Search Documents

By E. C. Lane

This paper is the first part of a report giving the results of the Bureau of Mines' twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,5 and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey.7 A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "competitive-price gasolines" and 105 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Miner at Bartlesville, Okla.

Jan 1, 1931

By C. Özgen Karacan

Longwall mining is an underground mining method during which a mechanical shearer progressively mines a large block of coal, called a panel, in an extensive area. During this operation the roof of the coal seam is supported only temporarily with hydraulic supports that protect the workers and the equipment on the coal face. As the coal is extracted, the supports automatically advance and the roof strata cave behind the supports. Caving results in fracturing and relaxation of the overlying strata, which is called "gob." Due its highly fractured nature, gob contains many flow paths for gas migration. Thus, if the overlying strata contain gassy sandstones or sandstone channels, gas shales or thinner coal seams which are not suitable for mining, then the mining-induced changes can cause unexpected or uncontrolled gas migration into the underground workplace. Vertical gob gas ventholes (GGV) are drilled into each longwall panel to capture the methane within the overlying fractured strata before it enters the work environment. Thus, it is important, first to understand the properties of the gas reservoir created by mining disturbances and, second, to optimize the well parameters and placement accordingly. In this paper, the production rate-pressure behaviors of six GGVs drilled over three adjacent panels were analyzed by using conventional multi-rate drawdown analysis techniques. The analyses were performed for infinite acting and pseudo-steady state flow models, which may be applicable during panel mining (DM) and after mining (AM) production periods of GGVs. These phases were analyzed separately since the reservoir properties, due to dynamic subsidence, boundary conditions and gas capacity of the gob reservoir may change between these two stages. The results suggest that conventional well test analysis techniques can be applicable to highly complex gob reservoirs and GGVs to determine parameters such as skin, permeability, radius of investigation, flow efficiency and damage ratio. The insights obtained from well test analyses can be used for a better understanding of the gob and for designing more effective gob gas venthole systems.

Jan 1, 2009

By L. C. Brichta

During a study of the Badger-Peacock area from October 1950 to June 1953, the Federal Geological Survey and the Federal Bureau of Mines completed nearly 98 miles of resistivity profiling and drilled 96 test holes aggregating 17,628 feet of bore, In addition, seismic profile measurements were made along 8 traverse lines for an aggregate length of about 16,600 feet. The geophysical surveys were conducted by the Geophysics Branch of the Geological Survey; the drilling was done by the Bureau of Mines. Electrical-resistivity measurements disclosed 21 low-resistivity anomalies and 1 high-resistivity anomaly. Correlation of the resistivity data with the geological information revealed by the drilling disclosed that the low-resistivity anomalies indicated either slumped shale deposits in limestone sinks or undisturbed deposits of shale lying in erosional depressions in the limestone. The high-resistivity anomaly indicated hard, undisturbed limestone at or near the surface.

Jan 1, 1958

By Byron S. Gottfried

This Bureau of Mines report presents a method for combining the distribution curves at different specific gravities of separation, for a given piece of coal-cleaning equipment and a given raw coal feed, into a single, generalized distribution curve normalized with respect to specific gravity and, therefore, independent of the specific gravity of separation. Illustrative generalized distribution curves, based upon Bureau of Mines collected data on industrial operations, are presented for five different types of coal-cleaning equipment. The well-known concept of probable error is extended to the generalized distribution curve. It is shown that the conventional probable error is directly proportional to the specific gravity of separation. A number of sample calculations, illustrating the use of the generalized distribution curve and generalized probable error, are presented in the appendix.

Jan 1, 1977

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1956 was made under a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 120 samples of aviation gasoline and for 38 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' 1956 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 17 producers of aviation jet fuels are represented.

Jan 1, 1957

By John W. Sweeney

Shales and clays from Illinois were sampled, tested, and evaluated to determine feasibility of producing lightweight aggregate by rotary-kiln methods. Sampling procedures and the 1 ,,,y of the Pennsylvanian shale units are discussed. Chemical, X-ray spectrographic and X-ray petrographic analyses were run on the samples to determine if a correlation existed between chemical mineralogic composition and expansion. Preliminary expansion testing was conducted in a muffle furnace. Rotary-kiln tests were conducted in a 16- inch by 14-foot rotary kiln. The weight of the aggregate ranged from 27 to 59 pounds per cubic foot. Concrete cubes employing the aggregate were tested to determine the qualities of the concrete. Compressive strength of the concrete using the 7-bag of cement cement per cubic yard mix, after autoclave curing for 6 hours, ranged from 2,950 to 6,750 psi. No correlation was found between the chemical, X-ray spectrographic, and X-ray and petrographic analyses and expansion, Sixteen samples made suitable lightweight aggregates in the laboratory rotary kiln. The expansion temperature range of eight of the samples was extremely narrow, and difficulties would probably be encountered in processing these materials commercially.

Jan 1, 1965

By L. L. Oden

The Bureau of Mines has studied a number of processes to remove Cu from molten steel scrap with the objective of determining if any of the laboratory methods studied warranted in depth research investigations. Experimental approaches included oxidizing Cu from steel containing other metals that form stable mixed oxides with Cu (AI, Cr, Fe, Mn, Mo, and V), injecting the same metals as oxides to simplify the mechanism of complex oxide formation, partitioning Cu into alkali or alkaline earth silicate slags or oxide-moderated sulfides, and coremoving Cu and S by injecting active compounds of Ca and Mg. The most promising tests, producing nearly 0.3 pct Cu in the slag, used Ar injection of K20-moderated Na2S-FeS below the surface of molten steel containing about 0.6 pct Cu and protected by a CaO-SiOz slag; however, in depth research investigations currently are not felt to be warranted.

Jan 1, 1987

By S. M. Shelton, W. A. Calhoun

"INTRODUCTION Discovery and development of a southwestern Arkansas quicksilver district are recent history. In July 1930 4/, a specimen was discovered near the Little Missouri River in sec. 1, T. 7S. R. 26 W., which was identified as cinnabar. In the summer of 1931, Leo Yount began prospecting for cinnabar near the Little Missouri River. In the fall of that year he operated a small three-tube retort near the present Parker Hill mines and produced several flasks of quicksilver. Yount optioned a considerable block of ground containing the best showings in the Little Missouri River area, and on February 19, 1932, he and W. C. McBride, Inc., of St. Louis, Mo., formed the Southwestern Quicksilver Co., which was the largest producer in the district until operations ceased in September 1934.The Southwestern Quicksilver Co. installed a rotary furnace on Parker Hill in April 1932, which treated ore from the three principal mines Gap Ridge, Parker Hill, and Parnell Hill. In 1934 production was entirely from the Gap Ridge and Parker Hill mines. Nothing was done at Parnell Hill except a little small-scale work on a share basis.Mercury Producers, Inc., later took an option on the holdings of the Southwestern Quicksilver Co. and in June 1935 began operations. The company produced considerable quicksilver before the lease and option were surrendered in the summer of 1936. Most of the work of Mercury Producers, Inc., was on Parnell Hill, but some work was done on Parker Hill and at the Bell prospect on ground not controlled by the Southwestern Quicksilver Co."

Mar 1, 1942

By A. Adams

The Bureau of Mines determined the composition of the vapors liberated during thermal decomposition of aluminium nitrate nonahydrate. Small samples were heated from room temperature to 5500 C with initial heating rates from 500 to 2000 C/min. Gases were rapidly swept away from the heated chamber with Ar and subjected to immediate analysis in order to minimize reaction between the components. In addition to H20, four N-containing compounds were identified: HN03, N02, NO, and N20. Nz could not be determined in the presence of the nitrogen oxides, and at-tempted separation from the oxides led to the formation of more nitrogen. Relative amounts of each component were found to vary over a period of time; however, total amounts measured with different heating rates were reasonably constant and were typically as follows: 84.2 pct HN03, 7.1 pct N02, 4.3 pct NO, and 4.2 pct N20. HN03 and NO were determined from chemical reactions with a permanganate solution, N20 was measured with a mass spectrometer, and NO2 was measured with a spectro-photometer. Details of the methods used are described. Since NO2 and NO can readily be converted to HN03, about 96 pct of the N from the decomposition can be recovered as HN03

Jan 1, 1987

By O. C. Blade

A summary of the characteristics of motor gasoline for the winter 1951-52 is presented in table I, and for comparison, a similar summary for the winter 1950-51 is shown in table 2. Trends of some of the more important characteristics over a period of years are shown in figures 1 and 2. The results of this survey show that octane numbers have risen slightly since the summer of 1951 but are below the record levels of the winter of 1950-51. The fractions of a unit change since the summer preceding have resulted in the research and motor-method octane values being virtually the same as the figures for the survey of summer 1950. In volatility characteristics the winter gasolines have changed very little. Average Reid vapor pressures are 10.5 pounds for both grades of fuel compared to 10.4 and 10.5 pounds for premium and regular-price gasolines, respectively, of the winter of 1950-51.

Jan 1, 1952

By J. W. Town

Recrystallization studies on chrome-bearing spinel materials were made by the Bureau of Mines to determine the effects of certain fluxing agents and cooling rates on the chromium-to-iron ratio of recrystallized spinel. Statistically designed and evaluated tests showed that the ratio of chromium to iron in naturally occurring chrome spinel could be increased from 1.5 to 1 to over 7 to 1 and that the ratio of chromium to iron in the chrome-spinel in a stain-less steel slag could be raised to over 18 to 1. Silica, magnesia, and lime had significant positive effects, while alumina had a significant negative effect. Cooling rates of 200 C per hour in a programmed spiral globar electric furnace were satisfactory for growing crystals of recoverable size.

Jan 1, 1967

By Wm. W. Odell

In distributing natural and mixed gas, the industry is each year confronted with the problem of manufacturing gas in increasing amounts as the supply of natural gas becomes more nearly exhausted. The manufactured gas is now used in mixtures with the still available natural product, and will subsequently be used straight as a substitute gas. The gases that might be considered, and are producible by tried and developed processes, include water gas, carbureted water gas, and coal gas. Singularly, these gases can be used in this manner in ordinary appliances only when proportional amounts of them in the mixtures do not vary beyond rather definite limits, unless burner adjustments are made. The limits are defined by the specific gravity, content of inerts, and burning properties of the respective gases. Anticipating a future standard for city gas lower than that of natural gas during the period when considerable natural gas is available, there is justification for considering the possibility of re-forming natural gas and making a product that has substantially the same properties as other gases which can readily be generated. This report gives the results obtained during a series of tests made under a cooperative agreement by the U. S. Bureau of Mines with the Ohio Fuel Gas Co., re-forming natural gas at Toledo, Ohio, in full-scale operation in a water-gas generator having a grate area of 25.1 square feet. ACKNOWLEDGMENTS The Ohio Fuel Gas Co. constructed a special water-gas generator for the tests and provided men and the necessary funds for its operation. Appreciation is expressed for the general spirit of helpful cooperation which was evidenced in the activities of all those who took part in the work. Particular acknowledgment is made of the assistance rendered by C. W. Wallace, manager, and by C. F. Cramer, superintendent, and A. Upp, foreman of the plant.

Jan 1, 1929

By Andrew M. Leszcykowski

The Bureau of Mines (Bureau) conducted mineral investigations of the Payette Crest-South Fork area in west central Idaho near McCall, Idaho, in 1989. There are no known producing mines or mineral production from the area. Forty-seven samples were taken (stream sediment, rock. and placer); no identified mineral resources were delineated.

Jan 1, 1991

By G. M. Kintz

In safety work a study of past accidents is of value in determining means of reducing future accidents of the same character. This is particularly true with reference to coal-mine explosions. Data from publications of the United States Bureau of Mines and from published reports of the State inspector of coal mines of Colorado are presented in this circular in the belief that they will be of value to operators by indicating methods of preventing future coal-mine explosions. The tables included are complete only with regard to major disasters. The Bureau of Mines considers as a major disaster one in which five 'or more men are killed. However, this circular also includes a considerable number of minor disasters, Various explosions in the coal mines of Colorado from 1883 to 1932, inclusive, are listed with information available as to their probable cause, number of men killed and measures which, if they had been in use at that time, might have prevented them. John McNeil, first Colorado State coal-mine inspector, on page 43 of his first report for the period ended July 31, 1884, made the following recommendations for the prevention of explosions in the coal industry: True causes could be traced either to insufficient ventilation, carelessness and lack of rigid discipline in carrying on energetic ventilation and other precautions needed to be enforced in a mine giving off explosive gases. *** When any quantity of fine coal dust is observed in an entry, air course, or room it should be made damp and be removed from the mine, and thus beep every place as free from dust as possible. *** A system of bratticing close up to the face of each and every place in the mine from crosscut last made (whether gas should just then show its presence or not) which should not be more than 50 or 75 feet according to the nature of the mine.

Jan 1, 1933

By G. S. Scott. R. L. Grant

Ammonium nitrate (NH4NO3), a white crystalline chemical compound composed of 35 percent nitrogen, 60 percent oxygen, and 5 percent hydrogen, has again attracted attention, due largely to the recent catastrophe on April 16 and 17, 1947, at Texas City, Tex. The fire and subsequent explosion on the steamship Ocean Liberty, outside the harbor of Brest, France, on July 28, 1947, has fur- ther increased the interest in the properties of ammonium nitrate. As a result of the Texas City disaster, several laboratories have undertaken research to determine more certainly what causes ammonium nitrate to detonate and under what circumstances. This is not the first time that ammonium nitrate has been involved in a disaster, and its properties reviewed from the standpoint of safety. The disaster at Oppau, Germany, in 1921, which involved an equimolec- ular mixture of ammonium nitrate and ammonium sulfate, prompted an intensive study in Europe and in America. In the United States the properties of am- monium nitrate are now of especial concern because very large quantites are being manufactured and shipped in interstate commerce and abroad. Many an- monium nitrate factories, which were built during the war, will manufacture increasing amounts of this compound for use as a fertilizer. It is the purpose of this report to present a brief summary and biblio- graphy of the published experimental facts about the properties and behavior of ammonium nitrate. The reader is referred to original publications for greater details of the investigative work, and for theoretical discussions. This report also includes a survey of ammonium nitrate fertilizer of the type involved in the Texas City explosions. In the past, authorities have not always agreed on the degree of hazard involved in the manufacture and handling of ammonium nitrate, as the following quotations from the literature indicate: Munroe (82) quoted the following from Turner's Chemistry (a book pub- lished in 1835): "When this salt is exposed to fire, it liquefies, emits aqueous vapor, dries and detonates." Berthelot (14) in his book, Explosives and Their Power, 1983, wrote: "Ammonium nitrate from the point of view of its volatility, and cn account of many considerations, may be regarded as a typical explosive substance."

Jun 1, 1948

By Ad. Breyre

[Internal-combustion engines have been used in Belgian mines for a long tine. As early as 1899, the use of these engines underground was considered, but the general policy was to prohibit such an application unless ministorial permission was granted' in special instances. At that time only gasoline engines were available, and a few of these were installed as stationary engines, although in general they were replaced later by electric or compressed-air motors. However, the number of gasoline locomotives continued to increase. Regulations governing the use of these locomotives soon were formulated and as early as 1920, when a now set of regulations was promulgated, the use of gasoline locomotives in mines could be authorized by the Provincial Inspection Department and no longer depended on obtaining a ministerial decision. Since 1931 this authorization may be given by the Chief Inspector of Mines, Director of the Mining District. Since 1920, safe practices have boon incorporated in the regulations.]

Jan 1, 1940

By Mayo D. Hersey

This problem was taken up by the Bureau of Mines as a result of the oxygen explosion at the Jefferson Physical Laboratory of Harvard University , and other similar explosions , in order to supply technical information which would serve as a basis for safety precautions in the future . At the Harvard inquiry the fact was emphasized by the Massachusetts State Chemist , Mr. Walter M. Wedger , that we do not know the limiting pressures and temperatures above which compressed oxygen and lubricating oil are capable of spontaneous explosion . The problem is also of importance to the Army and Navy and to the Bureau of Mines in connection with the hazards incurred in the use of compressed and liquified gases in the repurification of helium. In fact , the risk of fires and explosions due to traces of lubricating oil coming into contact with high pressure oxygen is of serious interest to all concerned with the manufacture and use of oxygen , a commodity which is now being produced and distributed on a rapidly increasing scale . Part of the money expended on this investigation was from Army and Navy funds . The problem was undertaken by the Bureau of Mines at the suggestion of Dr. Charles E. Munroe , Chairman of the Committee on Explosives Investigations of the National Research Council , and referred to the Pittsburgh experiment station of the bureau.

Jul 1, 1923

By Ad. Breyre

Internal-combustion engines have been used in Belgian mines for a long time. As early as 1899, the use of these engines underground was considered, but the general policy was to prohibit such an application unless ministorial permission was granted in special instances. At that time only gasoline engines were available, and a few of these were installed as stationary engines, although in general they wore replaced later by electric or compressed air motors. However, the number of gasoline locomotives continued to increase. Regulations governing; the use of these locomotives seen were formulated and as early as 1920, when a new set of regulations was promulgated, these of gasoline locomotives in mines could be authorized by the Provincial Inspection Department and no longer depended on obtaining a ministerial decision. Since 1931 this authorization may be given by the Chief Inspector of Mines, Director of the Mining District. Since 1920, safe practices have been incorporated in the regulations.

Jan 1, 1940

By W. J. Fene, G. W. Grove

An important activity of the Safety Division of the Bureau of Mines , in its efforts to reduce accidents , is the safety inspection of mines . Inspections are made at the request of the operators and are not connected with the inspections by the various State departments of mines . The operating management is furnished with a confidential report of the results of the Bureau's inspections , with recommendations for elimination of the hazards found . These mine - safety inspections include a study of mining practices , conditions , and equipment and in some cases the sampling and analysis of mine air and coal dust . The Bureau of Mines has no regulatory powers , therefore the recommendations made in these reports are merely suggestions , and operators are not required to adopt them . Mine inspections are a check on safety standards , methods , and practices and are essential to any accident -prevention program . A foreman or superintendent may be sincere in his efforts to operate a mine safely and believe that he has done everything possible to attain this end . However , experience has shown that because of his familiarity with the mine and the consequent " nearness " of its various features many unsafe conditions may be , and in most cases are , overlooked ; an inspector , particularly an outsider who is trained to look for hazards , can point out the unsafe conditions overlooked by the foreman or superintendent . Some companies employ safety engineers who make regular inspections of their mines , report substandard conditions and hazards found , and make recommendations for correcting them . Unless these recommendations are carried out the inspections have little value . In making recommendations , due consideration should be given to the feasibility of carrying them out ; the management may and very often does consider a recommendation impracticable because of the

Mar 1, 1935

By R. V. Higgins

Many contributions to methods of forecasting the performance of waterfloods of a five-spot pattern have been made by investigators. In most of these forecasting methods, a previously selected sweep efficiency is used, and other simplifying assumptions are employed to obtain the objective. In this paper the calculated oil recoveries from several five-spot single- and multiple-layer stratified reservoirs were made with a minimum of assumptions, and because of the techniques used, no previously selected sweep efficiency was required. As a result, the accuracy of the forecast is increased. Permeability curves and continuously changing saturation gradients are used in every section of the pattern. By means of a potentiometric model, the flood pattern is divided into channels, the centers of which are the streamlines. The channels are divided into cells. As flood water enters, the permeability and saturation of each cell change with time. In this study the production from multiple-sand layers of different absolute permeability but with the same relative permeability-saturation relations are combined. The results are shown for a single- and 10-layer reservoir with a permeability variation of 0.60. The oil rate, water-oil ratio, and recovery are shown as functions of time for a 2- and 20-centipoise oil starting in primary phase and after fill-up.

Jan 1, 1962