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By Sam S. Taylor

[The discovery of many oil fields in Illinois since 1936, and their rapid development have brought the problem of brine disposal to the foreground in that State. The ultimate magnitude of the problem is not yet known, but already it is treat enough to warrant technical investigation. The Bureau of Mines, therefore, has made a general survey of the methods of handling oil-field b brines in Illinois rend has studied in detail three subsurface disposal systems.]

Jan 1, 1940

By Robert S. Warfield

The Bureau of Mines investigated a geologically favorable area in the Beluga River coalfield in south-central Alaska to determine if there were sufficient minable coal reserves for onsite utilization to meet the projected thermal power needs of the Anchorage area. A program of diamond core drilling and sampling delimited a shallow saucerlike structure estimated to contain indicated reserves of more than 20 million tons of subbitminous coal in a seam over 50 feet thick that could be mined by opencut methods. A large sample of fresh coal was taken across the full width of the seam for washability studies. This sample, with 4 volume-percent of clay partings eliminated, contained 24.4 percent moisture and 16.8 percent ash and had a calorific value of 7,162 Btu per pound. The studies indicated that mechanical cleaning would be of doubtful value.

Jan 1, 1963

Tax for Toxic Waste Cleanup. - The Superfund Act of 1980 became effective April 1, and provides that producers of certain metals and chemical substances are to be taxed in order to fund toxic waste cleanup. Industry will provide 88% of the 5-year, $1.6 billion fund. The Environmental Protection Agency will administer the Act, but the Internal Revenue Service will be responsible for collection of the industry tax. Under the Act, nickel companies, for example, will be required to pay a tax of 0.225 cents per pound on pure nickel products produced or imported into the United States. Standard for Exposure to Lead. - The Occupational Safety and Health Administration (OSPA) has announced a stricter standard on the test of a worker's exposure to lead. Effective May 15, in all lead intensive occupations with the exception of those at primary and secondary lead smelters, a worker would have to be removed from his work station if the level of lead in his blood tests out at 60 micrograms of lead per 100 grams of blood, instead of the previous standard of 70 micrograms. In the case of primary and secondary lead smelters, the ruling has been stayed until June 1, 1981, to allow time for further study.

Jan 1, 1981

By J. S. Miller

The Bureau of Mines developed methods for fragmenting oil shale formations with chemical explosives to prepare oil shale for in situ retorting and to evaluate the extent of fragmentation by various methods. A combination of three methods of explosive fracturing was used: (1) The displacement and detonation of a liquid chemical explosive in a natural fracture system; (2) the use of 60-pct dynamite to relieve stress conditions of the rock around the wellbore; and (3) the use of pelletized TNT in a series of wellbore shots to fragment the oil shale. An attempt was made to seal or grout around the fragmented oil shale by drilling 67 holes and displacing approximately 200 bbl of neat cement in the fracture system to aid in evaluating the fragmented zone, Seven methods were used to evaluate the fragmented zone. The primary evaluation method was the recording of seismic waves to delineate the fragmented zone with results based on arrival time, amplitude, and record quality. The data from the seismic measurements indicated the extensively fragmented zone was approximately 95 ft in diameter and 70 ft thick. Results of the remaining methods of evaluating fractures--including air-flow tests, coring of the expected fragmented zone, elevation measurements to indicate overburden crowning, and surveys with high-speed camera, impression packer, and down-hole camera--agreed with and supported the data from seismic measurements. Further field application of explosive fracturing and evaluation methods is needed to determine when a zone of oil shale is effectively fragmented for efficient in situ retorting.

Jan 1, 1973

By E. R. Maize

This report is t e second of s series on roof movement in coal mines. The first (R. I. 3355)4/ dealt with convergence of roof and floor and movement of the surface accompanying and following extraction in a mechanized mine in which retreat of rib lines was rapid. The studies reported herein were made in a mine in which all the coal is loaded by hand, and movement of the rib lines was much slower in consequence. In choosing a site for this work, it was decided that the mine selected should have natural conditions akin to those of the first study and entirely different methods of working. To this end a cooperative agreement was made with the Crucible Fuel Co. through W. J. Whitaker, secretary, for conducting the work in the company?s Crucible mine, operating in the Pittsburgh bed in Greene County, Pa, This paper gives an account of the methods used in the investigation, excerpts from the data obtained, and such generalizations as can be made.

Jan 1, 1939

By M. R. Geer

Three coals from the Wilkes on - Carbonado district of Pierce County , Washington , were subjected to washability analyses to estimate the amount and quality of washed coal obtainable . Because the coals were unusually difficult to clean , the washability examinations were supplemented by table tests , tests in dense - medium cleaning units , and flotation tests . None of the coals could be reduced to the desired 10 percent ash by tabling and the response to flotation by two of them was poor . Dense -medium treatment provided coal of the desired quality , but with the most difficult coal the recovery efficiency was lower than usual .

Jan 1, 1964

By Laurance L. Oden, Jack C. White, Alan D. Hartman

The U.S. Bureau of Mines, under a Memorandum of Agreement with the American Society of Mechanical Engineers (ASME), established design criteria for a facility to field residues from municipal waste combustion. This facility, which is available to potential users on a cost-sharing basis, is also applicable to a variety of inorganic waste materials from smelting or melting operations. The design consists of a mechanical feed handling system, electric arc melting furnace, fume-off gas handling system, and thermal oxidizer for final off gas treatment. Screw conveyors and a bucket elevator deliver up to 2,000 Ib/h of minus I-in material to a three-phase electric arc melting furnace. This unique 800-kVe A furnace has a water-cooled shell and roof to minimize interaction of the melt with the refractory lining. The volume of the hearth below the slag taphole is approximately 1.2 st of steel. The furnace is sealed, allowing atmosphere control within the furnace and fume duct by nitrogen or inert gas injection. A jet-pulsed baghouse removes particulate from the off gas and serves as an acid gas scrubber. The clean off gas is heated to 1,800' F for 1 s in a propane-fired thermal oxidizer before being vented to the atmosphere.

Jan 1, 1993

By John D. Sullivan

In leaching copper ores knowledge of the rate of dissolution of the copper minerals and of the impurities is desirable. With knowledge of these two factors and data as to what minerals are present in the ore the metallurgist has an excellent start on planning a leach¬ing cycle to fit that ore. The rate of dissolution is rather difficult to predict, and the time required to leach a given ore may differ markedly from that required by another ore. The whole study as related to mixed oxidized and sulphide ores is one of relative rates of dissolution of the different copper minerals and the impurities in sulphuric acid and in ferric sulphate. The aim of leaching is to choose a cycle and strength of solvents to ex¬tract a maximum amount of copper and a minimum of impurities. The consumption of reagents per unit of copper dissolved is a function of the strength of the reagents used and the relative rates of attack on copper minerals and impurities. An opportunity may exist of ob¬taining the kind of electrolyte wanted for electrolytic precipitation and yet of saving on the consumption of reagents by modifying the strength of ferric sulphate and of sulphuric acid during the cycle to fit the time needed for dissolving the sulphide and oxidized minerals present. Former papers have considered the rate of dissolution of azurite, malachite, tenorite, chrysocolla, cuprite, chalcocite, boruite, and covellite in common leaching solvents. A paper soon to be written will consider some of the less important copper minerals. The present paper considers the rate of dissolution of copper from ores of the Southwest in sulphuric acid of varying strength and the ratio of sulphuric acid consumed to copper dis¬solved. In this study two ores containing the copper principally in an oxidized condition were used. A study of other ores, especially those containing high percentages of sulphide copper minerals, would be desirable, but since consumption of acid has paramount interest,

Jan 1, 1931

By Oliver W. Keener

This paper describing the methods and costs of mining at the Hartley-Grantham mine of the Century Zinc Co. in the Tri-State Lead and Zinc district is one of a series being prepared by the United States Bureau of Mines can mining practices, methods, and costs in the various mining districts of the United States. LOCATION, HISTORY, AND GEOLOGY The Hartley-Grantham Mine is located just outside the city limits of Baxter Springs, Kans., as shown in Figure 1. A plan of the mine is given in Figure 2, and Figure is a cross section through A - A of Figure 2.

Jan 1, 1930

By S. M. Runke

An ever-increasing demand for beryllium and beryllium alloys has directed attention to the milling of low-grade domestic deposits as a possible means of supplying part of the Nation's ore requirements. The United States generally produces less than 10 percent of its annual supply. For example, new supply in 1953 was estimated at about 9,250 tons, of which the United States imported 8,500 tons. Domestic production was only 750 tons.2/ Since record high prices for beryl in 1952 and 1953 did not greatly increase domestic product ion, the United States must develop mechanical beneficiation processes to use low-grade deposits and reduce dependence on foreign sources

Jan 1, 1954

By George H. Schnakenberg

This Bureau of Mines publication describes a passive personal sampling device for N02 in air, developed by the New York University Medical Center under Bureau Grant G0133066. The sampler has been successfully demonstrated in the field and in the laboratory. In corroborative laboratory trials the agreement with reference method is excellent. The overall accuracy is approximately ±5 pct of reading to a precision of about ±l pct. All evidence indicates that these samplers should indicate the time-weighted-average N02 concentration to the above accuracy and precision equally well in the field since effects of wind velocity and relative humidity are negligible and the effects of temperature are about 0.1 pct per °F. The duration of exposure and the approximate temperature are the only data that need to be collected in the field. A two-step analysis procedure in field or service laboratory is then used to obtain the total cumulated exposure to N02 in parts per million-hours (ppm times hours), which can be converted to the time-weighted-average concentration of N02 in ppm by dividing cumulated exposure by the duration of the exposure.

Jan 1, 1976

By W. I. Nissen

This Bureau of Mines report presents the design for a commercial-sized flue gas desulfurization (FGD) demonstration plant that uses the citrate process. The goal of the Bureau's citrate process is to minimize the undesirable environmental impacts of industrial plants emitting SO2-bearing gas. The FGD plant is located at the George F. Weaton powerplant, Monaca, Pa. Construction was completed in April 1979 and will be followed by preliminary testing and a 1-year testing and evaluation program. Design capacity of the FGD plant is 156,000 scfm of 0.2-volume-percent-SO2 flue gas yielding about 16 tons of sulfur per day. The plant is intended to (1) clean fly ash, SO2, and Cl- from the gas while cooling the gas in a venturi scrubber, (2) absorb SO2 from the gas using 1,200 gpm of a countercurrent-flowing citric acid-sodium citrate-sodium thiosulfate solution, (3) react the absorbed SO2 in two 13,000-gal stirred closed vessels with added H2S, thus precipitating elemental sulfur and regenerating the citrate solution for recycle, and (4) recover the sulfur from the slurry by air flotation, followed by melting in a heat exchanger and separation from the occluded citrate solution in a sulfur decanter at 35 psi and 135° C.

Jan 1, 1979

By L. C. IlsLey

In January, 1922, a conference relative to trailing cables for use with permissible mining machines was held at the Pittsburgh Experiment Station of the U. S. Bureau of Mines. At this conference it was recommended that the bureau take steps to investigate the rubber-sheathed type of cables and to bring about the establishment of a list of approved cables. Effective until such time as a complete investigation could be made, the bureau asked the several manufacturers holding approvals for mining machines to recommend cables for use with their machines. In general the cables recommended were tentatively approved. Due to the lack of available personnel, no actual tests of cables were made until mid-1927. Meanwhile a field investigation of trailing cables was made at 20 mines of three coal companies in western Pennsylvania, and samples of cables were obtained from the manufacturers for laboratory tests. Twenty-five samples of the concentric-type cable, representing the product of five manufacturers, were obtained for the tests. These cables were of four sizes, as follows: 3 cables of No. 2 B & S gage, 17 cables of No. 3 B & S gage, 3 cables of No. 4 B & S gage, and 2 cables of No. 6 B & S gage.

Jan 1, 1929

By P. M. Daling

This report, sponsored by the U.S. Bureau of Mines, presents the results of an examination of the safety of the impactor shaft sinking system in comparison to conventional shaft sinking technology. Detailed study of the impactor system was also performed to identify and recommend design changes for optimum safety conditions. A comparison of the impactor machine and its support systems with conventional shaft sinking was made on the basis of relative risk levels. Risk incorporates measures of both the frequency and the potential consequence of accidents. A safety evaluation of the component operations of the impactor shaft sinking system was performed using a Failure Modes and Effects Analysis (FMEA) methodology. The results of this analysis show generally that the impactor shaft sinking system is safer than conventional shaft sinking. The potential risk of conventional shaft sinking operations could be reduced by an average of over 35 percent with use of the impactor shaft sinking system. Design change recommendations to further improve the safety of the impactor system include a revised fire suppression system, improved access to and from the operator cabs, reliable noise attenuation measures, and improved communication systems. An operational safety manual was also developed for the impactor shaft sinking system.

Jan 1, 1982

By E. G. King

An earlier Bureau of Mines report4 provided low-temperature heat-capacity and entropy data for three sodium vanadates. This report continues the study of vanadates by presenting analogous data for three crystalline calcium vanadates - calcium metavanadate (CaV206), calcium pyrovanadate (Ca2V2O7), and calcium orthovanadate (Ca3V208). No similar data for these compounds have been published previously. MATERIALS All three vanadate samples were prepared by the Bureau of Mines by heating stoichiometric mixtures of reagent-grade calcium carbonate and vanadium pentoxide.5 Calcium metavanadate was prepared at 610° to 660° C. A stoichiometric mixture was heated for 17 days with intervening grindings, mixings, and adjustments of composition, as shown necessary by chemical analysis. The final analysis gave calcium oxide, 23.48 pct. (theoretical, 23.57 pct.) and vanadium pentoxide, 76.32 pct. (theoretical, 76.43 pct.). The sample also contained 0.11 pct. acid-insoluble matter. The X-ray diffracton pattern showed no lines of free calcium or vanadium oxides. No X-ray diffraction patterns were found in the literature for any of these substances.

Jan 1, 1961

By Sidney Katell

The reaction of coal, oil, or natural gas with air and oxygen and/or steam yields a gas containing varying amounts of impurities. Depending on the raw material and the end use of the product, these impurities include solids, such as dust or slag, and gases, such as hydrogen sulfide, carbon dioxide, and nitrogen. Considerable effort has been expended in developing and operating purification systems, and the literature is replete with equipment data and operating results. The research problems, the design, and the operation of the various systems have been the subjects of patent applications, journal articles, and textbooks.

Jan 1, 1959

Vanadium, molybdenum, and a titanium-10 percent vanadium alloy were evaluated for their susceptibility to stress corrosion cracking in a number of corrodents. Tests were conducted utilizing conventional U-bend techniques with subsequent evaluation in a pneumatic constant-load apparatus. Vanadium and molybdenum were generally resistant to stress corrosion cracking in the media studied. U-bend specimens of vanadium showed evidence of stress corrosion cracking in 6 li hydrochloric and 18 li sulfuric acids; however, tensile stress specimens exposed to these solutions did not exhibit stress cracking. Similar results were obtained when U-bend specimens of molybdenum were immersed in 10 percent formic acid. Titanium-10 percent vanadium alloy was susceptible to stress corrosion cracking in 10-percent (2.85 li) hydrochloric acid solution. Heat treating the alloy greatly reduced its corrosion rate and its susceptibility to stress cor-rosion cracking in this medium.

Jan 1, 1965

By J. A. McAllister

In the course of a study of domestic Manganese resources, 2-ton representative samples of ore were taken by Bureau of Mines' engineers from the Payday claim, Weber County, and the Newcomb-claims, Rich County, Utah. The Payday No. 1 deposit is situated 13 miles northeast of Huntsville, Weber County, Utah. The manganese ore is a. replacement deposit in limestone and consists of manganese oxides imbedded 'in clay and also as the cementing agent consolidating small pebbles and pieces of quartz and limestone.

Jan 1, 1949

By Peter J. Clarke

The petroleum industry continued to be the most important mineral activity in Bahrain during 1978-79. Revenues generated by the petroleum sector increased from $378 million' in 1977 to an estimated $419 million in 1978 and approximately $522.5 million in 1979, despite decreasing production over the 2 year period. There were two oilfields that produced revenues for Bahrain, the Awali oilfield, the nation's only onshore producer, and the Abu Sa'fah oilfield, located in the Persian Gulf, north of Bahrain, The Await oilfield has been decreasing output from a high of 27,973,000 barrels in 1970 to 19,000,000 barrels in 1979. Bahrain shared the revenues from the Abu Sa'fah oilfield with Saudi Arabia, as settlement of an ownership dispute. For the first time, in 1978, revenues from the Abu Sa'fah oilfield represented over 50% of the total receipts from the petroleum sector. The years 1978-79 saw the gradual takeover of the Bahrain Petroleum Co. (Bapco), formerly a subsidiary of the California Texas Petroleum Co. (Caltex), by the Government-owned Bahrain National Oil Co. (Banoco). By yearend 1978, Banoco owned 60% of Bapco, and Caltex the remaining 40%. The Government-owned company controlled exploration concessions, managed domestic marketing of petroleum products, and controlled natural gas production and marketing. On December 15, 1979, the Bahrain Government completed full takeover of the Bapco operations. Bapco will continue to own and operate the 250,000-barrel-per-day oil refinery located near Sitrah, as well as handle foreign marketing of petroleum products.

Jan 1, 1981

By Ronald F. Balazik

This Bureau of Mines study identifies and examines the costs of Federal, State, and local environmental protection controls on domestic phosphate rock mining, The costs include the expenditures needed to comply with government regulations and the effects that these expenditures and regulations have on supply. The study analyzes costs of environmental impact assessments, air and water quality standards, reclamation laws, potential solid waste controls, and local government restrictions. In addition, an industry survey and the Bureau's Minerals Availability System (MAS) are used to evaluate land management policies that restrict access to phosphate resources, Conclusions drawn from these analyses confirm that (1) domestic phosphate mining has incurred substantial control costs and may be subject to significant new regulatory costs in the next several years, (2) certain environmental controls can discourage mining investment, (3) environmental policies governing land-use controls affect the disposition of sizable phosphate resources, and are key determinants in the development of those resources on the Federal do- main, and (4) environmental costs could diminish the competitiveness of domestic producers.

Jan 1, 1983