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By C. E. Coleman, Joseph D. Davis

During some distillation experiments conducted by the Bureau of Mines in cooperation with the Trent Process Corporation it was observed that amalgams of heavy petroleum oils and finely pulverized coal tended to produce a denser coke than that obtainable from the coal when retorted alone . Even anthracite coal when retorted with oil yielded a coke . This led the writers to believe that by mixing a lowrank coal ( sub-bituminous or even lignite ) - with asphaltic oil and retorting it, a coke suitable for domestic fuel could be made . Thus there was contemplated the production of domestic coke and the utilization of a low- grade oil in one operation . - In order to decide on the practicability of this process , it was necessary to know the value of products obtainable by such a method , as compared with those obtained by separate distillation . A laboratory method was therefore devised , and while it was realized that no small - scale testing apparatus for destructive distillation gives results that are directly applicable to commercial - scale operations , by keeping distillation conditions uniform for comparative tests , results were obtained valuable for purposes of comparison . The plan was to distill mixtures of coal and oil in a laboratory retort , and then distill the constituents separately under the same conditions . The comparative quantities of products yielded were thus directly obtained , and their quality was determined by analysis . The following are the main points investigated : ( 1 ) Quantity and quality of coke ; ( 2 ) Quantity of oils boiling below 221 °C . ( gasoline stock) and oils boiling at 221 to 300° C . ( kerosene stock) ; and ( 3) Quantity and quality of gases .

Jan 1, 1922

By John T. Neubert

Between 1988 and 1990, the U.S. Bureau of Mines studied the mineral resources of San Juan National Forest to appraise and determine types and locations of deposits that could be mined economically now and in the foreseeable future. The study included a comprehensive field examination and literature search. Substantial amounts of lead, zinc, copper, gold, and silver have been mined from within the Forest in the La Plata, Rico, Silverton, and Dunton areas. At least one buried 200 million ton stockwork molybdenum deposit occurs in the Rico area. Similar size porphyry copper deposits occur at the surface and about 1,700 feet below the surface in the Bedrock Creek area of the La Plata district. Numerous smaller base-and precious-metal and uranium deposits have been prospected and mined throughout the Forest. Coal, oil, and gas have been or are currently being produced in the western and southern parts of the Forest. Carbon dioxide occurs in the western part of the Forest. Strategic elements occurring within the Forest include platinum, palladium, cadmium, gallium, indium, bismuth, and tellurium; however none of these elements is economically recoverable at present. Several geothermal areas are scattered across the eastern two-thirds of the Forest. Industrial minerals within the Forest include sand and gravel, limestone, and decorative stone.

Jan 1, 1992

By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESRJ spectrum of the hydroxyl (· OH) radical spin adduct with .the spin trap 5,5-dimethyl-1-pyrrolintt-N-oxide has been obtained in suspensions of freshly ground quartz particles. The concentration of the spin adduct (and hence of the • OH radicals) increases with the amount of grinding. The dust's potential for the generation of the· OH radicals is maximum when fresh (i.e., immediately after grinding) and decreases to 50% in about a day on storage in air. Studies involving metal chelates .indicate that the • OH radical formation involves mainly the silica surface and H20 rather than the Fenton reaction. The results suggest that hydroxyl radical reaction(s) could be important in the lipid peroxidation and fibrogenicity by quartz dust, particularly .in acute silicosis. INTRODUCTIONIn this paper we report on our electron spin resonance (ESR) detection of the formation of hydroxyl (·OH) radicals in aqueous suspensions of freshly crushed quartz particles. This work was undertaken with a view to find possible clues to the role of free radicals in the pathogenesis of quartz-induced fibrogenicity, commonly known as silicosis. We noted that while silicosis is one of the major health hazards in coal and mineral industries, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still poorly ·understood (Reiser and Last, 1979; Singh and .Rahman, 1987). It is generally thought, nevertheless, that the action of quartz particles on the biological membranes is the starting point of the silicotic process (Parazzi et - al., 1968). A possible clue to the mechanism of the membrane damage by quartz particles, in terms of the role of oxygenated free radicals, is suggested by the following observations. A suspension of quartz particles in contact with alveolar macrophages has been reported (Gabor et al., 1975; Koike et al., 1982) to initiate an enhancement of lipid peroxidation, defined broadly as the oxidative deterioration of polyunsaturated components of lipids. Hydroxyl (· OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (Halliwell and Gutteridge, 1985) and of initiating lipid peroxidation in lysosomal membranes. (Fong et al., 1973). Arong other lines, it is known that exposure of cell membranes, fatty acids, and unsaturated food oils to ionizing radiation, which generates· OH radicals, causes rapid peroxidation (Halliwell and Gutteridge, 1985). Thus • OH radicals (and also other oxygenated species such as Oi, 10 2, and H20 2) might be expected to play a role in the toxicity of quartz. Earlier studies of the aqueous chemistry of quartz suspensions have reported detection of H2O 2 (Kalbanev et al., 1980), implicating the formation of ·OH radicals as transient species. However, we are not aware of any report of the detection of • OH radicals in quartz reactions, and thus the present study was undertaken. Since it-is known that, because of their high reactivity (hence short lifetime) in aqueous media, the • OH radicals cannot be detected via ESR directly (Finkelstein et al., 1980; Buettner, 1982) we have used .ESR combined with the spin-trap methodology (Finkelstein et al., 1980) for studying the· OH formation. The results show that· OH radicals are indeed formed in aqueous suspensions of freshly ground quartz; thus pointing to ·a possible new clue to the cytotoxicity of freshly formed quartz particles and thereby to silica fibrogenicity."

Jan 1, 1988

By D. B. Gawthrop

"One of the properties of an explosive, of interest to the user, is its ability to transfer detonation across an air gap to another explosive charge. This Property is of particular importance with permissible explosives used in coal mines, since they are relatively insensitive to detonation when compared to many of the commercial dynamites used in metal mining.An essential characteristic of an explosive is that it shall always be sufficiently sensitive to propagate detonation completely. An insensitive explosive constitutes a hazard because of (1) the danger of drilling into unexploded portions of charges of explosives which have partially misfired, and (2) the likelihood of a low order of detonation, or the burning, of all or part of the charge in a hole prepared for blasting. The latter condition not only usually produces large volumes of poisonous gases, but it is particularly hazardous in gassy or dusty coal mines where explosions may result.The Bureau of Mines and manufacturers of explosives determine the sensitivity of explosives to detonation over an air gap by means of a [(halved-cartridge gap test,"" for which the ends of the cartridges of explosive exposed to one another, are cut off. Since in blasting, the crimped ends remain on the cartridges used, this investigation has been made to ascertain the effect of the crimped paper ends on the distance detonation is propagated over an air gap as compared with the propagation distances obtained when the crimped-paper ends are removed."

Nov 1, 1932

By T. J. McDonald

The methods used and the results obtained in the application of high-expansion foam on a recent fire in an operating mine in western Pennsylvania were reviewed. This is the first instance where foam has been applied extensively to a fire under actual mining conditions although considerable research has been conducted and experimental fires have been controlled. The Bureau of Mines began investigating the foam-plug technique in 1957 in its experimental coal mine, following reports of successful trials in Eng-land, where the basic methods, using the normal ventilating current, were developed. Early in the research it was apparent that the normal ventilating current in mines in the United States would not provide adequate air pressure to drive a foam plug the distance that might be required. Subsequently, the Bureau of Mines developed a portable high-expansion foam generating unit consisting of a fan having relatively high pressure potential, net, sprays, and metering equipment. To date, foam generators have been constructed by the Bureau, by at least one operating coal company, and by one manufacturer of safety equipment. A number of units from the latter supplier have been adopted by coal-mining companies as an integral part in their firefighting installations.

Jan 1, 1961

By Robert C. Dyni

The use of techniques and equipment designed to pneumatically place backfill into an underground mine opening through boreholes for subsidence abatement has historically met with limited success, largely due to the inability to directly monitor the placement of the backfill in the opening. The success of a backfilling project cannot be guaranteed if it is not known whether the underground opening has been completely filled with backfill material. To overcome the inability to directly monitor backfill placement, the U.S. Bureau of Mines developed a pneumatic backfilling system that allows for direct viewing of the backfill as it is placed in an underground mine opening. This system utilizes a recently developed pneumatic nozzle coupled with an instrumentation package that allows for real-time observations and measurements of backfill placed in an underground opening through a borehole. The nozzle utilizes a high-velocity airstream to redirect backfill falling through a pipe in the borehole and directly in front of the nozzle; the airstream redirects and propels the backfill horizontally into the .mine opening at over 100 ft/s. The instrumentation package, mounted directly to the nozzle, contains a video camera, high-intensity lamps, laser-rangefinder, electronic compass, and water sensor.

Jan 1, 2010

By S. R. Zimmerley, C. H. Schack

"INTRODUCTION The pilot-mill concentrator at Boulder City, which has a nominal capacity of 40 tons per day, was planned and built to investigate further the beneficiation of domestic manganese ores that have been concentrated successfully in the ore-dressing laboratory. As milling of manganese ores in general is a new field, it is necessary to prove the success of laboratory processes by means of large-scale operations employing standard milling equipment, and thus to obtain engineering and metallurgical data essential to designing and operation of full-scale concentrating mills.The first ore tested in the pilot plant was the Three Kids Annex manganese ore from the Las Vegas Wash area 15 miles southeast of Las Vegas, Nev. The deposit was worked for its high-grade ores during the First World War From 1930 to 1939, 4,500 feet of diamond drilling was completed by a private company. Diamond drilling started by the Bureau of Mines in November 1940 and completed in July 1941 aggregated 6,600 feet. Exploration by the private company and the Bureau outlined reserves of about 1,000,000 tons of ore assaying plus 28 percent manganese. A much larger tonnage of lower-grade ore also was outlined by the drilling.Because of its physical nature, the Three Kids Annex ore had long proved unamenable to concentration by ore-dressing methods. The ore is a mixture of manganese oxides (wad) filling the pores and to some extent replacing a silt composed of very fine grains of volcanic tuff, quartz, feldspars, other silicates, and clay. Some gypsum occurs as fillings along fracture planes. The ore is light and very porous. Upon wetting, it disintegrates into granular but friable particles and a large amount of slime. It is these characteristics that make the ore so difficult to concentrate."

Sep 1, 1947

By D. W. Bridges, Donald R. Peterson, Masami Hayashi

Techniques are described for recovering about 80 pct of the cobalt and nickel contained in superalloy scrap by anodic dissolution of the scrap and simultaneous electrodeposition of a pure cobalt - nickel alloy at the cathodes in an electrolytic cell partitioned by permeable diaphragms into separate anode and cathode compartments . Superalloy scrap was alternatively prepared for subsequent anodic dissolution either by melting and casting massive scrap into suitably sized anodes , by packing moderate - sized discard scrap in inert metal baskets that subsequently served as anodes , or after concentrating the superalloy portion of grinding debris , by magnetic separation to reject corundum or other abrasives , slagging any remaining abrasives from molten grindings , and finally casting the superalloy metal into anodes . In the processing , purified electrolyte -- 1 N in NiSO4 and in NiCl₂ , and 0.1 N in CoSO4 and in CoCl2 --was charged to the cathode compartments and discharged from the anode compartments at a rate sufficient to overcome the backward migration of ionic impurities from the anodes to the cathodes . Discharged electrolyte was purified by reacting it first with SO2 and next with limestone , and then recirculated to the cathode compartments , in which a 50 pct cobalt - 50 pct nickel alloy was deposited on either blanks of stainless steel or starting sheets of cobalt - nickel alloy . The process was made self - sustaining by either adding H2SO4 to the catholyte feed to throttle the rate of cobalt - nickel deposition , thereby compensating for the slower rate of cobalt - nickel dissolution from the anode and losses occurring in electrolyte purification , or alternatively , adding H₂SO4 to

Jan 1, 1964

By W. E. Bruce, James Paone

Drillability or a measure of drilling performance has been based on ( 1 ) hardness and toughness of rocks , ( 2 ) power input to the drill compared with total volume of hole , and ( 3 ) penetration related to resistive forces of rock on the applied penetrative forces . An analysis of some representative previous work is made . Experimental drillability curves from AX- size diamond core bit performance in eight different rocks ranging from dense hard taconite to soft limestones are presented . Results show that in small bore diamond drilling , compressive strength and possibly other rock properties may be a useful parameter in predicting drilling rates .

Jan 1, 1963

This paper on. the physical and chemical properties of crude oils from California fields is one of a series of reports on the oil-producing districts of the United States., The paper includes a short discussion of results, tabular data, and individual analyses of eight California crudes. Analyses of other crude oils from California have been published in Reports, of Investigations 2595,3/ 2608,4/ and 28465/. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1931

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the Items is confidential. It present's analytical data for 4,608 samples, representing the products of 101 companies. The samples were collected during December 1956, January and February 1957. As in previous surveys, the gasolines covered by this survey include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation. A list of the Notional Motor Gasoline Survey reports published during the post 10 years is given on page 5.

Jan 1, 1957

By J. T. McCartney

In an effort to correlate the size of pyrite particles in coal and coal-particle association with the removal of pyrite before burning, the Bureau of Mines conducted a study of 61 coals presently being used for electric power production. The results were obtained by visual microscopic studies of polished briquets of minus l4-mesh samples. Mean pyrite particle sizes ranged from 20 to 400 microns and proportions of pyrite contained in coal particles to an extent greater than 50 percent by volume (estimated) ranged from 20 to 95 percent. These parameters were correlated with reductions in pyrite accomplished by float-sink tests at 1.60 sp gr on 14-mesh, 3/8-inch, and 1-1/2-inch samples. The correlation coefficients between pyrite removal and mean pyrite particle size were 0.89, 0.84, and 0.79, respectively, for these samples. Correlation coefficients between pyrite removal and coal-pyrite association parameter were 0.92, 0090, and 0.85, respectively. It is apparent that extent of pyrite removal can be fairly well predicted from microscopic analysis.

Jan 1, 1969

By W. D. Walker

The trend toward encouragement of worker participation in accident prevention in the coal mines of the United States is not new; however, it has been given added impetus in recent years and is now definitely progressing. It has been found by experience that, although there are many approaches to a mine-safety program that will include the workers themselves as well as their supervisors, no one way is suitable under all circumstances. It requires the concerted efforts of many agencies working along parallel lines toward a common goal. The following seven principal agencies, using somewhat different methods, are listed to illustrate how this problem is approached throughout the coal-mining industry 1. Federal Bureau of Mines. 2. State mining departments (in individual States where coal is produced). 3. Programs conducted by individual mine operators. 4. Programs conducted by mine workers' organizations (unions). 5. Institutes, societies, and other educational organizations. 6. Coal operators' associations (regional and national). 7. Universities, college, and high schools. Each of the seven approaches to safety are discussed briefly, and their methods end contributions, such as publications and other activities, are listed.

Jan 1, 1953

By John R. Dudo

The Bureau of Mines Morgantown Petroleum Research Laboratory, with the cooperation of the Penn York Oil Company, cored the Dewdrop, Bradford Third, Lewis Run, and Sartwell sands in the Sartwell oilfield, McKean County, Pa. This report contains a review of the geology and depositional history of the field and an evaluation of the feasibility of secondary recovery of oil from the Bradford Third and Sartwell sands by waterflood or gas drive. Core analysis, geologic data, and electrical and radioactivity logs were used to evaluate the reservoir characteristics. Reservoir geometry, rock properties, fluid characteristics and saturations, and relative permeability-saturation relationships were used to assess the floodability of these two sands. The results of this study indicate that between 53,000 and 61,000 barrels of oil can be recovered by water or gas injection. The success of a waterflood or gas drive will depend on the field injection rates of the reservoirs comprising this oilfield. Following an economic evaluation, additional field work is recommended to further test the floodability of the reservoir.

Jan 1, 1967

By A. H. Roberson, F. S. Wartman

For many years , it has been the common practice at most copper mines to recover copper in solution in effluent mine water by precipitating the copper with scrap iron.4/ The technique employed varies from simply throwing scrap iron or tin cans into the waste ditches to passing the water through elaborate launder systems containing detinned scrap and baled cans . In general , a considerable amount of low - cost copper has been recovered that otherwise would have been lost . Iron consumption usually varies from 1 to 1-1/2 pounds of iron for each pound of copper recovered . The grade of the precipitate may be as much as 90 percent copper.4/ ,5/ Where the consumption of iron is materially greater , its cost is likely to be the determining factor of profit . In times of emergency, when the demand for scrap iron for remelting increases the cost of the iron sharply, and the supply of tin cans is not large enough to meet requirements , recovery of the copper might not be economical . The three principal reactions that take place when an acid mine water containing iron and copper salts in solution is brought into contact with metallic iron are : (1 ) Copper is precipitated and an equivalent amount of iron is dissolved , CuSO4 + Fe Cu + FeSO4 ; ( 2) ferric salts are reduced to ferrous salts , Fe2 (SO4 ) 3 + Fe = 3FeSO4 ; and (3) the free acid in the solution reacts. with metallic iron to produce ferrous sulfate , H2SO4 + Fe = H2 + FeSO4 . = Because of the reported high.consumption of iron (5 to 6 pounds per pound of copper precipitated ), when copper in water from the Hornet mine of the Mountain Copper Co. ( California ) was precipitated upon scrap iron , a series of tests was made to determine . the . optimum treatment, time , and consumption of iron .

Feb 1, 1944

By A. J. Kraemer

This report on the physical and chemical properties of typical crude oils of California is the 'eighth in a series on the producing districts of the United States. It includes discussion of results, tabulated data, and individual analyses of typical California crudes. Additional analyses of crude oils from the fields of Fresno, Kern, Los Angeles, Orange, end Ventura Counties will be published later in another Serial of the Bureau, but the summary tabulations are presented here. The samples represented in this report were collected over a rather wide interval of tine, the early samples having been obtained during the fall of 1919, and the most recent ones dating from the summer of 1923. It is thought that the samples are fairly representative, both of the older settled production and of the new flush production of the southern California fields.

Jan 1, 1924

By S. M. Shelton

Preliminary work in the investigation of electrolytic manganese, as reported4/, showed promise for a practical procedure of continuous production. Laboratory work was continued in the direction of process simpliication to determine an economically feasible procedure that would require a minimum of expensive equipment for plant erection and a minimum of reagent consumption for operation. Results furnished enough evidence to indicate that modifications of the process could be made leading to simplified procedure and with no sacrifice in operating efficiency. A supply of at least 200 pounds of the metal was desired for alloy research, and it was believed worth while to utilize available facilities in a search for difficulties that were not encountered in the laboratory and that might arise in larger-scale operation. Consequently, an experimental pilot plant was erected. The plant was designed for a capacity of 15 pounds per day of metal and operated under simulated plant practice.

Jan 1, 1938

By S. M. Shelton

Preliminary work in the investigation of electrolytic manganese, as reported J, showed promise for a practical procedure of continuous production. Laboratory work was continued in the direction of process simplification to determine an economically feasible procedure that mould require a minimum of expensive equipment for plant erection and a minimum of regent consumption for operation. Results furnished enough evidence to indicate that modifications of the process could be made leading to simplified procedure and with no sacrifice in operating efficiency. A supply of at least 200 pounds of the metal was desired for alloy research, and it was believed worth Mile to utilize available facilities in a search for difficulties, that were not encountered in the laboratory and that might arise in larger-scale operation. Consequently, an experimental pilot plant was erected. The plant was designed for a capacity of 15 rounds per day of metal and operated under simulated -plant practice.

Jan 1, 1938

By Arnis Mangolds

A study of the technical and economic feasibility of using a unique undercut and fill system developed by USBM engineers to mine steeply pitching coal is discussed. A brief resource assessment has indicated that significant reserves exist in most coal regions to justify the development of a safe and economical method of extracting steeply pitching coal. The undercut and fill system combines hydraulic coal cutting with unassisted gravity fluming of the coal slurry. Mining occurs across strike and the extended entry is backfilled to provide uniform strata control and an impermeable water and air barrier. Subsequent mining occurs beneath the previously filled stope such that the roof consists of a solid, controlled back. In addition to providing positive roof and hanging-wall support, the backfill system eliminates subsidence potential, post-mining drainage, and the danger of spontaneous combustion from naturally drafting air currents. A unique through-flowing ventilation system permits passage of return air through the production face via ducting located at the backfill-coal junction. This provides a constant supply of fresh air at the face, eliminates the need for brattice cloths, and provides an additional escapeway for the miners. The preliminary estimates indicate a production rate in the neighborhood of 31.9 tons/ manshift. Capital costs are approximately $3.17/raw ton over a 20-year life with an initial investment per annual ton of $48.29. Total cash-costs for labor, supplies, power and benefits range in the vicinity of $19.59 for a 704,460 ton/year mine, or a total cost of $22.76/ton. These costs do not include federal and local taxes or post-of-money; however, the cost of coal is well within the area selling price.

Jan 1, 1981

By S. J. Schatzel, P. W. Jeran, W. P. Diamond, F. E. McCall, F. Garcia, J. C. LaScola, T. P. Mucho

The National Institute for Occupational Safety and Health, Office for Mine Safety and Health Research, is investigating the geologic and mining factors influencing the migration of longwall gob gas. One goal of these studies is to optimize methane drainage strategies to reduce the volume of gob gas that reaches the underground workplace. As part of this research effort, longwall gob gas flow paths in a mine operating in the Pittsburgh Coalbed, PA, were investigated using SF6 tracer gas. Tracer gas released into the ventilation airflow underground generally stayed in the bleeder system and was vented at the associated bleeder fan shafts. Tracer gas injected into an inactive (intaking) gob gas venthole migrated to the two inby producing ventholes on the study panel, indicating that all three ventholes were in communication. The tracer gas that was injected into the gob generally stayed in the gob and only migrated to the ventilation system in response to the venthole on the study panel closest to the injection hole going off production. Tracer gas flow velocities in the longwall gob reservoir and factors influencing the production performance of gob gas ventholes in the study area are also discussed.