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By G. H. Martindill

Complex chemical and physical changes occurring during carbonization result in a heterogeneous system composed of gaseous, liquid, and solid phases, whose relative proportions and chemical compositions change constantly as temperature increases. Studies in which the participating variables are isolated and controlled should be useful in formulating the mechanism of coal carbonization. The most characteristic property of a coking coal is its ability to form a plastic mass at a certain stage of the carbonization process. During this period it is believed that fluidity of the coal influences the properties of the resultant coke. This report gives results of an investigation by the Federal Bureau of Mines of the influence of the maximum fluidity attained by the charge on the physical quality of the coke or char produced. As a first approach to the problem, researchers investigated high-melting-point pitches, which are relatively simple carbonaceous materials. The plastic properties of these pitches, prepared specially for this work, varied greatly; their fluidities, as measured by the Gieseler plastometer, covered most of the fluidity range characteristic of coking coals. Blending these pitches with increasing pro-portions of fine coke progressively reduced their fluidities. Coal-pitch and coal-coke blends also were treated; their fluidities were varied by changing their blending ratios. The various blends were carbonized in a small-scale carbonizer and the resistance of the carbonized residue (char) to abrasion was determined in a small-scale tumbler test, using the Roga drum.

Jan 1, 1960

By F. G. Miller

[Petroleum technoloF;istz and 1 rot-re s s ive OT e:?ztors. con stantl;, are striving to increase the percentage of oil that y to recovered from reservoir rocks throe::;:: wells. The exhaustive studies that have been made of the function of natural r:; as in t h-_ T r odI action of oil, for cx<n.mTnle, have aidedd of.erators greatly in incroasin,&apos; the q-:Arrntity of oil recovered from reservoirs. i.rtural gas dissolv3d in ar--d otinerwwisa &apos;1s&apos;.,ocintjd under rre3suro with oil in roscrvoir roci.s, howover, i:; not the only source of energy available for moving oil through sa&apos;:&apos;l to wells. l becoming "reservoir-energy conscious&apos;t engineers hr-vo -d o^.rued t}:-Lt in many petroleum reservoirs the edgewater flanking t -,e oil accum.-,lation conetitutos a potential source of onergy capable, tL-ou;_h rro? gr control, oil&apos; increasing oil-recovery efficiencies materially. i o ]enter is ti-.-,, on-cronchinunt of water into the oil- and gas--fillod ?art of the reservoir considered as an evil to be combatted by devious mot&apos;:r:ci :i,.t r,ttL er a natural conseque::c4, incident to the withdrawal of oil nna gas from the wells, that nay be T.usod advantrt eou ;ly in lonr`t}toning tr e r&apos;lowin g lift of wells a.nd, i norcas in:; the economic recovery of oil and Little is known about the by which water off: oratos in driving nil throe:gh reservoir roc:-.:,, nd i:. a scorcity of rubli:;Lad informs-¬t .on nn rates of :)Ov.:m.,:- t of : r.tcr ..at v:1:11 res,-_lt in ^r i-nu oil recoveries. Bureau of :fines engine_:? ; - reciate. the r,aucity of scientific knowledge or. the &apos;test methods of a,r.lying the natural water arive to in¬crease oil-recovery efficiencies ant ,i.;?l __-itir?,~ ting irties that will, they hope, Contribute to t.1&apos;.e T ros?Jr.t. small _ %nd of information now av tilable on tt:e cubjoct. This r».crt a oyno-.::is or brief comrilnt.ion of r,ublished data and thought accuinulnt.~d so far, to la)or;~.tory ox-:erimnntrr¬tiorn and, further rosoarch on the z_rrinciplos unri;rlyir..g the natr.rr+1 eater drive no it nffocts oil recovery. :Lie writer:: Lore that t.i.c cx-nositiorn of a?rzilable inforr-at ion i rcs?r.toi in the rernrt r .-II .i ,.1rtt cor_jt_-i:ctive tho.-_.I_t and efforts loadir,-z to -:ard more con.r .ote extraction n;&apos; o tl from reservoirs.]

Jan 1, 1938

By M. Didyk

In this report, the application of the PHU/MVS program is demonstrated through the use of a simple but realistic mine ventilation program. The report details, the problem description, the input data required and the various output features of the simulator. The PSU/MVS program is written in Fortran IV for use with IBM 370/168 computers. A version of the program that can be used in CDC computers is also available. A ventilation network consisting of 531 branches, 300 nodes and 5 fans took 48 seconds for solution on The Pennsylvania State University&apos;s IBM 370/168 computer. Appendix I of this report is the User?s Manual for the program. Appendices II and III contain the input data listing, and selected output listing for; the application. Appendix IV provides tables for leakage, friction factors and shape factors.

Jan 1, 1977

By Paul M. Tyler

The alkali metals , sodium and potassium , and more particularly sodium , occur abundantly in chemical combination with other elements . The elements themselves are available in metallic form but are so active chemically that they oxidize rapidly in contact merely with the air . Potassium will even catch fire spontaneously in air , and both the metals will decompose water with explosive violence . Inasmuch as they are almost as soft as wax they are not suitable for the structural or other mechanical uses characteristic of ordinary metals , and consequently the uses of these elements even in the metallic condition are based upon chemical rather than physical qualities . Sodium metal is used largely as a commercial reducing agent , but potassium metal is rarely found outside of chemical laboratories . Numerous salts and other compounds of these elements enter largely into world trade and are commercially very important , but none of these compounds except sodium peroxide and sodium cyanide are made economically from the metals . Sodium is generally considered as rather an uncommon metal , but in point of annual tonnage produced it is far more important than mercury , magnesium , molybdenum , bismuth, cadmium, cobalt , gold , silver , or the various rarer metals .

Apr 1, 1932

By D. H. Chambers, Arnold M. Lansche

Electro recovery by amalgam methods was investigated to determine the feasibility of recovering pure cadmium from cadmium sponge produced during purification of zinc electrolyte at electrolytic zinc plants . Actual material used in this work was air- oxidized cadmium sponge . An acid rinse and zinc displacement technique was developed to amalgamate this oxidized cadmium . ( In - plant use of the recovery process would probably not require this step because of the fresh state of the sponge . ) Zinc was completely removed from amalgamated sponge by selective oxidation with air . Zinc - free cadmium amalgam was circulated by an electromagnetic pump through an electrolytic cell where cadmium of 99.9+ percent purity was electrodeposited onto a rotating aluminum cathode . Polarographic methods were developed for determining cadmium and zinc in mercury and in sulfuric acid solution .

Jan 1, 1964

By G. W. Jones, F. E. Scott, R. E. Kennedy

Methylene chloride , dichloromethane CH2C12 , a low - boiling and highly volatile organic chlorinated compound, is used extensively as a refrigerant in air conditioning installations , as an intermediate in organic synthesis , and as a solvent for cellulose acetate and other materials . As its vapors are not inflammable in air at ordinary temperatures , it can be used to advantage where it would be highly dangerous to use ordinarily inflammable solvents . The question has been raised as to its inflammable range in pure oxygen and in air enriched with oxygen . To find the answer to this question, tests were carried out with various mixtures of methylene chloride , oxygen, and nitrogen mixtures . It was found that methylene chloride has wide limits of inflammability in pure oxygen . Additional tests were then made to establish the complete range of inflammability of these gases . The methylene chloride employed in the tests was cbtained from the Eastman Kodak Co. It had a reported boiling range of 40.5 ° to 42.0 ° C. and a density of 1.322 at 20 ° C.

Oct 1, 1943

By Hamid N. Maleki

Cooperative efforts by the Bureau of Mines and Agapito & Associates, Inc., Grand Junction, CO, achieved the research objective of showing that data from measurements of the rate and change in rate of mine roof movement can be effective in detecting roof instability. Several instruments and techniques have been used to monitor roof movement and to detect imminent roof caves during pillar robbing. Early detection of unstable conditions can provide time either to withdraw personnel and equipment or to allocate supplemental support to prevent injury or down-time. Critical convergence rates were determined both manually and electronically. The detection of critical rate of movement has been shown to be an effective tool in ground control efforts.

Jan 1, 1988

By Fei Chen, Lesley J. Gaydos, Laurence M. Demers, Douglas C. Kuhn

The fibrogenic effects of silica in experimental animals and humans has been extensively studied (I 7, 20). However, the pathogenesis and molecular mechanisms underlying lung injury and fibrosis resulting from silica exposure remain to be elucidated. It is well-documented that silica can stimulate monocyte-macrophage lineage cells to produce cytokines and growth factors, including interleukin-I (IL- I) (20), tumor necrosis factor-ex (TNF-cx) (I 7), insulin-like growth factor-I (IGF-1) (4), and transforming growth factor-P (TGF-P) (24). Consequently, it has been suggested that the fibrogenic effect of silica may be mediated by cytokines in the fater stages of silicosis. During the early phase of interaction between silica and the pulmonary alveolar macrophage, several direct and indirect lines of evidence suggest that reactive oxygen intermediates (ROI) may play a pivotal role in silica- induced tissue damage (2I, 22). One of the most important components of and contributors to ROI is nitric oxide (NO) produced from L-arginine and molecular oxygen under the catalytic influence of NO synthase (NOS) (I 9). At present, at least three NOS genes have been cloned: a constitutive neuron NOS, a constitutive endothelial cell NOS and an inducible NOS (iNOS) (16). A number of factors have been shown to differentially induce iNOS gene expression in different cell lines including bacterial cell products and foreign antigens. During inflammation, NO is a double-edged sword in terms of the host immune defense mechanisms and the physiologic response to an inflammatory insult. The macrophage is one of the major cellular sources of NO. During the early phase of acute inflammation, NO produced from the macrophage appears to facilitate the clearance of pathogens and promotes a local relaxation effect on the microcirculation of vascular smooth muscle. When the production of NO is left unattenuated, especially under oxidative stress, direct cytotoxic effects of NO can emerge through the formation of peroxynitrite as a result of a reaction between NO and superoxide (2).

Jan 1, 1998

By J. E. Crawshaw

"The few previous observations of the effect of turbulence on limits of inflammability have been made on a small scale in turbulence produced either by a fan or by movement of the mixture.By a suitable amount of turbulence from a fan the lower limit of methane was 5 per cent as compared with 5 per cent observed for quiescent mixtures in the same vessel.3 With a streaming movement of the gas mixture within the range of speed from 35 to 65 centimeters per second (69 to 128 feet a minute) the lower limit was approximately 5 percent,4 For a quiescent mixture of ethane the lower limit was 3.10 per cent ethane, but with fan running at a moderate speed a 3 per cent mixture exploded.5The object of the tests herein reported was (1) to determine the lower limit of natural gas in a mixture of natural gas and air Which would be ignited and propagate violently when the turbulence was produced by explosives fired from a cannon into the mixture; (2) to observe the behavior when the mixture contained less than this low limit; and (3) to determine how turbulence produced by a fan affects thin limit.Four series of tests were run, three of which were to determine the effect of different sources of ignition: Tests with (1) an electric igniter; (2) 3F black blasting powder stemmed with 2 pounds of dry fire clay stemming used to ignite the mixture, and (3) 40 per cent straight nitroglycerin dynamite unstemmed. The fourth was made to study the effect of turbulence produced by a two-speed electric fan, using an electric igniter as the source of ignition.In both series of tests with explosives, charges of 50 and 200 were used to determine the effect of increased quantity of explosives on the lower limit of natural gas."

Jul 1, 1930

By Alan A. Bergeron, J. L. Michels, R. L. Collins

Advanced communication and monitoring systems were developed and demonstrated in three underground mines representing different mining techniques, geographical areas, and material mined. The first mine was a large coal mine in western Pennsylvania that used room and pillar techniques and continuous mining methods. The system developed for this mine provided private telephone channels, environmental monitoring, and control of underground equipment, all on a single coaxial cable, with all system operations under the direction of a minicomputer. Many advanced features were incorporated into the system, such as paging of roving personnel, two-way section wireless, through-the-earth emergency communication, and redundant signal paths. Television was multiplexed into the system for underground equipment surveillance. A hoist radio system completed the complement of equipment at the mine. The second mine was a magnetite ore mine in eastern Pennsylvania that used block caving mining techniques. A radio system was developed that provided two-way communications between trackless vehicles and roving personnel. A unique system of uhf/vhf repeaters combined with a flleaky-feeder" transmission line offered operational and emergency features not previously found in mine communication systems. Evacuation alarming, personnel paging, fan-hole drill operator communications, and maintenance and safety vehicle dispatch were provided. The system required no dispatcher and operated during power failure. A hoist communications/shaft inspection system completed the installation. The third mine was a deep silver mine in the Cour d’Alene district of Idaho. The system developed for this mine utilizes a single wire pair to provide up to 14 voice channels. A unique combination of PBX, telephone carrier system, and intercoms offered private conversations, selective signaling, and emergency backup communications. Two hoist communication systems were installed to provide a voice link and in-cage belling signal between hoistman and cage.

Jan 11, 1981

By Lloyd Williams

1. This investigation shows that the Poplar Creek is the most important bed in Scott County from a production standpoint. Although the Poplar Creek bed contains the largest reserve, the Big Mary has a larger recoverable reserve. Estimates of reserves also have been made for the Pewee, Red Ash, Windrock, Upper Pioneer, Jellico, and White Oak beds. 2. Known measured and indicated reserves of coal, based on a minimum bed thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated to be 143 million tons as of January 1, 1954. Of this total, 74 million tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By James C. Cawley

The Bureau of Mines has empirically determined ignition probability versus current for resistive circuits in an 8.3% methane-air atmosphere. Simple ignition probability, defined as the number of ignitions divided by the total number of sparks, was determined, and the corresponding currents were recorded. The experiment was designed to minimize the probability of not observing an ignition that should occur during a series of tests. For resistive circuits in 8.3% methane-air mixtures, the experimental results indicate that ignition was not achieved below 2,000 rnA at 20 V dc, 350 rnA at 30 V dc, 150 rnA at 40 V dc, and 175 rnA at 50 V dc. The simple probability of ignition corresponding to these currents is esti-mated to be, respectively, 1.0 x 10-6, 1.7 x 10-7, 3.0 x 10-7, and 1.0 x 10-5 The ignition mechanism seems to break down below this point, implying that a threshold current value exists below which spark ignition does not occur.

Jan 1, 1987

By Lloyd A. Morley

This report abstracts project work performed under USBM Grant GO155003 during the period 4 November 1975 to 3 November 1976. The research was funded, as a continuance of previous support from USBM Grants GO133077 and G0155003, to gain further knowledge in mine electrical system safety. Five reports have been separately produced, all under the grant title, "Coal Mine Electrical System Evaluation," and are as follows: 1. Volume I - Continuous Monitoring, 2. Volume II - Transient Analysis, 3. Volume III - Shielded Cables, 4. Volume IV - Computer Modeling, and 5. Volume V - Battery and Battery-charging Safety. Abstracts of these comprise the balance of this document with one exception. The task ?d-c offsett currents," does not fall under the scope of the other report volumes and, further, the material to be presented does not justify a separate report. Hence, this subject concludes the Executive Summary.

Jan 1, 1977

By R. Hogg

"The basic population balance models for agglomeration processes are reviewed and procedures are described for extending their applicability to systems with size-dependent rate constants and to the formation and growth of porous agglomerates from rigid, solid particles. Simplified procedures for the further extension of the models to include simultaneous agglomerate growth and breakage arc also described. IntroductionThe association of small particles into clusters or agglomerates is a significant factor in many facets of particle processing. Agglomeration processes are widely used to facilitate handling, storage and utilization of fine powders. Processes such as coagulation or flocculation are used to aid solid-fluid separation in dispersed particulate systems. Agglomeration also occurs as an accompaniment, often unwanted, to other particulate processing operations such as fine grinding, mixing and blending, transport and flow.Reliable agglomeration models are needed for improved understanding of the processes in general and of the complex role of numerous, interacting variables as well as for direct application to the design and control of industrial processes such as flocculation, granulation and pelletization. Ideally, the models should account for the primary forces responsible for agglomerate ·formation and growth, the effects of external forces on process dynamics, the development of agglomerate structure and its role in the process itself, and the effects of concurrent processes such as structure modification (e.g. compaction) and agglomerate breakage or degradation.In its most general form, the process of agglomeration involves taking discrete, independent particles, bringing them into contact with one another, promoting (or allowing) interparticle adhesion to occur and then causing structure rearrangement, usually under the action of external forces. The relative importance of these steps varies with the nature of the particulate system being agglomerated and with the kinds of agglomerates being produced. Coagulation or flocculation of particles dispersed in fluids is generally dominated by the contact and adhesion steps. In the granulation of powders, on the other hand, particles are already in contact so that structure rearrangement is the principal step."

Mar 1, 1992

With a growing concern over mine fires, prevention and suppression are hot topics. NIOSH researchers Michael Trevits, Alex Smith and Edward Thimons discuss their research in the area. The leading causes of US mine fires include flame cutting and, welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions and spontaneous combustion. From 1990 through 2007, there were 1601 reportable fires that occurred in the US mining industry -an average of 89 fires per year. The fact that mine fires are occurring with alarming regularity reinforces the importance of recognizing and eliminating the potential hazards. These statistics also show the need for improved control and suppression technology to ensure worker health and safety if a mine fire does occur.

Jan 1, 2008

By Liane L. M. Kadnuck

This report summarizes the results of a hydrologic research study conducted by the U.S. Bureau of Mines (USBM) in cooperation with Energy West Mining Co. at the Deer Creek and Cottonwood Mines, near Orangeville, UT. The USBM evaluated hydrologic and overburden failure data to assess the response of local ground water to underground coal mining in single-and multiple-seam conditions. Fourteen springs located over the two mines were investigated in the study along with overburden failure response caused by longwall panel extraction. Spring discharge was compared to climatic variation and time of undermining to quantify response to undermining. Spring discharge had been reduced owing to below-normal precipitation during the period evaluated. The response of springs to mining in the vicinity was influenced in part by the thick overburden present at the study site the presence of hydrophilic clays and mudstones in the overburden stratigraphy, and elevation of the springs above mine level, which buffered the effects of undermining.

Jan 1, 1994

By Michael G. Zabetakis, Israel Liebman, Henry E. Perlee

Flammability studies conducted to date on stratified methane - air and pentane - air mixtures in air indicate that location and extent of a flammable layer are affected by molecular diffusion , gas motion , and propagation of flame . In initially quiescent mixtures , the lower limit - of - flammability zone may be determined by assuming molecular diffusion alone governs mixing rate . The upper limit - of - flammability zone can be predicted in this manner only for stratified layers with small concentration gradients ( less than 0.2 volumepercent per inch ) ; where large concentration gradients are encountered ( for example , as much as 30 volume - percent per inch ) , the initial - mixture methane concentrations that yield flammable mixtures are larger than anticipated . Flames propagating through heterogeneous quiescent methane - air atmospheres in the direction of the concentration gradient exhibit flame speeds at any point that corresponds to the flame speed of the homogeneous gas mixture having the same gas composition as that of the point in the heterogeneous system . In flowing mixtures with large concentration gradients , the degree of mixing prior to ignition does not appear to affect the flame velocity and emitted radiation appreciably in a 6.5 - ft - diameter gallery .

Jan 1, 1964

By J. H. Field

Synthesis of hydrocarbons by the Fischer-Tropsch reaction in a hot-gas- recycle system was demonstrated to be technically feasible. This project was undertaken, by the Bureau of Mines, to determine if the system was operable and to ascertain the optimum conditions for the production of gasoline. Carbon steel turnings packed with a void volume from 88 to 90 pct. were satisfactory catalysts, but steel catalysts with greater void volume, either turnings or steel wool, were not as active. Good temperature control with a pressure drop of less than 0.5 pounds per square inch (p.s,i,) per foot of catalyst bed of turnings was obtained by operating with a recycle to fresh feed ratio of 20 and by splitting the total gas flaw and injecting portions into the reactor at different entry ports.

Jan 1, 1961

By Carlton E. Brown

This report contains information on the cells or containers used to hold a known small depth (usually 1 mm. or less) of the dust-containing liquid from impinger, 5/6/ filter-paper,7/ and other samples collected from the air while the particles revealed by a microscope (equipped with a 16-mm., 0.25- or 0.50-N. A. objective and ordinarily used with axial light-field illumination) are counted in order to obtain an index of the concentration of dust in the sampled air. Information is given on such subjects as the kinds of cells available, kinds used, actual depths of cells, and construction of simple, inexpensive cells. ACKNOWLEDGMENTS The interest, encouragement, and assistance received from H. H. Schrenk, chief chemist of the Health Division, in the preparation of this report are gratefully acknowledged, as &apos;is all other assistance received.

Jan 1, 1945

By Edward Cogan

Equilibrium phase diagram studies of zirconium- rare earth metal alloys by the Bureau of Mines at its Albany Metallurgy Research Center prompted the development of a rapid gravimetric method for determining rare earths in zirconium in which the rare earths are absorbed from sulfuric acid solution of the alloy on a cation exchange resin . The sample in 10 percent H2SO4 is introduced into the column , the zirconium is eluted with 10 percent H2SO4 , and the rare earths are eluted with (NH4 )2SO4 solution and precipitated with NH4OH . A tracer technique was employed to determine the efficiency of the procedure . Y203 and europium 154 - 152 (Oak Ridge ) were added to 10 g of zirconium and taken through the entire procedure . Recovery averaged 97.6 percent on 0.002 μg europium in the rare earth fraction . Rare earths were determined in the range 0.10 to 90 percent .

Jan 1, 1964