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By Everett A. Sondreal

Data are presented on the characteristics of lignites with emphasis on the composition and fusion properties of the ash. Differences in the analyses of commercial-grade lignites are related primarily to variations in moisture and ash contents. Lignite ash is generally characterized by high concentra¬tions of alkaline earth oxides and a greater tendency for retention of sulfur in the ash than higher-rank coals. Composition of ash varies significantly within and between mines. The differences within mines are significant for short distances and may be eliminated under certain circumstances by normal mixing occurring during mining. The sulfur in lignite averages 0.6 percent and is found primarily in the organic or pyritic forms with only a trace of the sulfate. During the stan¬dard laboratory asking procedures, from 60 to 100 percent of the original sul¬fur is retained in the lignite ash. Trace elements, such as uranium and germanium, in the ash from commercial¬-grade lignites are present in low concentrations, but others, primarily copper and silver, are present in specific samples in concentrations approaching those found in some commercial ores.

Jan 1, 1968

By A. D. Mah

Thermodynamic data on compounds of arsenic and sulfur were critically evaluated by the Bureau of Mines. Changes of standard enthalpy and Gibbs energy, and logarithms of the equilibrium constants were tabulated as a function of temperature for reactions involving these compounds.

Jan 1, 1982

By S. Gallagher, C. A. Hamrick, A. G. Mayton, R Sonier, R. L. Unger

Introduction Industrial safety professionals recognize that adequate illumination is essential to a safe and productive work environment. The need for effective, lighting in underground coal mines is even greater.1 Designing appropriate lighting systems for these mines is no easy [ ] task because of the unique environment and work procedures encountered in underground coal-mining operations. Miners must depend totally on artificial lighting systems to see. Moreover, the working face is a low-reflectivity and low-contrast environment and is continually advancing or retreating.2 Laboratory mock-ups have been a major part of the process lighting equipment manufacturers must under- go to design an underground machine-mounted lighting system. The mock-ups often have taken considerable time. Furthermore, modifications to a lighting system (using different luminaires with an existing configuration or changing a luminaire's location, orientation, etc.) could require more time with additional mock-ups and laboratory measurements. Understanding the need to improve this situation, the US Bureau of Mines has developed an alternate method for facilitating lighting system mock-ups. A PC-Program (CAP),* with the latest software technology enables users to design, alter, and evaluate under- ground machine-mounted illumination systems. Lux levels and distance are measured as the luminaire is moved incrementally through angular traverses about horizontal and vertical axes. The measurements and angles subsequently are entered into the model. From this input data, three-dimensional isolux or isofootcandle profiles are constructed for luminaires that can be placed at various locations and orientations on a mining machine. As an example, Figure 1 shows a computer display of 21.5 Ix or 2.00 fc profiles for luminaires mounted on a simulated mine-shuttle car. Using this information, the model allows the user to determine the lux level at different locations in space about the shuttle car. How the model calculates illumination During initial development of the CAP model, the isolux profile of the luminaire was determined using the inverse square law (ISL) .3 The method of gathering data comprised recording a single measurement of distance at 21.5 ± 1.21x (2.00 ±11 fc) for angular traverses following 0.09 rad (5 degree) increments. This data was then used to find the illumination in space for any other distance at a given azimuth and elevation using the ISL. Limitations, however, exist with this method.4 The main one is that the ISL assumes a luminaire is a single point source of light, so long as the distance is greater than five times the 1al;gest dimension of the luminous area of the luminaire.5 Also, by using a single measurement to calculate the illumination for a given luminaire in the CAP model a large error could result from an inaccurate measurement.

By E. K. Stanek

This research study was performed on a case study basis and can be divided into two parallel thrusts: electrical and thermal energy conservation. Energy consumed annually in mining and refining operations represents about 6% of the 80 quadrillion Btu's consumed nationally. In the electrical portion of the study, five areas were addressed: optimal dispatching of on-site generation, high-efficiency motors, conductor selection, power factor correction, and high efficacy lighting. In the case study mine which has a multiple unit on-site generation system, optimally dispatching units can save significant energy. The other four methods are difficult to justify on a retrofit basis due to capital costs. In the thermal portion of the study, a thermodynamic analysis was performed on the reverberatory smelting process possible areas of energy conservation were identified as radiation and convection heat losses from the furnace arch and the dumping of high energy content smelting slag. It has been shown that materials currently available can provide the means of reducing heat loss from the reverberatory furnace. It has also been shown that a significant amount of energy may be recovered from the slag. However, these are both subject to further study and validation.

Jan 1, 1982

By Murray Weintraub

The Bureau of Mines investigated the aerodynamic factors that control the functioning of the blowcase devices used in pneumatic processes for dispersing solids. Alumina powder of 8-micron mass-mean diameter was placed in 0.75- inch-diameter by 10-inch-long cylinders} and a blowcase technique was employed. It was determined that dimensions and gas rates for discharging the powder from the cylinder by a stream of gas may be calculated by assuming a fluidization mechanism and extrapolating residues to a desired finite quantity or to zero at the terminal velocity. The state of agglomeration of a powder at discharge may be determined from measurements of the velocity required for zero residue.

Jan 1, 1967

By Louis A. Turnbull, JOSEPH J. SHIELDS

The Bell & Zoller Coal & Mining Co. recently completed construction of two slopes at Mine 3 near Zeigler , Ill . The slopes are in the Big Muddy River Valley , and construction was particularly difficult because the strata from the surface to a depth of 70 feet comprise water saturated sandy clay and sand . Many mining companies have similar shaft- and slope - sinking problems , and because these slopes were satisfactorily completed and now are in use the methods followed during construction are described in this information circular . It is believed that other companies with similar problems . will benefit by adopting the methods followed at Mine 3 .

Apr 1, 1949

By George J. Conroy

Electrical power generation was studied in a laboratory-scale, open-cycle vortex MHD generator, which offers several advantages over straight-channel generators that require separate combustors. Compactness, lower capital cost, and high-energy release are obtained by combining the combustor and generator into one unit in the vortex generator. In addition, the vortex generator uses a simple solenoid rather than the more complex and expensive saddle magnet required for straight channel generators. Although the vortex generator must utilize combustion gases with a low Hall coefficient in order to be efficient in direct comparison to the linear generator, the primary motivation for this experimental device in terms of ultimate objective was to investigate the vortex generator with applications to direct coal firing and with combustion taking place in specially designed expansion nozzles. The vortex device offers one decided advantage over the linear device in this regard because slag deposits do not degrade or short-circuit the coaxial electrodes as is the case for a linear machine. The experimental vortex generator consists of a modified cyclone burner 7 ½ in ID by 21 in long, with the inner wall used as one electrode together with a coaxial center electrode. Power was obtained by impressing an axial field of 3,000 G from an air core solenoid magnet. Tests were conducted by seeding natural gas seeded with potassium acetate and burning with preheated oxygen-enriched air. Power generation was lower than calculated because theoretical plasma velocities were not achieved.

Jan 1, 1972

By Thomas M. Barczak

This U.S. Bureau of Mines report describes methods to enhance the capacity, stiffness, and timber utilization of wood crib supports. Since stiffer supports minimize strata deflections that contribute to roof instability, efforts to maximize crib stiffness while maintaining stability through a wide displacement range should be a design priority. The stiffness and capacity of conventional crib designs, employing alternating layers of wood timbers that are loaded perpendicular to the grain, can be increased by increasing the interlayer contact area or by using higher strength wood. Contact area can be increased by using wider timbers or employing more timbers per layer. Concepts that provide parallel-to-the-grain timber loading will provide substantial increases in crib stiffness and capacity. Two concepts that utilize this principle are examined: (1) an original South African design that constructs wood cribs from preformed layers (mats) of timber where short blocks are oriented vertically between horizontal slabs; and (2) a design that employs full lengths of timber placed vertically in the interior of a conventional crib structure. These designs also provide more efficient timber utilization by providing greater support capacity per volume of wood used in the crib construction.

Jan 1, 2010

By P. G. Clites

This study was conducted to determine the patterns of heat transfer to water-cooled copper crucibles during vacuum arc melting. Values of heat flux from the ingot to the crucible were determined during nonconsumable electrode vacuum arc melting of zirconium and during consumable electrode vacuum arc melting of titanium) zirconium) and steel. The results of these studies con-firm the existence of a high thermal resistance between the ingot and the crucible wall which results from the shrinkage of the ingot as the metal solidifies. Maximum heat flux occurs near the top of the ingot where maximum values of heat flux of 1.4 X 106 Btu/ft2 hr were observed during small-scale consumable electrode arc melting of zirconium and titanium. The maximum heat flux for consumable electrode arc melting of 8-inch-diameter ingots was 0.5 X 106 Btu/ft2 hr. The effects of electrode material) electrode diameter) arc current) and arc potential on heat flux from the ingot to the crucible were studied. Data were also obtained on crucible wall temperatures and on the effect of very narrow annular water jackets.

Jan 1, 1967

By J. S. Gomer

The U.S. Bureau of Mines conducted Cu exchange tests for six common clays under simulated in situ leaching conditions. Regression equations were obtained from the data expressing the Cu exchange capacity as a function of Cu concentration, pH, and temperature. Using these equations, an analysis was made of the impact each clay could have on overall Cu recovery. The results suggest that Ca and Na montmorillonite clays could have a major impact on Cu recovery and that attapulgite and illite clays could have a smaller, but still significant, impact. Kaolinite and ripidolite clays pose little threat to loss of Cu from in situ leaching solutions.

Jan 1, 2010

By Joan T. May

Federal Bureau of Mines studies showed that some organic amine hydrochlorides can be used as dehydrating agents for producing anhydrous magnesium chloride from hydrates and brines. Laboratory-scale tests showed that double salts are formed by reacting 35 percent magnesium chloride brine or spray-dried magnesium chloride with pyridine hydrochloride. Heating decomposed these double salts to anhydrous magnesium chloride and recycle pyridine hydrochloride. Pyridine hydrochloride also chlorinated any magnesium oxide in the spray-dried magnesium chloride. The anhydrous magnesium chloride obtained by the method described contained less than 0.8 percent oxygen. More than 98 percent of the organic amine hydrochloride was recovered.

Jan 1, 1978

By C. M. Frost

The hydrodesulfurization characteristics of a residual fuel prepared from Wilmington, Calif., crude oil were determined at temperatures from 600° to 900° F, pressures of 200 to 800 pSig, and space velocities from 0.2 to 2.0 Vo/Vc/hr, using cobalt molybdate type catalysts. A prediction equation, developed from the experimental data, satisfactorily predicts the fraction of total sulfur that can be removed under any combination of operating conditions within the ranges investigated. Yields and properties of the low sulfur product are correlated with the fraction of total sulfur removed. Kinetic calculations show that the apparent reaction order and activation energy change with space velocity and temperature.

Jan 1, 1970

By Thomas C. Miller, Charles E. Mongan

"This publication is a progress report on Bureau of Mines studies in applying sonar techniques to roof-control problems in coal mines. Preliminary tests in the laboratory were made on layers of roof rock. To apply the experience thus obtained, a unit was designed and constructed and was used underground.The term ""sonar technique"" refers to the system of generating a beam of sound waves, shaping and directing the beam, introducing the beam into a medium to be studied, and examining any returning waves with a view of inferring the nature of the material traversed by the waves and the presence of interfaces or obstacles in the medium.The theory and actual underground experiments indicate that the sonic method is feasible. Information from physical tests made in the Bureau's Experimental mine confirmed the validity and potential usefulness of the sonar method. Lighter and more compact apparatus is desirable, and permissible equipment suitable for use in gassy or dusty mines must be developed. However, no particular difficulties are anticipated; consequently, this scientific approach to the exploration of roof strata shows definite promise. INTRODUCTIONThe problem of roof control in the coal-mining industry is of major importance. More than 50 percent of all coal-mine fatalities and 25 percent of all nonfatal serious injuries are caused by falls of roof, face, or ribs. The Bureau estimates that more than $128 million was spent by the coal-mining industry in 1958 for supporting roof."

Feb 1, 1960

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spin trapping methodology has been used to study the reactions of manganese dusts with glutathione, employing a-{4-pyridyl-1-oxide)·N-tert-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as spin traps. The results show evidence for the glutathionyl radical formation in the reactions of both MnO2 and manganese (Ill) acetate with glutathione. Based on these experimental observations, we hypothesise that the mechanism of neurotoxic effects of manganese might be due to the fact that the generation of glutathionyl radicals depletes the glutathione pool and reduces the glutathione shield against free radical products of dopamine metabolism and manganese induced reactive oxygenated species. IntroductionExposure to manganese compounds often occurs as the result of foundries and mining operations (1. 2). Other significant sources of environmental manganese include coal-fired power plants and burning of residual and crude oil (3, 4). Lately gasoline combustion has also started to contribute since manganese (methyl cyclopentadienyl manganese tricarbonyl. 0. 125 g/gallon) is being used instead of lead as an antiknock ingredient in automobile fuels (5. 6). Although manganese is an essential element in certain biological processes it is toxic in excessive amounts. The manganese toxicity is mainly associated with the nervous system (7-9). Symptoms frequently observed in manganese poisoning or manganism are disorientation, memory loss, anxiety, compulsive laughing and crying, mask-like faces, akincsia rigidity and tremor (10). In spite of numerous investigations to understand the mechanism of manganese induced injury. it has not been possible to localize the initial chemical lesion responsible for altered physiology and ultimate cell death. This may perhaps he the reason for failure in developing a successful therapy for manganese intoxication."

Jan 1, 1990

By Charles Sabine

In 1984 and 1985 at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied a 27,420-acre part of the 36,600-acre Southern Inyo Wilderness Study Area, CA-010-056, in order to evaluate the mineral resources. The study area is located in Inyo County, CA, near the town of Lone Pine, about 180 miles north of Los Angeles. The study area takes in most of the western slope of the southern Inyo Mountains. Terrain is steep and rugged; the climate is arid. The study area is underlain by folded and faulted marine sedimentary rocks dating from Ordovician to Triassic, Triassic volcanic rocks, and Jurassic to Cretaceous plutonic rocks. Most mineralization was along faults and shear zones in sedimentary rocks. The study area includes most of the Russ and Lone Pine mining districts which produced over one million dollars in gold, silver, lead, and zinc, mostly between 1860 and 1890. A few mines produced ore as late as 1951. Most production was from the Reward, Silver Spur, Long John, and Pennsylvania mines which are outside the study area. Presently, there is no mining activity in the study area; some development work was done at the Reward mine between 1981 and 1984. Dolomite marble is quarried from the base of the range outside the study area. There are currently about 70 mining claims in the study area.

Jan 1, 1986

By G. W. Marks, A. H. Roberson

"Previous investigation 4/ has demonstrated that some of the aliphatic amines are suitable absorbents for 302, This paper reports the results of physical studies of a number of such amines with the object of determining which is most favorable as an absorbent.Monoethanol amine, diethylene triamine, and triethylene tetramine appear to be the most promising of all the amines studied, and most of this report has been devoted to studies of the physical properties of their aqueous solutions, which contain varying amounts of SO2.PURITY OF MATERIALSAll of the amines used were of commercial grade, because the primary object of this research was the investigation of a proposed works process rather than the accumulation of scientific data.The aminoethyl derivitives of ethylene diamine, namely, diethylene triamine, triethylene tetramine, and tetraethylene pentamine, only recently have been produced commercially. The chemistry of aliphatic amines is complex, and these newer derivitives have not been investigated, completely. Chemically pure material is not on the market, and since definite physical standards have not been published, one could not be assured of a pure product even if the commercial material was refined.The compilation of physical constants for the pure amines would involve much time—consuming effort without materially enhancing the value of this paper, as this work was not devoted to the development of fundamental standards."

Oct 1, 1938

By Ed D. Thimons, Douglas E. Pollock, Andrew B. Cecala, Gregory J. Chekan, Jay F. Colinet, John A. Organiscak

Researchers at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) work to reduce respirable dust exposures in mining operations. One focus of this research is silica dust control for surface and underground operations in the metal/nonmetal mining industry. PRL researchers analyze dust sampling results from the Mine Safety and Health Administration (MSHA) to identify high-risk occupations to guide research efforts. Research is then conducted in an effort to improve existing technologies and/or develop new controls for reducing worker exposure to airborne silica dust. During the last few years, PRL researchers have conducted research related to the following goals: improving protection provided by enclosed cabs on mobile surface mining equipment, reducing dust generation from surface drills, reducing dust levels in iron ore operations, and developing a new method to clean dust from workers’ soiled clothes. A description of each of these controls and subsequent dust reductions quantified through site surveys will be provided.

By W. L. Brien, O&apos

Molybdenum alloys with good strength properties at elevated temperatures were produced by the powder metallurgical internal oxidation method previously applied to tungsten and known as oxyreaction strengthening. Commercial molybdenum powders were blended with 0 to 10 pet of a reactive powder, ZrMo2. The effects of composition, blending procedure, and sintering conditions on strength properties at elevated temperatures were studied. Strengthening was attributed to zirconium in solid solution with molybdenum and to the presence of submicrometer particles of Zr02. Several alloys had tensile strength and stress-rupture properties com-parable with those of the best commercial alloys. The maximum tensile strengths obtained were 92 kpsi at 1,200° C and 53 kpsi at 1,316° C. The maximum stress-rupture life at 30 kpsi and 1,200° C was 145 hours.

Jan 1, 1974

By G. L. Oldright, J. D. Sullivan, W. E. Keck

"An apparatus and procedure developed in the laboratory of the South-west Experiment Station of the Bureau of Mines are capable not only of determining the rate and volume of penetration of solutions into porous materials but also of determining the total volume of voids within particles of porous material, and the density. The method is applicable to ores, bricks, concretes, tiles, filter bottoms, or other porous materials of this nature. As will be made clear in the descriptive matter to follow, the method measures (a) the volume of voids within the porous materials and is not concerned with the interstitial space between the particles.Porous materials usually contain some large voids and also pores that are capillary in nature. To measure the total volume of voids in a sample it is necessary to replace the gas or gases within the voids with some liquid of known density. The large cavities can be filled quite readily, but under ordinary conditions a long time may be required to fill capillary pores. As many porous materials are of a decomposable nature it is necessary to evacuate the porous materials and then submerge them in a liquid of known density to bring about saturation in a short time. Then by the use of a hydrostatic balance the volume of porous material (solid itself) can be determined. To determine the volume of porous material plus voids it is necessary to coat the sample with some material, such s paraffin, which will prevent solution from entering the voids; then, by means of a hydrostatic balance, the volume of porous material plus voids is determined and by subtracting that of the porous material from this the volume of voids is ascertained. The rate of penetration of solutions can be determined either (a) by measuring the change in weight as the sample becomes saturated when immersed ni a liquid of know density, or (b) by measuring the volume of liquid penetrating with a dilatometer. In either instance, due to the fact that some penetration takes place as soon as the sample comes in contact with solution and before a reading can be taken, the sample must be paraffined to determine the total volume of penetration. Since many porous materials partly decompose and disintegrate in liquids the rate and volume of penetration can better be measured by dilatometer than by the change in weight, as saturation takes place when immersed in a liquid. The details of procedure for determining (a) total volume of voids, and (b) rate and volume of penetration are given in this paper."

Oct 1, 1930

By D. Bienstock, J. H. Field, M. J. Lempel

A computer program is presented to perform the detailed and numerous calculations required for determining the interface temperatures and steady - state heat flow through a furnace wall composed of several refractories in layers . A method is developed that will allow the designer to determine the various thicknesses for each refractory layer to minimize either the total wall thickness or the cost of the wall per unit of area . A sample problem is presented and analyzed to illustrate the techniques involved .

Jan 1, 1964