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By P. T. Brooks

Semipilot scale tests were made to demonstrate a newly developed electrorefining process which could be extrapolated to commercial scale in producing high-purity nickel and cobalt from crude nickel metal and high-grade ferronickel. The new process comprises application of solvent extraction techniques to remove and separate cobalt and iron from nickel and the electrodeposition in diaphragm cells of pure nickel and cobalt from chloride-based purified electrolyte. Using water insoluble organic amines, the solvent extraction operations enabled production of commercial-sized nickel and cobalt cathodes of higher purity than that of commercial electrolytic metals. The solvent extraction operation for separation of cobalt from nickel was made simpler than the conventional method. Furthermore, the solvent. extraction operation for iron removal made possible the electrorefining of ferronickel without the prohibitive loss of nickel resulting from the method ordinarily used for iron removal.

Jan 1, 1970

By J. R. Bartels

Operation of underground coal mine mobile equipment is usually done in a restricted workspace with reduced visibility. This work environment puts machine operators in awkward postures for tasks that require awareness of their surroundings and fast reactions to avoid hazardous situations. Using experienced equipment operators as a source, researchers conducted an investigation that developed a method to gather data on the needs and practices of machine operators while controlling the machine and the reasons for needing particular operational cues. The method used was an interview technique including a survey questionnaire and visual aids. The data gathered defined operator cues and work positions for the cutting and tramming phases of remote controlled continuous mining machines used in underground coal mines. Analysis techniques to determine which cues an operator sees from a variety of positions utilizing a computer simulation is shown to be potentially useful to the mining industry for design of work practices and workplace layout and could impact equipment design and selection for improved worker safety. Conclusions indicate that the survey was a good research tool to collect data and helped investigators understand important visual cues. Using this information, researchers were able to analyze the visual cues an operator can see from a given work position and posture.

Jan 1, 2009

By D. D. Harbuck

To decrease reliance on foreign sources for the strategic and critical metals gallium and germanium, the U.S. Bureau of Mines identified and developed processing technology for two domestic sources of these metals: a Tennessee zinc residue and a Utah ore. Sulfuric acid (H2S04) solutions were used to solubilize gallium and germanium in both sources. Statistically designed experiments showed that the most important parameter for high metal extraction from zinc residue was the H2S04 concentration. At a concentration of 2.9M H2S04, 95 pct of the gallium was extracted, and at a concentration of 0.6M H2S04, 73 pct of the germanium was extracted. Controlled H2S04 concentration was also the key for high metal extractions (97 pct Ga, 87 pct Ge) from the Utah ore. Such control was achieved using a two-stage countercurrent leach circuit. Testing showed that the insoluble germanium in both the residue and ore was tied up with silica. Several methods for overcoming this problem are given. To recover gallium and germanium from the leach solutions, the solvent extractants octylphenyl acid phosphate (OPAP) (for gallium) and LIX 63-OPAP (for germanium) were identified. These extractants were tested in separate, continuous, solvent-extraction circuits yielding a gallium recovery of 94 pct and a germanium recovery of more than 90 pct.

Jan 1, 2010

By F. W. Hoertel

Tungsten from the hydrogen reduction of WF was vapor - deposited to coat MERM (Material Evaluation Rocket Motor ) graphite and rhenium- lined graphite nozzles . These nozzles have surface configurations that preclude the conventional fabrication of high- density- tungsten liners . Operation at 550 ° C produced selectively placed uniform coatings of specified thicknesses at near theoretical density . An acceptable coating could not be deposited on a beryllia nozzle because of an undesirable side reaction between the substrate and one or more of the products of the reduction reaction .

Jan 1, 1964

By Tilman M. M.

The effects of substituting cobalt for nickel on the acid corrosion resistance of two types of austenitic stainless steel were determined. Cobalt substitutions to a maximum 2.2 weight-percent were made in types 302 and 309 stainless steels. Total immersion corrosion tests were made in 10 volume-percent hydrochloric acid, and boiling-acid tests were conducted in 65 weight-percent nitric acid and in undiluted glacial acetic acid. For modified type 309 in acetic acid, corrosion rates decreased for additions greater than 0.57 weight-percent cobalt. Corrosion rates increased as cobalt was increased up to about 1 weight percent for modified type 302 in nitric and hydrochloric acids and for modified type 309 in nitric acid, but these rates decreased with a further increase in cobalt content. A gradual increase in corrosion rates with increasing cobalt content was shown for type 302 in acetic acid and for type 309 in hydrochloric acid. Cobalt substitutions in larger amounts (above a ratio of 8 Ni to 1 Co) may increase the corrosion resistance of the austenitic stainless steels.

Jan 1, 1965

By H. B. Brunot, L. C. IlsLey

The design , construction, inspection , and test for permissibility of a storage- battery locomotive outfit in accordance with the requirements of Schedule 15* represents a large amount of work, first on the part of the locomotive manufacturer and secondly on the part of the Bureau of Mines . Detailed information of the first investigation under the schedule is presented here . This investigation covers the inspection and test of a storage- battery locomotive manufactured by the Geo . D. Whitcomb Co. , Rochelle , Ill . , to which Approval No. 1500 was assigned ,

Feb 1, 1923

By H. Kenworthy

The purpose of the study described in this publication is to develop methods for recovering simple master alloys or single metal components from discarded and scrapped S-816 alloy, The Bureau of Mines started this investigation late in 1955 after the need became apparent for a method of reclaiming high-temperature alloys from an ever-increasing accumulation of rejected and wornout jet engine turbine buckets. Laboratory studies showed the following: (1) Pyrometallurgical separations are not selective enough, (2) several methods can be used for effective chemical dissolution of the major constituents of the alloy, (3) a master alloy or complex salts of cobalt and nickel can be separated, (4) chromium, contaminated by several other metals, may be segregated, and (5) more time and effort need to be expended in separating the minor constituents and improving the purity of the major metals removed. Difficult and incomplete chemical separations were attributed to the complexity of alloy composition, as were the long tedious chemical analyses o' products. For determination of several of the metallic components, standard methods of separation and routine analytical procedures had to be considerably modified to achieve satisfactory results. The overall technical problems involved in separating S-816 components do not appear to be insurmountable; however, refinement of several of the methods used in this investigation is desirable.

Jan 1, 1961

By Robert K. Koch

The reactions of alumina and alumina monohydrate with wet hydrogen fluoride gas were studied by the Federal Bureau of Mines to determine the feasibility of producing commercial-grade aluminum fluoride from offgases generated by pyrohydrolysis of siliceous fluorspars. The test results showed than an aluminum fluoride reactor operating at maximum efficiency could retain 96 percent of the fluorine contained in off-gases generated by pyrohydrolysis of siliceous fluorspar. The requirements are a reactor temperature of 200° C. and a reactor entrance gas containing 5 mole-percent hydrogen fluoride. Partial pressure equilibrium constants were determined for the reaction of alumina monohydrate and wet hydrogen fluoride gas from 200° to 350° C. and for the reaction of alumina and wet hydrogen fluoride gas from 350° to 700° C. Both reactions are reversible, and they proceed in directions that are dependent upon the temperature and the relative HF:H2O concentration. Logarithms of the equilibrium constants were used to plot the reaction isobars; these can be used to calculate the theoretical maximum efficiency of a reactor processing wet hydrogen fluoride gas between 200° and 700° C. The theoretical maximum efficiency decreases with increasing temperature.

Jan 1, 1961

By Roy C. Bartholomae

This U.S. Bureau of Mines study found that the performance of the active noise cancellation hearing protector in a reverberant field was mixed. The performance varied when the conditions changed from ideal to nonideal. The active noise cancellation (ANC) component provided substantial additional noise reduction from 125 to 500 Hz for all testing conditions (broadband noise or pure tones both with and without safety glasses). While the ANC under ideal conditions provided additional attenuation from 500 Hz and below, under nonideal pink noise conditions the ANC amplified noise below the 125-Hz third octave band. There was a middle band of frequencies at which the ANC amplified noise levels ranging from 630 to 4,000 Hz. The results for pure tones showed that attenuations were higher but that they followed the same general trend.

Jan 1, 2010

By W. W. Agey

Under terms of cooperative agreements, the Federal Bureau of Mines Inter-mountain Experiment Station assisted the General Services Administration (GSA) in operating the manganese-ore purchasing depots at Deming. N. Mex., and Wenden, Ariz. A resident metallurgist stationed at the depots directed sampling of the ore lots for assaying, took samples for amenability testing, calculated acceptances for payments to shippers, and served as technical adviser to the depot manager. The Intermountain Experiment Station at Salt Lake City, Utah, tested the amenability of the ores to determine how much of the manganese could be recovered in concentrates assaying a minimum of 40 percent manganese (Mn) and containing a maximum of 16 percent iron (Fe), 15 percent silica (Si02) plus alumina (AI203), 0.3 percent phosphorus (P), and I percent copper (Cu) plus lead (Pb) plus zinc (Zn). All chemical analyses of the ores and test products were done at Salt Lake City. In all, 567 ore lots submitted to the Deming depot were tested by flotation to determine their amenability to concentration into specification-grade material; 421 lots were amenable, and 146 were unamenable, primarily because of high copper content or excessive silica or iron in the flotation concentrate. Chemical analyses totaling 42,700 were made on the ores submitted to the Deming depot and on the products of the amenability-test program.

Jan 1, 1959

By G. W. Jones

In the course of experiments on the stabilization of acetylene gas by addition of other gases, notably hydrocarbons such as methane, propane, and butane, it was observed that large quantities of carbon black are produced during the explosion of acetylene or mixtures of acetylene with the, above hydrocarbons, the added hydrocarbon being essentially decomposed into hydrogen and carbon. It is known that in the complete absence of air acetylene explodes upon application of an intense ignition source at pressure above 5.9 p.s.i. gage. The same is true of mixtures of hydrocarbons and acetylene. However, the pressures necessary for explosion are considerably higher in the case of these mixtures and depend on the amount of added hydrocarbon. The present report contains data on gaseous products and the physical characteristics of the carbon black formed by explosion at elevated pressures of various mixtures of acetylene and hydrocarbons as well as other gases, such as hydrogen, helium, nitrogen, and carbon dioxide.

Jan 1, 1950

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1953 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 101 samples of aviation gasoline which include, for the second time in this series of reports, data on some samples of grade 108/135 aviation fuel. Data also are given for 32 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' production in their laboratories and the results sub-mitted to the Bureau of Mines for compilation. The products of 19 manufacturers of aviation gasolines and of 19 producers of aviation jet fuels are represented.

Jan 1, 1954

By J. L. Konchesky

The technical feasibility of gasifying powdered, noncoking, low-rank coal with steam in an externally heated tube has been demonstrated. The tube, 112 ft. of alloy-steel tubing shaped into a helix, served as an electrical conductor of electricity used for heating. The effects of the following variables were studied: Residence time of coal in reactor, average reaction temperature, steam concentration, and rank or geologic age of coal. Reaction pressure was maintained in the range 19-26 p.s.i.a. High carbon conversions and large yields of synthesis gas were obtained with low-rank coal. In one test, for example, about 88 pct. of the carbon in a subbituminous C coal was gasified at 1,910* F. with a residence time of 1 sec. The gas contained 58 pct. H2, 19 COD 15 CO, and 3 CH4; the yield was 30 cu. ft. (at 32' F. and 14.7 p.s.i.) of synthesis gas (CO + H2) per pound of dry coal.

Jan 1, 1960

By Fremont T. Johnson

Credited with production of more than 164,000 flasks Of quicksilver from 1876 to 1944, the Oat Hill mine has ranked third in output in the United States. During World War II, when the demand for mercury was high, this property was selected for diamond drill with the purpose of increasing ore reserves so that production could be maintained or, if necessary, increased. Although the existence of marginal-grade ore (fill material) left in the stapes and possibly of virgin ore of good grade had suspected in certain parts of the Oat Hill mine, no factual information to tonnage, grade, or location was available. In close cooperation with the Federal Geological Survey, the Bureau of Mines studied old records and the few available incomplete maps. Diamond drilling began in November 1943 and was completed in December 1944. Twenty-eight holes aggregating 8,121 feet were drilled, in only parts of the promising areas disclosed by the study of the data available. Detailed data on the work done by the Bureau as well as a brief history of the property and some operating details are described in this report.

Jan 1, 1949

By Jack L. Woodward

The evolution of surface mining equipment has resulted in larger, faster haulage units, loaders, etc., resulting in increased demands on steering technology. Careful analysis of these systems was warranted to determine if steering-related safety problems have been introduced. The objectives of this program were to: 1. Define the generic types of steering systems being used on mobile mining equipment used in surface mining operations. 2. Gather information on steering-related accidents in mining operations. 3. Assess the need for initiating government-sponsored research into steering system technology. A comprehensive literature survey was conducted concurrent with extensive contacts with mining operations, mining equipment manufacturers, steering system component manufacturers, and government agencies. A Technical Evaluation Group composed of representatives from the above organizations was formed to review the data gathered. It was concluded that the steering systems in use on surface mining equipment are reliable and do not present a safety problem. The Society of Automotive Engineers, Inc. is active in pre-paring voluntary consensus standards to assure that the minimum levels of performance are defined for industry.

Jan 1, 1979

By J. G. Donaldson

Cobalt-tungsten binary deposits were formed in laboratory experiments by hydrogen reduction of the anhydrous mixed vapors of cobaltous chloride and tungsten hexachloride. The materials were sublimed in seperately heated zones of reaction tube and were transported in a stream of purified helium into the deposition section of the tube where the chloride gases were reduced to metal by a countercurrent flow of hydrogen. Heattreating of the near stoichiometric binary metallic deposits converted nearly all to the intermetallic compound Co3W, however, small quantities of both cobalt and tungsten remained. Mechanical tests showed that the tensile strength of heat-treated 75 percent cobalt-25 percent tungsten deposits was twice as high as that of similarly treated deposits of cobalt.

Jan 1, 1965

By Edward G. Cunney

Track in underground bituminous coal mines was investigated and technology was taken from other industries in order to obtain information on conditions that impair the safety and efficiency of the track and to develop guidelines and useful information on the construction, inspection and maintenance of mine track. Volume 1 contains information on the investigations, observed track conditions, useful technology from railroads and other industries, derivations of track condition descriptors and limits, conclusions, and recommendations. Volume 2, Guidelines, contains recommended standards and practices for mine track. It includes the relation of track conditions to safe speeds; descriptions and limits for measurable track features, such as gage; descriptions of conditions for track components that are normally not measurable, such as subbase soils; construction requirements and techniques; inspection requirements and methods; and methods for managing and performing track maintenance work. It does not repeat the summary or? derivations. Volume 3, Inspection Handbook, summarizes recommended standards and procedures from Volume II and provides related information for ready reference by inspectors in the mines. As a research product to be used in mines, it does not repeat the summary, derivations or references.

Jan 1, 1977

By Beverly W. Dunning

The effect of vacuum melting on the elimination of gases and nonmetallic inclusions for six low-alloy steels was investigated. The purpose of these studies was the analysis and comparison of differences in gas content and inclusions in air-melted and vacuum-melted steel. Data obtained from melts of 1-1/4 to 20 pounds indicate that vacuum melting decreases the number and size of nonmetallic inclusions and at the same time increases the degree of dispersion of the remaining inclusions. These improvements are undoubtedly related to the elimination of approximately 80 percent of the nitrogen and 90 percent of the oxygen as well as most of the undesirable metallic trace impurities.

Jan 1, 1961

By L. K. Weaver

Bureau of Mines investigated the progressive impact that petroleum (crude oil and condensate) operations in the Gulf of Mexico have had on onshore operations and the expected effect of increasing activities in this area on future petroleum supplies from domestic sources. The data analyzed include capital expenditures, number of wells drilled, success ratio for exploratory wells, daily production per completion, annual producing rates, and oil reserves. The report compares offshore and onshore data and ascertains trends in petroleum industry operations. Observed data and trends indicate that in the near future Gulf of Mexico development and production will continue to increase relative to total U.S. petroleum activity. By 1975 annual oil and condensate production from the Gulf of Mexico is expected to be in the range of 750 million bbl to 1,150 million bbl, and account for approximately 20 to 30 pct of the estimated total domestic production.

Jan 1, 1969

By R. L. Grant

[p(,ton~to'rs 'ar-IV uscG.. to explode 9crnli .... sible c}:plosivcs, dynamites, or other hiGh uxplosives. This ?,...!xplosion or detr)nation is brought about by th\.:J energy which i liberated as a cOl":"Lb' nation of concusBion and heat wl1en the ? detonator is fired. 'm Ot:18t? I'l(jrds~ liThe detonator is the key VI: ich unlocks the enerGY of a llgh? explosIve""? (8) :1/. Being sensitive nd latently dangerous, detonators ITl.ust lTIeet t\V0 primary requirerDentr: They must be ..;.afe to handle and IT. list? detonate' when (l,esired, the ... eby iIr.parting deton:l.tion to the explo8ivc cJ.1Cire-e.]

Jan 1, 1941