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By E. G. King

Sodium-aluminum and calcium-aluminum silicates are important rock-forming minerals. While many of them are of only theoretical interest, several are of practical importance--as ceramic raw materials and as potential future sources of aluminum. Heretofore, thermodynamic data for these minerals were incomplete; and in many instances missing data were difficult to estimate reliably. This has seriously hampered thermodynamic calculations pertaining both to the natural formations of these minerals and to their decomposition in sintering and fluxing reactions. This paper reports the results of the Federal Bureau of Mines measurements of low-temperature heat capacities of four crystalline silicate minerals--dehydrated analcite (NaAlSi2O6), hexagonal anorthite (CaA12 Si208), lawsonite (Ca2Al2Si2080?2H20), and leonhardite (Ca2Al4Si8C24?7H2O). It augments previous similar measurements of related minerals, which were summarized recently.4 The measured heat-capacity data were used to derive entropy values for the four minerals at 298.15° K. Some relations between these entropy values and those of other similar minerals were discussed. These relations illustrate the difficulty of estimating entropy values of tertiary (or higher) silicates.

Jan 1, 1961

By A. L. Engel

This report describes results of laboratory-scale experimental treatment of nine ores containing gold and silver, including samples of products of previous plant treatment, from ore deposits in California and Nevada. The samples treated were taken by engineers of the Bureau of Mines during investigations of these ore deposits. The information reported is of interest for development of the mining districts represented or in future Investigations of similar ores from other sources. The treatment methods were as simple as possible. More complicated treatments were tried when required, The applicability of the methods and their limitations in treating the ores are shown by the data in this report. The following treatment methods were employed in the experiments described: Screen analyses were made to determine distribution of values in various screened-sized portions of crushed ore, or to determine optimum size to which a particular ore should be crushed or ground to liberate values, and some-times to determine residual values in various-sized portions of treated material.

Jan 1, 1961

By Thomas Jenning, C. M. Keithly

"INTRODUCTION This report is one of a series. 4. 5. 6/ concerned with presenting historical development, and operating data on secondary-recovery projects in various States to stimulate interest in sound secondary-recovery programs. Preceding reports in this series have dealt exclusively with descriptions of and results obtained by water flooding in three states, but no recent publication of comparable purpose describes gas-injection 7/ practices. The authors intend to present material relevant to the development and operation of gas-injection projects in Illinois, with particular emphasis on those producing from oil-bearing horizons that had been depleted to a point near the economic limit of operation by past oil-recovery methods.Most operators realize that the energy expended on the movement of fluids through gas-expansion- or gas-cap-type oil reservoirs to producing wells must be supplemented to attain maximum recovery of the oil present. Under favorable conditions, many operators choose to maintain oil-propulsive forces at or near their original magnitude by injecting extraneous fluids into a reservoir or recycling produced fluids early in the life of a field. More common, and less desirable, is the practice of replenishing these forces after primary producing methods become unprofitable. The lattes practice has been adopted in many stripper fields in Illinois and most of the oil-producing States during the last 40 years, but other old oil fields, and oil properties within those fields which were partly exploited by secondary--recovery methods, also may offer favorable opportunity for further development. To encourage and, aid operators in the development of gas-injection projects in the old oil fields of the United States, four projects have been described in detail in this report."

Nov 1, 1944

By James A. Wasson

This report analyzes the petroleum-production potential of the basal Greenbrier dolomite zone, Sycamore-Millstone field, Sherman District, Calhoun County, W. Va., through the application of certain secondary-recovery methods. The well logs obtained and the core recovered from a well in this formation permitted an evaluation of the productive capability of the reservoir, Approximately 120,000 stb of oil may be produced from a 20-acre five-spot unit at breakthrough if the property is waterflooded. At an assumed limiting producing gas-oil ratio of 20)000 sef/stb, approximately 69,000 stb of oil should be recovered by low-pressure gas drive.

Jan 1, 1967

By J. L. Konchesky

The technical feasibility of gasifying powdered, noncoking, low-rank coal with steam in an externally heated tube has been demonstrated. The tube, 112 ft. of alloy-steel tubing shaped into a helix, served as an electrical conductor of electricity used for heating. The effects of the following variables were studied: Residence time of coal in reactor, average reaction temperature, steam concentration, and rank or geologic age of coal. Reaction pressure was maintained in the range 19-26 p.s.i.a. High carbon conversions and large yields of synthesis gas were obtained with low-rank coal. In one test, for example, about 88 pct. of the carbon in a subbituminous C coal was gasified at 1,910* F. with a residence time of 1 sec. The gas contained 58 pct. H2, 19 COD 15 CO, and 3 CH4; the yield was 30 cu. ft. (at 32' F. and 14.7 p.s.i.) of synthesis gas (CO + H2) per pound of dry coal.

Jan 1, 1960

By S. W. Parr, T. E. Layng

There is presented below the results of experiments made on six samples of Utah coals furnished through the U. S. Bureau of Mines , under an agreement dated June 16th , 1920. The details of all values for all runs are tabulated and presented herewith . Clear The samples, consisting of approximately 150 pounds each, were received at the University of Illinois , on June 15 , 1920 , and are listed as follows : Creek , Wattis , Castle Gate , King , Standard , and Aberdeen . The proximate and ultimate, analyses of the various ccals from that region , representing all the types included in these samples , have already been made by the Bureau of Mines , and are available . * Similar determinations were also made on the particular samples forwarded for purposes of these experiments . The results obtained on the coal as received did . not very in any material feature from the values reported by the Bureau, they are shown in Table 1. It is of importance to note only that the oxygen content is uniformly high , namely approximately 9.5 to 11.5 per cent of the as- received coal , while the oxygen - hydrogen ratio is also high, being on the average approximately 2 ( oxygen) to 1 ( hydrogen) .

Sep 1, 1921

This summary of State laws on explosives was compiled primarily to ascertain what subjects relating to their control have been acted upon by each State legislature and, in general, how they have been treated. It does not include any legislation passed after 1942, or any proclamations, regulations, or administrative orders. It does not purport or attempt to be authoritative. If any problem arises involving interpretation of the statutes of any particular State, the original source must be consulted for the exact words used by the legislature. This summary, however, will be useful in determining whether relevant statutes exist, and in locating them quickly with a minimum of effort. It will be of value also in comparing statutes in one State with similar statutes in other States to determine what construction has been placed upon them by the courts of these jurisdictions or to contrast the varying provisions of many States upon a similar subject. To make these comparisons easier, the statutory provisions for each State have been grouped under several major topics in outline form. Although this sometimes has resulted in disruption of the continuity of individual acts, the increased general clarity and availability of comparable sections have more than justified the procedure followed.

Jan 1, 1943

By J. J. Bean

This paper, describing the milling practice at the oxide concentrator of the International Smelting Co., is one of a series on milling methods and costs being published by the United States Bureau of Mines. GENERAL DESCRIPTION The oxide concentrator is properly an integral part of the Tooele plant of the. International melting Co., located 5 miles from Tooele, Tooele County, Utah. It has a capacity of 300 tons of ore per day and uses an all-flotation process to treat custom siliceous oxidized lead ores obtained principally from the Tintic district in Utah. Ores found amenable to the process are purchased on a custom basis, the principal tonnages being obtained from the Tintic Standard and North Lily mines.

Jan 1, 1933

By Wilbert J. Huff

The work of the Explosives Division, Bureau of Mines, United States Department of the Interior, for the fiscal year ended June 30, 1939, is described in the following pages. This paper is the fourth of a series of annual reports covering the activities of the division since July 1, 1936. The studies outlined in this and preceding reports of the series have been conducted under the direction of the author and the respective unit leaders to whom specific credit is indicated.

Jan 1, 1940

By W. R. K. Wu

Studies are reported on the structure of coal and coke with the graphical , statistical densimetric method based on the relation between the molecular volume per carbon atom ( M / C ) and the atomic hydrogen - carbon ratio ( H / C ) . Previous work , mostly from chemical and physical investigations , is critically reviewed . Difficulties in evaluating the ring increment are demonstrated for coal and coke for the statistical densimetric method based on the additivity of atomic volumes of constituent elements . A new diagram is presented for the graphical method . Methods are introduced for correcting M /C and H/C for the presence of minor constituents in coal and coke . With the graphical method , the fractions of aromatic carbon atoms in the total carbon atoms are estimated for a coal , a resin , and 5 petrographic components ; the types of condensed structure in the fundamental units of molecules are discussed for these substances , 28 coals , and 6 " average " cokes at 500 ° to 1,000 ° C. It is also shown that the number of rings in the fundamental units of coal generally increases with increasing rank and that of coke , with increasing carbonization temperature .

Jul 1, 1960

By F. E. Brantley, D. M. Yergensen, D. A. Martin

Fluidized - bed roasting was investigated as a means of decomposing gypsum and gypsum mixtures to produce a gas rich in sulfur dioxide and a lime or portland cement residue . Ninety- eight percent desulfurization of gypsum in a 10 - inch fluidized- bed reactor took 1.5 hours at an operating temperature between 1,200 ° and 1,225 ° C. A cement- type residue was obtained but had to be refired at 1,450 ° C before mortar prepared from it met the physical specifications for cement .

Jan 1, 1963

Heavy liquids have come into use in ore-dressing investigations, as they make possible the separation of an ore into its specific-gravity components. A paper containing a general dissertation on heavy liquids has been written by John D. Sullivan,4 and the practical application of heavy liquids is explained by Box and Crabtree5. Some heavy liquids become discolored after continued use, and the lack of transparency impairs their value. Since they are fairly expensive, reclaiming is desirable. This paper briefly discusses the preparation and care of some of the more common heavy liquids.

Jan 1, 1928

By J. J. Burns

Disasters such as occurred at Oppau, Germany, in 1921, at Tessenderloo, Belgium, in 1942, and in this country at Texas City, Tex., in 1947 clearly indicate the explosive hazard associated with the manufacture, storage, and transport at ion of ammonium nit rate The importance and extent of the hazard may be Judged from the large amount of ammonium nitrate produced and transported annually in this country. Between July 1, 1947, and June 30, 1948, it was estimated that the United States produced 461,528 tons of ammonium nitrate commercially for agricultural purposes alone .5/ In addition, U. S. Army Ordnance plants have manufactured and shipped 779,730 tons of ammonium nitrate fertilizer to Germany, Japan, and Korea.6/

Jan 1, 1953

By H. P. Hamlin, W. A. Grosh

Samples of clays , shales , and argillites from 21 locations were subjected to preliminary bench- scale tests for bloating properties , and several samples were tested for ceramic properties . Samples showing favorable bloating properties were further tested in a pilot - plant - scale rotary kiln . Physical characteristics and concrete -making properties of the bloated products were determined . The Decorah shale from one area made a suitable material for a lightweight aggregate ; however , the limestone layers in the formation must be eliminated or the resulting activated lime must be controlled by quenching .

Jan 1, 1963

By David L. Veith

Caustic scrubbing followed by silica flotation with cationic ether primary amine proved effective in upgrading commercial magnetic concentrates to supergrade products containing 2 percent SiO2, or less. Samples representing 41 million long tons per year of commercial magnetic concentrates from the Lake Superior region were tested by the Bureau of Mines. Bench-scale and pilot plant research indicated an estimated potential of 32 million long tons per year of superconcentrates to be available. Two pilot plant investigations yielded superconcentrates containing 1.1 and 1.9 percent SiO2 that were derived from commercial concentrates containing 7.0 and 4.2 percent SiO2, respectively. Corresponding iron recoveries were 90 and 93 percent at reagent costs of just over 33 cents per long ton of superconcentrates produced. Additional sources evaluated on a bench scale resulted in iron recoveries of 72 to 95 percent in products containing 1.7 to 2.0 percent Si02. Although reagent cost ranged up to 60 cents per long ton of superconcentrate, it is probable that these costs would be reduced in plant applications where benefits are derived from material and reagent recycle.

Jan 1, 1974

By B. J. Dalton

The Helium Research Center, Helium Activity, Bureau of Mines, is presently engaged in a critical examination of all of the PVT data on helium that appear in the literature. The long-range objective is the development of a single equation of state for helium that will allow all of the thermodynamic properties to be calculated and will reproduce all of the data within the accuracy with which the data are known. A preliminary objective is to obtain the best values of the second virial coefficients and to develop an equation that will reproduce the best values as a function of temperature. The method of treatment consists in expressing the PV product of a gas, for a given isotherm, in terms of a power series in either the pressure or the density and evaluating the constants by least squares solution. Associated with these functions whose coefficients have been evaluated by least squares, the following errors, or deviations, are of interest; the standard error of a single measurement; the standard error in each coefficient; and the standard error of the resulting function.

Jan 1, 1964

By R. R. Wells

An important activity of the Bureau of Mines is the continual search for new sources of minerals. As a part of the investigation of strategic mineral deposits in the United States, samples of mercury ores were submitted to the Ore Dressing sections of the Salt Lake City and Albany stations for metallurgical testing. This paper gives data summarizing the results obtained from laboratory beneficiation studies of mercury ore samples submitted during the period 1941 to 1947. Ores tested included three from Jackson County, Oreg., one from Valley County, Idaho, one from Storey County, Nev., and one from Sonoma County, Calif. In general, the ores from Oregon were not amenable to concentration by flotation because of intimate association of cinnabar with other minerals or because of extremely low grade. One Oregon ore was amenable to direct distillation provided lime was added to reduce corrosion of the retort.

Jan 1, 1950

By N. A. Gokcen

In this Bureau of Mines report, appropriate equations correlating the activity of water with the activities of electrolytes in binary and multicomponent solutions have been derived for computer calculation. It was found that the half-integer power series are far superior to the integer power series, for both types of series having the same number of terms. The pro-posed method of calculation is capable of accurately yielding the activities of all components from the measurements of the activity of a single component at various concentrations. This method replaces the cumbersome and objection-able method of graphical integration of the Gibbs-Duhem equation. Two novel methods are proposed for determination of activities of electrolyte solutions important in hydrometallurgy; (1) Water vapor pressure measurement by differential pressure transducers having an accuracy of 0.001 pet, and (2) transpiration method with an inert gas bubbled through concentrated solutions followed by the analysis of the evaporated and redissolved electrolytes with specific ion electrodes having a sensitivity of ±10-10 molal. The first method is suitable for nonvolatile electrolytes, and the second, for volatile electrolytes such as hydrogen halides, HN03, H2S03, etc. The existing methods of estimation of ionic activities have been surveyed, and the best method has been selected, discussed, and summarized.

Jan 1, 1979

By J. L. Johnson

The U.S. Bureau of Mines investigated the recovery of tin and silver from the Coal Creek deposit in the Talkeetna Mountains, AK. Approximately 5 million st of reserves grading 0.2 pct Sn with silver credits of 0.2 tr oz/st have been delineated by drilling. A 10-to 25-pct Sn gravity concentrate was produced by treating the minus 20-mesh ore with a spiral, then regrinding to minus 65 mesh and tabling. Sulfide contamination in the gravity concentrate was as high as 60 pet. Sulfide flotation of this concentrate produced tailings containing 40 to 50 pet Sn. Overall recovery was 76 pct for tin but only 5 to 10 pct for silver because of losses during sulfide flotation. Other methods tested to clean the concentrate included cassiterite flotation, gangue flotation, nitric acid leaching, and wet and dry magnetic separation. Tin beneficiation tests on the minus 325-mesh fraction included cassiterite flotation, vanning, sulfide flotation, and fuming. The bench-scale and locked-cycle tests were used to estimate the mass flows for a 1,000-st/d plant.

Jan 1, 2010

By D. S. Kingery

Investigations over several years have disclosed that the principal manners of occurrence of shuttle-car injuries are in order: 1. Victims in contact with roof or crossbars. 2. Victims in contact with ribs or timber legs. 3. Victims falling from, or jerked from, shuttle cars. 4. Victims in contact with overhanging brows or protruding pine for pin timbers, or water lines. 5. Contact with persons or collisions with parked equipment. 6. Victims injured by roof falls or falling timbers caused by knocking out roof supports with shuttle cars. 7. Victims injured by runaway shuttle cars. 8. Victims injured while loading or unloading timbers or other materials from shuttle cars. These recurring types of shuttle-car accidents reflect the physical conditions of the working sections, certain safety deficiencies in shuttle-car maintenance and design, and unsafe practices by operators.

Jan 1, 1952