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By M. Vanpée, H. G. Wolfhard

Jets of hot gases issuing into explosive gaseous mixtures are efficient agents of ignition . The ignition temperature is defined as the temperature of the jet as it enters the cold explosive mixture which is just high enough to produce ignition . Such data have been published recently.5/ The investigators note especially that no correlation seems to exist between hot - gas ignition temperatures and spontaneous ignition temperatures , although there is a rather loose relation with limit flame temperatures . Before a more quantitative theory of the hot - gas ignition process can be attempted effectively , several questions must be answered : ( 1 ) Can the reactions leading to ignition be described by an Arrhenius type activation energy? ( 2 ) Is ignition preceded by an induction period ? ( 3 ) What is the rate - determining process of the ignition ? (4) And how does turbulence affect this type of ignition ?

Jul 1, 1960

By R. P. Beyer

Low-temperature heat capacities and standard enthalpy of formation of copper difluoride (CuF2) were determined by the Bureau of Mines. The low-temperature heat capacities were determined from 11 to 302 K by adiabatic calorimetry. The enthalpy of formation was determined by HC1 solution calorimetry. The standard values of entropy (S°) and enthalpy of formation (?Hf°) at 298.15 K are l8.65±0.03 cal/deg mole and -129.02±0.29 kcal/mole, respectively.

Jan 1, 1978

By M. W. Pullen

It is recognized that the determination of electrical resistivity of the earth within a given area may furnish information concerning the location of certain mineralized strata of economic importance. Present knowledge of the electrical resistivity of the various rock formations is almost nil, and the geophysicist who is detailed to make a survey of an area without any data as to the relative resistivity of the underlying rocks is greatly handicapped. Such surveys are usually made within areas known to contain mineral deposits to aid in locating desirable points for drilling. Usually these areas have been prospected by diamond drilling, and drill cores of the various rocks and ores are usually obtainable. Were it possible to make resistivity tests in a laboratory of the drill cores or from pieces of the rocks and ore within an area before attempting a field survey, this would indicate not only the advisability for such a survey but would aid considerably in the interpretation of the results of such a survey. To be of most value a definite method should be used for all such tests, and as yet such a method has not been established.

Jan 1, 1929

By THEO L. JOHNSTON

In preparing for war , Japan built an iron and steel industry that ranked high with other industrial nations . Deficient in raw materials for making iron and steel , it had to acquire the bulk of its iron ore and much of its coal and scrap iron from foreign sources . Steel manufacture, and fabrication , however , were reserved mostly for the Home Islands , where modern integrated plants produced the implements of war . The vulnerability of relying on imports during the war was recognized early, and steps were taken to exploit iron-ore deposits and develop treatment processes on the Home Islands in order to be as self - sufficient as possible . Although the industry had expanded considerably, the capacity of the large plants still was insufficient for military requirements, so other meth- ods of producing iron and steel were adopted, which in some ways illustrate the desperate effort made to supply the war machine. In developing the iron and steel industry, modern practices of other countries were studied and followed with modifications to suit Japanese con- Aitions. German and American technical ability and equipment played a large part in the program; however, the Japanese had competent furnace technologists capable of obtaining proper equipment performance. For the most part, the standard practice consisted of smelting iron ores in blast furnaces and then refining the pig iron to make steel in open-hearth furnaces. Electric furnaces played an important part, especially in the manu- facture of alloy steels. Various other methods yielded minor but significant production. Among the various other treatment processes used, the production of sponge iron in rotary kilns 'probably was the most important in producing melt- ing stock for steel making. Of special importance was the fact that sponge iron made from low-grade ores contained critical metals, such as nickel and chromium, so that the results were more significant than was generally believed.'

Mar 1, 1948

By S. H. Ash

THE MAGNITUDE of the drainage problem of the anthracite industry in Pennsylvania's Western Middle field is realized when it is known that in 1951 nine pumping plants in this field pumped nearly 36 billion gallons of water to the surface. This is almost 68,000 gallons per minute pumped against an average hydrostatic head of 350 feet for that year alone. In 1948 over 20,000 gallons per minute was pumped by relay pumps against an average hydrostatic head of 265 feet. In addition to the water pumped to the surface, it is estimated that 15,000 gallons per minute overflows to the surface from underground pools in idle mines. The volume (second-feet) of water pumped and overflow water is almost 1;z times the, average mean flow of the Schuylkill River at Pottsville for the 8-year period 1944--51 (7, 13).4 Mahanov and Shamokin Creeks drain an area of 99 square miles in the Western Middle field, and all surface drainage in this area must traverse some part, of the coal measures before entering these streams. On the basis of 46.03 inches of rainfall (the weighted average of 6 recording stations for 1948), the runoff from the drainage area during that period was 51 billion gallons, approximately 1 times the volume of water pumped by all mine-pumping plants in the Western Middle field. In other words, because of the pervious strata overlying the mine workings, approximately two-thirds of the total runoff in the drainage, area becomes mine water tributary to the pumping plants.

Jan 1, 1953

By Robert E. Hershey

1. This investigation shows that the most important beds in Claiborne County, from the standpoint of present production and reserves, are the Coal Creek and Jellico. Together, they contain 69 percent of the known recoverable reserves in the county. Reserves in five other beds are tabulated in this report; in order of quantity of reserves, they are: Blue Gem, Lower Pioneer, Pewee, Big Mary, and Rex. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated to be 60 million tons, as of January 1, 1953. Of this total, 55 million tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to permit making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By Robert N. Roby

"The Moffet-Johnston property was investigated by the Bureau of Mines with the object of determining the presence of ore reserves that might be utilized during the war emergency. Preliminary examination was made during May and Juno 1943, as a result of which the Johnston 'tunnel was cleaned out and repaired, the .mime was surveyed, and a small program of exploration was undertaken. This report describes the work performed and presents the data obtained.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts prelimi¬nary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs benefication tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.The chemical and spectrographic analyses were made at Reno, Nov., under the direction of A. C. Rico, acting engineer in charge, Rare and Precious Metals Experiment Station, Bureau of Mines. The ore-dressing tests were under the direction of Rollien R. Wells, metallurgist, at the Salt Lake City laboratories of the Bureau of Mines.The author acknowledges the cooperation and assistance of the lessee of the property, H.R. Hakes, who furnished nine reports and other information.The Moffet-Johnston property is in secs. 2 and 3, T. 3 S., R. 5 W., in the Tidal Wave mining district of Madison County, Montana.The portal of the Johnston adit is near the mouth of Bear Gulch, 9 miles northeast of Twin Bridges, Mont. It is reached by an improved dirt road that serves mining properties farther up Bear Gulch. The Moffet mine and the Mountain View shaft are now accessible from the Bear Gulch road over an access road recently completed by the U. S. Grazing Service. The Grazing Service road has also been supplemented by bulldozer trails built by the Bureau of Mines.An electric-power line extends from the Montana Power Co's substation at Twin Bridges to mines at the head of Bear Gulch and passes within 200 feet of the Johnston portal.The claims of the Moffet-Johnston property were located about 1900. A report by H. V. Winchel, consulting geologist, in 1904 indicates that most of the development on the Johnston adit was completed by that date. At the time of the Winchel report, the Moffet workings had just penetrated the first ore shoot (fig. 4)."

Sep 1, 1946

By M. A. Trevits

During the time period from 1990-2007, 1601 reportable fires occurred in the U.S. mining industry (an average of 89 fires per year). The leading causes of U.S. mine fires were flame cutting and welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions, and spontaneous combustion. The fact that mine fires continue to occur with an alarming regularity reinforces the importance of recognizing and eliminating the potential hazards and the overall need for improved fire control and suppression technology to ensure the best possible outcome during a mine fire. The National Institute for Occupational Safety and Health (NIOSH) is conducting an evolving comprehensive program of research that is addressing mine fire prevention, detection, management and suppression. This paper presents a summary of recent research accomplishments and provides an overview of the next phase of the NIOSH mine fire research program.

Jan 1, 2008

By Clarence A. Wright, JAMES T. NORTON, JAMES G. PARMELEE

The object of this paper is to give to mining companies and to all others who are interested some idea of the possibilities in the treatment, by differential flotation, of lead-zinc ores of the Coeur d'Alene region and other districts. The purpose of these investiga.. tions is not to evolve a differential flotation process that would replace present methods of gravity concentration but rather one that could be applied to the relatively fine material and slime produced in the mills and treated unsuc_pessfully by gravity methods or by flotation. It is expected, of course, that the products to be obtained by differential flotation would be of much better grade than those now produced by flotation in the Coeur d'Alene mills. In view of the fact that it has been difficult to obtain representative samples of flotation feed from the mills, owing to the necessity of shipping the material wet and free from oil or other foreign matter that might be deleterious to the differential separation of the sulphides, the writers have felt justified in running flotation tests with the mill feeds in order to ascertain whether a differential separation of the sulphides could be effected. However, two different lots of flotation feed were tested for differential flotation, and the results of tests of one of these are given in this report. It is hoped that it will be possible later to test out the flotation feed for differential flotation on a large scale in some of the mills. This paper covers part of the investigations carried on by the United States Bureau of Mines in cooperation with the Idaho Bureau of Mines, the University of Idaho, and certain mining companies of the Coeur d'Alene region. Although the results of the tests included in this report are not to be considered final, they indicate possibilities and may suggest others leading to a solution of the problem of separating lead and zinc sulphides by differential flotation in the treatment of certain ores.

Jan 1, 1921

By N. S. Dalal, V. Castranova, X. Shi, W. Wrr, V. Vallyathan

"SUMMARY Data presented here indicate that freshly fractured silica exhibits surface characteristics and biologic reactivity distinct from aged silica, and on this basis we propose that these surface features may lead to enhanced manifestations of lung Injury. Grinding of silica produces ~10"" Si and SI-O (silicon-based) radicals per gram of dust on the particulate surface which are characterized by an electron spin resonance (ESR) spectrum centered around g = 2.0015. These silicon-based radicals react with aqueous media to produce OH radicals, which are demonstrable using a DMPO spin trap. The concentration of silicon-based radicals in silica decreases with aging in air and exhibits a half-life of ~30 h, whereas its ability to generate OH radicals in aqueous solution decreases with a half-life of ~20 h. However, on storage in aqueous media, the concentration of silicon-based radicals end the dust's ability to generate OH radicals decrease significantly within a few minutes. Freshly ground silica is also more biologically reactive than aged silica, because freshly crushed silica activates a greater respiratory burst In alveolar macrophages than aged silica, i.e., storage of ground dust in air decreases silica-Induced superoxide anion secretion, hydrogen peroxide release, and NBT reduction by 25%, 68%, and 43%, respectively. Furthermore, compared to aged silica, freshly ground silica exhibits a greater cytotoxic effect on cellular membrane Integrity, i.e., a 1.5-fold increase in LDH release from macrophages, a 36-fold increase in hemolytic activity, and a three-fold increase in the ability to induce lipid peroxidation. Because acute silicosis is frequently associated with occupations in which freshly fractured crystalline silica of respirable size is generated, the present study suggests that fracture-generated silicon-based radicals may play a significant role in the pathogenesis of this disease. AM REV RESPIR DIS 1955; 133:1213-1218IntroductionOccupational exposure to crystalline silica can be associated with either chronic or acute pulmonary disease. Chronic silicosis becomes manifest 20 to 40 years after first exposure and is characterized by development of concentric hyalinized nodular lesions in the lung with the de-velopment of dyspnea over a period of several decades. Acute silicosis, on the other hand, is manifested by a rapid on-set after exposure and is characterized by the accumulation of an amorphous granular lipoprotein exudate in the airspaces and rapid development of respiratory disability within a few years (1-3).Information is growing concerning the etiology of chronic silicosis. Studies sug-gest that several mechanisms may be in-volved in the development of fibrosis. Lung injury may result from silica-induced release of lysosomal enzymes from alveolar macrophages (4, 5). In ad-dition, silica-induced activation of su-peroxide anion and hydrogen peroxide release from alveolar macrophages may result in oxidant-induced damage to lung parenchyma (6). Silica exposure can also result in the release of mediators from alveolar macrophages which enhance the proliferation of fibroblasts and the syn-thesis of collagen by these pneumocytes (7, 8)."

Jan 1, 1988

By R. S. Dean

[Methods s of preparing the manganese metal that has been used in chemical and metallurgical investigations have passed through a cycle. Most of the investigations made before the turn of the century, used Moissen's pyrophoric manganese.3/ This material was made by electrolysis into a mercury cathode and distillation in vacuo. The material was essentially pure, and investigations in which it was employed (with proper precautions against oxidation) led to accurate results on tie intrinsic behavior of metallic manganese.]

Jan 1, 1941

By Perry G. Cotter

As a portion of a general program for the synthesis of hard materials, a method was sought by which the hardness and density of tungsten carbide (WC)-cobalt compacts could be increased. It was demonstrated by Cotter that these improvements in quality could be made by employing an electric-resistance sintering process in which heat and pressure are applied simultaneously to presintered compacts composed of powdered tungsten carbide and cobalt. This conclusion was based on tests of material prepared by Cotter on welding equipment in use at the U. S. Naval Engineering Experiment Station, Annapolis, Md., and at Rensselaer Polytechnic Institute, Troy, N. Y. Rockwell-hardness tests made at Norris and core-drilling tests made at the Mount Weather Station of the Bureau of Mines indicated that, for some purposes, carbide material made by this process might be superior to the chemically analogous commercial products prepared by ordinary sintering methods. A program to develop optimum conditions for the electric-resistance sintering of tungsten carbide-cobalt compacts was initiated. The program was followed by a systematic evaluation of the hardness and density of compacts prepared by this method along with a series of carbide compacts furnished by various manufacturers. This paper presents a description of the electric-resistance sintering of tungsten carbide-cobalt compacts and the results of comparative physical tests.

Jan 1, 1955

By W. L. Acherman

Molybdenum, tungsten, and vanadium were found by the Bureau of Mines to possess generally superior chemical and galvanic corrosion properties in many aqueous corrosive media at temperatures up to the boiling point. The corrosion resistance of vanadium in certain solutions was further improved by alloying it with such metals as columbium, tantalum, and titanium. was susceptible to a type of crevice corrosion in mercuric chloride solutions, but no other instances of crevice corrosion were encountered. With few exceptions, molybdenum, tungsten, and vanadium were not adversely affected when coupled with dissimilar metals in galvanic corrosion experiments; in some cases one or both members of a couple were protected by contact. When exposed to aqueous ammonia spray at 60° C, all three metals were attacked, but they were moderately resistant in spray environments of substitute ocean water and ammonium dihydrogen phosphate.

Jan 1, 1966

By J. M. Stuve

This Bureau of Mines investigation measured the low-temperature heat capacities of FeOC1(c) and FeC13(c) in the temperature ranges of 6 to 305 K and 4.6 to 300 K, respectively. The standard entropies (S°, 298.15 K) of FeOCl(c) and FeC13(c) were derived as 19.73±0.03 cal/deg-mole and 35.33±0.07 cal/deg-mole. A large lambda transition was observed in the heat capacity of FeC13(c) at 8.4 K. The standard enthalpy of formation (?H°f, 298.15 K) of FeOC1(c) was determined to be -98.23±0.22 kcal/mole by HC1 solution calorimetry. High-temperature enthalpy measurements (H-H298.15) of FeOC1(c) were determined to 700 K by precision drop calorimetry. Standard thermodynamic formation data and related functions were tabulated at various temperatures for FeOC1(c) and FeC13(c).

Jan 1, 1980

By P. L. Woolf, J. P. Morris, E. Foerster, G. R. Zellars

Measurements of vapor pressure can be used to determine the thermodynamic activities of the components of metallic solutions . The determination of activity by this method requires accurate values for the vapor pressure of the pure component and for its partial pressure above the alloy solution . This investigation was conducted to measure the vapor pressure of liquid manganese for use in future studies of the activity of manganese in various liquid alloys . In related investigations in the Bureau's Pyrometallurgy Laboratory , vapor pressures of copper , iron and nickel have been measured and activit 4 5 6 have been determined in the iron- copper and iron- nickel systems . Difficulties were experienced with manganese which were not encountered in the previous investigations . Manganese oxidizes readily and greater care was needed to maintain an oxygen- and moisture - free atmosphere in the furnace . In addition , liquid manganese wet the refractories and there was a tendency to foam and splash on introduction of the carrier gas . Because of these difficulties several variations in the experimental procedure were studied . These were first tested with silver which has a vapor pressure of the same order of magnitude as manganese but is relatively inert at high temperatures . Although no significant changes in the original procedure resulted from this work, considerable data were obtained for silver and have been included in this report . Bauer and BBrruunnnneerr7/ have reported the only extensive investigation of the vapor pressure of liquid manganese . However , their results are not consistent with the data obtained by McCabe and Hudson for solid manganese . Measurements of the vapor pressure of silver have been reported by McCabe and Birchenal1,2/ Schadel and Birchenall , 10/ Harteck , 11 / Fischer , 12/ and von Wartenberg.13 / Generally , these investigators conducted their measurements at lower temperatures than were used in this study .

Jul 1, 1960

By Don Steffa

Drift mining, according to California mining terminology - and it is distinctly a California development - is the blocking out and extraction (breasting) of the auriferous gravels of an ancient buried stream either through tunnels, inclines, or shafts; it is one of the minor divisions of the larger classification known as placer mining. The contribution of each of these divisions and of lode mining to the gross production of gold in California totals as follows:3 [ ] The total amount of gold recovered from the placers of California from 1848, when Marshall discovered the precious metal in the mill race at Coloma, to 1928, was $1,226,515,404. The same period saw a total gold production from all operations of $1,823,562,360.

Jan 1, 1932

By W. L. Cornell

The Missouri Pb ores are the only domestic Co resource being mined and processed for other metals; therefore, they present a viable short-term opportunity for Co production. Lead, zinc, and copper concentrates are produced from the ore. The Cu concentrate can contain up to 30 pct Co and the Pb concentrate up to 15 pct Co. Since Co is detrimental to the processing of the Zn concentrate; the remainder of the Co is rejected to the tailings. The tailings can contain as much as 50 pet Co originally present in the mined ore. Researchers at the U.S. Bureau of Mines have successfully tested on a continuous basis a process that recovers a bulk sulfide concentrate from mill tailings. The concentrate contains up to one-half of the Co and from 50 to 90 pct of the Pb, Zn, and Cu. Concentrate weight represents 10 pet or less of the total tailings.

Jan 1, 1989

By Robert K. Koch, Henry E. Blake

Laboratory tests were made to determine if aluminum fluoride of commercial grade could be synthesized by reacting alumina hydrate with dilute ( 25 to 75 grams per liter of fluorine ) aqueous fluoride solutions . • Products containing up to 90 percent aluminum fluoride ( A1F ) were synthesized by reaction of alumina trihydrate ( A120 3H2O) with either dilute hydrofluoric acid ( HF ) or ammonium fluoride ( NHF) solutions , the ammonium fluoride solution resulting from ammonia ( NH ) desilication of a hydrofluoricfluosilicic acid ( HF - H₂ SiF ) solution . Fluorine recoveries of over 80 percent were obtained with either type of solution . The hydrated precipitates of AlF, and ( NH4 ) , A1F ( ammonium aluminum fluoride ) obtained by reacting hydrated alumina with these solutions were subsequently converted to anhydrous AlF, by controlled heating .

Jan 1, 1964

By K. O. Bennington

Cancrinite is one eonstituentof "red muds," a high-volume waste product of alumina production by the Bayer process. The Bureau of Mines determined the thermochemical properties of cancrinite as part of a program to provide such data for minerals of industrial importance. Cancrinite [Na7.68(A16Si6024)(N03)1.68 (H2O)4.1] was synthesized by reacting aluminum silicate gel with a solution of NaOH and NaN03, and the composition was determined by chemical analysis, differential scanning calorimetry, and thermogravimetric analysis. The heat of solution was determined by hydrofluoric acid solution calorimetry. The standard enthalpy of formation at 298.15 K, ?Hf°298, is ?Hf°298 = -3,487.97 ±2.6 kcal/mol, and the standard enthalpy of formation from the oxides and NaN03, ?H°298, is ?H°298 = -215.20 ±l.8 kcal/mol.

Jan 1, 1983

By Rogers F. Davis

This publication has been prepared to supply manufacturers and industrial users a listing of mobile diesel-powered equipment and subassemblies approved and certified by the Bureau of Mines for use in nongassy noncoal mines and tunnels. This revised and supplemented listing supersedes an earlier publication2 released in 1963. Testing of diesel-powered equipment is one phase of the Bureau's program of health and safety that concerns approval of electrical and diesel equipment designed to prevent explosions, fires, shocks, or toxic hazards in underground mines, when such equipment is used and maintained properly. Manufacturers submit machinery and component parts to the Bureau for study of their design, safety features, and use. Equipment must pass exacting tests and must meet strict requirements established through research and experience and outlined in the Bureau's permissible schedules before the Bureau approves it for safe use in mines.

Jan 1, 1968