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By James W. Ballard, H. H. Schrenk

"The X-ray method of quantitative determination is advantageous because it permits determination of compounds rather -than ions or elements; for example, the direct determination of quartz in silicates,4/,5/,6/ The method also takes into account the finest particles of a sample, which may be lost in wet chemical methods because of solubility or in petrographic methods because of limitation of the microscope. The sample is usually reduced to a powder and is easily prepared,7/ only a few milligrams of material being necessary. The sample and its chemical composition are not destroyed and may be used for further analysis by X-ray diffraction or by other methods.This paper presents in detail some of the more essential problems that arise in the application of X-ray diffraction to quantitative chemical analysis, Photometric measurements are discussed in connection with line intensities and the choice of X-ray film. The internal standard method, successfully used in spectrographic analysis, is applied.Copper K-alpha X-rays from a demountable research-type X-ray tube were used with a camera of 20 centimeters radius with a cast-lead-slit collimating system. A combination of a tilted wedge and a lead-slit collimating system permitted irradiation of a large amount of sample with X-rays. This tended to minimize errors due to possible inhonogeneity of the sample, to decrease the time of exposure, and to keep the lines on the X-ray film to a minimum width. There was sufficient dispersion of the lines for satisfactory analysis of most samples. Power was furnished the tube by a. source of constant high potential consisting of a synchronous motor generator furnishing 500-cycle power to a 100-kv. transformer, rectifying valves, and a condenser filter circuit. The X-ray tube was operated as a gas-type tube at 35 kv, and 20 ma,, the exposure times varying from 1 to 2 hours. The constant output of X-rays from the tube, indicated bar an exposure meter built for the purpose, was satisfactory.The recording microphotometer8/has been described. It was found preferable to a nonrecording instrument for measuring blackening of lines above a background on X-ray films. This background, which usually occurs, is sometimes complicated by numerous peaks from lines of complex diffraction patterns. is microphotometer record of the pattern, therefore, facilitates the location of the background 'and the measurement of the heights of the peaks and thus contributes to the accuracy of a determination."

Jun 1, 1946

By H. Stanley Benson

This report is an account of research conducted to improve the performance of and then further field test Draft Power Sensor (DPS) equipment, the use of which enables a bulldozer operator to optimize his machine's work rate. Significant improvements were made in DPS hardware, and extended field testing was conducted at two working strip mines: the Glenharold Mine of Consolidation Coal Company, near Stanton, North Dakota, and the Beulah Mine of Knife River Coal Company, near Beulah, North Dakota. This report documents the increase of bulldozer work production by greater than twenty percent while using the Draft Power Sensor when compared to baseline work production without benefit of the Draft Power Sensor. Research was done by Southwest Research Institute under contract with the Bureau of Mines.

Jan 1, 1980

By M. L. Williams

In recent years the use of visual aids has expanded the? field of safety education. This is a modern adaptation of a method employed in ancient times, when simple paintings and drawings were the only means of recording current events. In its present application, visual aid employs sound and silent motion pictures, stripfilms, lantern slides, descriptive posters, and color. According to Roberts,3/ "Visual education is a method of imparting information which is based on the psychological principle that one has a better conception of the thing he sees than of the thing he reads about or hears discussed." Dent4/ further defines visual aid as "all the materials used to facilitate the understanding of' the written or spoken word."

Jan 1, 1951

By L. Douglas Smoot

This research program was a theoretical and experimental study to improve understanding of the mechanisms of flame extinguishment in methane-coal dust-air-suppressant mixtures. This final report is a summary of work conducted during this grant, sponsored by the Bureau of Mines. Work under this new grant closely followed a recently completed contract for the Bureau of Mines that was conducted at this laboratory, and results of the earlier contract are also summarized in this report, as required in the grant work statement. The experimental effort was concentrated on supplementing the limited data available to describe laminar flames in methane-coal-air-suppressant mixtures. The theoretical effort was devoted to developing a comprehensive model that could be used to explain and extrapolate the experimental data. Selected for study were the following flames: Methane-air; methane-air plus KHCO , KNO3, K C204, KBr, Al203 or Monnex; methane-coal dust-air; coal dust-air with size, volatiles content, and concentration as variables, and coal dust-air plus KHCO3, KN03, KBr, NaCl or CaC03.

Jan 1, 1978

By Jack G. Croeni

The Bureau of Mines developed a method to extrude low-density tungsten powder billets into rods and sheet bar with high-energy-rate forming equipment. Billets were compacted and sintered in an atmosphere of hydrogen to obtain a density of approximately 60 percent. Extrusion was conducted at reduction ratios of 6.25 to 1 and 9 to 1 at 1,800° C to prod e high-density, sound material. Yield strengths obtained were higher than those of material produced by conventional powder-metallurgy techniques, but ductility was lower at high temperatures.

Jan 1, 1966

By Robert A. Cummings

A rock mass classification system has been developed for support estimation in mines using caving methods. The developed system (MBR System) accepts readily-obtainable geotechnical properties, and mining geometry, to develop a rating that permits recommendations for drift support in block caving mines. The data base includes major active United States caving mines. The method is intended to be used for planning and estimating purposes and for preliminary support design. The Manual explains the organization and nature of the MBR System, its derivations, details of required input data, methods for assessing the data and for developing rock mass ratings, and techniques for selecting the most appropriate mine support recognizing mine requirements and desired stability. A worked example is provided.

Jan 1, 1984

By P. M. Gruzensky

Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step. With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C, and contained at least 100 grams of bismuth per liter, An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.

Jan 1, 1956

By Bruce K. Cantrell, Jon C. Volkwein

Exposure to mineral aerosol is an occupational health hazard in mining and mineral processing industries because of the risk of developing pneumoconiosis. Agricola (1556) described this hazard for metal mining in Carpathia. He described shortness of breath and consumption, conditions that are now associated with asthma and emphysema. By the end of the nineteenth century, several respiratory diseases were known to affect miners, including silicosis and coal workers' pneumoconiosis (Fletcher, 1948; Seaton et al., 1981). For example, silicosis, not tuberculosis, was clearly recognized as the hazard in the Vermont granite quarries and stone-cutting sheds (McFarland, 1927). The Gauly Bridge Tunnel disaster in the mid-1930s caused the deaths of an estimated 700 workers by acute silicosis and focused the nation's attention on this disease (Cherniack, 1986). By the mid-twentieth century, it was clear that risk of simple pneumoconiosis is associated with a miner's cumulative exposure to mine aerosol in the respirable size range and that prevention lies in reducing that exposure through regulation (Seaton, 1986). In the United States, regulation of mine worker exposure to airborne mine dust is the responsibility of the Mine Safety and Health Administration (MSHA) in the U.S. Department of Labor. The key legislation relating to improved mine worker health was the Federal Coal Mine Health and Safety Act, enacted in 1969 (U.S. Congress, 1969) and subsequently amended as the Federal Mine Safety and Health Act of 1977 (U.S. Congress, 1977). MSHA receives technical assistance from the National Institute for Occupational Safety and Health (NIOSH). NIOSH also provides recommended exposure limits (RELs) for contaminants to MSHA. MSHA's regulation of mines includes the establishment of a dust standard administratively based on the these RELs. Some mine operators must submit a dust control plan designed to meet the dust standard. Periodic mine inspections determine if mines are com- plying with both the dust standard and the dust control plans (MSHA, 1991). The most common dust measurements are those for respirable dust (according to the definition given in Fig. 26-7), that is, the fraction of aerosol particles able to reach the gas exchange region of the lungs. The other health-related size fractions (inhalable and thoracic-see Fig. 25-1, and "total" dust) are also occasionally measured. A "total" dust measurement is defined by the common practice of the last 30 years or so, using 25 mm or 37mm plastic cassettes (e.g., from PAL, MIL, SKC ). The types of mines have been categorized

By J. E. Doo1ey

To process and use the heavy ends of petroleum effectively, the development of suitable separation and characterization procedures not currently available was required. A systematic procedure was developed by the Bureau of Mines using such techniques as isothermal and molecular distillation, chemical treatment, silica-alumina gel chromatography, gel permeation chromatography, and spectrometry. Using these techniques, the Bureau achieved a detailed separation and characterization of a 370° to 535° C distillate from Gach Saran, Iran, crude oil. Such a systematic procedure and the semiquantitative data resulting therefrom should be of value in selecting feedstocks and in optimizing petroleum processing operations.

Jan 1, 1973

By Alla D. Mah

The energies of combustion of two carbides of tungsten and two carbides of molybdenum were measured , and the corresponding standard heats of combustion were derived . The results are as follows : WC : AH298.15 ( combustion ) = -285,940 ± 250 cal /mole , W₂ C: AH298.15 (combustion ) = -490,660 ± 400 cal /mole , Mo₂ C : AH298.15 ( combustion) = -439,350 ± 600 cal /mole , MoC : AH298.15 ( combustion ) = -269,800 ± 1,000 cal /mole . The combustion heats were combined with the heats of formation of the corresponding metal trioxides and carbon dioxide to obtain the following heats of formation : WC : AH298.15 ( formation ) = -9.6 ± 0.4 kcal /mole , WC: AH298.15 ( formation ) = -6.3 ± 0.6 kcal /mole , Mo₂ C : AH298.15 (formation) = -11.0 ± 0.7 kcal / mole , MoC : AH298.15 (formation ) = -2.4 ± 1.0 kcal /mole . The heats of combustion and formation of MoC are tentative .

Jan 1, 1963

By George S. Rice, Li C. Ilsley.

A remarkable explosion of fire-damp caused by a discharge of lightning at the new shaft at the Sitalpur coal mine, has been reported by the Chief Inspector of Mines of India, who gave the following details: "The explosion occurred during a thunderstorm, and the evidence showed that a flash of lightning had, to all .appaarances, passed down the shaft causing disruptive disohalges at certain points between the guides and the winding rope, Tending the latter at two places situated respectively 228 feet and 278 feet frem the surface, The distance between the winding rope and the side of the shaft was 6 feet 4 inohes, indicating a spark gap;of this width, and an intensity of discharge which could not fail to ignite the explosive mixture of gas and air known to be present in the shaft."

Feb 1, 1920

By J. T. McCartney

In an effort to correlate the size of pyrite particles in coal and coal-particle association with the removal of pyrite before burning, the Bureau of Mines conducted a study of 61 coals presently being used for electric power production. The results were obtained by visual microscopic studies of polished briquets of minus l4-mesh samples. Mean pyrite particle sizes ranged from 20 to 400 microns and proportions of pyrite contained in coal particles to an extent greater than 50 percent by volume (estimated) ranged from 20 to 95 percent. These parameters were correlated with reductions in pyrite accomplished by float-sink tests at 1.60 sp gr on 14-mesh, 3/8-inch, and 1-1/2-inch samples. The correlation coefficients between pyrite removal and mean pyrite particle size were 0.89, 0.84, and 0.79, respectively, for these samples. Correlation coefficients between pyrite removal and coal-pyrite association parameter were 0.92, 0090, and 0.85, respectively. It is apparent that extent of pyrite removal can be fairly well predicted from microscopic analysis.

Jan 1, 1969

By Robert F. Droullard

The Bureau of Mines has investigated techniques of using gross alpha or beta detectors to continuously measure working levels. Both methods measure radioactive particulates collected on a filter paper using a constant airflow. Inherent-error studies indicate a value of about ±3 percent for the gross alpha method and about ±8 percent for the beta method in typical mine atmospheres. However, the beta method avoids problems associated with alpha detectors and is therefore more useful. Applications of these continuous working-level detectors include work area monitoring of exposure levels in underground openings, such as mines and caves, and calibrating personal dosimeters exposed over extended time intervals.

Jan 1, 1977

By William H. Holley

Thirteen additional preservative/fire retardant systems were applied to Ponderosa pine and evaluated for flammability both before and after water leaching. The more promising four systems were given a thorough evaluation for flame spread, toxic gas and smoke density levels, resistance to decay, and compressive strength. The most promising system on the basis of history of usage in the mine, ease of application and low cost as well as overall performance is the Fyreprufe/ACC Albi 107A/ 144 combination. A survey of inspection tools and instruments, identified equipment which could be assembled into an inspection kit for use in determining the extent of decay and/ or impregnant retention levels in mine timber. A literature search identified those high fire hazard areas found in a typical mine. Timber and other wooden structures used in such areas should be treated with an acceptable fire retardant system. A survey of insurance companies revealed that the use of such treated timber in the mines would probably have little or no impact on the rate structure.

Jan 1, 1980

By James J. Scott

Eleven workshops were held in various locations throughout the country in an attempt to reach the many diverse groups working in various mineral commodity areas and special ties. These meetings were held between March 1, 1974 and June 25, 1975. They were held under the auspices of the Bureau of Mines Contract to the University of Missouri-Rolla which was designed to help define Bureau research and development priorities. At each workshop a summary of current Bureau research and development was presented and the attendees were asked to present their ideas on what Research and Development programs should be undertaken to meet their needs locally. Participants included representatives of federal and state agencies, educational institutions, mining companies, equipment companies and other interested parties. The workshops covered under this report include lead mining in Missouri, limestone mining, coal mining both surface and underground in the midwest and in the Rocky Mountain area, iron mining in Minnesota, two top management meetings on institutional problems and, finally, a special two-day meeting on roof control.

Jan 1, 1977

By C. W. Smith

The U.S. Bureau of Mines; Tuscaloosa Research Center, in cooperation with the U.S. Army Corps of Engineers under interagency Agreement No. 14-09-0078-1510, conducted a comprehensive sampling program of 10 upland disposal sites along the Alabama, Black Warrior, and Tombigbee River systems in Alabama. Samples from each site were characterized according to particle size, chemical analysis, mineralogical content, and potential end use. Additionally, samples were subjected to the Toxic Characteristic Leachate Procedure to determine the presence of potentially harmful heavy metals. Based on the results of these studies, each sample was determined to have properties amenable for use as aggregate in general-purpose portland cement concretes and certain asphalt concrete applications.

Jan 1, 2010

By John Nagy

To facilitate increase in the rate of coal production the Bureau of Mines conducted a study several years ago, on the basis of which the allowable charge limit for permissible explosives in single-hole blasting was raised from 1.5 to 3.0 pounds. Further demands for accelerated production led to consideration of multiple blasting in coal, a practice that is deemed hazardous and is not permitted by most States in this country. In multiple blasting, 10 to 20 pounds of explosive or more may be detonated in a coal face within a fraction of a second, which might result in blown-out or blown-through shots with possible ignition of gas or coal dust. As experimental evidence was lacking, in January 1949 an investigation was undertaken in the Experimental coal mine at Bruceton, Pa., principally to study and compare with single blasting the condi-tions under which simultaneous multiple blasting and particularly multiple short-delay blasting may be practiced without danger of igniting gas or coal dust in mines. The first report on this subject was presented at the last international conference of mine safety research. Since that time numerous additional experiments have been made; because of other pressing problems the work has been brought temporarily at least to a conclusion. This paper is the second report on the problem. It does not contain a detailed description of all test conditions and test arrangements, many of which were described 2 years ago in part 1 (now available as Report of Investigations 4868), but the conclusions are based on the entire study. A more complete review, which will incorporate data from the entire investigation, is being prepared as a Bureau of Mines bulletin. Up to the present time, short-delay blasting of coal in commercial mines has been introduced only experimentally in Washington and in a few mines elsewhere. If the system is adopted more generally, new problems may arise, and the study may have to be reopened.

Jan 1, 1952

By G. St. J. Perrott, N. A. Tolch

"PURPOSE OF TESTSThe propulsive strength4 developed by the Cardox blasting device depends on the thickness of disk, weight of heater element, and weight of carbon dioxide charge. It might be supposed that the maximum weight of carbon dioxide that can be charged into the shell should give the greatest strength. However, according to the ballistic pendulum, the maximum weight of carbon dioxide with certain conditions of heater and disk has less propulsive strength than a smaller charge; in one condition of test a loss of 39 per cent in propulsive strength was noted. It is therefore of interest to study the effect of the variables that determine the strength of Cardox.ACKNOWLEDGMENTGrateful acknowledgment is made to A. B. Coates, associate mechanical engineer who developed the testing method for measuring pressures in the Cardox shell.DESCRIPTION OF DEVICEThe Cardox blasting device as fully described by the bureau in Report of Investiga¬tions 2920 (1929), consists essentially of hollow—steel shell, cylindrical in shape, an electrode, valve assembly, shearing disk, and discharge cap. The shell is prepared for use by inserting a heater element, closing the open end with a shearing disk, and screwing in place the discharge cap. The charge of carbon dioxide enters the shell through the electrode.The heater element is fired by an electric igniter of the match—head type. The heat released by the heater element completely gasifies the carbon dioxide and raises the pressure of the gas until it is enough to shear the disk."

Apr 1, 1931

By R. A. Franks, J. C. Edwards, L. Yuan

To determine the critical air velocity for preventing smoke rollback, diesel-fuel fire experiments were conducted in the National Institute for Occupational Safety and Health’s (NIOSH) Pittsburgh Research Laboratory’s Safety Research Coal Mine. Such information is necessary for preplanning and implementation of ventilation changes during mine fire fighting and rescue operations. The fire intensity varied from 50 to 300 kW depending on the fuel tray area. Airflow in the 2-m- (6.6-ft-) high, 2.9-m- (9.5-ft-) wide coal mine entry was regulated during the course of each experiment. The airflow was measured upwind from the fire as an average over the entry cross-section with an ultrasonic airflow sensor and was recorded dynamically with a mine monitoring system. The extent of smoke reversal was monitored with light-obscuration monitors, ionization smoke sensors and visual observations. Experimental results for the critical air velocity for smoke reversal as a function of fire intensity compared very well with model predictions based upon a computational fluid dynamics fire dynamics simulator.

By A. S. Moore

The Bureau of Mines is doing research and development work on removing acid-gas impurities from synthesis gas made directly from coal. Since conventional gas scrubbers, packed towers and bubble-cap columns, are expensive to construct and difficult to operate with viscous solutions, one aspect of the work was developing a compact, agitated, gas-liquid contactor for use with concentrated absorbents. The efficacy of the agitated contactor for absorbing carbon dioxide in diethanolamine increased with increasing solution rate, turbine speed, diethanolamine concentration, and carbon dioxide concentration in feed gas, and with decreasing liquid-gas ratio. It was unaffected by pressure between 200 and 300 p.s.i.g. and little affected by temperature between 115 and 190° F.

Jan 1, 1961