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By Robert F. Chaiken

An absorption-desorption model of particle reactivity was employed to describe the observed relationship between two apparently diverse phenomena which have been the subject of considerable study at the U.S. Bureau of Mines: (1) coal-rock dust reflectance and (2) coal-rock dust explosibility. The model accounts for heterogeneities in particle-size and material properties; however, in the present report, only particle-size distribution is considered. A mean particle-size parameter, appropriate to the explosion extinction process, is derived, and then taken as appropriate to describing optical reflectance. The derived form-to-function relationships for the two processes, when compared with experimental data, suggest that a problem exists with previously derived theory relating optical reflectance to rock dust concentration. A reexamination of that theory leads to a new theoretical expression, changed by a factor of 2, for the variation of rock dust concentration with reflectance which is in quite good agreement with experimental results. The current work offers justification for measuring and establishing rock dust requirements for specific coal dust size distribution(s) found in the mine-distributions that undoubtedly depend on the mining method and the type of coalbed.

Jan 1, 2010

By Edward J. Chuhta, Joseph E. Chilton, Robert J. Timko

in underground mines to measure worker exposure to various gases such as methane, carbon monoxide, and nitrogen dioxide (NO2). Even in relatively small concentrations, NO2 can produce harmful side effects in underground workers. Mines using equipment powered by diesel engines, carrying out explosive blasting operations, and performing extensive arc welding and/or cutting work will have measurable quantities of NO2 released by these processes. Workers in these areas often use gas monitors to warn of excessive gas concentrations and to help them determine when to increase ventilation air that will dilute these gases, thus minimizing exposures to this gas. Portable gas monitors, used to measure NO2 levels, must be calibrated before each use. Calibration is typically performed using a small portable pressurized cylinder containing a certified gas mixture. The certified NO2 standard mixture, usually 10 ppm NO2 concentration, is diluted with either air or nitrogen gas. To determine the stability of commercially available portable gas standards, two different cylinders containing NO2 in nominal 10-ppm concentrations were examined. One cylinder was diluted in air, the other, in nitrogen. Baseline NO2 mixtures were generated using a standard liquid NO2 permeation tube operated at a constant temperature. Final dilutions of the test gas mixtures were made with air or with nitrogen using a mass flow-controlled gas dilution system. This study showed that, when a permeation-type NO2 generator is used, the electrochemical sensors in portable NO2 monitors provide identical results for gas mixtures whether they are diluted with air or with nitrogen. Two different gas monitors, one with a two-electrode sensor and one with a three-electrode sensor, were used to measure gas concentrations in the two commercially available cylinders. One month after the cylinders were delivered, the NO2-in-nitrogen cylinder, stated to contain 10 ppm NO2, measured 8.13 ppm. The NO2-in-air cylinder, also stated to hold 10 ppm NO2, measured 6.88 ppm. Therefore, before using NO2 gas cylinders to calibrate monitors, it is recommended that their concentrations be verified either by manufacturer recertification or by comparing the stated cylinder gas concentrations to a laboratory-based permeation tube-generated standard.

Dec 1, 2005

By Wm. O. Vanderburg

This paper describing the milling methods at the Hughesville concentrator of the St. Joseph Lead Co., Hughesville, Mont., is one of a series of similar papers being prepared by the U. S. Bureau of Mines on practices at the various mills in the United States. The writer expresses his thanks for the courtesies extended by the officials of the company while visiting the property and acknowledges the assistance and helpful suggestions given by R. H. Willcomb, general manager, and Carl Martin, mill superintendent, of the Hughesville Division f the St. Joseph Lead Co.; and E. D. Gardner, supervising engineer, U. S. Bureau f Mines, Southwest Experiment Station, Tucson, Ariz., in gathering and compiling the data herein presented.

Jan 1, 1931

By William A. Beck

"In 1912 bauxite was discovered in the Andersonville district, which lies in the 28th and 29th land districts of Georgia and comprises parts of Sumter, Macon, and Schley Counties. Mining was begun in May 1914 by the Republic Mining & Manufacturing Co. Considerable ore has been produced in this region since that time by individual interests and by the American Cyanamid & Chemical Corp., which acquired the property formerly owned by the Republic Co.The area was examined in the fall of 1941 by representatives of the Bureau of Mines and the Geological Survey, after which a prospecting program was begun by the Bureau. Drilling was started on December 26, 1941, and continued until November 18, 1943. A total of 1,192 holes was drilled in the district, and 3,679 samples were taken and analyzed.Mineral exploration agreements were signed by 146 property owners covering 42,128 acres. Holes were drilled on 121 of these properties, which have a total area of 38,778 acres.Drilling under this project disclosed several new deposits, of which four have been completely delimited. Previous prospecting in this area by mining companies did not find bauxite, as it lies under heavy overburden. Work by the Bureau indicates 14,412,000 long tons of ore containing 30 percent or more alumina. The total tonnage is divided as follows:Georgia State Highway Routes 26 and 4-9 traverse the district. The Central of Georgia Railroad passes through the center of the entire district (see fig. 1).The project was initiated by J. R. Thoenen, supervising engineer, Non-metals Mining Section, Mining Division, Bureau of Mines. It was under his general supervision until July 1942, after which it was under the general supervision of E. J. Lintner and Rowe McCrae, district engineers for Georgia, South Carolina, and Flordia, respectively.John C. Feeley, Jr., was project engineer from December 1941 to April 1942. Other engineers who assisted in the work on the project are R. E. Babcock, T. M. Romslo, Don M. Coulter, and Walter T. Lewiecki.Acknowledgment is due the metallurgical staffs at College Park, Md., and Tuscaloosa, Ala., for analyses of samples and beneficiation tests.Acknowledgment is also expressed to Alfred D. Zapp, M. W. Harris, Elmer Kneedler,and Parke D. Snavely, of the United States Geological Survey, for their aid, data, and maps.Bauxite was discovered in the Andersonville district in 1912 on lot 187 of the 28th land district, in Sumter County. This lot is situated about 1.5 miles west of the Flint River, on the south slope of the valley of Sweetwater Creek. Mining was started in May 1914 by the Republic Mining & Manufacturing Co. This and adjacent properties were acquired in 1930 by the American Cyanamid & Chemical Corp., which has been operating there since."

Dec 1, 1949

By Christopher Van Dyke, Knox Van Dyke, Lixin Wu, Jaime Gutierrez

"I. INTRODUCTION(SILICA, THE LUNG, INFLAMMATION, AND FIBROSIS)Inhalation of respirable-size silica (0. I to 5 µm in diameter) deposits the particles in the deep spaces of the Jung where oxygen is exchanged. The resulting pattern of inflammation is substantially different compared to that observed from other inhaled substances such as carbon, polystyrene titanium dioxide etc. 1 Following the inflammatory reaction the body attempts to isolate the damage by walling off the area via fibrosis. 2 The unique nature of the inflammatory response to silica makes it logical to infer that fibrosis is a later-stage manifestation of the initial inflammatory damage. In addition to the inflammation extensive lysis and cellular death particularly to macrophages and neutrophils, can occur, depending on the dose of silica.' The ingestion of significant amounts of silica by macrophages and neutrophils produces an inflammatory sequence which activates the lipoxygenase pathway of arachidonic acid metabolism and produces platelet activating factor (PAF) and leukotrienes (LT).4·5II. CALCIUM IONOPHORE MIMICS SILICA TOXICITY IN VITROPhagocytic cells exposed to silica in vitro produce PAF and LT. This response is reminiscent of phagocytic cells exposed to the calcium ionophore (A23 l 87) in the presence of ionic calcium.6-8 A23 l 87 forms a complex with free ionic calcium which passes through cellular membranes, thus transporting calcium inside the cell. The increased intracellular calcium concentration triggers the production of small amounts of prostaglandins large amounts of LT. PAF and. depending on dose cellular death (see Figure 1 ). Could silica cause LT production and cellular death by a similar mechanism? How could silica - an inert solid - act in a similar fashion as a soluble stimulant? Clearly the negative SiO2 and OH- surface of silica can bind calcium ions9 and therefore could theoretically act as a solid-state ionophore releasing bound calcium inside of cells following phagocytosis."

Jan 1, 1998

By L. W. Kelly

The purpose of this paper is to describe several methods that have been employed in successfully recovering roof bolts in Indiana, Illinois, and western Kentucky coal mines, the States where successful roof-bolt recovery was started. As far as is known, the first bolts were recovered in a mine in western Kentucky in January or February 1951. In April 1951 a meeting was held at that mine to discuss the recovery of roof bolts. The meeting was attended by A. D. Sisk, former Chief, Kentucky Department of Mines and Minerals; and L. W. Kelly, Federal Bureau of Mines; and officials of the coal company. Inasmuch as roof bolting was in its infancy, the thinking regarding roof bolts at that time was on the problem of getting them in, not getting them out; consequently, the thought of recovering them was revolutionary. The subject was discussed at length from all angles, and it was finally agreed that, if certain safeguards were taken, no agency represented at the meeting would oppose the practice. That this decision was sound has been proved, as thou-sands of bolts have been recovered in the Middle West without a lost-time accident. Recovering roof bolts is a simple operation; consequently, no complicated equipment had to be designed or built for this purpose. However, about 5 years ago, officials of the Traux-Traer Coal Co. conceived the idea and constructed a mechanical device for recovering bolts that has been very successful and has been copied widely in this area. This device will be discussed in detail in part II of this paper.

Jan 1, 1958

By Arno C. Fieldner

This is the fifth of a series of annual reports4/ of technologic investigations conducted by the Bureau of Mines on the occurrence, properties, mining, preparation, and uses of coal. The research of the Bureau is carefully coordinated with the requirements of the producing and consuming industries, with a view to conservation of resources of coal in mining and use, and conservation of the health and lives of workmen employed in these industries. Such coordination is facilitated by the wide range of specialization of the several groups on engaged in studies concerning coal. Here are reported correlated studies ranging from paleobotanic analysis of the formation of coal as it occurred some millions of years ago to the effect of mechanical methods of mining on present-day employment in mines. As this is a summary of the current work of the Bureau of Mines, so the Bureau likewise has provided a condensed review of the outstanding current work of others on research and technology of coal 5/.

Jan 1, 1940

By D. Caruso

The health and financial costs of cumulative injuries are plaguing the mining industry. Industry leaders are concentrating on reducing the risk of injury to their workers through design and redesign of work environments. While ergonomics is not a currently regulated field, many mines are realizing that the only way to tackle their most costly injuries, cumulative injuries, is to make the proactive choice to understand those injuries, their root causes and to make workplace changes to prevent them from occurring. Reduction of these injuries not only improves the health and morale of the workers but increases productivity and profit for the companies. Knowledge and reporting of ergonomic risk factors by employees and ergonomics committees is key to these changes and to the reduction of cumulative injuries. NIOSH is developing strong relationships with industry associations and equipment manufacturers to leverage their communication abilities to transfer knowledge to their customers and make a difference in the health and safety of U.S. miners. The benefits of a formalized approach to reducing these injuries along with examples will be presented.

By Lynn L. Rethi

This U.S. Bureau of Mines report summarizes common obstacles found when attempting to implement health and safety strategies in small mines and small businesses in general industry. Recently, the U.S. Mine Safety and Health Administration focused much of its attention on addressing health and safety issues at small mines. Some of the more innovative interventions practiced by small businesses in general industry are discussed for consideration of their applicability to the mining industry. The most effective intervention strategy that was developed for small businesses is the Occupational Safety and Health Administration Consultative Program. The details of this program and other intervention strategies used by small mines and small businesses are presented.

Jan 1, 1995

By R. J. Leary, W. M. Mahan, F. X. Tartaron

A new type of apparatus for prerefining molten blast furnace iron and to reduce the cost of subsequent steelmaking consists of a funnel - shaped device lined with firebrick into which a horizontal stream of molten pig iron is directed tangentially at the top . The rotary motion thus induced causes the stream to flatten itself upon the wall and flow in a spiral path to the outlet ; thus , the device was termed " vortex cone .' Oxygen and other refining agents are impinged upon the flowing metal in the cone where reaction is facilitated by the large metal surface exposed and the turbulent flow pattern . Experiments with water in 1 - foot - diameter funnels provided an idealization of the flow patterns to be expected with molten iron . A brick - lined reactor 3 feet in diameter was built for desiliconizing molten pig iron in lots of 1 to 2 tons . At flow rates of 0.3 to 0.5 ton min - 1 (430 to 720 tons per day ) this apparatus was 64- to 90 - pct effective in desiliconization with oxygen efficiencies of 19 to 41 pct . Detailed experiments to develop basic engineering data are underway , and adaptation of this principle to other reactions and reactants is planned .

Jan 1, 1964

By Otto Ruhl

The Oronogo-Webb City-Duenweg district is in the northeastern part of the Tri-State zinc and, lead field. Its metal-mining history dates from the early 1850's. For some years prior to 1918 it ranked as the leading producing area of the entire Tri-State field, but by 1920 most of its mines had been abandoned and allowed to fill with water. Its mine operators had-been attracted, to the newly discovered and richer deposits around Picher, Okla. In 1943, the Orenogo Mutual Mining Co. was exploiting the Oronogo Circle deposit in the northern end of the district, and the Federal Mining & Smelting Co. was preparing to mine on its holdings in the southern part near Duenweg. The area between these two operating units ranked as the largest single block of ore reserves under water in the Tri-State field. In 1942, engineers of the Bureau of Mines, in collaboration with the William Stewart Engineering Co. of Joplin, collected all available mine maps, mine reports, and logs of old drill holes in the inundated area. From a careful study an appraisal of these data, the reserves in the block were calculated at 20,647,800 tons of ore containing 606,440 tons of 60-percent zinc concentrates and 46,970 tons of 80-percent lead concentrates. The ore was estimated to contain 1.76 percent recoverable zinc and 0.18 percent recoverable lead.

Jan 1, 1949

By Raymond B. Ladoo

SOAPSTONE

Feb 1, 1922

By K. O. Bennington

The thermodynamic properties of aegirine, of composition [(Na0.869Fe30+7362 Fe20+16Mn0.03Ca0.1121)(A10.141Sil 9738)(06)], were experimentally determined at the Bureau of Mines as part of its efforts to advance minerals technology. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -641.12±0.73 kcal/mol. The standard enthalpy of formation from the oxides is AH298 = -37.136±0.509 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 19.1 to 304.6 K. The derived standard entropy is S298 = 38.03±0.14 cal/mol?K. The heat capacity was measured over the range 348 to 1,198 K by differential scanning calorimetry. These experimentally determined data were combined with data from the litera¬ture to calculate the Gibbs energies of formation and equilibrium constants of form¬ation over the temperature range of the measurements. Standard enthalpies of forma¬tion are given as functions of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -600.36 kcal/mol.

Jan 1, 1984

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By H. H. Hill

"The wide publicity that is given to the discover; of new oil fields has led many people to believe that our supply of crude petroleum is practically in- exhaustible and that in order to keep pace with the demand for petroleum products, it is only necessary to drill a few more wells in some of the south-western states. It is not generally realized that, although many famous fields have been developed in Oklahoma, Kansas, Texas and Louisiana during the past few years, the production of crude oil in 1919 was not sufficient to meet the demand and it was necessary to import approximately 53,000,000 barrels from Mexico.Continued efforts are being made to recover a larger percentage of the oil underground by improvements in methods of drilling and in handling producing properties. Improvements are also being made in methods for handling the oil after it has reached the surface which will result in reducing losses through leakage and through evaporation. These methods for cutting down waste in production and storage, if universally adopted, will no doubt result in appreciable increases in our supply of crude oil."

Nov 1, 1920

By A. R. Rule

Research was done by the Bureau of Mines to determine the effect of a low-molecular-weight polymer on wet grinding of quartz, dolomite, and a copper ore. A 5-in ball mill equipped with a torque sensor for precise measurement of input energy was used for batch grinding tests. Grinding parameters were determined from size distribution data on the feed material and ground product. Zeta potential measurements were made to determine the effect of the polymer on the surface properties of the three materials, and a viscometer was used to measure the effect of the polymer on slurry viscosity. The addition of the polymer caused a sharp increase in the negative value of the zeta potential for all three materials, indicating that pronounced adsorption was taking place. At a constant slurry percent solids, addition of the polymer caused a similar reduction in slurry viscosity for each material. For quartz, dolomite, and the copper ore, grinding efficiency, as measured by kilogram of product per kilowatt hour passing a given screen size, was not affected by the addition of the polymer. However, the lowering in slurry viscosity caused by addi-tion of the polymer permits grinding at a higher slurry percent solids.

Jan 1, 1985

Determine the appropriate spacing and alarm levels for carbon monoxide and smoke sensors used for fire detection in underground coal mine conveyor belt entries. Background Fire represents one of the most severe hazards in underground coal mines. Early-warning fire detection in underground coal mines is essential to successfully implement and execute evacuation and control measures. Both carbon monoxide (CO) and smoke sensors have the ability to provide reliable early-warning capability, provided that they are spaced properly and set at the appropriate alarm levels. The U.S. Bureau of Mines conducted a series of large-scale experiments where a small coal fire was used to ignite a conveyor belt at air velocities of 0.76 to 6.1 m/s. The test configuration was purposely designed to model a worst-case fire scenario for fires that develop within conveyor belt entries in underground coal mines. During the tests, CO and smoke levels were continuously measured to determine alarm times and alarm levels as the fire intensity progressed. The data from these tests indicated that for a given sensor spacing, the time to reach a preset alarm threshold depends upon the belt entry air velocity and cross-sectional area. Analysis of this data resulted in the equations and nomographs for CO and smoke sensor spacing, and alarm levels contained in Bureau of Mines RI 9380, "Fire Detection for Conveyor Belt Entries."

Jan 1, 1993

By F. E. Cash

"Explosions in bituminous coal mines are preventable. The combination of adequate ventilation, thorough rock-dusting, and water on the cutter bars of mining machines and of empty and loaded cars will certainly reduce the hazard to a minimum, if not remove it entirely. This is the attitude taken by the Woodward Iron Co. in lessening or removing the dust and gas explosion hazard from its Dolomite and Mulga mines.This report was made possible through the willingness of Frank H. Crockard, president of the Woodward Iron Co. to make records available and to authorize their publication for the benefit of the coal-mining industry.The compilation of these data and preparation of maps was facilitated by the cooperation of M. Heard, general superintendent of coal mines, J. B. Whatley, assistant general super-intendent of coal, and R. P. Whetmore, chief mining engineer.The Dolomite and Mulga mines are about 16 miles southwest of Birmingham, Jefferson County, Ala., on a company owned and operated railroad which connects ore mines, coal mines, coke ovens, and furnaces.In the Dolomite property there is a 30°, 860-foot, double-tracked slope for hoisting, three manway and air slopes and one air shaft, all in rock.At Mulga there is a 220-foot hoisting shaft, an air shaft and two manways, and material and air slopes, all in rock to the coal bed.The coal in both mines comes from the Pratt bed, which is the next coal above the Mary Lee bed in the Warrior Basin. The coal is horizontal or slightly undulating, with thickness varying from 36 to 72 inches and averaging 50 inches.The method of mining is essentially room-and-pillar with modifications for mechanized sections. The mines produced approximately 1,100,000 tons with 2,328,309 man-hours exposure n 1929 and 900,000 tons with 1,697,436 man-hours exposure in 1930.Through the work of the safety department the entire personnel in the coal mines, as well as in other departments, makes safety an essential part of efficient operation.Both mines are gassy; Dolomite produces about 334,000 cubic feet and Mulga about 919,000 cubic feet of methane every 24 hours.The ventilation maps, two of Dolomite mines (figs. 1 and 2) and one of Mulga (fig. 3) give as much of the details of ventilation as is practicable to put on maps of such scale. As will be seen from these maps there are two main ventilating fans in Dolomite mine and two in Mulga mine and the general direction of the air travel is indicated by long arrows to fan 1 and short arrows to fan 2 in each mine. Each fan has a gas or steam auxiliary drive and each mine has a complete fan and power unit ready for operation in emergency.In Dolomite, recently taken data show that fan 1 exhausts 82,000 cubic feet of air per minute at 3.2-inch water-gage pressure, with an analyzed methane content of 0.15 per cent, and fan 2 exhausts 115,500 cubic feet of air at 3.8-inch pressure and 0.10 per cent of methane. In addition, a Capell fan at No. 2 air shaft is a standby or emergency unit.In Mulga recently taken data show that fan 1 exhausts 83,000 cubic feet of air per minute at 3.0-inch pressure and 0.18 per cent of methane, and fan 3 exhaust 119,000 cubic feet of air per minute at 5.4 inch pressure and 0.35 per cent of methane. Fan 2 at No. 2 shaft is a standby or emergency unit for the Mulga mine.The ventilation is on a split system in both mines. All part split and total returns are measured, sampled, and analyzed weekly, requiring one man two days each week. During December, 1930, 77 samples were collected and analyzed in Mulga and 78 in Dolomite. Two weekly reports covering part of December, 1930, are given here so that they can be studied to show control of ventilation in the Dolomite and Mulga mines. In the event that a split sample shows more than 0.50 per cent of methane, immediate steps are taken to lower the explosive-gas content. The reports follow:"

Mar 1, 1932

By J. B. Zink, M. J. Peterson

A semiquantitative spectrochemical method was developed and applied to the analysis of ash of U.S. coals . A low- temperature ashing procedure was used to minimize the loss of volatile elements . The analytical procedure provides for the estimation of 68 elements including major , minor , and trace constituents . Standards for the trace elements were prepared in a synthetic base mixture that approximates the average composition of U.S. coal ashes . Excitation was achieved with a d- c arc , spectra were recorded photographically , and interpretation was made by visual comparison of spectra of unknowns with spectra of graded standards series . Thirty- six trace elements were found in the analysis of 900 samples . Details of the procedure are presented , including sample and standards preparation , excitation and exposure conditions , spectral lines used , and approximate limits of detectability .

Jan 1, 1964

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the items is confidential. It presents analytical data for 3,924 samples, representing the products of 116 companies. The samples were collected during June, July, and August, 1954. As in previous surveys, the gasolines covered by this survey include those from both large and small suppliers, The data were obtain& by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation, A list of the National Motor-Gasoline Survey reports published during the past 10 years is given on page 5.

Jan 1, 1955