Search Documents

By C. H. Fisher

Coal carbonization, the basis of a major industry, consists in heating coal in the absence of air at various temperatures (ranging from 500° to 1,000° C.) that are selected according to the kind of products desired. During this treatment, the complex organic substances that comprise the major part of the coal are converted into several useful products that are quite different from the original material. The principal products of coal carbonization or distillation are coke and gas. These products, as well as others of which lower yields are obtained (light oil, tar, and ammonia), occupy an important place in present-day commerce and civilization. This paper is concerned with the composition of the tar and light oil, which, as complex mixtures of organic compounds, are the source of many important dyes, inter-mediates, medicinals, resins, etc. The volatile products obtained when bituminous coals are destructively distilled or carbonized are tar, aqueous liquor, and gas. These products vary in composition and properties, depending on the nature of the coal and the temperature and conditions of carbonization. The tar is a dark, rather thick and viscous liquid at ordinary temperatures, becoming semisolid when cooled to the freezing point of water. The aqueous liquor (chiefly water) contains several inorganic substances and certain organic compounds, which, because of their solubility characteristics, have been extracted from the tar. The carbonization gases consist chiefly of carbon dioxide, carbon monoxide, hydrogen, hydrogen sulphide, ammonia, methane, ethane, ethylene, and several hydrocarbons of higher molecular weight. The hydrocarbons of higher molecular weight (benzene, toluene, xylene, etc.) may be re-moved as liquids from the gas by suitable means. This liquid and the first fractions obtained on distilling the tar are known as light oil.

Jan 1, 1938

By G. S. Scott

Safety problems in the mining and allied industries have led the Bureau of Mines to investigate over a period of years; the flammability (explosibility) of many types of combustible atmospheres principally at ordinary pressure; the results of these investigations have been made available as a bulletin. However, more recently, the demand for information on the flammability of gaseous mixtures at high and low pressures has increased greatly. In particular, the rapid development of high-altitude aviation has brought demands for information on the flammable (or explosive) characteristics of certain gases and liquids at low pressures. The present report gives the results of about 900 tests made to determine the flammability of the lighter paraffin hydrocarbons mixed with air and nitrogen at pressures of 400 200, 100 and 70 ram. Hg. The gases tested include natural gas, methane, ethane, propane normal butane and isobutane. The minimum pressures at which these gases are capable of propagating flame whorl individually mixed with air also were investigated.

Jan 1, 1952

By Frank G. Horino

This report describes an instrument designed by the Bureau of Mines for quantitatively identifying texture of rock surfaces produced by grinding or extremely rough surfaces beyond the range of commercial surface measuring instruments. The transducer for the instrument is a linear variable differential transformer that converts mechanical motion caused by surface roughness, waviness, and lay to an electrical output. The electrical output is recorded graphically as an X-Y plot of the line traversed on the rock surface. Details of the synthesized device and its calibration are given. The sensitivity of the unit is 2 percent of the scale setting of the amplifier. The horizontal scale is adaptable from ¼ inch to 15 inches of specimen length with a sensitivity of 0.01 inch if a 10 to 1 magnification is used and 0.1 inch if a 1 to 1 magnification is used.

Jan 1, 1968

By A. F. Colombo

The differences in starch demands that occur between ore types subjected to the anionic flotation of calcium-activated gangue and the range of residual starch contents expected to give the best metallurgical response were evaluated on a batch and pilot plant basis. A phenol-sulfuric acid procedure was used to determine the residual starch contents in the iron ore slurries. Three pilot plant campaigns on samples from a group of orebodies located on the Marquette Range, Michigan, showed that in the rougher flotation pulp, a residual carbohydrate range of 25 to 100 ppm, which is equivalent to a 0.5 lb/short ton spread, yielded optimum results. Concentrates assaying at least 65 percent Fe and less than 6.0 percent Si02 and containing more than 80 per-cent of the recoverable iron were obtained. Both batch and continuous research indicated that starch adsorption is calcium modulated and relatively unaffected by the fatty acid additions employed. Residual starch level is not a critical control factor, but the addition must be adjusted to about 25 to 50 ppm residual starch and kept in this range for most effective utilization of the added tapioca flour.

Jan 1, 1972

By T. A. Henrie

A technique was devised for measuring the rate of chemical reactions between reactive metals and molten-salt mixtures at high temperatures. The rate of the heterogeneous reaction between high-purity titanium metal and titanium trichloride in molten sodium chloride was determined. The reaction is surface-controlled, and the heat of activation is 8.29 kilocalories per mole TiC13. An active site or reaction nuclei is created by adsorbing a TiC13 molecule at the metal surface. Reaction of the second TiC13 species forms an activated complex that decomposes into three TiC12 molecules.

Jan 1, 1963

By A. G. Starliper

The report covers studies by the Bureau of Mines on the removal of metallic values in two waste products from the Longhorn tin smelter at Texas City, Tex. One product was a slag that contained tin, tungsten, iron, tantalum, and columbium. The other product was a spent acid solution that contained tin, tungsten, iron, lead, copper, zinc, and silver and that came from presmelting treatment of impure tin concentrates. Molten slag was treated with sulfur or sulfur compounds and with coke, calcium carbide, or gaseous reductants to form tin sulfide that volatilized from the charge and to reduce tungsten along with iron and silicon to form a carbon-bearing metallic layer. The metallic layer was treated by an oxidizing alkali roast and then was water-leached to extract the tungsten. The waste acid was used in other experiments to dissolve an iron-tin- tungsten alloy (hardhead) obtained by direct reduction of the slag. An insoluble fraction containing tungsten, silver, silicon, columbium, and tantalum was removed, and copper was cemented on metallic iron, Tin was recovered by cementation on zinc plates, and lead was precipitated by adding sulfate ion. Iron was precipitated by increasing the pH which left a solution containing principally zinc. Slabs of hardhead were electrolyzed in an electrolyte consisting of waste acid to plate out groups of metals at different pH?s. The time did not permit thorough exploration of this method of treatment.

Jan 1, 1962

By W. N. Cathey

Many materials including carbides, silicides, phosphides, borides, nitrides, oxides, and metals were studied by the Bureau of Mines as potential fuel cell catalysts for electroreduction of oxygen in a 1[N]H2S04 electrolyte. The objective of this study was to assess the potential of abundant, low-cost materials as substitutes for platinum or to increase the catalytic efficiency of platinum. Several compounds were rejected because of their reaction in the corrosive environment of the oxygen electrode. However, some of the remaining were the most active catalysts. Activity of carbides such as tungsten carbide could be improved by doping with platinum-group metals, by varying stoichiometry, or by sputtering on a layer of platinum. While no catalysts were found with activity as high as platinum, some compounds were shown to be deserving of further investigation.

Jan 1, 1979

By HOWARD I. OSHRY, James W. Ballard, H. H. Schrenk

Photometric instruments were designed and built for use with X- ray and spectrographic apparatus for the investigation and analysis of a variety of materials of hygienic interest . The instruments are simple in design , may be constructed economically , and have a number of features that make them stable and easy to operate . They are readily adaptable for measurement of either X - ray diffraction patterns or spectrographic films or plates . Because of these features and the interest shown in the instruments , they are described in detail , and reference is made to their application in the laboratory .

Apr 1, 1942

By Mark R. Pettitt

The results of an extensive research and development program to reduce the noise generated during coal cutting are presented. The characteristics and magnitude of continuous miner coal cutting noise sources are defined. This work consisted of development of a simulated coal ,cam to facilitate above-ground coal cutting tests, noise measurements in a reverberant acoustic chamber during simulated mining operations of a continuous miner (cutting the simulated coal scam), and noise measurements in an underground coal mine during continuous miner operation. In-mine and laboratory test results were in excellent agreement for both A-weighted overall levels as well as A-weighted one-third octave band spectra. Methods to reduce coal cutting noise are presented. These methods take full advantage of the dynamic characteristics of the forces generated during coal cutting. Dynamic cutting force isolation was shown to be a very effective technique. Finally, a continuous miner was equipped with a cutter head that incorporated (among other design factors) cutting force isolation. Successful, lung term, in-mine use of the cutter head demonstrated coal cutting noise at the operator's station of less than 90 dBA and 50% coal, 50% rock cutting of less than 93 dBA.

Jan 1, 1985

By Charles Sabine

The U.S. Bureau of Mines studied mines and prospects in the Bristol/Granite Mountains Wilderness Study Area (WSA) in 1982. The 45,000 acre WSA, located in the eastern Mojave Desert of California, is underlain by Mesozoic plutonic rocks with scattered roof pendants of Paleozoic (?) metasedimentary rocks. Two mines and six prospects are identified; one mine, the Silver Lode Mine, and a prospect of unknown name are adjacent to the area. The Silver Lode Mine has occurrences of silver, lead and zinc. Within the study area, the Comanche Mine has occurrences of iron and copper and the Iron Victory Prospect has an occurrence of iron. None are large enough to constitute a resource. Occurrences of magnesian marble at the Comanche Mine, Iron Victory Prospect, and elsewhere in the area contain too much MgO for commercial use other than agricultural soil supplements or crushed stone. Transportation costs to markets would exceed the value of the rock. At the Comanche Mine, situated in a roof pendant of marble, about 10 tons remain of a 110-ton pod of magnetite which contained 42.5% iron, and less than 50 tons remain of a mineralized fault breccia which averaged 2.5% copper and 0.3 oz/ton silver. Magnesian marble contained 41 to 45% CaO and 14 to 16% MgO. Primary and secondary silver, lead, zinc, and copper minerals are disseminated along altered joints and in quartz veins in quartz monzonite at the Silver Lode Mine, adjacent to the WSA. Analytical data are sporadic; samples contained as much as 0.12 oz/ton gold, 1.8 oz/ton Silver, 1.1% lead, 3.8% zinc, and 0.3% copper. Mineralized zones in the workings are not resources, but they might indicate possible silver-lead-zinc resources at depth. At the Iron Victory Prospect, lenses of magnetite and hematite with some chalcopyrite occur in a skarn lone in a marble roof pendant. About 110,000 tons of iron-rich rock, averaging 47.2% iron, are present; the largest lens contains about 30,000 tons. About 150,000 tons of magnesian marble, averaging 41.0% CaO and 11.7% MgO, are also present. Deposits of stone, and sand and gravel in the WSA are too distant from markets to be resources. Occurrences of energy minerals were not identified.

Jan 1, 1984

By E. G. Davis, H. P. LeVan, L. S. Smith

Leaching of a Georgia umber ore when using both ferrous sulfate and pickle liquor was studied in the laboratory . The ferrous sulfate content of the leach solution was the major factor affecting the extraction of manganese from the ore . Time , temperature , and the sulfuric acid content of the leach solutions had relatively little effect on leaching of manganese from the ore ; however , these factors did affect the amount of iron extracted from the umber and/or precipitated from solution . Simulated countercurrent leaching of the ore with pickle liquor containing 130 gpl (grams per liter ) ferrous sulfate ( 48 gpl ferrous iron ) produced a pregnant solution having 16 gpl manganese and 41 gpl iron . Filtration tests of the leach slurries indicated that separating the leach solution and solids by vacuum filtration was impractical , whereas pressure filtration was feasible when the cake thickness was limited to about three- fourths of an inch . Fired pellets of the filter cake yielded a firm , hard product analyzing 56 percent iron and less than 0.1 percent sulfur .

Jan 1, 1964

By Ernest E. Berger

"INTRODUCTIONOne of the outstanding problems in the normetallic industries, and one which involves two of the greatest of these industries, cement and gypsum, is the reaction of Portland cement with calcium sulphate. To all Portland cement clinker there is added in the manufacturing process, a small amount of retarder, as a necessary ingredient of the finished product. This retards the initial set, increases the strength, and adds to the plasticity of the cement so it will have the desired working and setting qualities. The retarder commonly used is gypsum, (CaSOA.2HO), which is the hydrous form calcium sulphate. Calcium sulphate is also available as plaster of Paris (CaSO4 1/2 HC) and anhydrite (CaSO4). The purpose of this inquiry was to determine the form or mixture of forms best adapted for retarder. The problem is complicated by the fact that cement clinker is a complex mixture of calcium silicates and aluminates, and that clinker from different mills, making cement of approximately equal quality, differs considerably in chemical constitution. Thus the same retarder may give very different results with different types of clinker, especially in the percentage of retarder required for the same degree of retardation.It has been known for some time that a small percentage of plaster of Paris will greatly retard the time of set of Portland cement as well as increase its strength and plasticity, but whether gypsum and anhydrite will have a similar effect is as such disputed question. The offects of gypsum have received little consideration in laboratory research because, even though it will not retard a clinker when the two are mixed in the laboratory, as has been noted in some instances, the cement will have a normal set when the two arc mixed in the large tube mill at the plant, so that practically, gypsum seems to be equally as goou as plaster of Paris, and because of the great saving in cost it has been used almost exclusively."

Sep 1, 1925

By C. Van Dyke, K. Van Dyke, J. Gutierrez, C. Nowack

"Using propidium assay and flow cytometry, we examined how silica exerts its toxicity toward phagocytic cells employing the human neutrophil as a model. This toxicity appears to be associated with calcium bound to silica. Once the silica with calcium is phagocytized, the extra calcium causes the death of the cell. Using ""Ca we found that 6 to 10% of millimolar calcium is bound to milligram amounts of respirable-sized silica (diameter of 5 µ.m or less) at physiological pH. If the silica particles arc coated with an organosilanc (Prosil 28). calcium binding is decreased by 60% as is cell death. Pretreating with INDO IAM (a chelator of intracellular calcium) reduces the cellular death by 80%. Nonfibrogcnic particles- polystyrene beads or coal dust-produced 10% or less cell death in a 4-h period. Silica with no added, external calcium appears to exert toxicity to neutrophils; however, pretreating cells with EDT A decreases cellular death to the level of nonfibrogcnic particles. Chronic toxicity with silica-calcium appears similar to the chronic toxicity in gout where particles cause a cycle of inflammation. c 1993 Academic Press, Inc.Silicosis is an occupational disease caused by the inhalation of fine particles of silica, usually between 0.1 and 5 µ.m in diameter (1). A recent hypothesis explaining silica's toxicity suggested that surface free radicals caused damage to cells (2). This explanation appears doubtful, however, since the addition of silica to water, such as that found in biological systems, quenches free radicals; also, such a hypothesis does not provide basis for a persistent inflammatory pattern that lasts for years. Kane et al. (3) proposed that silica's toxicity resulted from an excessive concentration of calcium ions within the phagocytic cell (macrophages). However, the mechanism that was capable of linking silica to an excess of intracellular, ionic calcium was not explained. The surface of silica is certainly involved because covering the surface with polymers or phospholipids decreases silica's toxicity (4-6).When silica is engulfed by macrophages platelet activating factor and leukotrienes are produced (7, 8). This is the same inflammatory pattern produced by phagocytic cells exposed to the calcium ionophore A23187 and ionic calcium. How could silica be acting like A23187? Perhaps calcium binds to silica extracellulary and then is released intracellulary following phagocytosis; the latter process, in a sense a ""piggy back"" process, would permit activation of inflammation and cell death mechanisms."

Nov 1, 1995

By C. J. Chindgren

Two air classification systems were built and tested as separatory devices for recovering the nonferrous metal values from shredded automotive nonmagnetic reject scrap. A horizontal air system with a capacity up to 16 tons per hour was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Shredded automobile reject material containing aluminum, copper, and zinc values of about $55 per ton were air-classified in the horizontal elutriator. Ninety-six percent of the metal was recovered in a 74-percent metal concentrate. Tandem operation of both classifiers recovered 92 percent of the metal in an 80-percent concentrate while rejecting 87 percent of the nonmetallics. Heavy media separation of the air-classified concentrate produced an overall recovery of 91 percent of the metal in the form of a 99-percent metal concentrate.

Jan 1, 1971

By B. W. Naugle

A small-scale laboratory coke oven similar to those described by Swiniarski, Cryan, and Altieri and Fuchs, Sandhoff, Taylor, and Gauger was built by the Bureau of Mines in 1943. Tests made since that time have indicated that such a small oven is of questionable value in predicting the coking pressures to be expected in commercial coke ovens. This summary of the work done has been prepared at the suggestion of the Advisory Committee to the Bureau of Mines-American Gas Association Survey of Carbonizing Prop¬erties of American Coals.

Jan 1, 1948

By D. B. Dow

The study of oil production methods with reference to the amount of oil originally pressent in the oil-bearing, formations has developed the fact that-ordinary methods-of production remove only a part of the oil actually present. In fact, it is generally realized that when a field is abandoned more oil remains in the sand than has ever been removed. As a consequence of this realization, the petroleum engineer has devoted considerable tine in recent years in devising methods for increasing the percentage of recovery. His studies have indicated that in most cases the total production of a field is dependent upon the available gas rather than upon the available oil. Mien the gas in the sand is exhausted, oil production ceases even though there may be enormous quantities of oil remaining unrecovered. Consequently, any method of conserving the gas or increasing the supply of gas will increase the ultimate recovery from a field. The practice of producing oil under vacuum increases the effectiveness of the gas remaining in the sand, as well as furnishing more gas by evaporating the light fractions of the crude. Pumping ' compressed gas or air down selected wells of a lease has been found to increase the production of oil from the surrounding wells. Studies of oil and gas ratios have indicated that much of the available gas has been wasted as far as its effectiveness on oil production is concerned. his has led to the development of "stop cocking"3 and the practice of producing under back pressure3, which methods aim, to obtain more effective work from the gas with reference to the amount of oil delivered to the well.

Jan 1, 1926

Geological discontinues in the coalbed, such as faults, sandstone channels, permeability facies, lithotype changes, and large scale partings in the coal seam, can cause intermittent production problems or produce unexpected amounts of water or gas from degasification boreholes. These discontinuities not only can impact methane emissions into the mine workings, especially if they hinder proper and effective degasification of the coalbed but may act as conduits for methane flow from gassy strata into advancing mine workings. The effects of these discontinuities are still under debate by mining and gas production experts. This study presents a numerical investigation using reservoir simulations of the effects of partings and permeability facies and lithotype changes on the production performances of vertical and horizontal degasification boreholes, as well as the emissions during longwall operations. In this work, the grid block was designed in a multi-layer 3-D structure which enabled spatial descriptions of the geometries and properties of the discontinuities within the coal seam. The studied coal seam discontinuities and their properties were distributed arbitrarily within the model. Production was simulated by vertical and horizontal boreholes. Degasification boreholes operated two years prior to start of the mining. The results of this numerical study show that in coal seams with major heterogeneities and discontinuties, the geometry and location of the boreholes are important for improved gas production. These considerations are also important for controlling methane and water inflow into the working environment during longwall mining.

Jan 1, 2008

By H. A. Doerner

From thermodynamic calculations3 Maier predicted that zinc oxide Land methane would react at specified temperatures substantially according to equation (1). (1) ZnO + CH; = Zn (gas) + CO + 2H2 Other reactions that may take place are: (2) CH4 = C + 2H2. (3) ZnO + CO = Zn (gas) + CO2 (4) ZnO + H 2 = Zn (gas) + H2O . Maier predicted that 870°C. would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1), at equilibrium, would be substantially complete at or above 927°C.

Jan 1, 1931

By K. K. Kershner

To meet an increasing demand for high-purity cobalt, the Bureau of Mines has conducted investigations for producing this metal. Cobalt having a purity of 99.95 percent or higher is needed to determine heats of formation, corrosion resistances, phase diagrams, and other basic properties of the element and its compounds. This grade of cobalt may be used for preparing radioactive metal. As a result of its investigations a detailed procedure, which is of practical significance to the production of high-purity cobalt, has been developed by the Bureau for purifying cobalt solutions and for electrolytic deposition of the metal. Cobalt metal, which had a purity of 99.99 percent with reference to metallic contaminations, was deposited electrolytically. Qualitative spectrographic analysis showed only traces of calcium, copper, iron, magnesium, nickel, and zinc.

Jan 1, 1956

As mining operations in the United States (US) have become more productive, controlling the dust exposure of mine workers has become more challenging. In response, US mining operations are applying basic controls at elevated levels and are looking to emerging control tech­nologies in an effort to better control airborne respirable dust levels. The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) conducts research to develop and/or improve control technologies that reduce the respirable dust exposure of workers in underground coal mines. The goals of this research involve optimizing the use of water sprays and ventilating air, as well as, evaluating emerging control tech­nologies. An overview of dust controls typically utilized in underground US coal mines will be provided. An update on ongoing PRL research efforts that are evaluating new control technologies will also be presented.

Jan 1, 2008