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By M. D. Schlesinger

As part of the development of processes for producing synthetic fuels from coal, the Bureau of Mines prepared a special jet fuel in a pilot plant for evaluation by the Air Force. This jet fuel had all the required physical properties, including the important specifications of high heating value and high density. However, the finished fuel did not pass the stability test specified by the Air Force and conducted by the Southwest Research Institute in a high-temperature research coker. The cause for this instability is being investigated because pure compounds of the type identified in this fuel are known to be stable. The tar acid oil used was a 230° to 300° C. fraction of low-temperature tar obtained by carbonization of a West Virginia bituminous coal in the pilot plant of the Consolidation Coal Co. Both the desulfurization at 400° C. and saturation at 300" C. were done in the vapor phase at 2,500 p.s.i.g. After catalytic treatment and distillation the final jet fuel had a boiling range of 194° to 247° C., a net heating value of 18,420 B.t.u./lb. and a specific gravity of 0.8463 60° F./60° F. It also had u pour point below -62° C., and at 0° C. its viscosity was 4.5 cs. The oil was virtually all bicyclic, 41 pct. noncondensed and 56 pct. condensed.

Jan 1, 1961

To improve the air quality in large-opening stone mines by developing better ventilation techniques, including appropriate fan selection in conjunction with air-coursing methods. Background Stone mines are the most common underground large-entry mines in the United States. Data from the Mine Safety and Health Administration (MSHA) for the year 2000 indicate that there were 162 active nonmetal underground mines in the United States, of which 117 were stone mines. Many underground stone mines are drift mines developed from previous quarry operations. Typically, these room-and-pillar mines have entries that are 20 ft or higher and at least 40 ft wide. These large dimensions lead to a very small ventilating pressure loss, even when significant air quantities move through the mine. This is especially true of drift mine operations where ventilating pressure losses of <0.25 in w.g. are common. Underground stone mines with shafts that are<200 ft deep typically have ventilating pressure losses that are <2 in w.g. The pressure losses through these mines are much lower than those of a typical coal mine or deep metal/nonmetal mine. Therefore, the ventilation techniques and principles are quite different. In addition, because of new MSHA regulations that limit the concentration of diesel particulate matter, these mines may need to greatly increase their ventilation airflow. Therefore, large-opening mines need a fan that can move large air quantities and operate at low static pressures. There are three fan types for mine ventilation: centrifugal, axial vane, and propeller. Centrifugal fans are uncommon in underground stone mines as they are often associated with mines requiring the highest of ventilation pressures. Axial vane fans are widely used in all types of mining operations. They are the most common fan type currently found in underground large-opening stone mines. However, they typically do not operate at low static pressures with high efficiency. Propeller fans are currently uncommon in underground stone mines. They are designed for low static pressures and large air quantities at higher efficiency. This fan type best suits the ventilation needs in large-opening stone mines?they produce large air quantities at low pressure losses. Mines with air shafts<100 ft long and at least 12 ft in diameter have fairly low mine static pressures and may also benefit from propeller fans.

Dec 1, 2002

By Robert B. Worthington

This investigation was undertaken to develop a more efficient copper smelting practice that would help meet the increasingly stringent antipollution standards. Continuous smelting to copper and a 0.8-to 5-percent copper slag using pure oxygen has been demonstrated for several hours at a time in a unique double furnace, which was devised to overcome the heat losses inherent in a laboratory furnace. The use of pure oxygen to effect the smelting and conversion of copper sulfide concentrate in a single unit to produce blister copper and a very high S02 concentration provides a much reduced gas volume for more economical and thorough sulfur recovery. Although the process was successfully demonstrated for several hours at a time, extended test work using longer runs will be required to balance the system and to obtain test data for adequately demonstrating its technical feasibility.

Jan 1, 1973

By Sam S. Taylor

The disposal of oil-field brines by injection into subsurface formations other than fresh-water-bearing strata is a positive method of eliminating the harmful effects of mineralized water on fresh-water supplies, vegetation, and aquatic and other animal life. The methods used most generally for the disposal of brines produced with oil are (1) impounding in evaporation ponds, (2) controlled diversion into surface streams, and (3) injection into subsurface formations. Various States recognize one or more of the methods as legally authorized procedure. As a general rule, impounding brine in ponds and solar evaporation have not been entirely successful, principally because of the large volumes handled; the porous nature of the soil, and the low rate of evaporation. Likewise, the diversion of brine into freshwater streams by controlled dilution has not proved satisfactory in some areas, especially in parts of Kansas and Oklahoma where the rainfall is relatively low, because it has been impossible to obtain enough fresh water for such dilution.

Jan 1, 1939

By A. Landsberg

Chlorination of sulfide minerals and several prepared metal sulfides was studied. The resulting data were analyzed with respect to kinetics of the reactions and application to nonpolluting methods of winning metals from sulfide ores. Sulfides of iron, copper-iron, nickel, lead, zinc, silver, bismuth, arsenic, rhenium, molybdenum, and tungsten were investigated at temperatures up to 600° C. Copper-iron, lead, and zinc sulfides showed at least some product-controlled (parabolic) kinetics at the lower temperatures within the temperature ranges studied, but only nickel and silver sulfides had chlorination rates controlled by parabolic reaction kinetics in the commercially important temperature range of 450° to 600° C.

Jan 1, 1975

By J. Roth

The purpose of the present study is to increase the safety of explosive storage. This was accomplished by: a) review of the histories of recent and past magazine explosions to define causes and trends; b) observation of present-day explosive storage conditions and practices at active mines; c) examination of existing Federal regulations on explosive storage to determine whether they address all conceivable safety problems, whether they contain redundant or obsolete standards, and whether their intent is clearly stated; d) recommendation, for safety improvements and for revision and clarification (if necessity) of governmental regulations. Magazine explosions are rare. A recent increase in magazine explosion frequency must be attributed to a large increase in deliberate (criminal or malicious mischief) explosions. Fires of various origins account for the remaining explosions of the past decade. During 1884-1926 several lightning-generated explosions occurred in non-metal magazines, but none recently. It appears that the contents of a well-constructed, metal magazine are immune to direct lightning strikes, regardless of whether the magazine is grounded or not grounded. Grounding a metal magazine cannot be harmful, but it may well be superfluous. Magazines were observed at 34 widely separated mines and storage problems were discussed with personnel at these mines. In general, storage conditions and practices were found to be satisfactory. Usually, only small quantities of explosives are stored on mine property since most explosives are brought in by suppliers when needed. MSHA and BATF standards on explosive storage appear to cover safety aspects adequately. However, certain revisions are recommended to clarify some of these standards and to reduce inconsistencies in their enforcement.

Jan 1, 1983

By Michael Schmitz, John A. Organiscak

ABSTRACT: A method (patent pending) has been developed to determine the quality of environmental cab filtration systems. This method utilizes specially configured filter cartridges to remove carbon dioxide from the ambient air with the environmental cab’s air filtration system. A real-time gas monitor is placed inside an unoccupied cab with the filtration system running to time decay the carbon dioxide to its lowest concentration or equilibrium level. The outside carbon dioxide concentration level can be measured concurrently with another gas monitor or with the same inside cab gas monitor during a representative period before and after the inside sampling is conducted. Cab filtration system leakage is comparatively deduced from the difference between the special cartridge filter efficiency and overall cab efficiency. Laboratory trials have illustrated that desirable high efficiency test filter configurations (greater than 99 % efficiency) can be devised, but have air quantity and test time limitations. These trials also demonstrated that CO2 penetration was reflective of controlled air leaks around a high efficiency filter under equilibrium conditions. This report examines the elements of this patent pending method.

By F. E. Walker

The Bureau of Mines determined total sulfur and sulfur forms for coal in 283 counties in 29 States and 2 fields of the State of Alaska. Specifically, organic, pyritic, and sulfate sulfur were measured of approximately 2,900 samples, and they include most of the coalbeds in the United States.

Jan 1, 1966

By F. E. Walker

The Bureau of Mines determined total sulfur and sulfur forms for coal in 283 counties in 29 States and 2 fields of the State of Alaska. Specifically, organic, pyritic, and sulfate sulfur were measured of approximately 2,900 samples, and they include most of the coalbeds in the United States.

Jan 1, 1966

By William M. Schafer

Forage plots were established on agricultural lands contaminated by acid mining waste. The acid produced through oxidation of pyrite and other sulfides caused elevated solubility and plant availability of copper, zinc, and arsenic which killed vegetation and polluted surface and groundwater. Soil amendments including agricultural lime (CaCO3), hydrated lime (Ca(OH)2), phosphorus, and organic matter were used to reduce the toxicity of metals. Several acid-tolerant grasses were used to vegetate the amended soils. Various soil extraction techniques were used to see which best correlated with vegetation performance. The extractions corresponded to three "forms" of metals in soil including soluble (water-saturation extract); plant-available/weakly adsorbed (DTPA extract); and total (HNO3/H202 extract). Of the extractants tested the DTPA levels appeared to correlate best with metal levels in plant tissue. The DTPA soil extractant serves as a useful tool in predicting potential phytotoxicity of mine waste materials.

Jan 1, 1989

By Jr. Sayre

Results of studies of reservoir and wax-precipitation temperatures relating to wax deposition in the reservoir of the Bradford oil field are presented in this report. During 1949 and 1950 Bureau of Mines engineers made temperature measurements in 42 wells, which indicate that the Bradford Third-sand temperatures range from 59.7° F., at 1,150 feet, to 71.9° F., at 2,040 feet. Reservoir temperatures measured at the same depths in newly drilled wells and oil-producing wells differed as much as 4.5u F. Injection-well temperatures measured during water injection showed that the temperature of the water entering the sand was 11.5° F. lower than reservoir temperatures before injection. The cooling in the formation resulting froth the injection of low-temperature water was 11.5° F. in the vicinity of the injection-well bore, and a maximum of 2.1° F. 200 feet from the injection well. Sand temperature, after 5 months of water injection, was reduced 1.5° F. 90 feet from water-injection wells. The temperature at which wax begins to precipitate from solution in crude oil was determined at atmospheric pressure for 26 samples and ranged from 51° to 67° F. Oil samples from wells producing no water had wax-precipitation temperatures ranging from 51° to 58° F. and wax contents from 2.20 to 2.97 weight percent, whereas the samples from wells producing water and oil had wax precipitation temperatures ranging from 580 to 67° F. and wax contents from 2.57 to 3.42 weight percent .

Jan 1, 1952

By J. W. Stevenson

The Bureau of Mines investigated the influence that atmospheric pressure changes exert in a gassy coal mil on a ventilating air current with a system of bleeder entries. During the season when abnormal barometric fluctuations usually occur, recording instruments monitored the air current ventilating an active coal-producing area. It HL he rate of coal production caused a more significant change in methane concentration than did barometric change. The hazard that accompanies methane release due to expansion of the gob gases during atmospheric lows was minimized by the effective bleeder system.

Jan 1, 1966

By Mark I. Copeland

This study was conducted by the Bureau of Mines to determine the effect of steel reheating practices in burning natural gas on the amount of silicon required to prevent the formation of copper on steels containing up to 1 wt-pct Cu. Formation of copper, which causes surface hot shortness, was readily prevented by as little as 0.3 wt-pct Si and by 2 vol-pct excess oxygen in the furnace atmosphere when reheating steels containing up to 0.8 wt-pct Cu. Up to 0.8 wt-pct Si content and careful control of reheating conditions were necessary for steels containing 1 wt-pct Cu. Best conditions for these steels were reheating to 2,200° F (1,205° C) in burning gases containing 2 vol-pct excess oxygen, and then to higher temperatures in gases of 6 vol-pct excess oxygen. Slag and mold wash were not detrimental on steels reheated for 8 hr by a soaking-pit-type furnace schedule, but they were problematical on steels heated for 2 hr by a pusher-type furnace schedule. The effect of silicon contents on scaling rates also was determined.

Jan 1, 1974

By D. D. Bolstad

This report describes the construction and use of a direct-reading azimuth protractor (DRAP) by the Bureau of Mines for measuring fracture orientations in mines, tunnels, or other excavations having a magnetic environment. The DRAP allows a rapid and simultaneous measurement of dip and azimuth of dip of a fracture plane. The instrument is rugged, lightweight, and easily constructible from standard hardware items. The DRAP can measure dip to within ±0.5° and azimuth of dip to within ±5° of corresponding values obtained with a Brunton compass.

Jan 1, 1974

By F. A. Rutledge

The W. E. Dunkle mine, sometimes called the Costello Creek coal mine, is 8 miles N. 20° W. of Colorado Station on the Alaska Railroad. The presence of coal in this area has been known since the district was extensively prospected for gold between 1911 and 1915. At that time, coal from this deposit was used by miners for blacksmithing. The increased demand for coal resulting from government defense projects in Alaska led to exploitation of this deposit in 1941. The inability of Alaska coal mines to supply the quantity of coal required by public and private consumers and by the armed forces in Alaska was responsible for establishment by the Army of the Coal Procurement Section of its Alaska Department. It proposed to investigate the deposits and to expedite production from the Alaskan coal fields. The Bureau of Mines closely cooperated in this program. The quality of the Dunkle coal and the favorable location of the deposit caused it to be one of the properties chosen for investigation under a joint Army-Bureau of Mines-Geological Survey program.

Jan 1, 1948

By S. P. Sandoval

Several researchers have shown that the surface of chalcopyrite becomes hydrophobic under oxidizing conditions. Because dissolution of copper from chalcopyrite in dump leaching occurs under oxidizing conditions, the U.S. Bureau of Mines studied the effect of surfactants on chalcopyrite leaching under dump chemical conditions. Surfactants were selected for study because they can lower interfacial tension. The tests were conducted in shaking water baths using 250-mL Erlenmeyer flasks in statistical experimental design formats. The addition of nonionic surfactants increased copper extraction in the fernc sulfate leaching of chalcopyrite when sufficient Fe3+ was present. A positive interaction between Fe3l+ concentration and surfactant concentration was demonstrated. Copper concentration in the leachhing solutions was increased by as much as 100 pct at 25° and 50° C by adding nonionic surfactants. ionic surfactants decreased leaching. The structure of the nonionic surfactants and their hydrophile-lipophile balance (HLB) influenced surfactant performance. The branched hydrophile of an ethoxypolyol was beneficial to surfactant performance. The ethoxypolyol was the superior surfactant at 25° C, but became unstable at 50° C. Four surfactants, an ethoxyalchohol and three block copolymers, performed best at 50° C.

Jan 1, 1990

By Fredrick L. Johnson

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 25,640 acres of the 29,680-acre Devil?s Garden Lava Bed, 21,040 acres of the 28,660-acre Squaw Ridge Lava Bed, and 9,100 acres of the 12,600-acre Four Craters Lava Bed Wilderness Study Areas (OR-D01-D02, OR-001-003, and OR-001-022, respectively) in order to evaluate their identified mineral resources. The study areas are located in Lake County, OR, about 50 air miles southeast of Bend. No mineral resources were identified in the three study areas. The areas are almost entirely underlain by recent lava flows. Cinder cones occur in each of the areas; however, the best cinder occurrences are in the Four Craters Lava Bed study area. Slab lava, of facing stone quality, is scattered throughout the Devil?s Garden Lava Bed study area, and to a lesser extent, in the Squaw Ridge Lava Bed study area.

Jan 1, 1987

By Arnold B. Hubbard

This report presents a hydrogenolysis study undertaken to obtain information on the constitution of the kerogen or organic material in Colorado oil shale and to determine some of the properties of the hydrogenolysis products. The high yield of hydrogenolysis products was separated, so far as possible, into type compounds; a number were identified. The results thus obtained were used as a basis for proposing the possible existence of certain structures in kerogen. To the authors&apos; knowledge, few or no hydrogenolysis studies have been made of Colorado oil-shale kerogen by others. However, this method has been used in studying the constitution of coal. In general, the coal studies involved treating pulverized coal at different temperatures and hydrogen pressures with different catalysts. In some instances different solvents were used during the treatments.

Jan 1, 1959

By G. E. McElroy

[During the period July, 1923, to April, 1924, we made a large number of careful determinations of the resistance to the passage of air in selected sections of airways in the metal mines of Butte, Mont. The experiments were conducted with the cooperation of the Anaconda Copper Mining Co., Frank D. Cannon, mining engineer of that company, and Fred P. Gaethke, mining engineer of the bureau, assisted in carrying out this work. This paper summarizes the, main group of data obtained in the form of a table, of friction factors, or coefficients of friction that is, values of K in the generally accented formula or air flow of [P = KSV or H = KSV2 ] where, in units customary to mining practice;]

Jan 1, 1925

By C. Özgen Karacan

Degasification and methane control in underground coal mining is an important area augmenting conventional ventilation in order to prevent possible fires and explosions due to excessive methane emissions. Coal bed reservoir engineering has been applied for many years to coalbed methane production. In recent years, modeling the flow and draining methane, not only from coal bed itself but also from the overlying strata, have been recognized as important areas of expertise for supplementing underground ventilation. This paper demonstrates the applications of coal bed reservoir engineering and modeling techniques for optimizing and controlling methane emissions in longwall and continuous miner sections. Practical applications and some considerations are presented for reservoir modeling, borehole performances, and face emission predictions for various coal bed and borehole configurations. A section on field reservoir studies and well bore log analyses for methane control are also presented as a complementary way of controlling methane and optimizing ventilation.

Jan 1, 2009