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By Don B. Hunter

The Bureau of Mines investigated the extraction of alumina from calcined kaolin by leaching with boiling RCI in a train of three 50-gal continuous, stirred reactors. Slurry discharged from the reactors con-tained an excessive amount of fines, which impeded solid-liquid separation. Autogenous grinding of coarse solids that accumulated in the reactors was the source of the fines. This report describes modifications to the reactors and to the operations that led to decreased fines generation and improved solid-liquid separation. Modifications to the reactors included custom-made impellers, the addition of a baffle system, a subsurface slurry discharge system, and slower rotation of the impellers. Concurrent testing of a continuous horizontal belt filter showed that the form filtration rates were increased from 350 to almost 1,000 Ib/h+ ft-2 when the modified reactors were used.

Jan 1, 1984

By F. B. Petermann

Two-stage electric smelting tests, using small submerged arc furnaces, were made on high-iron manganiferous materials from the Pioche District, Nev., and the Cuyuna Range, Minn. The object was to reduce sufficient iron in the first stage to give a slag with a favorable Mn to Fe ratio for smelting to ferromanganese in the second stage. The nodulized flotation concentrate from the Pioche District contained 29.2 percent Mn and had a Mn to Fe ratio of 2.3:l. When smelted with coke and silica or alumina as flux, more than 90 percent of the manganese was recovered in slags with Mn to Fe ratios of 10: :24:1. The Pioche slag was smelted to ferromanganese using coke and lime- stone or dolomite as flux. The ferromanganese was high in silicon but other- wise met specifications. Recovery of manganese to ferromanganese in this step was 73 to 78 percent. Overall recovery of manganese was about 70 percent. The sintered flotation concentrate from the Cuyuna Range material contained 12.9 percent Mn and had a Mn to Fe ratio of 0.3:1. When smelted with limestone as flux, about 83 percent of the manganese was recovered in a slag with a Mn to Fe ratio of about 6:1. The Cuyuna slag was smelted to ferromanganese with coke and limestone for flux. Recovery in this step was 61 percent of the manganese in a high silicon ferromanganese. Overall recovery of manganese was about 50 percent.

Jan 1, 1963

By Martin A. Elliott

The Bureau of Mines began its investigation of the use of Diesel engines underground to provide technical information necessary to assist this development in the United States. It was considered desirable to furnish such assistance because successful European developments/ in this. field had indicated that Diesel mine locomotives might be safer than electric trolley locomotives. The Bureau has recognized for some time the importance of eliminating the hazards associated with underground haulage systems using bare trolley wires. For example, each year 30 to 40 fatalities occur as a result of electrocution by contact with bare trolley wires. In 1943 and 1944, 101 men were killed and extensive property damage occurred as a result of mine fires started by falls of roof grounding the bare trolley wires.

Jan 1, 1948

By Charles Prasky

The Bureau of Mines investigated the conversion of nonmagnetic iron minerals to magnetic form through reduction Toasting operations. The primary objective was to obtain a concentrate that could be used as a direct shipping material for blast furnace consumption. Crude iron materials from the Steep Rock Lakes, Ontario, area were prepared into a blend of 8 parts siliceous ore, 3 parts pyritic ore, and 1 part tailings. Experimental work included laboratory reduction roasting tests, two continuous 10-day campaigns, and one 12-hour test all in a 34-inch by 36¬-foot rotary kiln. The objective of the project was achieved in producing an iron concentrate containing about 66 percent iron with over 90 percent iron recovery. Desirable operating conditions were developed in the kiln but optimum process variables were not completely established.

Jan 1, 1969

By A. T. Sweet, G. Douglas Gardner

"INTRODUCTION In the ammonium sulfate process for the production of alumina from clay,,3/ the clay is baked with amonium sulfate at about 400ºC. to form anhydrous ammonium alum and free ammonia or ammonium carbonate. The alum is leached from the baked product with water and circulating liquors and is purified by recrystallization. Aluminum hydroxide is precipitated by treating thus alum the alum the ammonia or ammonium carbonate from the baking step. Ammonium sulfate is recovered from the filtrate for reuse, and the aluminum hydroxide precipitate is calcined to produce high-purity alumina. In this process, as in other acid processes for the production of alumina, 4/ a large part of the iron in the clay is extracted. The iron tends to build up in the leach liquors and contaminate the crystals, so that its elimination is one of the most important problems in the process. A number of large clay deposits occur in the Western States. Those that have boon explored most extensively 5/contain an average of 24 to 30 percent available A12O3 and 2 to 8 percent available Fe2O3. 6/ The available Fe2O3 content of various other clays ranges from less than I percent to more than 20 percent. The available Al2O3 or Fe2O3 is usually 90 to 98 percent of the total but may be much less. In generals the iron content bears no fixed relation to the alumina content and may vary widely within a given deposit."

Jan 1, 1948

By John M. Gomes

Two molten salt systems were evaluated as electrolytes for the repetitive recovery of tungsten from tungsten oxide (W03) made by calcining commercial-grade ammonium paratungstate. Using a sodium chloride-sodium fluoride-potassium aluminum tetrafluoride electrolyte at 800° C, 1 pound of 99.8 percent tungsten was recovered for each 2.7 kilowatt-hours of energy consumed. The metal contained 1,100 ppm carbon, was in dendritic masses of spherical grains, and had an apparent bulk density of 5.41 g/cm3. T ngsten of 99.9 percent purity was won from a sodium pyrophosphate-sodium tetraborate-sodium chloride electrolyte at 1,000° C; 6.0 kilowatt-hours of energy was consumed for each pound of metal recovered. The metal contained 120 ppm carbon, was in dendritic masses of hexagonal acicular crystals, and had an apparent bulk density of 7.25 g/cm . Each metallic impurity--aluminum, calcium, copper, iron, nickel, and silicon--in the two tungsten products was 16 ppm or less.

Jan 1, 1966

By E. B. Kester

A study of the composition of the corresponding fractions of a primary and a high-temperature tar was undertaken to throw light on the net results of the pyrolysis of the primary products of coal decomposition in high-temperature coking practice, with reference both to total quantities of the chemically similar constituents and to their distribution throughout the boiling range. No exactly parallel investigations are on-record. The distribution of substances in high-temperature tars, however, is fairly well understood. Such tars are more or less similar, for they consist of the more stable phenols, aromatic and olefinic compounds resulting from the pyrolytic decomposition of a wide variety of primary tar constituents. For example, from a typical distillation curve for high-temperature tar phenols it may be seen that the greatest portion of the phenols distills between 180° and 220° C., a fairly narrow range. Low-temperature tars, on the other hand, are more complex, and hence exhibit dissimilarities from one to the next. Edwards, who has made a study of the acids, bases, and neutral oil of four low-temperature tar distillates, shows that the bases and neutral oil are evenly distributed among the fractions but that the concentration of the acids is greatest in the 200° to 230° fraction. Morgan and Soule find that in tar from the "Carbocoal" process, the 237° to 281° fraction has the highest acid content, whereas Davis and Parry find the 200° to 225° fraction of Freeport tar richest in phenols. Previous investigators have noted the following differences between primary and high-temperature tar: In the latter, naphthalene and anthracene occur in large quantities, the paraffins and naphthenes are negligible, the percentage of higher phenols is much lower than in primary tar, and the lower and more stable aromatic hydrocarbons have increased. In an endeavor to reconcile the change undergone when a primary is converted into a secondary tar, the writers have been unable to find references dealing with the extent of change which any one of the constituents of primary tar may undergo when subjected to secondary heating effects in the presence of other components, and the amount of the more stable compounds that may be expected from a given starting material.

Jan 1, 1932

By Wilbert T. Malenka

In its search for a highly productive mining system for anthracite beds pitching from 100 to 200, where conventional mobile equipment cannot be used) the Bureau initiated a longwall project by introducing a shearer drum cutter loader of European origin. Because of the undulating nature of the roof and floor and changing bed thicknesses, the machine proved inflexible and extra work was required in lifting bottom coal and blasting top coal.

Jan 1, 1966

By Carlton E. Brown

Impinger dust-counting methods are used by industrial hygienists for determining the number concentration of unhygienic siliceous dusts in industrial atmospheres. Various statements have been made regarding the size of the smallest particles revealed by the microscopic employed in such determinations. Published data on the subject are quite limited. This report presents information on the size of the smallest particles revealed by light-field and dark-field techniques applied to impinger and electric precipitator samples collected from experimentally established aerosols of silica dust and bituminous-coal dust. Size distribution and number concentration of particles of the various sizes in the aerosols were determined from samples collected by thermal precipitation simultaneously with the impinger and electric precipitator samples. The size of the smallest silica and bituminous-coal dust particles determined in the light-field counting method used was about 1./1, . There was relatively little variation in the values from 8 impinger and 33 A.-C. precipitator samples of silica dust and 13 impinger and 13 A.-C. precipitator samples of coal dust. The coefficients of variation of the values from the four sets of determinations were low, ranging from ± 7.7 to t 10 percent. This size of 1,14 is close to the limit of resolution of the microscopic method used and to various previously suggested values. The size of the particles determined in the dark-field counting method used was smaller than the size (about 0.28A ) of the smallest particles determined in the light-field, oil-immersion method used for the thermal precipitator samples.

Jan 1, 1951

By D. R. Torgoson, Th. G. Sahama

"This paper contains some new thermodynamic data for silicates in the series Mg2SiO4-Fe2siO4 and MgSiO3-FeSiO3 and gives the results of a thermodynamic attack on the problems of stability end parageneses.. Although some data are lacking satisfactory agreement with mineralogical and petrological observations is indicated.The use of thermodynamic methods in mineralogy and petrology has been rather limited, because accurate thermal data, especially for the more complicated and more important rock-forming minerals, have been too scanty to permit any systematic application to problems in those fields. It is, nevertheless, a fascinating task to investigate to what extent the mode of occurrence and the stability relations of the minerals and mineral parageneses, as revealed by petrological and mineralogical observations, agree with predictions of thermodynamics. At the present stage of development calorimetric data are needed for most of the abundant silicate minerals.Measurement of the heats of solution in hydrofluoric acid of minerals in the series Mg2SiO4-Fe2SiO4 and MgSiO3-FeSiO3 affords a ready means of obtaining their heats of formation from the oxides. Combination of such data with entropy and heat-capacity values gives a means of obtaining free energies of formation from the oxides, which, in turn, are connected di¬rectly with stability and paragenoses.The two silicates of magnesium, Mg2SiO4 and MgSi03, occur as rock-forming constituents as forsterite and clinoenstatite or enstatite. The orthosilicate (forsterite) forms a series of isomorphic mixtures with ferrous-orthosilicate (fayalite). The continuity of this series, suggested by petrological observations, has boon proved experimentally by Bowon and Shairer.4/ The present work shows that those minerals constitute a series of perfect solid solutions - that is, a series of solid solutions for which heats of formation from the individual pure silicates, Mg2Si04 and Fe2SiO4, aro negligibly small.The metasilicates of magnesium and iron also form an isomorphic series. However, this series differs from the forstorito-fayalite series in the fact that the most iron-rich mixtures, between about En10Fs90 and pure Fs, appear to be unstable with respect to the paragenesis iron-rich olivine plus quartz. The supposed instability of pure FeSiO3 as a crystalline compound, at least at high and at moderate temperatures, is remarkable, as no crystal struc¬tural reason for such instability is apparent. The present work indicates, also, that these minerals form a perfect series of solid solutions and throws additional light on the instability question.In the following, the samples used in this investigation will be described. For each of the natural olivines and orthopyroxenes, with the exception of sample L, a chemical analysis was made of the purified and actually used fraction. All the analytical work was carried cut by Oleg v. Knorring, and the specific gravity determinations, by moans of a pycnomctcr, by Oiva Joensuu, both of the University of Helsinki, Finland. The determinations of the optical properties were made by Mrs. Toini Mikkola, of the Geological Survey of Finland."

Feb 1, 1949

By W. L. Dare

The Federal Bureau of Mines is publishing a series of studies on the methods and costs of mining uranium on the Colorado Plateau. This report describes the longwall-mining methods and techniques used at the Radon mine, Big Indian district, San Juan County, Utah. The tabular Radon ore body lies on the southwest flank of the Lisbon Valley anticline, strikes N. 10° W., dips 7° SW., and has an average thickness of 4-1/2 to 5 ft. The mine is developed by a three-compartment vertical shaft, a haulage level driven beneath the ore, and a system of drifts driven within and parallel to the strike of the ore.

Jan 1, 1961

By O. C. Blade

The oil fields of Arkansas, all situated in the southern part of the State, have played an important part in the development of petroleum production in the northern coastal plain region of the Mid-Continent area. From the first discovery of oil in southwest Ouachita County in 1920 to December 31, 1930, a total of 480,167,5604/ barrels of crude petroleum has been produced from' this region. Development of the Arkansas fields proceeded rapidly after 1920. The El Dorado field was discovered in Union County in 1921. Drilling in Ouachita County resulted in the discovery of the Smackover field in 1922 and subsequently in the development of the whole southern area. To November 31, 1939,459 / producing wells had been drilled in 25 fields, aggregating 53,7356 acres of proved territory in 6 counties. Peak annual production for the State was reached in 1925, when 80,823,7007/ barrels was produced, resulting largely from flush production from the Smakover field, which rose td an average of 444,9507 barrel daily during that year. During 1924, 1925, and 1926 Arkansas ranked fourth among the oil-producing

Jan 1, 1940

By Gerald H. Groenewold

Reclamation of surface-mined landscapes is commonly defined only in terms of biological productivity. Other critical concerns associated with surface mining include the long-term quality of groundwater and stability of the postmining landscape. Meaningful reclamation design must address all these concerns. Reconnaissance of postmining landscapes indicates that three types of instability occur in these settings. These include: area-wide settling, localized collapse, and piping. Area-wide settling is most pronounced during the first year after contouring but appears in precontouring valley areas where frozen materials are contoured with a dozer. Although severe in some settings, development typically ends within one year. Piping appears to be a severe and long-term problem in some settings. Piping usually begins soon after contouring ceases and may continue for several years. In some postmining landscapes, piping has only started to develop after as many as five years of apparent stability. Piping is controlled by a combination of physical and chemical conditions in the spoil. A key factor is the presence of highly dispersive materials in the near surface. The design of a stable postmining landscape requires the integration of severe critical factors. These include: 1) detailed knowledge of the distribution of overburden materials with emphasis upon the delineation of highly sodic sediments; 2) proper equipment selection; and 3) a consideration of climatic factors. For reclamation to be successful, it must consider the entire landscape, not merely the soil zone. Any approach short of this will lead, at best, to temporary solutions.

Jan 1, 1980

By L. A. Readdy

Pilot Hole "X" was drilled to test the formations through which the ventilation shaft for the proposed U.S.B.M. demonstration oil shale mine will be drilled. The history of the drilling of Pilot Hole "XI' is presented. This historical summary provides the details of method used during the drilling of this hole. Problems encountered during drilling are discussed. The quantities of drilling mud and other materials used to drill the hole are documented.

Jan 1, 1977

By Foster Fraas

Electrostatic separation depends on a number of electrical and mechanical properties such as conductance, contact potential, dielectric constant, and particle shape. In routine testing it is desirable that the application of each of those properties be investigated. The conductance property is best utilized in a separator having an ionic field, whereas the contact potential requires a separator with a pure static field. Dielectric constant and particle shape also influence the response in these two fields. There is no separator on the market that can be adjusted for all these requirements. The separator described in this paper is satisfactory for this purpose and is provided with a dielectric electrode, which permits formation of high-intensity static fields.

Jan 1, 1951

By Eric G. Kok

Complying with respirable dust standards is presently a critical problem for many longwall faces equipped with double drum shearers. Results are presented of research performed to increase the quantity and optimize the distribution of the water supplied to the shearer drums to control the shearer operator dust exposure. The effect on the total respirable dust produced by the shearer was also examined. During the research effort, a simple and inexpensive manually controlled valve system was designed and implemented on a shearer to distribute the water supplied to the shearer drums. Research showed that increases in water quantities are beneficial but associated pressure increases may induce respirable dust boilover negating potential advantages. Other essential parameters such as location of shearer operator, outside spray orientation and air quantity were considered in the evaluation.

Jan 1, 1986

By K. L. Cashdollar, C. K. Man, J. R. Gibbins

Oxyfuel combustion is currently one of the principal technological options being considered for capturing carbon dioxide from pulverised coal power plants. In oxyfuel combustion, coal is burnt in a mixture of recycled flue gases and added oxygen instead of in air. In principle this yields a flue gas containing only carbon dioxide, water vapour and small amounts other impurities. Oxyfuel combustion is superficially similar to combustion in air, but there are inevitable differences. This paper describes ignition tests on pulverised coal suspensions using a suite of coals of different rank and from different countries of origin and over a range of oxygen and coal concentrations of interest for oxyfuel combustion. The ignition tests were carried out using the National Institute for Occupational Safety and Health (NIOSH) 20-litre explosion chamber. The purpose was to determine how easily the various coals ignite and burn in mixtures of O2 and CO2 compared to their combustion in air. The residual char volatile and ash contents for the ignition residues were measured using a thermogravimetric analyser (TGA), allowing Q factors (i.e., enhancement in apparent volatile yield due to higher heating rates and/or heterogeneous reactions) to be determined and compared. An ignition index has been derived from the explosion and char data. This index has been used to rank low volatile coals for ignition propensity in air. The results show that to obtain ignition and combustion comparable to that in air, the oxyfuel O2-CO2 gas mixture must contain over 30% O2. Keywords: CO2 capture, combustion, pyrolysis, oxyfuel.

By D. B. Taliaferro, Thomas Jennings, C. M. Keithly

"INTRODUCTION This report describes the methods of development and operation and gives the results of controlled water injection into oil sands in Illinois. It is the third of a group relating to water-flooding operations in various States; previous reports have covered projects in Oklahome 5/ and Kansas.6/ Systmatic water flooding has been in progress, in these States, for more 10 years. In Illinois the Tide Water Associated Oil Co. has been injesting water into one or two wells on each of five leases in the Robinson Acknowledgments This study was made under the general supervision of R. A. Cattell, chief engineer, and H. C. Fowler, assistant chief engineer, Petroleum and Natural Gas Division, Bureau of Mines, Washington, D. C., and N. A. C. Smith, supervising engineer, Petroleum Experiment Station, Bureau of Mines, Bartlesville, Okla., and under the direct supervision of Ludwig Schmidt, senior petroleum engineer, Bureau of Mines, Bartlesville, Okla.The cooperation of the operators who are conducting water-flooding projects and who have made this report possible by furnishing data on their operations is gratefully acknowledged. The writers are grateful also to the following members of the Bureau of Mines for assistance in preparation and criticism of the manuscript: C. J. Wilhelm, Franklin, Pa.; and Gustav Wade, R. E. Heithecker, and Peter Grandone, Bartlesville, Okla. The illustrations were prepared by Helen Cramer, Petroleum Experiment Station, Bureau of Mines, Bartlesville, Okla."

Aug 1, 1944

By E. C. Lane

"INTRODUCTION The first important discovery of petroleum in New Mexico was near Dayton, Eddy County, where the Brown well was drilled in 1909, and small quantities of oil were produced. In 1911 and 1912 wells were drilled in McKinley County, but commercial production did not begin until the discovery of the Hogback field, San Juan County, in 1922. The discovery well in the Artesia field, Eddy County, drilled in 1923, gave impetus to active drilling in many areas. Since 1924 New Mexico has produced petroleum in commercial quantities and since 1930 the State has joined the ranks of the big produc¬ing States, being sixth or seventh in total production in recent years.Production by years. 1924 to 1940, inclusive, taken from annual figures in Bureau of Mines Minerals Yearbook, are given in table 1. The total production shown is 274,331,000 barrels. Andreas 3/ has published production figures for the year 1940 and a resume of all production to the end of 1940. Data from his report are presented in table 2 for each field sampled. The cumulative production, as given by Andreas, is 270,618,575 barrels."

Aug 1, 1942

By M. D. Aldridge

The results of a two-year research effort aimed at improving communication systems in coal mines is reported. A review of communication methods presently used in coal mines is presented. Theoretical and-experimental results of a four pronged effort in the areas of (1) through-the-earth propagation, (2) paging system design, (3) improvement of wired telephone systems, and (4) carrier current systems are described. Auxiliary systems not included in the above are considered briefly. Various conclusions are drawn in light of practical constraints and the needs of the mining industry. The study clearly demonstrated the need for nine communications to be designed on system basis. The viability of new technology for providing reliable mine communication for improving mine safety and operating efficiency is shown.

Jan 1, 1973