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By Thomas M. Kohler, Gerald L. Finfinger, Gregory M. Molinda

The Bureau of Mines has completed an investigation of the effectiveness of methane drainage in the Lower Sunnyside Coalbed at Kaiser Steel Corp.'s Sunnyside No. 1 Mine in Utah. Most of the previous at- tempts to drain methane gas using long horizontal holes were conducted in the Eastern Coal Province. From the high degree of success realized in these efforts and the large body of knowledge gained from associated research, it seemed natural to extend the technology to western coalfields. Previous work had indicated that properties affecting gas drainage were variable in the Sunnyside Coalbed. In an attempt to characterize these properties, four degasification holes were drilled from the out- side entries of an advancing section. The holes were drilled to lengths of 780, 1,680, 1,315, and 1,047 ft and produced initial flow rates of 50,000, 180,000, 340,000, and 240,000 f t3/d, respectively. A total of over 300 million f t3 of commercial-quality gas has been removed from the Sunnyside Coalbed. The four holes have reduced face emissions by 78 pct.

Jan 1, 1986

By John C. Holtz

"INTRODUCTION Information on the gaseous products from the detonation of explosives has been obtained in two ways. In the first, the atmosphere in mines is analyzed after blasting, and in the second, the gases found after detonating an explosive in a testing apparatus are analyzed. The Bureau of Mines, in a cooperative research 3/ that compared data obtained in the field with those obtained in the testing station, showed that the results were not in entire agreement. The production of carbon monoxide was found to be governed chiefly by the oxygen balance of the explosive, but the production of oxides of nitrogen did not change in so simple a manner. Because of the increasing interest in correlations between the composition of the explosive and the production of toxic gases, it seemed desirable to continue the investigation.PURPOSE OF INVESTIGATIONAs field tests are both time consuming and expensive and as field results are affected by factors that are not always under control of or clearly evaluated by the operator, the purpose of this investigation is to develop a testing-station procedure that will reproduce the gaseous products quantitatively under known conditions analogous to those that may be expected in the field. In addition, the factors affecting the formation of toxic gases, particularly oxides of nitrogen, will be studied,"

Apr 1, 1940

By M. C. Irani

This Bureau of Mines survey of methane emissions indicates that total daily emissions have declined from 227 MM ft3 in 1971 to 214.7 MM ft3 in 1973. The highest average daily emissions in million cubic feet per day observed in U.S. bituminous coal mines were, in decreasing order, Monongalia County, W. Va., 40.7; Marion County, W. Va., 23.1; Buchanan County, Va., 22.1; Washington County, Pa. , 12.4; Greene County, Pa. , 11.7; McDowell County, W. Va. , 11.4; Cambria County, Pa., 9.8; Jefferson County, Ala., 9.5; Wyoming County, W. Va., 6.0; Marshall County, W. Va., 4.8; and Indiana County, Pa., 4.8.

Jan 1, 1974

By R. V. Ramani, C. B. Manula, A. Owili-Eger

The mine ventilation system consists of the fan, the roadways, and the regulatory devices. Sufficient fresh air must reach each working face in the mines to render harmless noxious, toxic, and respirable pollutants and to provide for the breathing of men. This is achieved by the proper selection of fan and regulatory devices. Because a mining system is dynamic, the mine ventilation system must also be dynamic. In short, mine ventilation engineers are frequently called upon to provide answers to the following questions: 1. Given a mine or the projected plan of a mine, what fan must be selected for the quantities specified in the section? At what point in its characteristic must it be operated? Are any speed changes or changes in blade settings warranted? 2. What should be the regulation in a section to insure cer¬tain desired quantity in that section? How does it affect the overall ventilation system? 3. What are the effects of driving a new shaft? Where should it be located? What size fan should be installed in the shaft? How does this affect the overall ventilation sys¬tem? 4. How much quantity increases can be obtained by cleaning up falls and streamlining roadways and by driving addi¬tional parallel airways? These questions are in no way exhaustive, nor are answers easy. Most of the operational and planning problems discussed above are to a cer¬tain extent solved by ventilation engineers using rules of thumb from experience. Both natural conditions and regulatory requirements have changed so drastically recently that use of scientific methods in ventilation planning and of faster methods in evaluating the plans is a must. Fortunately, computers offer the greatest hope for good

Jan 1, 1975

By Roy T. Sorensen

As part of its mission to maintain an adequate supply of minerals to meet national needs and maximize mineral production from domestic sources, the Bureau of Mines is investigating the recovery of alumina by hydrochloric acid leaching of kaolinitic clay. Most iron impurities are leached from the clay along with the alumina and must be removed before or during crystallization to aluminum chloride hexahydrate. The thermal decomposition step then provides an alumina product of acceptable iron analysis. Miniplant studies of a Bureau-developed solvent extraction technique, using a tertiary amine in kerosene diluent, have demonstrated that the iron content in aluminum chloride leach liquors can be reduced to levels of less than 0.007 wt-pct (7 ppm), expressed as Fe203. Entrained and dissolved organic matter in the purified pregnant leach liquor from the solvent extraction circuit can be reduced to less than 2 ppm by using a fabric-packed coalescer and subsequent activated carbon treatment. Investigators discovered that a steady buildup of zinc accumulated in the solvent phase within the extraction circuit, proportional to the amount of leach liquor treated. The solvent phase zinc analysis increased by 0.01 wt-pct ZnO for each 1,000 gal of pregnant leach liquor purified.

Jan 1, 1981

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

1, Introduction This report is submitted in fulfillment of the requirements of USBM Contract No. J0255017, "Development of Emergency Escape Systems Guidelines for Underground Metal and Nonmetal Mines" Under this contract the history of past mine fires was studied. Representative metal and nonmetal mines were surveyed and escapeways, refuge chambers, life support, and emergency hoist requirements were studied to determine the problems in complying with the proposed regulatory standards and their enforcement by MESA Mine Inspectors. In addition, a computer program was written to evaluate mine evacuation performance. The completed program is included in the appendix. 1. 1 Historical Review of Metal and Nonmetal Mine Fires Early records of mine fires are poorly documented because there was no statutory provision for reporting fires to the Bureau of Mines. The survey of representative mines during the course of this contract indicated that many small fires still go unreported even though they are now required to report all fires A recent report survey approximately 80 disasters in metal and nonmetal mines, (6 ) Table I is a summary of some of these fires. Historically most metal and nonmetal mine fires have been caused by electrical problems. Spontaneous combustion and the use of welding equipment are the other major causes of mine fires(14) Although not documented, many mine personnel agree that 30 percent to 40 percent of underground metal and nonmetal mine fires have their origin from cigarettes and other smoking related materials. The number of fires related to spontaneous combustion is decreasing and equipment fires are on the increase. The reduction of spontaneous combustion fires can be attributed to the use of sandfill in more mines and the increase in equipment fires to the increased use of LHD equipment.

Jan 1, 1976

By B. W. Gandrud, G. D. Coe

"INTRODUCTION The Southern Experiment Station of the U.S. Bureau of Mines, cooperating with the University of Alabama and Alabama coal producers, has made a series of investigations of the washability of coal from commercially important bens of Alabama. The results of 13 investigations pertaining to the Mary Lee, Clark, Black Creek, Jefferson, Pratt, Corona, Carter Brookwood, Blue Creek, Thompson, and Woodstock beds have been published. 4/ This report, the fourteenth of the series, deals with run-of-mine coal from the Henry Ellen bed at the Acmar No. 5 mine of the Alabama Fuel & Iron Co.The Acmar mine is 1/2 mile west of Acmar, Saint Clair County, in the northern part of the Cahaba field. Present production at the mine is about 800 tons per day, all of which, accept the lump coal, is treated in jigs. The washability data were obtained by means of screen-sizing and float-and-sink tests. There are included, also, tests showing the extent of liberation of impurities by recrushing the coarser sizes of coal from the top bench and tests showing the flakiness in selected sizes.SAMPLING AT THE MINEThe Henry Ellen bed at Acmar consists of two benches separated by a shale parting. At the point of sampling the top bench was 6 feet 3 inches thick and contained a 1-inch and a 1 1/2-inch band of bone. The bottom bench was 5 feet thick and was separated from the top bench by 20 inches of shale. In taking the samples for the washability study the working face was squared up, and a representative 2-ton section was out from each bench. The shale parting was discarded, according to usual mining practice."

Nov 1, 1936

By J. E. Conley

Available statistics show that the demands of the American chemical industry for sodium sulphate have been increasing slightly in recent years. The supply from domestic sources, particularly In the form of byproduct salt cake from the acid manufacturers, has been tending to decrease due to the growing manufacture of synthetic acid. Both hydrochloric and nitric acids are being synthesized from their elements. The natural result has been that a smaller amount of salt cake is available. Simultaneously, the expansion of the Kraft paper industry, especially in the South, has brought about greater demand for sodium sulphate in that section. This dean is being met by domestic byproduct salt cake, by imported German sodium sulphate made from potash waste liquors, and by favorable situated domestic deposits of Glauber salts and tile anhydrous salt, thenardite. No shortage of natural sodium sulphate exists in the United States, but usually such deposits occur in semiarid regions far removed from transportation facilities and from markets. Moreover, the major portion of the natural deposits is Glauber salt or mirabilite (Na2SO4 ? 10H20), which must be dried or dehydrated in order to meet consumer requirements. The water of hydration represents, roughly, 55 percent of tae total weight of the crude salts and therefore has a very important influence on transportation costs. In marry instances the cost of getting, even the dehydrated product to market is the deciding economic factor. Therefore, the recovery oil production of anhydrous sodium sulphate from plant-.waste liquors or from natural brines of suitable composition might be economically feasible. The U.S. Bureau of Mines, at its nonmetallic Minerals Experiment Station, New Brunswick, N. J., has, for a number of rears, been investigating the commercial possibilities of treating the complex saline mineral polyhalite (K2SO4?NgSO4?2CaSO4?2H20) for the recovery of potash and magnesia. Certain proposed processes (1, 2, 3, 4)4/ yield waste liquors that contain the bulk of the magnesium and sulphate originally combined as magnesium sulphate in the polyhalite molecule. Sodium chloride In limited concentrations is also present, as extensive beds of salt occur in strata overlying the polyhalite deposits. A typical waste liquor would contain:

Jan 1, 1936

By F. E. Wormser

"Arsenic has been recently quoted at 10 1/2 - 11 cents per pound, an increase over the prevailing price of last fall, when arsenic was cents, as against pre-war prices around 4 cents is evidently a sustained demand for this material. The following statements are intended to summarize briefly some particulars regarding arsenic.Commercial arsenic is the white arsenious oxide (As203). This is the form in which it is generally marketed, as the uses of arsenic demand its industrial application in this form. Arsenic as an element finds rather restricted use in the hardening of lead shot, ere it is to some extent replacing the use of antimony, while white arsenic is employed in a variety of manufacturing processes, chief of which is the manufacture of insecticides and sprays. The poisonous nature of most arsenic compounds, the commonly known ones being paris green and lead arsenate, and its relative cheapness, make arsenic a material suitable for this purpose. The stimulation of agriculture during the war greatly increased the demand for arsenical insecticide. Glass making consumes a large amount of arsenic as it has been impart increased brilliancy to the glass. Crude commercial arsenic is often used to kill weeds along railroad tracks. Arsenious oxide is used also for preserving hides, while the disulphide, AS2S2), finds an application in dehairing hides for the finest grade leather, as it least affects the product. Orpiment (As233), is used in textile dyeing. Wall paints and wall paper formerly consumed considerable arsenic in the form of paris green, but this use has been largely,given up due to the poisonous nature of the dust from the product. Sodium arsenate for a similar reason, is now little used in printing where it had found application. The great objection to arsenical yes and paints is the risk of poisoning from use of the manufactured article. Sodium arsenite is the principal poisonous in¬gredient of many cattle and sheep dips. Arsenic compounds are also used medicinally."

Jan 1, 1920

By T. C. Green

A two-phase program evaluated commercial proximity warning devices and then served to design and develop an automatic electrostatic field strength measurement device with improved performance. The Phase I program consisted of test and evaluation of three commercial proximity warning devices, all of which operate on the principle of electrostatic field intensity measurement for determining proximity to high voltage power lines. Performance testing of these devices utilized full-scale cranes and power line systems and a scale model facility. The evaluation results were reported in the Phase I report entitled "Evaluation of Proximity Warning Devices" dated 22 February 1980. Under the Phase II program, a microproressor-based data acquisition system was designed and developed to collect and measure field strength at distributed points around the crane boom. This unit (referred to as the Distributed Sensor AC Electrometer) measures the field strength about a crane boom using 17 distributed sensors. Keyboard control is provided for the equipment operator. Measured field strength values are displayed on a line printer and recorded on magnetic tape. Laboratory testing of this unit demonstrated performance characteristics and field strength measurement accuracy within the design goals. A Phase III measurements program is proposed using the AC Electrometer to map the field strength contours about power line configurations.

Jan 1, 1981

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By G. H. Keith

The Bureau of Mines determined the mechanism(s) involved in observed anomalous changes in mechanical properties of vanadium-base alloys. Tensile properties of electrorefined and commercial-purity vanadium-base alloys containing up to 5 atomic percent molybdenum or titanium were measured between 77° and 673° K. Snoek oxygen and nitrogen peak heights were measured to determine the changes in dissolved interstitial content caused by increasing quantities of solute. In addition, changes in lattice parameter were followed wit: precision X-ray techniques. Softening, observed in alloys containing titanium, is explained by the formation of a second-phase titanium compound with oxygen or nitrogen. However, because of partitioning of titanium between compound formation and solid solution formation, about five times the stoichiometric amount was required for complete reaction. Addition of 1 percent titanium drastically lowered the strengthening due to strain aging, at 673° K, and 2 percent titanium essentially eliminated it. All alloys were ductile at 77° K. Variations in the tensile properties of the molybdenum-containing alloys are explained by variations in the amounts of interstitial impurities present. The molybdenum did not react with these impurities and had no effect on strengthening due to strain aging. Commercial-purity vanadium alloys containing more than 2 percent molybdenum were brittle at 77° K.

Jan 1, 1969

By L. K. Weaver

The Bureau of Mines has started an engineering study of oil recovery by miscible-phase displacement. As a preliminary part of the investigation a literature and patent study was made to prevent duplication of work already done, to become acquainted with those actively engaged in research of this type, and to learn where the recovery method has been attempted. This bibliography gives results of this study. The bibliography includes 254 references to U.S. and foreign patents and published literature relating to miscible-phase displacement processes of oil recovery. It is divided into the following sections: (1) U.S. patents, (2) foreign patents, (3) literature references, (4) author index, and (5) publication and source reference. The patents and literature references are listed alphabetically by author by intervals of years. References to February 1963 are included.

Jan 1, 1963

"While control of dust-related diseases, the objective of the Generic Mineral Technology Center for Respirable Dust, is of prime importance from the human standpoint it is also essential to the economic well-being of the mining industry (FIGURE 23). Although significant progress has been made, the problem continues to be a major concern to the mining community. An increasing global demand for coal and other minerals means that production and the number of miners employed is on the rise. Therefore, the importance of this research to the mining industry cannot be overemphasized.The five areas of dust research are 1) control of dust generation, 2) dilution, dispersion and collection of dust in mine airways, 3) characterization of dust particles, 4) interaction of dust and lungs, 5) relationship of mine environment, geology, and seam characteristics to dust generation and mobility. Some experimental projects where the research is conducted almost exclusively in the laboratory may still rely on industry for imput. No industrial resources are necessary to the research of the non-experimental projects, for example computer modeling .The remaining research is classified as experimental and these projects do require interaction with industry in varying degrees. Periodic trips to mining sites in Western Pennsylvania, Southern Ohio, and West Virginia are necessary to record measurements or collect samples. Or companies may provide needed samples or equipment to the university for use in the laboratory. On several projects interaction is limited to advice or information supplied to the researcher by industry personnel."

Aug 31, 1989

By Bruce K. Cantrell, Stephen W. Stein, Kenneth L. Williams, David Hassel, Harvey Patashnick

In June 1992, the Mine Safety and Health Administration (MSHA) published the "Report of the Coal Mine Respirable Dust Task Group, Review of the Program to Control Respirable Coal Mine Dust in the United States." As one of its recommendations, the report called for the accelerated development of two mine dust monitors: (1) a fixed-site monitor capable of providing continuous information on dust levels to the miner, mine operator, and to MSHA, if necessary, and (2) a personal sampling device capable of providing both a short-term personal exposure measurement as well as a full-shift measurement. In response to this recommendation, the National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Center, initiated the development of a fixed-site machine-mounted continuous respirable dust monitor. The technology chosen for monitor development is the Rupprecht and Patashnick Co., Inc. tapered element oscillating microbalance. Laboratory and in-mine tests have indicated that, with modification, this sensor can meet the humidity and vibration requirements for underground coal mine use. NIOSH is continuing that effort by developing prototypes of a continuous dust monitor based on this technology. These prototypes are being evaluated in underground coal mines as they become available. This effort, conducted as a joint venture with MSHA, is nearing completion with every promise of success. The immediate benefit of this effort will be to researchers, regulatory personnel, and mine personnel, by permitting evaluation of specific mining practices to see which expose mine workers to excessive dust levels. Using this information, mine personnel can optimize mining procedures to reduce dust exposure. MSHA and the operators will also be able to use the dust concentration data to judge whether dust plan parameters are adequate to continuously maintaining environmental dust levels below the applicable standard. The second development recommended by the Dust Task Group was a person-wearable version of the continuous dust monitor. It will be a monitoring system designed to provide a measurement of worker exposure to respirable dust, both during and at the end of the shift.

The selective placement of coal stripmine overburden is examined. Physical and chemical properties of spoil detrimental to revegetation and groundwater are detailed. The United States is divided into regions or similar problems. Five mining methods already used in the industry, that are capable of selectively handling waste are examined in detail. Technical and economic comparisons are made for the systems when applied to realistic mine settings. The same analysis is conducted for five novel methods capable of selectively handling waste. Comparisons are made between novel and existing methods. Suggestions for new and modified equipment are outlined. Recommendations for further research are provided. This volume contains all Appendices to the report.

Jan 1, 1981

By Eric E. Cather

A mineral survey of the Fisher Gulch RARE II area (A5299), Trinity County, California was conducted by the U.S. Bureau of Mines and U.S. Geological Survey. The Bureau of Mines was responsible for detailed examination of mines, prospects, and mineralized zones; the Geological Survey conducted geological, geochemical, and geophysical studies of the area. The area is underlain by the Salmon Hornblende Schist. Tonalite stocks 1.5 mi (2.8 km) to the east and northeast of the area intrude the schist and are closely associated with the nearby nines (Cox, 1967). The mines have quartz veins containing sulfides and gold in shears trending east to north past in the schist and tonalite (Hotz, 1972). Strewn and terrace gravel s occupy most of the drainages, many have yielded substantial quantities of gold.

Jan 1, 1981

By Tuncel M. Yegulalp

The objective of this study was to categorize mining operations in the stone, and sand and gravel industries into areas of similar ground control functions and define initial factors affecting operational safety in each area, by means of utilizing publicly available data, telephone interviews and on site observations. The findings and recommendations presented in this report are based on the information collected during the two phases of the project. They also contain, in part, the collective qualitative opinion of the operators with respect to government rules and regulations on ground control safety and the implementation of these rules and regulations by government inspectors.

Jan 1, 1981

By J. E. Spurr

"Zinc Industry in BelgiumBy March F. Chase, Consulting Metallurgist, Bureau of MinesBelgium for many years was the principal spelter producing country of the world. Gradually its production was surpassed by that of Germany, and Germany in turn lost first place by the production in the 77ti.tad States. For the ten years previous to 1914, 21.6 per cent of the world's spelter was produced in Belgium. Of this production approximately 40 per cent was exported. A large percentage of the balance was rolled and of the shoots thus produced a considerable quantity was also exported.From an economic standpoint even before the war, the Belgian industry was in a unique, if not praoarious, position. Dependent upon foreign countries for ore and foreign markets for sale of products, smeltor was at a distinct disadvantage when compared with some of those of other localities. These disadvantages were partly offset by cheap coal and labor and by whatever there is of value in experience and what we may term for want of a better expression smelting tradition. However intangible this latter may be, it did have and has today an influence on commercial operations.One must not overlook the effect it will have on the revival of the industry. It may not be the determining factor but the fact that for so many years this industry flourished in Belgium, and played such an important role in the industrial life of the country will decide many operators to attempt to re-establish their operations.In 1913 the Belgian spelter plants produced 204,220 long tons of spelter or approximately 20 per cent of the world's production. During this year 500,000 to of ore were treated. The actual value of all of the products derived from treating sine ore amounted to 225 million frames."

May 1, 1919

By Ronald D. Hill, Elmore C. Grim

1. Potential groundwater pollution resulting from large-scale surface mining in western states should be evaluated. 2. Criteria should be developed for the design, construction, operation, and abandonment of sediment ponds for maximum removal of suspended solids. 3. Methods should be developed for reducing suspended solids discharges from surface mines to less than 30 milligrams per liter. 4. A manual should be developed in the form of guidelines for sediment and erosion control planning and implementation. These guidelines must be designed to cover all phases of the coal surface mining operation (i.e., before, during and after mining). 5. A mine road manual should be developed for use by surface mine operators and State and Federal Agencies. Erosion, water control, and dust control should be covered in detail. 6. The block-cut, head-of-hollow fill, and mountain-top removal methods and techniques of contour mining should be evaluated, designed, and ultimately demonstrated in steep, mountainous terrain. Designs should be prepared for single and multiple seam applications. The demonstrations must show that these mining systems will secure rapid achievement of reclamation require¬ments and provide maximum, safe, economic coal recovery in an environmentally safe manner. 7. A Blasting Manual should be developed for use by industry and enforcement agencies. Stress should be placed on how to keep vibration levels and air blast pressures well below accepted safe criteria. Also, methods that can be used to control noise should be listed. 8. Investigations should be conducted on the effect of continued vibrations from blasting on structures that are near quarries. 9. Additional guidelines need to be developed for sampling and analysis of overburden material and associated coals for trace elements and noxious strata. Samples are extremely sensitive, and the source and manner of their collection, handling, storage, and treatment, as well as the techniques of analysis, need to be developed and described. This information can be used to predict possible future problems.

Jan 1, 1974