now used where more than one shift is worked per day. Physical conditions vary in different and in the same mining districts and determine, together with economical considerations, the systems of mining and the types of mechanical loading equipment to be used. The information presented in this paper may be helpful to operators or others who may contemplate installing a mechanical mining system. The equipment used in the mines described comprises conveyors, scrapers, mobile loaders, mobile conveyors, and combination of these types. The description of the mining systems and practices at the mines investigated is detailed only as they relate to and affect mechanization. In computing the operating data in mines that are not totally mechanized, employees not working directly on production have been charged to output from mechanized sections in proportion to the percentage of mechanization. The operating data for comparing various systems are for an average working dry, as the number of men working on idle days varies greatly in different mines.

Jan 1, 1939

By H. Kim, R. W. Plummer, T. J. Stobbe, W. G. Jones

"Exposure to airborne dust in coal mines has caused respiratory disease in coal miners. The causal agent in these diseases remains unknown, although the minerals found in and around the coal seam have been implicated. Toxicological studies designed to establish the effect of different mineral combinations and concentrations are lacking because the mineral content of coal mine dust has not been defined. This paper reports the initial results of a study done to characterize the mineral content of the coal mine dust found in a mine in the Upper Freepott seam in Northern West Virginia. Coal mine dust samples were collected using 4- stage cassette impactors at nine locations in the mine. The samples were analyzed by an x-ray microdiffraction film technique supplemented by energy dispersive scanning electron microscopy. Primary size modes of about 17 to 20 micrometers from the samples collected at the haulageway and the returnside of the continuous miner were found. From the returnside of the roof bolter samples, a primary size mode of 12to15 micrometers was measured. The minerals found in high percentages were illite, kaolinite, quartz, and calcite. The distribution of minerals in inter· and intra- location samples showed wide variations. Trends in these variations are presented. Stobbe, T. J.; Plummer, R. W.; Kim, H.; Jones. W.: Characterization of coal mine dust. Appl. Ind. Hyg. 2:95· 100; 1986. IntroductionDisease-associated dusts in coal mine environments continue to afflict miners in today's modern mines. The relationship between exposure to coal mine dust and the development of various respiratory diseases has been well recognized; however, the reasons for variation in occurrence of these diseases among miners in different geographic areas,(1) rank of coal seams,(2-3) and jobs (4) remain uncertain. Several papers have reported on the causal agent in the development of these diseases. Davis (5) found that the percentage of the non-coal minerals present in the lungs of deceased miners increased as the level oi pneumoconiosis became more severe. Reisner (6) reported that cell damage caused by coal mine dust increases with the mineral and quartz content of the dust and with the geo· logical age and rank of the coals. Two studies, investigating the in vitro effects of mineral dusts. reported by Seemayer and Manojlovic (7) also obtained positive correlation between cytotoxicity and the mineral content of coal mine dust. Gormly (8) postulated that destruction of macrophages by certain mineral dusts is the first step in the development of pneumoconiosis. In 1980, Adamis and Timar (9) reported that quartz. sandstone, slate. respirable colliery dust. bentonite, illite, and some kaolins had cytotoxic effects on rat peritoneal macrophages""in vitro."" Walton,(10) however, reported that the presence of high clay, illite, and kaolin mineral exposures reversed the hazards associated with increasing quartz exposures. This finding was supported by Le Bouffant and coworkers.(11) They reported that illite present in coal mine dust strongly inhibited the pathogenic effects of quartz while kaolin had a weaker inhibitory effect."

Mar 1, 1989

By James Westfield

Following is a brief history of Bureau of Mines Division of Coal-Mine Inspection activities that have favorably effected health and safety and reduced Injuries at coal mines: The Federal cline Safety Code for Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consulting with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous-coal and lignite mines for the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior on October 8, 1953, after further consulting with representatives of management and mine workers, and was incorporated in the 1952 and subsequent bituminous-coal wage agreements. The agreement of May 29, 1946, betweeen the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. Federal coal-mine inspectors also had temporary authority to close mines considered imminently dangerous, but authority under Executive Order 9728 was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1962

By T. G. Mayhew, A. A. Bergeron, R. J. Mahany

This report describes an operational communications system which provides remote intra-terrestrial wireless transmission of environmental information. Design and modification specifications of requisite equipment are included along with a detailed description of system operation

Jan 9, 1976

By J. J. Shields

With the increased use of mechanized equipment in mining bituminous coal, production panels are mined out rapidly. To keep current with the rapid completion of production panels, development work must be speeded up also. Although the same type of equipment usually is employed in development as in production places in the same mine, past output per man for development usually was less than from production panels. A study of development practices in 14 mines reveals a tendency toward equalization of the output per man between development and production.

Jan 1, 1957

By R. B. Moore

The story of helium is one of the romances of science . Probably nothing , except perhaps radium , compares with it in human interest . Helium is one of the best examples of a discovery in pure science that has wide commercial application . In 1868 , an eclipse of the sun was visible in India , several scientific men who were in India making observations of the eclipse turned a spectroscope for the first time on the solar chromosphere - that part of the atmosphere of the sun , about 10,000 miles deep , which merges into the corona . A bright yellow line was observed and was thought at first to be due to sodium . Janssen showed , however , that this line was not just the same as either the D or D₂ line of sodium, although it was extremely close to these lines , hence he suggested that the new line have the designation D₂ . Frankland and Lockyer decided that Dz was due to an element in the sun not previously discovered on the earth , and suggested for it the name "Helium" from the Greek work " Helios " the sun . For several years nothing more was done in connection with this element . In 1894 , Sir William Ransay , in conjunction with Lord Rayleigh , made his memorable discovery of argon in the atmosphere , which was announced at the British Association meeting in the same year . After this discovery , Ramsay looked for other sources of the element . Through Sir Henry Miers , he learned that Dr. W. F. Hillebrand , of the United States Geological Survey , had obtained an inert gas from certain uranium minerals , which gas he had decided was nitrogen . Ramsay believed that part of it might be argon ; he obtained from Hillebrand for experimentation , a sample of the mineral , cleveite , one of the uranium minerals , and after extracting gas from the mineral and purifying it , he ran it into a spectrum tube . The lines obtained ' were , however , different from those of argon; among them was the bright yellow line noted by Janssen . Thus was terrestrial heliun discovered .

Jun 1, 1922