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By G. L. Hundley

The Bureau of Mines has devised a procedure to recover chromium chemicals from concentrates derived from low-grade domestic chromites. These domestic chromites contain silicon and aluminum impurities at levels that are too high to permit processing by present industrial processes. The Bureau procedure consists of reacting chromite with molten NaOH under oxidizing conditions to form sodium chromate (Na2Cr04)' The reaction product is leached with methanol to recover the majority of the unreacted NaOH, then with water to extract the Na2Cr04 and the remainder of the NaOH. The Na2Cr04 product is recovered by evaporative crystallization from the aqueous solution. This report presents laboratory results of studies to determine the optimum leaching conditions for the reaction products of several domestic chromite concentrates. Results of solution purification and crystallization studies are also presented. The concentrates are from a variety of sources including the Stillwater Complex in Montana, Red Bluff Bay and the Kenai Peninsula in Alaska, and a Ni-Co laterite from southern Oregon. Sodium chromate crystals were produced that contained less than 0.01 pct NaOH.

Jan 1, 1988

By Steven J. Page, Wm. Randolph “Randy” Reed, John A. Organiscak

Researchers studying dust generation from blasthole drills developed a simple, quick fix that reduced respirable dust concentrations by more than 63% at the dump point. This device, which requires almost no maintenance, is small and inexpensive, and it will help operators maintain compliance to the dust standard. The thought process was that a reduction of respirable dust at any of the multiple sources on the drill, in this case the dust collector dump point, should reduce the total respirable dust generated by the drill. The U.S. Mine Safety & Health Administration (MSHA) has a coal respirable dust standard of 2 milligrams per cubic meter (mg/m3) for an 8-hour shift. MSHA and mine operators periodically collect personal dust samples to determine compliance with this dust standard. Drill operators have one of the highest exposure levels to respirable dust. This has been proven through many reviews of the MSHA dust sampling database. Prior to 1987, the highwall driller at surface coal mines had the most severe exposure to respirable silica dust, a trend that continues today based on MSHA's respirable dust sampling database. A review of the MSHA database for the years 1985 through 1992 shows that 81% of the respirable silica dust samples taken exceeded the permissible exposure limit for the highwall drill operator at surface coal mines. A more recent review of the MSHA database, for the years 1996 through 2000, shows that only 31% of the respirable silica dust samples taken exceeded the respirable silica dust limit for the highwall driller at surface coal mines. This suggests a substantial improvement in preventing the exposure of silica dust to the highwall drill operator. The drill operator, however, still tops the list of job occupations that have the highest exposure to respirable silica dust Respirable dust has been shown to be harmful to human health, especially when silica is present in the dust. It causes a disease known as silicosis, which can occur in three levels: chronic silicosis, which occurs after 10 years of exposure; accelerated silicosis, which occurs between 5 and 10 years of exposure; and acute silicosis, which can occur within a few weeks to five years of very high exposure to silica dust. Respirable dust consists of the dust particle size fraction whose median diameter is 4 micrometers (µm). The drilling machine generates high concentrations of respirable dust from several sources: drill table shroud leakage, dust leakage through the table bushing, dust discharge from the dust collector exhaust due to impaired filters, and dust entrained from the dust collector fines dumped onto the bench. The National Institute for Occupational Safety and Health's (NIOSH) Pittsburgh Research Lab (PRL) has been studying different methods to reduce respirable dust from these sources. During its testing, the institute identified a simple solution that reduces the amount of respirable dust generated at the collector dump point.

By R. C. Butman

The Lincoln Terminal System (LTS) is a stand-alone computerized training device that presents high quality visual displays, and audio messages to a student. A keyboard is provided for student input. A variety of student-machine interactive programs arc provided. These programs allow the author/instructor to evaluate numerical entries and responses to simple and compound multiple-choice questions (where a compound choice is defined to be more than one choice, ordered or unordered from one or more list(s) of choices. Descriptions of LTS applications, lesson development procedures, hardware provided and support facilities required are given. A contract history summary, and a bibliography of reports published under three successive BoM contracts supporting LTS development, is provided.

Jan 1, 1979

By J. R. Allsup

Air pollutants in exhaust gas produced from LP-gas (propane) were studied using both laboratory engines and vehicles. The objective of the study was to evaluate engine parameters relating to the advantageous use of propane as a low-pollution fuel. Some comparisons are made between gasoline, natural gas, and propane. Results show that engines can operate over a wider range of A/F with minimum carbon monoxide and hydrocarbon emission when using propane than when using gasoline. Mixture enrichment using propane is unnecessary during cold starts, thereby eliminating the emission penalty during warmup. Carbon monoxide and hydrocarbon emission using propane are unaffected by ambient temperature. The photochemical reactivity of hydrocarbon emission is considerably lower with propane than with gasoline.

Jan 1, 1972

By K. O. Bennington

The thermodynamic properties of hedenbergite, of composition [(Ca0,9516) (Mg0,0583Fe2+0.7134 Fe3+0.0934 Mn0,1366) (Si206)], were experimentally determined at the Bureau of Mines. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -680.96±0.855 kcal/mol. The standard enthalpy of formation from the oxides is AR-96 = -24.55±0.485 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 12.3 to 300.1 K. The derived standard entropy is S-98 - 41.218±0.148 cal/mol-K. High-temperature heat capacities were measured with a differential scanning calorim¬eter from 397 to 1,147 K. These experimentally determined data were combined with data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of measurements. Standard enthalpies of formation are given as a function of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -641.90±0.86 kcal/mol.

Jan 1, 1984

This NIOSH Toolbox Training program contains 52 different modules designed to stimulate safety discussions among your employees. Each module is intended to be completed in roughly 10 or 15 minutes, so a Toolbox Training session can be conducted once a week for the entire year. Each session counts toward your employee’s 8-hour annual MSHA refresher training, thus saving an entire day of work.. The modules are used to refresh employees on the procedures, policies, and practices of working safely at a specific mine site and can easily be tailored to fit conditions and situations found on your property. Every module follows the same format, so that as the weeks pass, miners will start to approach every safety situation in the same way. A typical Toolbox Training session contains five basic steps that cover all the information in the module. 1. Identification of the hazard and discussions about the types of injuries typically associated with the hazard. 2. Discussions of some of the causes of the hazard. The MSHA example included with each module should be referenced. 3. After the hazard and accident has been explained and understood, discussions about best practices and tips for avoiding a similar accident. 4. Review of similar conditions or near misses from your mine site using the leading questions on the form to start a discussion. Specific examples of equipment or structures on the site that could lead to the same accident should be discussed. The blank space on the module is used to add your own remarks and questions to supplement the given information. 5. Miners fill out the training record on the back of the form with name, initials, and date of training session. The modules are designed to be kept in a standard three-ring binder and easily photocopied. This way, the same set of modules can be used for years to come. A blank form is included that can be used to create more Toolbox Training modules. The key component of Toolbox Training is to start a discussion among employees that will allow them to see the hazards around them every day and respond to these hazards in a safe and consistent manner. To start a discussion, ask questions that need more than a one-word response. Get the miners to talk about similar situations from their own experiences and give suggestions about how to fix the hazards around them. Toolbox Training is a quick and effective way to cover specific mining hazards, but it only works if miners are involved in the discussion.

Jan 1, 2004

By Marvin L. Whisman

This report describes the preparation of tritium-labeled organic compounds to be used by the Federal Bureau of Mines in studying the role of certain gasoline constituents in gum-forming mechanisms. The gasoline constituents that have been investigated boil within a range of approximately 90 to 230° C. and can be classified as paraffins. naphthenes, olefins, diolefins, monocyclic aromatics, polycyclic aromatics, and organic sulfur, nitrogen,: and oxygen compounds. The technique of Wilzbach has been applied to more than 50 samples. Purification techniques have been developed that accomplish rapid and effective purification as well as removal of labile tritium in a one-step operation. Data are presented to show the rate of exchange between tritium and hydrogen that can be expected for a variety of compounds common to a full-boiling-range gasoline. These values should be useful to other investigators using tracer programs involving tritium labeled compounds.

Jan 1, 1961

By A. L. Engel

This report is a compilation of results of brief preliminary tests on sulfide ores that contained gold and silver and, in some cases base metals. It is a companion paper to a recent similar report on oxide ores. Simple treatment methods employing the least possible equipment sometimes produce satisfactory results on marginal ores and in small-scale operations. Investigations of typical ores from newly discovered or recently explored mining districts have been made in continuation of a long-established part of the hydrometallurgical and ore-dressing program of the Reno station, Bureau of Mines. The purpose of such investigations is to encourage the search for and development of mineral resources and particularly to assist in the economical exploitation of low-grade and marginal ores as well as the conservation and recovery .of values in products that were discarded from former operations because of inability to treat them profitably. Several of these investigations have been limited to preliminary tests of samples from prospecting operations, whereas same involved samples of old dumps or tailings piles. The test work in these cases was not extensive enough to warrant publication as individual reports, but is of considerable interest inasmuch as it indicates the possibilities as well as the limitations of treating the respective materials. The samples were representative of the districts from which they wore obtained, so this information should be helpful in the future development of these districts.

Jan 1, 1951

By A. C. Johnson

The Bureau of Mines explored the Three Kids deposit in 1941 as part of a strategic minerals program. Earlier mining and exploration had established the presence of a substantial tonnage of medium-grade wad ore, and drilling and sampling by the Bureau of Mines, in collaboration with the Federal Geological Survey, indicated an additional tonnage such that development and exploitation became more clearly feasible. Private interests, with Government support, undertook to produce metallurgical-grade manganese. The present paper describes the Bureau of Mines exploration and subsequent development. Manganese in the Three Kids area is found in one of the lower members of the Muddy Creek formation in a bed of fine sandstone and silt, which outcrops around the north edge of the River Mountains and generally dips 20° to 40° away from the hills. There is considerable variation in the thickness and grade of the ore. The ore is light weight, having a density of 1.2 to 2.

Jan 1, 1956

By D. Harrington

Every few weeks United States newspapers of 25 or 30 years age ran scare-heads telling of some mine disaster, which was a first-page attraction for a day or two and then was forgotton until another disaster occurred a few weeks later. Interspersed with these disasters were the so-called sniping mine accidents, causing the death of one or two mine workers. The summation of all types of mine fatalities usually exceeded 3,000 a year. In the period 1906-10, inclusive, there wore 84 major explosion disasters (or about 17 per year) in united States coal mines; the fatalities resulting from those disasters numbered 2,388 for the 5-year period. These frightful catastrophies helped to cause the total number of fatalities in our coal mines for the 5 years (including the fatalities from major explosions) to reach the enormous total of 13,288, an average of 2,658 per year. In addition, some hundreds of other typos of mining accidents swelled the annual fatality list to upwards of 3,000. This admittedly deplorable condition created so much Nation-wide comment that Congress was impressed with the necessity of having something done by the Federal Government with a view to trying to halt at least sonic of the excessive loss of life in our mines; in consequence, the Bureau of Mines was created and began to function in July 1910.

Jan 1, 1935

By Earle S. Burnett

Rotating piston deadweight gages have been used for many years for measurement of pressure to several hundred atmospheres. They have been calibrated by comparison of fluid pressures produced by various loads bearing on the piston bases, as measured by corresponding heights of balancing columns of mercury. When expressed in appropriate units, these ratios of column heights to piston loads are called piston constants. Experimental arrangements and procedures for their determination are presented in this paper, followed by a discussion of their significance and of their subsequent applications.

Jan 1, 1966

By J. S. Dunning

The objective of this research by the U.S. Bureau of Mines was to determine the effects of AI additions on the sulfidation resistance of Fe-Cr-Ni alloys. A series of Fe-Cr-Ni alloys with and without -additions of 4 pet AI were tested in a wet S vapor atmosphere at 677 C. A study of the morphology and composition of corrosion scales indicated a different corrosion mechanism for AI-free alloys compared with AI-containing alloys. Aluminum-containing alloys formed a compact, tightly adherent layer at the metal-scale interface that reduced corrosion rates by a factor of 3 to 10 compared with that of AI-free alloys. The thin, adherent AI-containing scale limited inward diffusion of 0 and S to the base metal and outward diffusion of Ni from the base metal. Aluminum-containing alloys formed a three-layer scale in oxidizing-S environments, while AI-free alloys formed a less protective two-layer scale.

Jan 1, 1989

By J. B. Zink, M. J. Peterson

A semiquantitative spectrochemical method was developed and applied to the analysis of ash of U.S. coals . A low- temperature ashing procedure was used to minimize the loss of volatile elements . The analytical procedure provides for the estimation of 68 elements including major , minor , and trace constituents . Standards for the trace elements were prepared in a synthetic base mixture that approximates the average composition of U.S. coal ashes . Excitation was achieved with a d- c arc , spectra were recorded photographically , and interpretation was made by visual comparison of spectra of unknowns with spectra of graded standards series . Thirty- six trace elements were found in the analysis of 900 samples . Details of the procedure are presented , including sample and standards preparation , excitation and exposure conditions , spectral lines used , and approximate limits of detectability .

Jan 1, 1964

By J. E. Hamak

This publication contains analyses and related source data for 266 natural gas samples from 20 States and 2 foreign countries. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of the U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1992

By H. J. Sloman

"INTRODUCTION Industry, including coal mining, has come to realize that to prevent accidents the human element must be given more consideration than was customary in the past. In formulating safety rules and regulations and in the enactment of laws governing mining, too often enforcement is emphasized rather than the means of gaining willing compliance.' The purpose of this paper is to call attention to the human side of accident prevention, and the approach to this important and much-discussed subject will deviate somewhat from the usual discussions.The human being is a complex mechanism, both physically and mentally. It is difficult to establish a common denominator for the actions of humans, except in general. In establishing mining laws, rules, regulations, and standards, the ultimate objective should be to gain the best possible response of workmen, so that optimum results in accident prevention may be obtained. The complexity of human beings is apparent when the many ways 1n which they differ are considered. Some of these differences are manifested in emotional and phlegmatic types, degrees of intellect or native intelligence; and in hopes, desires, aspirations, and philosophies of life. How much simpler ac¬cident prevention would be if the response to laws, rules, regulations, or standards were equivalent to the definite movements of puppets responding to pulls on strings. Each time, the strings are pulled in exactly the same way, the puppets will respond in exactly the same manner. Human beings, although having many similar characteristics, do not respond uniformly to identical ""string-pulling""; therefore, much study is necessary before the desired re¬sponses can be obtained. To achieve the ultimate in accident prevention, it must be ""worked at"" constantly. Regardless of the adequacy of safety laws, rules, regulations, or standards, good accident records will not ""roll in"" if dude consideration is not given to the personal traits of those most likely to be involved in accidents."

May 1, 1948

This report summarizes the results of a research project entitled "Fatal Accident Data Base Development." This project is the last project under Contract No. S0110601. Volumes I and 1I, "Industrial Engineering Study of Hazards Associated with Underground Coat Mine Production," summarize the original industrial engineering project and the Fatal Accident Report Analysis project. These projects were completed and accepted by the U.S. Bureau of Mines on December 10, 1971. Both volumes of the report have been made available by the Bureau to the public through the U. S. Department of Commerce technical information service. Another project under the same con tract, entitled "Equipment Operations Safety Study, ' was completed in January 1972 and the report was accepted by the U. S. B. M. at that time. The analysis in this Natal Accident. Data Lose Development report is closely related to analysis in both of the earlier reports. The original project involved an industrial engineering and safety of production operations for a representative sample of underground bituminous coal mines. The contactor was required to make recommendations 'in work practices, mining methods, equipment, and safety practices which can effectively reduce the fatality rate from rib and roof falls.' (Longwall mining methods were excluded from the study.) Time study and work element analyses were performed in over 50 mines as part of the field data gathering effort. Another requirement of the study was to develop sets of multiflow. Process charts, which are diagrammatic illustrations of the time-related interaction of mining, cycle job elements.

Jan 1, 1972

By W. M. McKewan

This U.S. Bureau of Mines report discusses wire ropes used for hoisting in U.S. mines. The in-formation presented was extracted from a large body of data compiled by the U.S. Mine Safety and Health Administration (MSHA) using a data base management system (DMS). Further, these extracted data were then manipulated to provide tables of data that show the types and amount of wire rope used for hoisting. This report describes the different types of wire ropes and how a DMS can be used to manipulate MSHA's wire rope inventory data. The data indicate that more 1-1/4-in-diam ropes, 6x27 construction ropes, and right lang lay ropes are used in U.S. mines than ropes of any other diameter, construction, or lay type.

Jan 1, 1991

By Robert M. Busche

[Recent developments in the gasification of coal, both by the Bureau of Mines and American industry, have intensified interest in the thermodynamic and kinetic principles necessary for understanding the reaction mechanism and rates and the physical changes that take place. In the course of a Bureau of Mines study of the kinetics of coal gasification at the Synthetic Liquid Fuels Demonstration Plant, Louisiana, Mo., a bibliography of approximately two references was compiled. They are listed n this publication and refer both to American and foreign sources.]

Jan 1, 1952

By D. E. Banks, J. K. H. Ma, Y. Rojanasakul, J. Y. C. Ma, C. J. Malanga

There is evidence to suggest that cell injury induced in alveolar macrophages (AM) following phagocytic activation by silica particles may be mediated through changes in intracellular free calcium [Ca 2+}. However, the mechanism of silicainduced cytotoxicity relative to [Ca2+], overloading is not yet clear. To provide a better insight into this mechanism, isolated rat AMs were exposed to varying concentrations of crystalline silica (particle size< 5 µm in diameter) and the fluctuation in their [Ca2+]; and cell integrity were quantitatively monitored with the fluorescent calcium probe, Fura-2 AM, and the membrane integrity indicator, propidium iodide (Pl). Results from this study indicate that silica can rapidly increase [Ca2+]; in a dose-dependent manner with a characteristic transient calcium rise at low doses (<0.1 mg/ml) and an elevated and sustained rise at high doses (>0.1 mg/ml). Depletion of extracellular calcium [Ca 2+]0 markedly inhibited the [Ca2+]; rise (˜90%), suggesting that Ca2+ influx from extracellular source is a major mechanism for silica-induced [Ca2+]; rise. When used at low doses but sufficient to cause a transient [Ca2+]; rise, silica did not cause significant increase in cellular Pl uptake during the time of study, suggesting the presevation of membrane integrity of AMs under these conditions. At high doses of silica, however, a marked increase in Pl nuclear fluorescence was observed. Depletion of [Ca 2+] 0 greatly inhibited cellular Pl uptake, induced by 0. 1 mg/ml or higher doses of silica. This suggests that Ca 2 + influx, as a result of silica activation, is associated with cell injury. Indeed, our results further demonstrated that the low dose effect of silica on Ca 2+ influx is inhibited by the Ca2+ channel blocker nifedipine. At high doses of silica (>0.1 mg/ml), cell injury was not prevented by nifedipine or extracellular Ca2+ depletion, suggesting that other cytotoxic mechanisms, i.e., nonspecific membrane damage due to lipid peroxidation, are also responsible for the silica-induced cell injury. Silica had no significant effect on cellular ATP content during the time course of the study, indicating that the observed silicainduced (Ca2 ... ); rise was not due to the impairment of Ca2 + -ATPase pumps, which restricts Ca2+ efflux. Pretreatment of the cells with cytochalasin B to block phagocytosis failed to prevent the effect of silica on [Ca2+]; rise. Taken together, these results suggest that the elevation of [Ca2+]; caused by silica is due mainly to Ca2+ influx through plasma membrane Ca2+,channels and nonspecific membrane damage (at high doses). Neither ATP depletion nor Ca2+ leakage during phagocytosis was attributed to the silica-induced [Ca2+]; rise.

Nov 1, 1995

By W. W. Adams

"A recent paper prepared by the writer summarized the results of an analysis of the accident records of 34 metal mines for the calendar year 1925. The present paper summarizes the results of a similar analysis of the accident records of 59 coal mines for the same year. This summary is based upon reports furnished to the Bureau of Mines, Department of Commerce, by operating companies that par¬ticipated in the National Safety Competition of 1925.The purpose of the Competition was to establish the lowest accident-severity rate, thus showing the smallest loss of time from accidents in proportion to total number of man-hours worked. The reports covered all lost-time accidents that occurred during the year, that is, all accidents that disabled an employee beyond the day or shift on which the accident occurred. Detailed information for each of the 59 coal mines is given in the appended table. Each mine employed at least fifty men underground; over half of than employed more than 200 men underground. Hence the accident records should be typical of those of large-scale mining operations in general where the company is devoting special attention to accident-prevention work. The mines covered by the reports are situated in eleven States: Alabama, Illinois, Indiana, Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Utah, Washington, and West Virginia.A tabulation of the reports covering the 59 mines showed an accident-frequency rate of 123 per million hours of ""exposure* and an accident-severity rate of 10.214 per thousand hours of exposure3. The total volume of exposure or employment was 29,117,561 hours, representing the equivalent of work of 12,000 men for three hundred 8-hour shifts. The records covered employment and accident above ground as well as underground, although they did not include stripping or open-pit mining. Accidents during the year resulted in 33 deaths, 1 permanent total disability, 28 permanent partial disabilities, and 3,510 temporary injuries. These accidents represented a loss of tine equal to 297,417 man days. In arriving at this lost-time equivalent, each fatality and permanent total disability was weighted at 6,000 lost days (see footnote 3), as specified in the scale adopted by the International Association of Industrial Accident Boards and Commissions; permanent partial disabilities were weighted according to nature of injury, in accordance with the scale adopted by the :Board; temporary injuries were weighted according to the actual number of calendar days during which the employee was incapacitated as a result of the injury."

Nov 1, 1926