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By D. N. Nilsen

A mathematical modeling method was developed by the Bureau of Mines for the prediction of the principal equilibrium species in the solvent extraction of copper. The use of models for predicting the amount of metal extracted can reduce the amount of experimental work required to characterize a system for purposes such as optimization studies. Models were developed for the extraction of copper from ammoniacal sulfate and carbonate solutions with commercially available extract ants commonly used by industry. Results from laboratory shakeout tests compared well with predictions of the equilibrium concentrations of copper and pH values. For example, the loading of copper onto the solvent was predicted for most cases within ±S pct of the measured values, and the pH to with-in ±O.l pH unit in sulfate systems and ±O.2 pH unit in carbonate systems. Both mechanistic and empirical extraction equations were developed from laboratory data for copper and ammonia. The empirical-based models were slightly more accurate than were the mechanistic-based mod-els. Industrial level concentrations of the aqueous and organic constituents were used in this work. Independent variables included copper concentration, ionic strength, and initial pH of the aqueous phase; extractants, diluents, and their concentration in the organic phase; and temperature.

Jan 1, 1988

By Nar S. Dalal, Xianglin Shi, Val Vallyathan

"INTRODOCTIONIn an earlier communication 1 from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates of free radicals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubini et al.2 have also reported the detection by electron spin resonance (ESR) of the formation of SiO. and Si-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum ( -10-10 torr>3 and subsequent exposure to air,3 and to other gases,4 these radicals were identified2 as being formed by the homolytic cleavage of the Si-0-Si bonds and the reactions of the Si• and SiO- radical with atmosphere. Fubini et al.2 also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anca5 bad reported that lipid ·peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radica1 studies on a given quartz dust sample have been reported, except for some earlier work from our laboratory.1·6·7 We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radica1 measurements on a freshly made quartz dust. The dust's free radica1 content was measured using ESR spectroscopy while its cytotoxicity potential was estimated via hemolysis. Hemolysis was employed as the toxicity test because it is a widely used method for estimating the potential of a dust for disrupting the cell membrane. 8 The fibrotic potential was followed by measuring the dust-induced lipid peroxidation, using linoleic acid as a model lipid. As discussed below, the results obtained suggest new clues to the mechanism of the quartzrelated cytotoxicity and fibrogenicity. MATERIALS AND METHODSReagentsCrystalline quartz particles with a size range of 0.2-2.5 mm were obtained from the Generic Respirable Dust Technology Center, Pennsylvania State University, University Park, Pennsylvania. These particles were crushed in air to obtain quartz dust samples with particle sizes smaller than 20 microns. We chose to work with a dust with mixed particle sizes, rather than a specific range, as an effort to simulate the mining atmosphere. An agate mortar-pestle arrangement was used for the crushing and grinding because of the close similarity of the structure of agate to that of quartz. Diethylenetriaminepentaacetic acid (DETAPAC) were purchased from Sigma. All other chemica1s were purchased from Fisher or Aldrich.Hemolysls ExperimentsHemolytic activity of silica was measured, following an established procedure,9 as the amount of hemoglobin released from a 2 % suspension of sheep erythrocytes after incubation with 10 mg of silica dust for one hour at 37 °C. The hemoglobin release was estimated via the absorbance at 540 nm using a Gioford spectrophotometer. The procedure was calibrated by substituting the silica dust by a phosphate buffer solution as a negative control (background) and O.S % Triton-X-100 as a positive control (100% hemolysis). The percentage of hemolysis was calculated as follows:"

Jan 1, 1990

By A. B. Hooker, E. J. Coggeshall

"Dry cells are modified wet primary cells in which the electrolyte is held by absorbent material so that it does not spill aid the cell jars are sealed to prevent evaporation of the absorbed electrolyte. Most dry cells in commercial use are modifications of the Leclanche wet cell. In their usual form they have a hollow cylindrical zinc negative pole that constitutes the containing vessel. An absorbent material, either as a lining in the zinc jar or a bag, separates the zinc cylinder and a rod or flat plate of carbon placed axially inside. A mixture of crushed coke, graphite, and manganese dioxide is tamped about the carbon rod, and the whole mass is saturated with salaanoniac-zinc chloride solution.Dry cells are suitable for services that require minute currents continuously or larger, though limited, amounts of current intermittently. Though limited in this way, they have a wide use, even in underground mining. This paper details some of the applications of dry cells in mines, particularly from the standpoint of greater safety through their use.APPLICATIONSThere are four fields of application of dry cells to mining: (1) Electric shot firing; (2) auxiliary lighting; (3) signaling; and (4) testing.SHOT FIRINGFiring an electric detonator requires very little electrical energy because although the current flow may be 1 to 3 amperes the duration of flow is so small (1 to 4 milliseconds) that the energy withdrawal per shot is almost negligible. Batteries for shot firing need not be large; they may be used for firing either single or multiple shots."

May 1, 1934

By Alexander May

This report describes a new method of weighing based upon observing the apparent weight of an object ill two separate pure gases. The method is presented in terms of experimental data which prove its soundness, but does not attempt to show the maximum accuracy possible with this technique. The new method incorporates the underlying principle that the apparent weight of an object is a linear function of the density of the atmosphere in which the object is weighed. The coefficients of this linear function are the true mass and volume of the object. From this functional relationship the true mass and volume of the object may be determined.

Jan 1, 1970

By G. S. Scott

In the course of the investigation into the causes, behavior, and control of mine fires, which the Bureau of Mines is now conducting, some attention was given to the subject of spontaneous heating. It is self-evident that the temperature of a pile of broken coal will rice if the rate of generation of heat exceeds the rate of brat dissipation and will fall if the opposite is the case. Factors that affect the rate of generation of heat are:

Jan 1, 1941

By Philip G. Burkhalter

Total yield and backscattered electron coefficients were measured in this Bureau of Mines study in an microanalyzer as a function of atomic number and of primary crier: ;y in the 15- to 35-kilovolt range. The electron coefficients were obtained indirectly from measurements of the specimen electron current and the primary beam current collected in a Faraday cage and were measured with a precision better than 0.5 percent. Secondary electron emission was suppressed with opposing potential applied to a screen grid surrounding the specimen. The values of the backscattered electron coefficients agreed with published values within 5 percent.

Jan 1, 1965

By M. V. HANSEN, Frank PERZ, Edward Thomas, C. H. SEELING

This is the second of a series of information circulars dealing with the control of roof and the prevention of accidents from falls of rock and coal . Their purpose is to focus the attention of the coal-mining industry on the most - common source of fatalities and injuries in mining coal and to disseminate information that may be helpful in combating the roof - fall hazard . Inasmuch as approximately 85 percent of roof - fall accidents occur in the face region , the importance of analyzing the accident - producing aspects of methods of roof support at the face or lack of method overemphasized . - - cannot be This circular is not intended to be an exhaustive treatise on methods of roof support in face regions but rather is a description of several methods of support that appear to offer distinct advantages with respect to safety and efficient operation .

May 1, 1948

By Russell E. Griffen

With the development of larger mine-haulage trucks in recent years, the visual field of the driver has diminished correspondingly. Specifically, the operator's lack of direct vision in the right front area and directly to the rear constitutes a serious hazard to personnel in nearby small utility vehicles. Recently developed electronic technology has made it possible to supplement the use of mirrors and fresnel lenses to warn the operator of specific collision dangers in the truck's blind areas. This Bureau of Mines report describes the results of a coordinated contract and in-house research program to develop and test in-mine prototype electronic systems to detect the presence of smaller vehicles within the blind areas of large mine-haulage trucks. Each system utilized transmitters installed on the smaller vehicles and receivers installed on the haulage trucks. Transmitting techniques tested included both low-and high-frequency radio waves. On-vehicle testing established the engineering feasibility of each approach. Further private sector product development to improve reliability and reduce system costs is recommended. Mining companies should consider the advantages of each type of system.

Jan 1, 1988

By Donald O. Capstick

A mineral survey of the approximately 144,000-acre Borah Peak study area was conducted by the U.S. Bureau of Mines in 1985 at the request of the U.S. Forest Service. The area studied included the Borah Peak RARE II roadless areas (No. 14210, 119,864 acres of land recommended for wilderness designation; and No. X4210, 18,440 acres of land recommended as non-wilderness) and other contiguous Forest Service administered land. The study area is in Challis National Forest in southeast Idaho about 30 miles south-southeast of Challis, ID. Burnt Creek, a conterminous study area to the northeast, on lands administered by the U.S. Bureau of Land Managment, was examined concurrently. Dolomite and limestone inferred reserve bases exceed 1 billion tons each within the Borah Peak study area. The material is widespread and of high quality. Extensive sampling and more detailed mapping are required to better define the resources; however, ample dolomite and limestone occur nearby, outside the study area. Dolomite is the main constituent of several geologic formations within the study area. Sample analyses indicate that the more than 1,000-ft-thick Jefferson Formation dolomite is the most pure and is equivalent to material being mined at a dolomite-to-magnesium processing plant near Addy, WA. Analyses from limestone-bearing formations underlying much of the study area indicate that large quantities of the limestone may be suitable for a variety of uses.

Jan 1, 1987

By R. G. Knickerbocker, T. E. Evans, D. R. Torgeson

"INTRODUCTION Sponge iron is a product resulting from the reduction of an iron oxide at such a low temperature that fusion does not occur, and the reduced particles retain substantially the same shape as the original ore. The removal of oxygen in the reduction process leaves the metal porous and reactive. Sponge iron may be compared in general to a chemically precipitated substance insofar as reactive properties are concerned. The high specific surface and the orientation of metallic structure are factors which probably contribute to the reactive properties of sponge iron.The term ""gaseous reduction,"" as applied to iron ores, required clarification. Strong evidence exists, for example, that ore is partly reduced to sponge iron by carbon monoxide in the blast furnace at temperatures around 800° C. at a point that may be as high as 30 feet above the tuyores. In 1923 and 1924, Sims and Wood attempted to reduce iron oxide with carbon in an Arsem vacuum furnace at 980° C. These investigators found that only 6 percent of the iron was reduced to metal when the iron oxide-carbon mixture was heated for 1 hour under evacuated conditions, whereas at atmospheric pressure 70 percent of the iron was metallized. Their results indicate that the process of iron-ore reduction at temperatures below the melting point of the ore may proceed largely, if not entirely, by the action of reducing gases even when the reducing agent is solid carbon. Therefore, the term ""gaseous reduction,"" as used heroin, is defined as a process in which iron ore is brought into intimate contact with a reducing gas produced in separate-equipment from the reduction chamber itself.A large amount of pilot-plant development on gaseous reduction of iron ores has been carried out by the Bureau of Mines at the Boulder Experiment Station and had as its objective the reduction of fine iron ore by means of producer gas. The use of use gas was prompted by two considerations: First, the possible utilization of large reserves of Western noncoking bituminous coals and lignites contiguous to iron-ore drewwing; and second, an investigation of the results that might be achieved in the pilot-plant gaseous reduction of fine iron ores by means of a relatively reducing gas. The results obtained, it was felt, would be of considerable value in indicating the direction which gaseous reduction experimentation must take for the development of a commercially practicable and economic process for the production of sponge iron."

Dec 1, 1946

By Welby G. Courtney

The Bureau of Mines conducted an exploratory field survey to determine the amount of airborne coal dust, the size distribution of the dust, and the rate of dust deposition in coal mine airways. The survey was taken at eight underground locations in operating coal mines. The rate of dust deposition in the airways depended upon the concentration of air-borne dust and decreased exponentially with distance from the dust source. The rate was seemingly independent of the size of the airborne dust particles. The rate of deposition, along a return, for the coal dust from a fade being mined with a continuous mining machine closely matched the rate for the rock dust from a trickle duster. A sample rock-dusting schedule for that return is presented; that is, the trickle duster should be operated for 3-112 hours after every five shifts to protect the average deposit of new float coal dust in the return, but operation after every three shifts is preferred, to protect an occasional heavier deposit.

Jan 1, 1982

By Susan M. White

Increased coal production, wider use of indiscriminate mining techniques, improved cleaning methods, and greater emphasis on clean fuels is increasing the rate at which wastes accumulate Over the next several years, Colorado Plateau underground coal production is predicted to increase. Currently, mine refuse is deposited in canyons or lowland areas near mines. This study presents information on the nature of coal refuse and disposal practices on the Colorado Plateau. Samples were collected and analyzed to provide information to help formulate alternative methods for reclaiming refuse piles. The analyses were based on determining the capability of unmodified refuse to provide a suitable medium for plant growth. Local topsoils which would be used in reclamation were used as standards. Potential environmental hazards were assessed also. A general cost analysis was done for both surface and underground disposal and the advantages and disadvantages of each were assessed. Several problems were identified which, if solved, would increase the effectiveness of state regulatory programs.

Jan 1, 1982

By Bernard J. Steblay

Two instruments have been constructed that extend microseismic data collection and processing capability for Bureau of Mines research in rock burst, coal bounce and outburst, and roof fall monitoring. The first instrument is a 13-channel tape-triggering system. This system allows better utilization of instrumentation tape recorders by collecting data digitally, turning the tape on only when valid data are present, and increasing the dynamic range of the recorder by using digital data. A digital-to-analog converter is used to provide analog output of the recorded digital data. The instrument records a much larger time slice of transient events than do current commercial devices. The second instrument is a microseismic energy measurement device. This device uses recent developments In integrated circuits to overcome the dynamic range and accuracy limitations of previous instruments. The analog signal is converted to a digital one, and then high-speed multiplication techniques are used to square the amplitude value in real time and integrate it.

Jan 1, 1983

By W. E. Wallace, P. Bolsaltis, M. J. Keane, B. L. Rauaboni

Thermal treatment of respirable size silica dust samples results in marked changes in their hemolytic activity. These changes can be correlated with changes in the characteristics of the particle surface as measured by infrared spectra, zeta potentials, and specific surface area. Silica samples from various sources (Min-U-Sil, fumed silica, and a NIOSH standard sample) were heated or calcined at temperatures ranging from 100-1095C. The hemolytic activity of the crystalline materials decreased after thermal treatment. The behavior of the fumed material was found to be more complex. Material of very large surface area (small particle size) exhibits an initial increase in hemolytic activity upon calcination. This result confirms other experimental observations pointing to a particle size of maximum toxicity. Tre changes in hemolytic activity can be related to infrared spectra and zeta potentials of the materials. The absorption band in the 3200-4000 cm-1 frequency region of the fumed material disappears upon heat treatment while a sharp, characteristic band at 3750 cm-1 increases in intensity. Zeta potential measurements conducted in the pH range of 2.0-10.5 exhibit a unique change in zeta potential v.s. pH profile with heat treatment. These findings indicate that the removal of active surface silanol groups by calcination results in reduced cytotoxicity, as measured by a hemolysis test.

Jan 1, 1988

By Ralph H. Whaite

To assist the anthracite industry obtain technical data on pneumatic packing, the Federal Bureau of Mines imported a pneumatic packing machine from Germany and installed it in a mine of a cooperating company in the Northern anthracite field of Pennsylvania. This report covers the second in a series of experiments in applying pneumatic packing for controlling strata movement (subsidence) above mine workings in the Pennsylvania anthracite region. The first experiment2/ was begun in January 1950, in a section of the mine where about 50 percent of the original coal remained in the form of pillars; since the company did not plan to mine the pillars in this particular area, pneumatic packing of the chamber voids was done for test purposes only. During this initial test the machine was operated on 204 shifts, and 652,400 cubic feet of breaker refuse material (22,834 tons) was packed into the voids of 16 chambers. The work was completed in December 1951.

Jan 1, 1956

By D. G. Kuehn

Mass spectrographic studies have been conducted on the positive ions and neutral species of glow discharges containing 1.0 pct S02 and 1.0 pct CO in helium. Measurements were conducted for gas pressures from 3.5 to 10.1 torr using both dc and 60-Hz ac excitation. The ion species that were observed included S+, SO+, SO+, 0+, O2+, C+, CO+, and CO2+ with lesser amounts of SO3+, (CO)2+, SCO+, and (SO?CO)+ or CS+2. Interpretation of the functional dependence of the various ionic and neutral species on pressure and applied power showed that CO reacted with the SO formed in the discharges to produce CO2 and sulfur. Deposition of elemental sulfur was observed in the plasma container.

Jan 1, 1973

By A. J. Keast

This circular is one of a series dealing with the exploration, equipping, and development of mining properties, prepared and published by the United States Bureau of Mines in cooperation with various mining and exploration companies in the United States and Canada. This series of papers will supplement an earlier one which covered the methods and costs of mining and milling at a large number of producing mines. The present paper describes the exploration, equipping, and developing of a group of 18 claims remote from rail transportation, and the transport of equipment and heavy supplies for a distance of 120 miles by tractor over ice and winter roads, and of men and lighter supplies by airplane.

Jan 1, 1933

By V. F. Parry

Subbituminous coal or lignite when stored in random riles or in ordinary bins in which the temperature fluctuates and air circulates quickly undergoes objectionable physical and chemical changes, which decrease the utilization value of the fuel and increase its tendency to ignite spontaneously. Slacking takes place, and the heating value decreases. Those changes are accelerated by fluctuations of temperature and by circulation of air through the storage space. When such coals are exposed to the weather they lose moisture rapidly. If evaporation from the surface of a lump proceeds at a faster rate than that at which it is replaced by moisture from the interior, the rate of shrinkage at the surface is greater than that at the interior; consequently stresses are generated at the surface which cause the coal to disintegrate. Likewise, when moisture is absorbed by the air-dried surface the outside layers expand at a faster rate than the interior, which results in further break-down. As these cycles are repeated the lump may disintegrate completely. Therefore, successful storage of low-rank coals depends on control of the factors that influence change of moisture.

Jan 1, 1941

By V. F. Parry

[Subbituminous coal or lignite when stored in random piles or in ordinary bins in which the temperature fluctuates and air circulates quickly undergoes objectionable physical and chemical changes, which decrease the utilization value of the fuel and increase its tendency to ignite spontaneously. Slacking takes place, and the heating value decreases. These changes are accelerated by fluctuations of temperature and by circulation of air through the storage space. When such coals are exposed to the weather they lose moisture rapidly. If evaporation from the surface of a lump proceeds at a faster rate than that at which it is replaced by moisture from the interior, the rate of shrinkage at the surface is greater than that at the interior; consequently, stresses are generated at the surface which cause the coal to disintegrate. Likewise, when moisture is absorbed by the air-dried surface the outside layers expand at a faster rate than the interior, which results in further break-down. As these cycles are repeated the lump may disintegrate completely. Therefore, successful storage of low-rank coals depends on control of the factors that influence change of moisture.]

Jan 1, 1941

By Cleo G. Rall

The value of brine analyses in the study of petroleum-engineering problems was recognized early in the history of petroleum. The Bureau of Mines before 1928 had indicated in several reports.3/ ways in which analyses might be used. Because of the confusion resulting from attempts to correlate the work of different chemists using greatly varying methods of analysis and systems of computation and expression of results, a paper presenting the methods used by the Bureau of Mines was prepared and published in 1928. This system of determining the characteristic constituents of oil-field waters and of calculating and reporting results has been widely adopted by the petroleum industry. The earliest and most obvious use of water analyses is determination of the source of water infiltrating into petroleum and natural-gas wells. For this purpose it is necessary that an analysis of the connate water of the formation from which the oil is produced be available and that an analysis of the contaminated water be made. By comparing these analyses with those of connate waters from formations higher in the structure, the formation from which the infiltrating water comes may be identified.

Jan 1, 1953