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By Charles B. Kenahan

The effects of ultrasonic radiation on the electrodeposition of copper-zinc, copper-cadmium, and copper-tin alloys from cyanide baths were investigated by the Bureau of Mines at frequencies of 18.5 and 38 kilocycles per second, and at acoustic intensities up to 0.5 watt per cm3. Significant changes occurred in the composition of the deposited alloys; some of these deposits were brighter, harder, more adherent, or of finer grain size than nonirradiated deposits. The irradiated deposits were also smoother and less porous, and they afforded better corrosion protection for the substrate metal in sodium chloride solution. The limiting current densities of the cyanide baths were increased by the application of ultrasonics. Anode and cathode current efficiencies also were increased, and cell voltages were lowered; the relationship of these effects to current density is discussed. Electrode potential measurements showed significant depolarization effects at both electrodes during ultrasonic irradiation. The resulting decrease in cell voltage was due chiefly to depolarization at the anode, and the anode became less passive.

Jan 1, 1967

By R. O. Kneisley

This U.S. Bureau of Mines report summarizes a study of large-scale strata response to longwall mining at a western U.S. coal mine. This study utilized surface and subsurface measurements, geologic mapping, in situ stress measurements, and pressure cell readings to characterize strata behavior. Preliminary analysis of surface subsidence and time-domain reflectometry (TDR) was used to determine a suggested main roof caving sequence. Coal ejected from the face apparently resulted from brittle failures that occurred because of lack of significant yield zone development. The combination of a strong coal with pronounced directional behavior, low overburden pressures, a good caving roof, and a high-production environment that minimized time-dependent loading apparently reduced yielding of the longwall face. The panel 1 headgate-entry design appears adequate; however, the abutment pillar and adjacent panel tailgate rib are highly stressed and may contribute to problems during second panel mining. The small chain pillar yielded after passage of the face, but the pillar width may be near maximum since evidence of a stressed core exists.

Jan 1, 2010

By D. Harringtong

"There has been much writing and argument on the subject of giving bonuses to miners, quarrymen, metallurgical and chemical workers, and others as a stimulus for safe work and for work safely done. Theoretically, everyone should be careful and should not need monetary or any other type of encouragement for the prevention of accidents; as a. fact, few people are careful, and this is primarily the reason way many if not most accidents occur. A bonus, however, is not simply money given away by an employer; it must be earned, so to speak, before it becomes due; in other words, if the standard established is not reached, no bonus is paid, and in many cases some disciplinary action is taken.The United States Bureau of Mines Is asked from time to time for suggestions for rewards to mine workers who have a good attitude toward working safely or who need some stimulus to cause them to make greater or more earnest efforts toward safety for themselves and their co-workers. A recent inquiry prompted the collection of data on some safety bonus systems from reports of this bureau's field engineers and others, and some of these Now given. Bonus practice at both coal and metal mines is included because a system used at metal mines is generally adaptable to coal mines; in fact, in numerous cases, bonus systems recently started at some coal mines are based on systems in vogue and giving satisfaction some metal mines; in-some instances, also, metal mines have been able to get good suggestions from coal mines or from the cement or petroleum industries. it .should be understood that a bonus, even as applied to the encouragement of safety, does not necessarily mean payment of money; in fact, some successful bonus systems have in them no direct money exchange; hence, the bonus as treated in this paper is that defined as ""Something given in addition to what is ordinarily received by, or strictly due to, the recipient.""Acknowledgment is given here to members of the safety division of the Bureau of Mines who sent in some of the information here presented; to the Engineering and Mining Journal and Mining Congress Journal, from which some items were abstracted; to various mining officials who gave data in one form or another; and to M. von Bernewitz, of the United. States Bureau of lines who aided in framing parts of this paper."

Jun 1, 1932

By L. W. Higley

Electrowinning metals from solutions leached from low-grade ores is becoming an increasingly important extraction method as the metal industry turns to pollution-free recovery processes. Lead-alloy anodes are used industrially in the electrolytic recovery of zinc and copper. However, associated with the use of these anodes are the inherent problems of stability and lead contamination of the cathode. In an effort to eliminate these problems, the Bureau of Mines has developed a relatively inexpensive lead dioxide anode for electrowinning metals from strong acid solutions. The anode was prepared by depositing Pb02 directly on a titanium blank in a strong HN03-Pb(N03)2 solution at 2.15 to 6.45 A/dm2 and 60° C. This anode was tested in zinc and copper electrowinning cells containing 200 gpl H2S04 and 35 to 100 gpl metal ions at the current density of 3.23 to 6.45 A/dm2. Contamination of the cathode by lead was =0.005 pet. A 30-day test at 6.45 to 12.90 A/dm2 in an electrolyte containing 200 gpl H2S04 and no metal ions resulted in a slight change in surface morphology of the Pb02 anode but no measurable change in anode weight or dimensions.

Jan 1, 1976

Control dust generated during overburden drilling at surface coal mines using either wet suppression or dry collection systems. Approach For the wet suppression systems, a range of water flow rates was tested over a number of holes. Each hole was drilled at a specific and constant flow rate. A recording flow meter was mounted in the water line near the control system pump. For the dry collection systems, each drill was tested with the front of the shroud set at different heights above the ground. Because of the irregularity of the ground surface, all height measurements were taken at the front of the shroud. Background Wet drilling systems consist of a water tank mounted on the drill from which water is pumped into the downhole air line. The water droplets in the bail air conglomerate dust particles as they travel up the the annular space of the drilled hole, thus controlling dust as the air bails the cuttings from the hole.

Jan 1, 1987

By Frank E. Federspiel

In 1986 and 1987, at the request of the U.S. Forest Service, the U.S. Bureau of Mines examined the 47,000-acre Electric Peak study area (part of the formerly-designated RARE II Non-wilderness Recommended Area no. 1609) to evaluate its' identified mineral resources. The study area is in Powell and Jefferson Counties, YT, about 30 mi southwest of Helena and 30 mi north of Butte. Three lode localities within the study area contain an estimated 159,000 tons of identified subeconomic resources containing gold, silver, and accessory lead, copper, and zinc. Resources at those localities range from 10,000 to 134,000 tons with grades ranging from 0.04 to 0.32 oz/ton gold, 0.92 to 16.42 oz/ton silver, 0.14 to 79.65 percent lead, and as much as 0.41 percent copper and 0.68 percent zinc. One property also contains 0.15 percent antimony. Gold, silver, and base-metal content in samples of poorly exposed mineralized structures indicate that further exploration may identify resources on seven additional study area localities.

Jan 1, 1988

Provide an inexpensive, remote actuated, stench-gas system which reduces fire warning time to underground work locations. Approach A mine's pager phone hard-wire network is used to release stench gas from pressurized canisters located near working areas. The release is initiated by placing a coded message into a control phone at some central location. How It Works Currently, in most mines, the decision to release a warning stench gas is made by mine management after communication from the mine of a fire or similar potentially dangerous situation. Stench gas is then released into the ventilation air and/or compressed air lines for dissemination throughout the mine. This can result in significant delays in warning time. Often, surface personnel must travel to distant shafts, or other release points, wasting valuable time. Also, the time for ventilation air to circulate from the surface to working locations can be long and the effectiveness of compressed air as a stench transport agent depends on whether the compressed air is being used at the face. The Bureau of Mines, through a contract with MSA Research Corporation, has designed and tested a warning system which avoids these problems. The system consists of multiple, pressurized stench-gas canisters located under-ground in the mine-ventilation network so as to provide quick dissemination of the released stench gas to working areas. Each stench-gas canister is hard-wire connected to a nearby pager phone and from there to a control phone at the surface or at a central in-mine site. In the event of a mine emergency, the canisters are activitated to release stench gas by placing a coded message into the control phone. A low amperage Signal sent from the control phone to the receiver phone closes a relay, which activates a release mechanism on the canister.

Jan 1, 1984

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies were determined calorimetrically for Na2Cr04, A reversible transition was found at 700° K with an isothermal heat of transition of 2,263 cal/mole. High-temperature X-ray diffraction analysis showed that the transition was a crystal change from the low-temperature orthorhombic form to the high-temperature hexagonal form. At 795° K the hexagonal form had the parameters a, = 5.691 and co = 7.478 A. Powder diffraction data for the high-temperature form are given and possible structures discussed. The melting point was determined to be 1,065° K with a heat of fusion of 5,810 cal/mole. Enthalpy and entropy increments from this investigation were combined with other data from the literature to calculate enthalpies of formation, free energies of formation, and equilibrium constants of formation from 298° to 1,400° K. Equations that represent enthalpies above 298° K are given.

Jan 1, 1972

By Paul Sands

Single- and two-stage tests were made with 6-inch, coal-cleaning hydrocyclones to determine the effect of hydrocyclone geometry, operating conditions, and feed composition on performance. Most of the testing was conducted in an open-circuit pilot plant that had a maximum capacity of about 9 tons per hour. The coals used in the investigation had top sizes of 1/4 inch and 28 mesh. Considerable latitude was found in the range of geometry variables that could be used without affecting performance adversely, although a certain minimum ratio of overflow to underflow openings had to be maintained for best operation. Two-stage cleaning proved distinctly better than operation with a single hydrocyclone, because clean coal lost in the refuse product of the primary unit can be partly recovered in the secondary. There is an unusually great difference in the specific gravities at which the individual sizes of the feed are separated in the hydrocyclone. This militates against high efficiency because maximum yield occurs when all sizes are cleaned at the same specific gravity. The size composition of the feed and, more particularly, the size composition of the impurity have a greater influence on the efficiency attainable in the hydrocyclone than in most other types of fine-coal cleaners.

Jan 1, 1968

By M. M. Hassan

This report describes the analysis tools developed at West Virginia University which can be implemented to optimally design coal mine electrical systems. The basic analytical tools for all power systems are the load-flow and short-circuit analysis. Well known programs have been developed for analysis of ac transmission and distribution systems, but they are not applicable to a system which has combined ac/dc distribution, such as a coal mine power system. Furthermore, the topology of a coal mine electrcal system changes continuously due to the movement of the locomotives on the track. In the first section of this report, algorithms for carrying out load flow and short-circuit analysis of a coal mine electrical system are described. Results from the study of a typical coal mine system are presented. In the second section a method is described to optimally size power cables for cyclic loads. The method is based on the development of a thermal-electric model for a low-voltage power cable. Results from experimental verification of the model are also presented. These techniques are useful in the safe, efficient, reliable and economical design of the coal mine electrical power systems.

Jan 1, 1979

By M. L. Bowser

Pulse-forming circuitry is described for use in explosives research that requires precise synchronization and control of events in order to investigate detonation parameters. Included are pulse generators for oscilloscope sweep control, counterchronograph actuators, and a raster-type oscillographic method for the determination of velocities of detonation that are applicable to studies on solid, liquid, and gaseous detonations. INTRODUCTION Prom time to time, requests have been received for information on electronic circuitry used in explosives work at the Explosives Research Laboratory, Bruceton, Pa. The methods used are not entirely original;4 5 6 however, modifications of earlier techniques and some novel design aspects have resulted in time-tested methods that warrant a more detailed description.

Jan 1, 1962

By R. V. Ramani, B. K. Belle

The increased effectiveness of a two-phase spray system (TPSS) over a single-phase spray system (SPSS) for dust suppression is reported in several laboratory studies. The dust collection efficiencies of SPSS and TPSS were studied in a model experimental longwall gallery facility at Pittsburgh Research Laboratory at NIOSH (USA). The experimental design consisted of two factors: pressure, and airflow. Each factor had three levels. SPSS experiments were conducted at only one pressure (1035 kPa) which is nearly 1.5 times higher than the highest air and water pressure for TPSS experiments. The results of the study are presented in this paper. While it appears that TPSS performed better than SPSS, the data is not sufficiently conclusive on this aspect. The differing spray characteristics of the chosen TPSS and SPSS nozzles did not allow a direct comparison of the two systems. In the TPSS arrangement, considerably greater turbulence in airflow is created around the shearer; it is likely that at least in the immediate vicinity of the tailgate drum, there is a roll back of the dust/mist cloud into the walkway. Therefore, positioning of the personnel upwind of the tailgate drum is necessary to avoid high dust exposures. The rate of decrease in concentration with TPSS is higher than that with SPSS. This may be due to the greater atomization of the water. The test set-up did not allow the study of conditions when coal is cut from tail to head where the potential for personal exposure is high. Changes in the experimental design are necessary to overcome some of the reasons expected for the inconclusive results.

By James W. Ballard

The facts are generally accepted that an atmosphere containing large quantities of any dust is objectionable to breathe and that some dusts are more dangerous than others. Therefore, knowledge of the com-position of dusts is important in evaluating the hazard entailed on exposure. At present, free silica, of which quartz is the most abundant form, is considered one of the most significant dusts, from the standpoint of pneumoconiosis, and one State5/ has established permissible limits of air dustiness on the basis of the free-silica content of rock. The amount 06 free silica in materials used for rock dusting also has been limited.6/ Determination of free silica or quartz, therefore, is important.

Jan 1, 1940

By William F. Hahn

This report describes an illumination system suitable for use in a slope under construction, Simulator work was performed using actual lighting hardware to verify adequate light levels to meet MSHA proposed regulation (as published in the Federal Register, January 13, 1977). The sequence of operating activities for two different slope driving sites are discussed and lighting requirements are defined for each,

Jan 1, 1981

By H. H. Schrenk, Carlton E. Brown

"INTRODUCTION The question as to whether or not the flow of water through pneumatic rock drills commonly used in this country keeps to a minimum dust disseminated into the air during drilling arose during a study of the dust-in-air conditions in Butte mines from February to July 1936 and December 1936 to June 1937 made by the Bureau of Mines in cooperation with the Anaconda Copper Mining Co., Butte, Mont, The purpose of this report is to describe the study, including some experimental work on the subject, and to give test results.ACKNOWLEDGMENTSThe help of the ventilation department of the Anaconda Copper Mining Co. in planning the study and collecting the data is gratefully acknowledged.EXPERIMENTAL CONDITIONSTests were conducted in an untimbered 6- by 8-foot crosscut in medium-hard granitic rock near the shaft station on an inactive level of one of the active Butte mines. Figure 1 shows the plan and section of the test location. Air was drawn from the shaft at the station, through the crosscut, and up through another shaft. The flow of air through the crosscut was decreased by a brattice downstream from the sampling location, so that relatively high, easily measurable dust concentrations would be obtained in the tests. Impinger samples for determing concentration of dust in the air were collected in an opening 51 inches wide, 29 inches high, and about 4o inches from the top of the rails in a wooden stopping about 16 feet downstream from the place where the test holes were drilled."

Apr 1, 1938

By G. T. Brow

An experimental method is described for testing diffusion of gases in crude oils at pressures and temperatures up to 3,000 psia and 200° F. A sampling technique was developed to withdraw by constant-pressure mercury displacement about 60 µl of oil from the diffusion cell through any of several 1/2-in vertically spaced capillary tubes and to trap about 4 µl of the oil in a specially designed microsampler. Oil trapped in the microsampler can be completely inserted in the sample inlet of a chromatograph. From analysis in a three-stage chromatograph (GLC), gas concentration in a sample is determined from the ratio of gas peak heights to area of peaks of reference components (hexanes or heptanes) in the oil. A diffusion coefficient is calculated from measured concentration profiles with known equations for diffusion in finite or semi-infinite systems, depending on whether the gas has or has not reached the end of the oil column. Results are given for a test of methane diffusing at 2,560 psia and 160° F in crude oil from the Weber Sandstone reservoir in the Rangely field, Colorado. A constant diffusion coefficient of 3.34 X 10-5 cm2 per sec was obtained which gives a good fit between calculated and experimental profiles determined at six times after start of diffusion. The maximum standard error of gas concentration determinations experienced with this method was ±0.88 ml per ml of gas-free oil.

Jan 1, 1970

By John R. Duda

The Bureau of Mines is developing estimates of capital investment, operating cost, and selling price for underground mines producing bituminous coal by various mining methods. This study estimates the required capital investment, operating costs, and selling prices for two hypothetical mines designed to produce 1.5 and 3 million tons per year (MM tpy)3 by using a longwall system in conjunction with a continuous-mining system. The coal properties being mined are assumed capable of sustaining a 20-year product Lon period. Wages and union welfare payments used in this study are those in effect as of December 6, 1975, as set forth under the National Bituminous Coal Wage Agreement of 1974. Costs of materials and equipment are based on January 1976 Indexes. Initial capital investment is $33.8 million for the 1.5-MM-tpy mine and $61 million for the 3-MM-tpy mine. Capital requirements, including deferred investments, were estimated to be $52.5 and $94.2 million, respectively. These figures translate into total capital investments of $34.87 and $31.31 per ton of annual production. Assuming a desired 15-percent discounted cash flow rate of return, with Federal income taxes at 50 percent, the required selling prices would be $12.06 and $10.94 per ton for the 1.5- and 3-MM-tpy mines.

Jan 1, 1976

By B. S. Covino

The Bureau of Mines has conducted a laboratory and field corrosion test¬ing program to determine materials of construction for the leaching and gas-sparging crystallization environments of the clay-HC1 process in order to more fully utilize the alumina from domestically available kaolinitic clays. Laboratory tests were used to determine the corrosion rates of 22 metals and alloys by weight-loss measurements in these two environments of the process. The results of this laboratory study were used both to suggest metals and alloys for field testing and to determine the effect of the individual solution components on the corrosion behavior of the metals and alloys. Results from the field tests were used to recommend Ta, Ta-2.5W, and Ta-10W for con¬struction of the agitators for the leaching process. The metals and alloys recommended for construction of the gas-sparging crystallizer heat exchangers were Ta, Ta-2.5W, Ta-10W, Nb, Nb-1Zr, Nb-3Zr, Nb-28Ta-10W-1Zr, Nb-10Hf-1Ti, and Zr for the first stage and Ta, Ta-2.5W, Ta-10W, Nb-28Ta-10W-1Zr, Nb, Nb-10Hf-1Ti, and Zr for the second stage.

Jan 1, 1981

These proceedings consist of an overview of the underground metal and nonmetal mina fire protection research currently being conducted by the Bureau of Mines. The following papers address the areas of prompt, reliable fire detection, fire planning and warning, fire suppression, and personnel protection. Selected topics are included here that cover fire protection systems for shafts, underground fueling areas, and mobile underground mining equipment; spontaneous combustion, improved stench, and product-of-combustion fire warning systems; computer-aided ventilation modeling; fire doors; and an investigation of fire hazards in mine timbers. The projects described provide a current documentation of problems being addressed.

Jan 1, 1981

By E. J. Matson

The Table Mountain copper deposit is in an isolated portion of north-eastern Churchill County, Nev. Although copper-bearing outcrops have been known to exist in the area since 1909, no copper ore has been mined. Development of the property has been hampered by poor roads and rugged topography. Until 1941, the last 4 or 5 miles to the property had to be traveled either by foot or pack animal. As a part of the Bureau of Mines program of investigation and development of domestic mineral deposits, a project was started at the Table Mountain deposit. The Bureau began its field work on July 29, 1947, and completed it on October 18, 1948. Thirteen holes aggregating 2,711 linear feet, were drilled; samples were analyzed - 509 from cores and 143 from sludges. This report contains a brief history of the district and a description of the geology, deposits, and drilling done by the Bureau.

Jan 1, 1949