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By Earl T. Hayes

[This work represents a continuation of the efforts of the Metallurgical Division of the Bureau of Mines to ascertain and apply knowledge of mineral physics to process metallurgy.]

Jan 1, 1941

By LeRoy D. Loy

The disposal of excess overburden from surface mining can be accomplished by use of a reclamation technique entitled head-of-hollow or valley fill. This report attempts to assess current valley fill regulations and practices, identifies inherent benefits and deficiencies, and develops concepts to enhance fill technology.

Jan 1, 1978

By Robert E. Barieau

General expressions for evaluating various thermodynamic properties applicable to the van der Waals equation of state have been derived. These formulas were subsequently used to evaluate various thermodynamic functions in the two-phase region. The results indicate that, for a van der Waals fluid, there is a finite discontinuity in the second derivative of the vapor pressure curve, in the second derivative of the chemical potential or Gibbs free energy at the critical point, and in the heat capacity at constant volume measured at the critical density. Numerical values are tabulated and graphs are presented for all functions calculated.

Jan 1, 1967

By Michael Rieber

Rail cars are referred to as "yellow-balled" when they are sufficiently old or damaged to preclude their efficient operation on long-haul or main line routes. For most coal carrying railroads, their alternative value is salvage. This, however, does not necessarily preclude their effective use, on a limited basis, by small mines located near existing trackage. Because of age, the sizes of these hopper and gondola cars ace currently 50 and 70 tons rather than the 100 tons commonly built at the present time. As a gathering system, yellow-ball rail could provide an alternative, particularly in Kentucky, western Pennsylvania and west Virginia, to coal trucks, conveyor belts and pneumatic pipelines [4, p.17], belts and pneumatic pipelines. Rail service of this type provides a limited alternative to track abondonment, a possible financial return to a railbank [3], a direct contribution to service demand on main lines, and a means by which many small eastern coal mines could retain or regain competitive viability [4]. In terms of energy efficiency, compared to trucking coal, the total direct energy impact (fuel) of yellow-ball rail can be expected to range from 280-990 Btu/ton-mile while that for trucks ranges from 1850-3120 Btu/ton-mile [2].

Jan 1, 1977

By R. E. Gray

[The purpose of the study is to investigate cases of subsidence over abandoned mined-out areas of the Pittsburgh Coal identified from published and unpublished sources and to determine through a consideration of the geology, topography, climate, mining activity, and evidence at ground surface, what mechanisms control subsidence .and under what circumstances it takes place. The study wan performed it two phases, the first to identify all documented incidents of subsidence in mined-out areas of the Pittsburgh coal Region; and the second, to study a particular portion of the region in detail, collecting pertinent data relative to the sites within, characterizing roil the nature of the subsidence and its economic consequences, and determining the applicability of the findings to other areas whore similar problems with the collapse of abandoned miner have been encountered.]

Jan 1, 1977

By J. D. Sargent

Selenium might be described as a paradoxical element, being either a metal or a nonmetal, a conductor or nonconductor, amorphous or crystalline, colorant or decolorant, and a hydrogenator or dehydrogenator. Selenium was discovered in 1817 by the Swedish chemist, Berzelius, while studying flue dust from the lead chambers of the sulfuric acid works at Gripsholm, Sweden, The ordinary stable form of selenium is a crystalline, grayish solid with semi-metallic luster. It melts at 217° C., boils at 684.8° C., and has a density of 4.79.

Jan 1, 1955

By S. H. Ash

As part of the work done at the Washington coal mines during the year 1929 , a study was made of the safety practices in and about the mines . Inasmuch as electrical blasting has made considerable headway it is interesting to note the manner in which it is done and the reasons why it was discarded at some of the mines . Blasting is done at the mines in the State by means of capped fuse , electric blasting " caps , " and in some instances by electric delay detonators . Black blasting powder with fuse is used at most of the open- light mines . The use of squibs was discontinued several years ago because the coal operators , without exception , recognized the dangers incidental to their use . Permissible explosive and dynamite are also used at some of the open- light mines . With the exception of some rock work and the driving of level work in gangways and air courses the explosive is detonated by means of capped fuse .

Apr 1, 1930

By D. G. Kuehn

Studies were conducted by the Bureau of Mines to determine the positive ions and neutral species produced in glow discharges of gas streams containing 1.0 percent NO in helium, 29 percent dry air in helium, and 1.06 percent NO in N2, Mass spectrographic measurements were conducted for gas pressures from 2.3 to 10.0 torr and dc currents from 10 to 20 mAo Ion species observed included NO+, N2 +, O2 +, N+, and 0+ with lesser amounts of He+, He2+, and N02+. Variations in various ionic and neutral species with discharge duration were interpreted to be consistent with an electrically induced dissociation of NO to produce N2 and O2. No nitrogen oxides were observed to form in glow discharges of the helium-air mixture.

Jan 1, 1975

By R. E. Hershey

1. Reserves were estimated for three coal beds: Lantana, Sewanee, and Richland. 2. Known measured and indicated reserves for all beds, based on a minimum thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, are estimated at 34 million short tons as of Januray 1, 1954. Of this total, 15 million short tons represents coal 28 inches and more thick. Areas in the beds were omitted from the estimate because available data relative to the bed characteristics were insufficient to permit making an estimate conforming with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves determined by this investigation.

Jan 1, 1956

By R. E. Head

[Recent investigations at the Intermountain Experiment Station of the Bureau of Mines at Salt Lake City indicate that metallurgists have given little attention to the occurrence of jarosite minerals in the oxidized ores of lead and silver. These investigations have also emphasized the importance of lowing when these minerals occur in the oxidized ores, especially those containing lead, silver, and gold, as their presence is a material factor in selecting a suitable kind of treatment. Since the question of the occurrence of jarosites in oxidized ores has come to the attention of the Bureau of Mines, investigation has indicated that plumbojarosite and argentojarosite are quite common. These two minerals appear to be widely distributed and probably escaped recognition by persons who had attempted to treat certain oxidized lead ores in which the jarosite minerals represented a material portion of the metal content. Consideration of the physical characteristics of the jarosites also indicates that in many cases failure to treat some of the oxidized lead ores with success has been directly due to the fact that the greater portion of their lead and silver content was present as plumbojarosite and argentojarosite. The data and the description of these minerals given in the body of this paper indicate that attempts to recover lead and silver from ores in which appreciable amounts of too metals occur is plumbojarosite and. argentojarosite would be unsuccessful if confined to gravity methods of concentration. There are undoubtedly considerable tonnage of oxidize lead ores in the various mining regions of this and other countries, and it is quite probable tat in some of these ores the metal content of lead and silver may be largely anglesite (lead sulphate) and cerussite (lead carbonate) but that they will also contain cerargyrite (silver chloride), argentojarosite, and plumbojarosite. The treatment of such ores therefore presents an important problem, since a product is discarded from]

Jan 1, 1928

By Martin Hertzberg

In this Bureau of Mines study, an equation is derived for the limit burning velocity for divergent, spherical propagation from an ignition kernel of radius, r: (Su)e = ( ) . For flame propagation into a preexisting, stretching velocity gradient of magnitude dv/dx, the limit velocity is (Su)e = (a dv/dx)1/2. These formulations are shown to be equivalent to the fluid dynamic concepts of Damkoh1er, Kar10-vitz, and Markstein. Existing data for the b10woff limits of flames are shown to give excellent agreement with those concepts provided that proper account is taken of two dilution effects: composition dilution caused by entrainment and velocity gradient dilution caused by flow expansion. Approximate flow-field solutions are also derived for the unburned gas motion above an upward propagating, spherical flame kernel in buoyancy-induced flows. It is shown that;, the upward hemisphere propagates toward a stagnation plane in a counterflow configuration involving the balance between the combustion force, which accelerates the cold gas upward, and the buoyancy force that accelerates the cold gas downward. The position of the stagnation plane above the upward propagating hemisphere is related to the ratio of the buoyant velocity, vb, to the burning velocity, Suo Extinction of the upward propagating wave occurs by flame stretch in that counterflow configuration when n = Vb/Su begins to exceed the expansion ratio, Pu/Pb' and the wave is blown off by its own buoyancy-induced flow field.

Jan 1, 1984

By S. H. Katz

"At the annual meeting of the International Association of Fire Engineers at Kansas City, Mo., in June, 1919, the Bureau of Mines offered to cooperate with municipal fire departments for the purpose of obtaining information regarding composition of the air in burning buildings. (Katz, S. H., Statement made at Convention of International Assoc. of Fire Engineers: Fire and Water Eng., vol. 66, July 16, 1919, pp. 129-30, also Fireman's Herald, vol. 78, July 12, 1919, pp. 48.) The gas-mask laboratory of the Bureau's experiment station at Pittsburgh sent vacuum bottles for taking samples to fire chiefs in twenty-five cities, who had signified their intention to aid in this work. It was hoped to obtain one hundred or more samples, because statistics in quantity are necessary for drawing reliable conclusions concern-in the likelihoods of encountering irrespirable as in burning buildings. This far, eleven samples have been received by the laboratory. Results of analyses and pertinent data regarding these samples are given in the accompanyingEight of the eleven samples contained, no carbon monoxide; seven of the eight were taken above the ground level and one below ground. One sample taken above ground contained 0.03 per cent carbon monoxide, and this quantity is not dangerous to breathe for a limited time. Of the three samples taken below ground, one contained no carbon monoxide; the other two contained 0.10 and, 0.35 per cent, respectively. This indicates that in a burning building, the hazard from carbon monoxide is much greater below the ground level. The cause undoubtedly lies in the poorer ventilation that is usually found in cellars or basements. Abundance of ventilation provides the necessary air for complete combustion, or if incomplete combustion does occur, the carbon monoxide generated by the fire is greatly diluted with fresh air and swept away by the current. It may be noted that the highest proportion of carbon monoxide was found in a cellar where a fire as burning among piled cases. The difficult access of air to the burning parts facilitated the formation and lib ration of carbon monoxide. The smoke here was very light and no difficulty was experienced in breathing. Some of the air containing dense smoke showed little change from normal air by analysis. Thus the density of smoke or the irritation and difficulty it causes in breathing are no indication of the presence of poisonous gas. None of the samples shows important oxygen."

Nov 1, 1920

By Geoffrey C. Huggins

Diagnostic: tests were performed on a production ST-5A Load-Haul-Dump machine manufactured by Wagner Mining Machinery Company to evaluate and rank order noise sources. The diagnostic evaluation indicated that the major noise sources were the transmission, the engine, and the cooling fan. This phase was followed by implementation of recommended noise control treatments, which included vibration isolation of the transmission, a transmission enclosure, an engine enclosure, and modifications of the inlet to the cooling fan. The final step in the program was an underground operational period which began on 31 August 1976 at the National Gypsum Mine in Shoals, Indiana. The noise control treatments successfully reduced the LHD operator noise exposure by 7 dB(A), thus increasing its allowable operation time by a factor of 2.7. Actual measurements made underground using noise dosimeters have indicated that, during, a typical shift, the noise control treatments have reduced the fractional exposure to an allowable level. The report discusses the mechanical aspects of the LHD, its noise sources, the treatments applied, the final levels achieved, and field experience with the noise-controlled machine.

Jan 1, 1977

Early in 1936 the Interstate Oil Compact Commission and other groups interested in forecasts of demand for petroleum requested the Bureau of Mines to make a physical inventory of crude-oil stocks in the United States. Accordingly, the 74th Congress -appropriated funds for conducting such a survey during the fiscal year ended June 30, 1937. In the discussions end hearings2/ relative to the need for the survey, the opinion was expressed that crude oil held is storage for long periods had lost so much of its gasoline content that the economic significance of total stocks should be discounted materially. Therefore, a primary objective of the survey was to

Jan 1, 1938

By R. H. Reist, R. D. Dey, V. Castranova, J. P. Durham, Y. Rojanasakul

"Silicosis is a fibrotic pulmonary disease produced by inhalation of silica-containing dusts (Peters, 1986). Chronic silicosis may develop 20-40 years after initial exposure to crystalline silica, and the disease may progress from a simple to a complicated form. Few symptoms are evident in simple silicosis with pulmonary function being relatively normal. However, chest radiographs reveal small rounded ·opacities in the upper lobes of the lungs. These silicotic nodules consist of collagen arranged in a distinctive circular pattern. As fibrotic changes become more severe, the disease progresses to complicated silicosis (progressive massive fibrosis). Complicated silicosis is associated with shortness of breath and decreases in pulmonary function characteristic ofrestrictive lung disease. Chest x rays reveal numerous large silicotic nodules which may be associated with scar emphysema. Several mechanisms have been proposed to explain the cellular events which result in silica-induced lung damage and fibrosis (Lapp and Castranova, 1993). They include: ( l) direct cytotoxicity of silica, (2) activation of oxidant and enzyme release from alveolar macrophages, (3) recruitment and activation of polymorphonuclear leukocytes, and (4) stimulation of fibroblast proliferation and collagen synthesis.Tetrandrine is a bisbenzylisoquinoline alkaloid derived from the Chinese herb Radix Stephania tetrandra. It has a molecular weight of 622.73 and an empirical formula of C38H420 6N2. The chemical structure of tetrandrine has been published previously by our laboratory (Castranova et al., 1991 a). Its structure is characterized by methoxy groups at C7 and C12 , uncharged nitrogens at N2 and N’2 and two 17-carbon ring members connected by a double oxygen bridge between Ca-C7 and C11-C12. Tetrandrine has been shown to reduce both silica-induced fibrosis and the elevation of lung collagen content in rats (Huang et al .. 1981; Yu et al., 1983; ldel, 1987). Furthermore, tetrandrine has been used as an antifibrotic agent in Chinese clinical trials (Li et al.. 1981 ). Preliminary results suggest that administration of tetrandrine to patients with silicosis results in substantial improvement of symptoms, increases in diffusion capacity, and decreases in the size of shadows on lung x rays."

Nov 1, 1995

By M. Copeland

Phase relations of gadolinium alloyed, up to 40 weight-percent (wt pct), with AISI 304-type stainless steel were established. Body-and face-centered cubic iron-rich solid solution phases and several intermetallic gadolinium-containing compounds of variable composition that approximated the formulas Fe9Gd, Ni7Gd2, Ni3Gd, Fe2Gd, NiGd, and NiGd3 were identified. The intermetallic phases Fe9Gd and Ni7Gd2 were noted to melt at about 1,080° C at about 0 to 2 wt pct gadolinium. The melting temperature of Fe9Gd increased with increas-ing gadolinium content to a plateau at about 1,230°C and 30 wt pct gadolinium, and the melting point of Ni7Gd2 decreased to a plateau at 900° C and 30 wt pct gadolinium where Ni3Gd, NiGd, and Fe2Gd coexist. Body-centered cubic iron solid solution was stable from 1 to 2 wt pct gadolinium to higher contents, 30 wt pct gadolinium or possibly more, and face-centered cubic iron up to 12 wt pct gadolinium below 1,200° C. The stability of these phases above 1,200° C was not resolved except for the mel points. A limited number of fabrication variables as well as mechanical and corrosion properties of alloys containing up to 5 wt pct gadolinium were studied. Equilibrating and forming operations were best conducted at about 940° to 1,080° C. Some variability in the yield and tensile strengths of alloys was noted; however, there was a continual decrease in ductility and impact resistance with increasing gadolinium contents. The resistance of gadolinium alloys to corrosion in water at 354° C was about the same as stainless steel.

Jan 1, 1965

By Alton B. Cook, G. B. Shea

"INTRODUCTION In February 1945, Captain (now Commodore) W. G. Greeman, U. S. N., Director, Naval Petroleum and Oil 3hale Reserves, requested the Bureau of Mines to assist the Navy in its wartime development of Naval Petroleum Reserve No. 1, Elk Hills field, Calif., to assure adequate supplies of petroleum products in the Pacific theatre. Unit Operation 4/,engineers desired pressure volume-temperature and viscosity data on the reservoir oil in the shallow oil zone to augment data previously obtained for the purpose of calculating reservoir performance and oil reserves. Accordingly, arrangements were approved by the Operating Committee far, the Bureau of Mines to proceed with a program of field sampling and laboratory determinations designed to obtain the desired information.To carry out the assignment, the Bureau transferred the necessary person¬nel, subsurface pressure, temperature, and sampling instruments, and laboratory equipment for analyzing subsurface oil samples from the Petroleum Experiment Station, Bartlesville, Okla., and the San Francisco, Calif., office and set up a temporary field headquarters in the Elk Hills. The program of work as out-lined by Unit Operation required the 6 months period March-August 1945 to complete during which time individual reports comprising data on pressure-volume-temperature relationships and reservoir oil viscosities as determined on subsurface oil samples and recombined oil and gas samples for 5 selected wells were submitted to Unit Operation.This report is a summary compilation of the data contained in the original reports supplemented by correlations of some of the physical properties of the reservoir oil with the A.P.I. gravities of the produced oil. The report also includes material-balance calculations relative to one of the oil horizons in the shallow zone. The Bureau of Mines believes that publication of the results of these analyses is a worthwhile contribution to the petroleum literature and of particular interest to the California industry."

Apr 1, 1947

By G. H. Martindill

Complex chemical and physical changes occurring during carbonization result in a heterogeneous system composed of gaseous, liquid, and solid phases, whose relative proportions and chemical compositions change constantly as temperature increases. Studies in which the participating variables are isolated and controlled should be useful in formulating the mechanism of coal carbonization. The most characteristic property of a coking coal is its ability to form a plastic mass at a certain stage of the carbonization process. During this period it is believed that fluidity of the coal influences the properties of the resultant coke. This report gives results of an investigation by the Federal Bureau of Mines of the influence of the maximum fluidity attained by the charge on the physical quality of the coke or char produced. As a first approach to the problem, researchers investigated high-melting-point pitches, which are relatively simple carbonaceous materials. The plastic properties of these pitches, prepared specially for this work, varied greatly; their fluidities, as measured by the Gieseler plastometer, covered most of the fluidity range characteristic of coking coals. Blending these pitches with increasing pro-portions of fine coke progressively reduced their fluidities. Coal-pitch and coal-coke blends also were treated; their fluidities were varied by changing their blending ratios. The various blends were carbonized in a small-scale carbonizer and the resistance of the carbonized residue (char) to abrasion was determined in a small-scale tumbler test, using the Roga drum.

Jan 1, 1960

By Xintan Chang

MFIRE is a computer simulation program that performs normal ventilation network planning calculations and dynamic transient-state simulation of ventilation networks under a variety of conditions. The program is useful for the analysis of ventilation networks under the influence of natural ventilation, fans, fires, or any combination of these. MFIRE simulates a mine's ventilation system and its response to altered ventilation parameters such as the development of new mine workings or changes in ventilation control structures, external influences (varying outside temperatures), and internal influences (fires). Extensive output enables detailed, quantitative analysis of the effects that the alteration will cause to the ventilation system. The program was developed at Michigan Technological University (MTU), Houghton, MI, with support from the Bureau of Mines. A personal computer (PC) version of the program was completed under contract for the Bureau by MTU. The purpose of this report is to document the installation and use of the PC version of the program MFIRE.

Jan 1, 1990

By Murray Jacobson

Facts obtained by the Bureau of Mines on the dust-explosion hazard in air of materials used in the plastics industry are presented for 313 samples studied in the laboratory. Information is given on ignition temperature of dust clouds and layers, minimum explosive concentration, minimum energy required for ignition, explosion pressure and rates of pressure rise, amount of inert dust required to prevent ignition and flame propagation, and, in some instances, on the limiting oxygen concentration in an atmosphere to prevent ignition by spark and by heated surface. The effects of particle shape, additives, and resin structure on explosibility are discussed. Relative explosibility of the materials is related to the ignition sensitivity and explosion severity and is denoted by an empirical index. Recognition of the degree of hazard will facilitate adoption of adequate measures for preventing ignition and explosion during manufacturing or processing.

Jan 1, 1962