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By F. Garcia, J. Cervik

Recent advances in the commercial separation of gases using membranes have renewed interest in the possibility of applying this technology to the recovery of methane ( CH4 ) from mining operations . This Bureau of Mines report briefly reviews the history of the development of membranes for gas separation , the theory of how they work , and their application to the separation of methane from air and associated problems . However , methane -air mixtures are difficult to separate with membranes because the pertinent gas couples , 02 - N2 , 02 - CH4 , and N2 -CH4 , have poor separation characteristics , as indicated by their separation factors of about 3 or less . Even if these separation factors were substantially higher , there is doubt that methane could be recovered economically from the low concentrations in mine ventilation exhaust ( 2 vol pct or less ) . The exhaust pressures are not sufficient for adequate separation . The power cost of compressing the methane recovered . these mixtures would far exceed the value of New discoveries could make separation of gob hole methane - air mixtures practical . These mixtures have much higher concentrations of methane (from 30 to 100 vol pct ) ; however , for safety reasons , be limited to gob gas with 60 vol pct CH4 or more .

Jan 1, 1988

By R. F. Waters

Laboratory-scale selective volatilization methods developed by the Bureau of Mines to recover germanium and gallium concentrates from coal fly ash and phosphorus furnace flue dust are summarized. In the better experiments between 85 and 98 percent of the germanium was recovered as the lower oxide and as sulfides, and between 75 and 97 percent of the gallium was recovered as the lower oxide and as the trichloride. Grades of the condensates were inconsistent and varied between a few tenths of a percent and 8 percent, depending on the method used. In the primary extractions of germanium alone the degree of enrichment surpassed 100 to 1, and for gallium the best ratio was 30 to 1. Upgrading of condensates by vaporization retreatment and by leaching and precipitation is discussed. An appreciable degree of mechanical preconcentration by attrition scrubbing and elutriation was possible on two fly ash samples.

Jan 1, 1967

By H. C. Fowler

Hydrogen sulphide associated with the gasps and vapors from certain crude oils now produced in the United States has forced a serious health and safety problem upon the petroleum industry. Although the presence of hydrogen sulphide in or occurring with Mexican crudes has been known for some time, it was not until recently that crude oils which give off poisonous amounts of hydrogen sulphide have been produced to any extent in the United State. The injurious effects of this poisonous gas were first recognized by the refiners along; the Atlantic and Gulf Coasts upon receiving shipments of crude petroleum from Mexico. The problem of combating the hazards of the gases and vapors given off by this petroleum become more important as the use of Mexican crude increased. In 1925, the Bureau of Mines and Public Health Service under cooperative agreement with the American Petroleum Institute, studied the causes rend effects of hydrogen sulphide poisoning. Bureau of Mines Bulletin 2312 is report of this investigation, and although written with special reference to refineries, it nevertheless contains much information that is of value to the producer of petroleum.

Jan 1, 1927

By W. P. Yant, H. C. Fowler

"INTRODUCTIONHydrogen sulphide is probably the most toxic gas associated with crude oil. Hydrocarbon (petroleum) vapors themselves are harmful to the human system, but hydrogen sulphide, when present, is usually more important from the standpoint of health and safety. These conclusions were reached in an investigation of the toxic gases encountered in the transportation end refining of high-sulphur petroleum. The results of that investigation are presented in Bureau of Mines Bulletin 23l. although the writers of Bulletin 231 paid no direct attention to the production of oil in the field, they attributed to hydrogen sulphide reports of accidents caused by gas in the oil fields of Mexico.During the development of oil fields in Texas, a ""poison gas"" was encountered that constituted a decided health and safety hazard. The present report discusses an investigation of this gas made in July, 1926.The major portion of the investigation was conducted in the Panhandle field of Texas, but the study also includes the Big Lake and McCamey fields.Scope of WorkThe work undertaken in each field included:Examination of the gas-coming from representative wells at various locations in the field; also analyses of the gas-air mixtures to which the workmen were or might be exposed.Observation of symptoms of poisoning and severity of these symptoms."

Oct 1, 1926

By Gary L. Hundley

As part of the U.S. Bureau of Mines program to reduce the Nation's reliance on foreign supplies for critical metals, a procedure was devised to separate and recover critical metals from mixed and contaminated super alloy scrap. The process uses both pyrometallurgical and hydrometallurgical methods to treat the scrap. The mixed scrap is converted to a matte containing 4 to 7 pct S by adding S directly to the molten metal. This matte is then granulated and ground to a minus 35-mesh particle size and leached with an HCI-CI2 solution. This process takes essentially all the Ni, Co, Cr, Fe, AI, and Mo into solution in a 3-h leach, leaving W, Ta, Ti, and Nb (Cb) in the residue. The Mo is recovered from the chloride leach solution by solvent extraction, and the Cr and Fe are recovered together by precipitation. The Ni and Co can be recovered individually by an existing solvent extraction-electrowinning process. The W is recovered by a caustic leach of oxidized Cl2 leach residue.

Jan 1, 2010

By Kenneth L. Cashdollar

This report describes three types of optical dust probes that have been designed, built, and tested by the Bureau of Mines. Each of the probes measures dust cloud concentrations by the attentuation of light. The first is a single-path-length probe, the second is a double-path-length probe, and the third is a single-path-length probe that employs jets of air to keep the windows of the light source and detector free from dust coating. The theory of operation and the calibration procedures for each of the probes are described. The results of the Bureaus laboratory, mine, and field tests of the probes are also reported.

Jan 1, 1981

This NIOSH Toolbox Training program contains 52 different modules designed to stimulate safety discussions among your employees. Each module is intended to be completed in roughly 10 or 15 minutes, so a Toolbox Training session can be conducted once a week for the entire year. Each session counts toward your employee’s 8-hour annual MSHA refresher training, thus saving an entire day of work.. The modules are used to refresh employees on the procedures, policies, and practices of working safely at a specific mine site and can easily be tailored to fit conditions and situations found on your property. Every module follows the same format, so that as the weeks pass, miners will start to approach every safety situation in the same way. A typical Toolbox Training session contains five basic steps that cover all the information in the module. 1. Identification of the hazard and discussions about the types of injuries typically associated with the hazard. 2. Discussions of some of the causes of the hazard. The MSHA example included with each module should be referenced. 3. After the hazard and accident has been explained and understood, discussions about best practices and tips for avoiding a similar accident. 4. Review of similar conditions or near misses from your mine site using the leading questions on the form to start a discussion. Specific examples of equipment or structures on the site that could lead to the same accident should be discussed. The blank space on the module is used to add your own remarks and questions to supplement the given information. 5. Miners fill out the training record on the back of the form with name, initials, and date of training session. The modules are designed to be kept in a standard three-ring binder and easily photocopied. This way, the same set of modules can be used for years to come. A blank form is included that can be used to create more Toolbox Training modules. The key component of Toolbox Training is to start a discussion among employees that will allow them to see the hazards around them every day and respond to these hazards in a safe and consistent manner. To start a discussion, ask questions that need more than a one-word response. Get the miners to talk about similar situations from their own experiences and give suggestions about how to fix the hazards around them. Toolbox Training is a quick and effective way to cover specific mining hazards, but it only works if miners are involved in the discussion.

Jan 1, 2004

By Bertrand L. Johnson

Pure talc is a hydrous magnesium silicate (Mg3Si4010(OH)2). Pyrophyllite, although it resemble: talc in certain physical properties and uses, is a hydrous aluminum silicate (Al2Si4010(OH)2) - like kaolin, except that kaolin has a somewhat different composition (Al2Si205(OH)4) and structure. Soapstone can be considered essentially an impure talc grid when pulverized is used for many of the same purposes as talc. Massive, compact varieties of talc often are called steatite. PROPERTIES Talc and pyrophyllite are characterizes; by their softness (hardness on Mohs' scale, 1) their greasy feel, pearly luster, white color, and perfect basal cleavage. They have similar crystal structures, and this similarity explains the close resemblance of the two minerals in physical acid chemical properties. Talc is a good electrical insulator, resists the action of most acids and alkalies, and has an exceptional heat-retaining capacity. Its specific gravity is about 2.7.

Jan 1, 1939

By F. E. Block

This investigation was made as part of a larger program to develop basically new methods for preparing yttrium metal in high-purity form. It was performed under a cooperative agreement between the U.S. Atomic Energy Commission (AEC) and the Federal Bureau of Mines. Laboratory-scale tests were made to devise methods for preparing high-purity, anhydrous yttrium trichloride, for reducing the yttrium trichloride with sodium or lithium, and for consolidating the resulting yttrium sponge into ingots.

Jan 1, 1960

By Frank B. Fulkerson

This is the second of two interrelated studies of waterborne transportation. The first study discussed transportation of mineral commodities on the inland waterways of the South-Central States.2 Together, the two surveys describe and analyze the flow of foreign and inland waterborne commerce of the gulf coast. All the principal mineral-industry imports and exports of the gulf coast are mentioned in the report, including metals, nonmetals, and mineral fuel products, The gulf coast foreign trade in mineral industry products was determined to be composed of a small number of commodities.

Jan 1, 1971

By F. M. Goodwin, John Campbell, G. W. Jones

"INTRODUCTION In cooperation with the Boston Edison Co. and the Boston Consolidated Gas Co. of Boston, Mass., a survey has been conducted continuously since 1929 by the Bureau of Mines to determine the general hazards of combustible gases and vapors in manholes of the Boston Edison Co. The New England Telephone & Telegraph Co. also has cooperated in the investigation, and tests have been made in its manholes from May 1, 1933, to October 15, 1937. Yearly reports. 6/ on the results obtained since the beginning of the survey have been published.The methods and procedure of conducting the survey in 1937 were the same as heretofore."

Jan 1, 1939

By K. E. Stanfield

One of the initial projects under the oil-shale research and development phase of the Synthetic Liquid Fuels Act, Public- Law 290, 78th Congress, approved April 5, 1944, was a survey of oil shales of the United States for the selection of a site for an oil-shale demonstration plant. The oil shales were assayed by the conventional Bureau of Mines retort method proposed by Karrick and described by Guthrie in a more recent publication. From previous experience and that had in making these assays, it became evident that the assay method should be modified or replaced by a more satisfactory one. There are several outstanding objections to the Bureau of Mines oil-shale assay method: (1) the oil yields are frequently smaller than those obtained by other types of assay equipment and by commercial retorts; (2) the assayed oil yield represents only a portion of the organic matter in the shale, which under more favorable conditions, may, Jae converted, more completely into oil; (3) the retorting procedure is controlled mainly by trial-and-error methods; and (4) the assay requires approximately 6 hours for completion.

Jan 1, 1949

By Frank T. Greene

An investigation of the quenching behavior of coal dust-air flames was carried out. The literature relevant to coal dust-air flames was reviewed, including information on the agglomeration, sedimentation, and dispersal of dust clouds. The simple equations relating the various concentrations involved in dust flame propagation are given and their implications elaborated. It is shown that the concentration seen by a moving flame in a sedimenting dust cloud can differ significantly from the concentration commonly measured in such experiments. The known dust cloud phenomena which appeared significant in flame propagation studies were experimentally evaluated, and quenching diameters, flame speeds, and lean propagation limits for several tube diameters measured. For Pittsburgh seam coal, the Minimum Quenching Diameter (MQD) for dust between 10 and 20 µm was found to be between 0.7 and 0.8 cm, and the lean propagation for 3.2-cm tubes to be approximately 200 mg/liter. Similar MQD data were also obtained for Pocahontas and Sewell coals, Beulah lignite, and a 50-gal./ton oil shale. The effect of temperature, coal particle size, and propagation tube material were also investigated.

Jan 1, 1981

By John Nagy, Austin R. Cooper, Murray Jacobson

Data obtained in the Bureau's study of dust explosions of 313 elemental metals , alloys , catalysts , and ores comprising 54 types of material are summarized . Information is given on ignition temperature , spark energy for ignition , minimum explosion concentration , explosion pressure , rate of pressure rise , and in some instances , the admixed inert dust and oxygen concentration in an atmosphere required to prevent ignition of dust dispersions . The effects of particle diameter on explosibility and pyrophoricity are also discussed .

Jan 1, 1964

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By Launa G. Mallett, Kathleen Kowalski-Trakofler, Robert H. Peters, Charles PH. D. Vaught, Peter Keating, William J. Wiehagen

On-the-job training is a common means of training or retraining workers and the practice may seem simple and straightforward. Doing it effectively however requires more thought and preparation than simply having someone follow an experienced worker around and watch what they're doing. Over the years, various techniques and practices have evolved that pass on the skills and knowledge of a trainer or coach in a manner that leads an inexperienced trainee to really absorb the information being taught. On-the-job training thus becomes less a haphazard show-and-tell and more a real transfer of information. The goal of this document is to describe how to develop or manage an on-the-job training program so that information is passed on from trainer/coach to trainee efficiently and effectively. By efficient is meant the best use of time and resources of all those involved in the training process, and by effective is meant that the trainee truly learns the skills and internalizes the knowledge needed to perform the job well. The first part of the document discusses topics to think about when developing a formal on- the-job training program. A structure based on coaching is suggested. Then a workshop designed to prepare trainers as coaches is described. Workshop materials include an instructor’s guide and trainee workbook. These materials can be used to train coaches and to assist trainees as they go through the learning process. Content related to specific jobs can be added to these materials to create targeted on-the job-training manuals. Structuring a formal on-the-job training program It is likely that some form of on-the-job training (OJT) is being conducted at your workplace. The formality of that training can range from a structured program to an informal “follow Joe around” method. If your program is completely unstructured, it may not be meeting current training needs. Worse, it may perpetuate bad habits and create “trained” employees who are not given the same information or evaluated to the same standards. Wiehagen et al. comment that, “Success in using unplanned OJT is usually dependent on the luck of the draw, that is, whether the informal trainer is competent at the task he or she is teaching, is motivated to teach, can organize the job into logical components, and knows something about good practices in teaching and evaluating” (2002, p. 27). It is only through planning a structured OJT program that consistency can be created and maintained. At the least, all trainees who have successfully completed such a program can be expected to perform at an established level—they will know what they must do to be successful.

Jan 7, 2005

Create two air splits along the longwall face to isolate the shearer-generated dust to the immediate face area, maintaining a cleaner split of air in the workers' walkway.

Jan 1, 1994

By I. Iwasaki

In recent years the rapid depletion of high-grade iron ores and the demand by blast furnace operators for increasingly low-silica ores have stimulated interest in flotation studies of low-grade iron ores, such as wash-ore tailings and oxidized taconites. Four processes have been reported for the flotation separation of these iron ores--anionic and cationic collection of the iron oxides, cationic collection of siliceous gangue, and anionic collection of activated siliceous gangue (5).5/ The effectiveness of any one method, however, depends largely on the mineralogical composition and on the physical structure of the sample; hence, a comprehensive study of the floatability of the individual minerals occurring in these materials is essential. A review of the literature shows that the floatability of hematite and magnetite has been frequently investigated, whereas very little corresponding information is available for goethite, or for its more earthy form, limonite, both of which are abundant in the Mesabi and Cuyuna ores (19). The purpose of this investigation was to formulate general information on the floatability of goethite. Vacuum flotation, contact angle measurement, and simplified flotation tests using a modified Hallimond tube were used. The experimental results were correlated with the electrokinetic properties of goethite as determined by streaming potential measurement. The results were used to interpret the batch flotation tests made on an artificial mixture of quartz and goethite.

Jan 1, 1960

By C. C. Stevenson, Thomas Varley

"The art of treating ores by the chloride volatilization process is still in the experimental stage. The process has not been sufficiently developed along chemical and metallurgical lines to state definitely just what place it will occupy in the metallurgical industry. The theory upon which the process operates has received the attention of prominent metallurgists for the past twenty years, and research and experimental work has been conducted by many investigators.Much of the experimental work done has never been published, and it seems that the accumulation of such results if made known would be an important aid to the further development of the process. The object of this paper is, therefore, to bring salient features of the process to the attention of the metallurgical industry, both for the purpose of furnishing information, and receiving from interested parties any comments which the reading of this article may suggest. A bulletin covering the work done at the Intermountain experiment station of the U. S. Bureau of Mines, situated at Salt Lake City, Utah, is in course of preparation.The chloridizing roast is usually accompanied by appreciable losses due, to the volatilization of the metals as chlorides during the roast, these losses often running as high as 30 per cent, depending upon the temperature, the character of the ores and the associated gangue material. It was not until 1891 that Croasdale, (Croasdale, Stuart, Engineering and Mining Journal, Aug. 29 1903) by observing this and stack deposits from the chloridizing roast, recognized the possibility of making volatilization a major instead of a minor feature of the roast. He then made tests on a large number of tires from different, localities, the result of which showed the, general application of the process. The main difficulty, as stated, by Croasdale, was the lack of a suitable means for recovering the fume from the furnace gasesIn 1913, Cottrell (See Mining and Scientific Press, March 29, 1913; alsoTrans. American Institute of Mining Engineering, September 1918. (Additional informa-tion is available from the owners, The Research Corporation of New lark, and Western Precipitation Co., .Los Angeles, Calif.), announced his invention of the electrostatic precipitator, which solved the problem of separating the solids from the furnace gases."

May 1, 1921

Improve the safety and comfort of operators of large mining equipment. Approach Develop an improved driver restraint system that is easy to use, reliable, and cost-effective, while providing increased protection in the event of a collision or rollover. The Novel Restraint System There are several problems associated with conventional lap-belt type restraint systems. Among these are: restriction of movement, lack of comfort, and fear of entrapment. Standard seatbelts become dirty and oily from lying on the vehicle cab floor and can ruin a driver's clothes. Some haulage equipment may not even have seatbelts available to drivers since they are sometimes removed during maintenance activities or as a result of vandalism. Recognizing a need to address such problems by providing a more acceptable means of driver restraint, the Bureau of Mines designed and fabricated a novel vest-type restraint system. The vest is designed to be worn during a driver's 8-hour shift and would be issued much like safety glasses, hard hats and safety shoes, thus becoming part of the operator's individual protective equipment and assuring that each vehicle has a restraint system when in operation. The vest-

Jan 1, 1985