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By Jerome J. Hoeppner, Walter W. Fowkes

The Federal Bureau of Mines has determined the distribution of forms of sulfur for several lignites and gasification chars and noted the changes induced by the gasification process . A method was adopted for quantitatively determining sulfide sulfur that was found to be present in the chars , although absent in the lignites . Changes in the behavior and distribution of sulfur forms were further investigated concerning the ashing of lignites and chars under standard conditions , as well as at various temperatures , and the determination of volatile matter applied to both chars and lignites . The authors concluded that the first and greatest change in the form of sulfur present in natural lignite , upon heat treatment , resulted from the reduction of pyritic and sulfate sulfur to sulfide . Organically - bound sulfur originally present is less reactive , but largely disappears on strong ignition . An appreciable part of the sulfur content of natural lignite is fixed in the char as sulfide and in the ash as water - soluble sulfate and will affect the summation of constituents , to a greater or lesser degree , in reporting the ultimate analysis of a lignite or char .

Jul 1, 1960

By H. W. Davis, Richard J. Lund

"In presenting the results of this survey on consumption of ferrous scrap and pig iron for the year 1935 the Bureau of Mines, responding to requests from industry, seeks to fill a major gap that has long existed in the field of metalliferous raw-material statistics. This type of information is designed to meet the needs of: (1) Consumers of ferrous scrap. including operators of blast furnaces, steel mills, ferrous foundries, and rolling mills; (2) marketers of scrap iron and steel, including large brokers who sell, and dealers who collect, prepare, and sell the material; (3) large scrap producers; (4) producers of iron ore, with which scrap competes indirectly; and (5) other individuals and agencies interested in more general economic analysis, since the scrap market has repeatedly been cited as one of the most sensitive of all industrial barometers, If the survey prover as useful as now seems probable, it will be continued annually with possibly an enlarged scope of treatment.The Bureau appreciates that its first efforts in this field may not meet all expectations: but it hopes to develop gradually, through suggestions, advice, and criticism from the industrial groups most interested, a type of analysis that will accord closely with technical processes and best meet the needs of all groups vitally interested in supplies and use of ferrous scrap. Constructive criticism and suggestions from industry regarding improvements to be desired in the conduct of future surveys on this subject will therefore be warmly received by the Bureau."

Nov 1, 1936

By Paul M. Tyler

The enormous deposits of greensand in New Jersey and elsewhere in the United States, many of them close to important octant industrial centers, constitute a perpetual challenge for research chemists to convert them into a commercial asset of national importance. Following the introduction of more concentrated fertilizers, comprising synthetic mixtures of more soluble salts, the quantity of greensand used directly upon the soil has diminished, but deposits of such material still have at least potential value locally for use not only as fertilizer but also as a water softener. An annotated bibliography of the already extensive Literature on greensand, virtually complete to about the end of 1929, has been issued by the Bureau of Mines3/, and the commercial aspects as well as the technology of greensand utilization are discussed in available publications, The purpose of the present circular, therefore, is merely to provide a brief outline of certain general essential considerations for use in appraising the potential value of a greensand deposit in any given locality.

Jan 1, 1934

By D. L. Paulson

The Bureau of Mines studied the feasibility of producing copper matte in an electric furnace from blends of copper concentrate similar to those currently smelted in a gas-fired reverberatory system at an installation in Tacoma, Wash. A 800-kva electric-arc furnace was used to determine the distribution of constituents when arseniferous concentrates are being smelted in an electric-arc furnace. Test results from smelting 40 tons of materials indicated that electric smelting is more like a conventional gas-fired system than originally expected. Although gas composition over the molten bath is much different in an electric furnace, the secondary constituents such as arsenic, lead, zinc, and antimony behaved the same as in a reverberatory furnace. The results established that an electric furnace would be compatible with sulfur and particulate recovery facilities that are being used.

Jan 1, 1976

By Jeffrey H. Welsh

The Bureau of Mines studied the use of computerized, continuous, remote monitoring systems for safety from power system faults in underground coal mines. In this report the need to improve protection against power system faults is documented, and types of faults are identified. The relationship between mine safety regulations and computerized, continuous, remote monitoring is analyzed.

Jan 1, 1983

By John A. Richards

This paper is one of a series being published by the Bureau of Mines on mining methods and costs. It describes briefly the manner in which slusher hoists and scrapers are used in connection with clock-caving methods at the Emma Nevada mine of the Consolidated Coppermines Corporation, Kimberly, Nev. Kimberly is in the Robinson mining district, White Pine County, 7 miles west of Ely. The district is served by the Nevada Northern -Railroad, which branches from the main line of the Southern Pacific at Wells, Nev., 140 miles north, Paved U. S. Highway 50 from Salt Lake City, Utah, to Reno, Nev., passes through Ely. The altitude at the collar of the Emma Nevada shaft is 7117 feet. The surrounding hills are covered with a sparse growth of juniper, pinon, and mountain mahogany.

Jan 1, 1940

By K. K. Kelley

The entropy values at 298.1° K. for the elements and inorganic compounds, on which sufficient data were available for calculation in 1931, were discussed in a previous publication (96).3 Since that time the specific beats at low' temperatures of many more inorganic substances have been determined, and considerable advances have been made in the realms of spectroscopy applicable to the determination of thermodynamic properties. Moreover, a critical study of the existing vapor-pressure data made by the author (98) furnishes entropy of vaporization results suitable for obtaining approximate values of the entropies of a number of gases from the entropies of the solids or liquids. Consequently, it appears worth while at the present time to supplement the former publication, giving the new values now obtainable and making such revision in the older values as the data warrant. The methods of calculating entropies were discussed in previous publications (96, 98) and will not be repeated here. ENTROPIES AT 298.1° K. FOR INORGANIC SUBSTANCES In the following pages, the same arrangement is followed as in the previous publication (96). All entropy values are expressed in 15° gram-calories per degree Kelvin per gram-formula mass of substance. The figures given for gases do not include the effect of nuclear spin, as is nearly universally customary at present. The estimates of accuracy in the case of the values obtained from heat-capacity data apply only to the existing measurements and to the necessary extrapolations as they are made. It is assumed usually that the substances are in such an energy condition at the lowest temperatures reached in the specific-heat measurements that the usual normal type of extrapolation may be made. No allowance is made for error in this assumption. The recent work on Gd2SO4. 8H2O and FeC13 illustrates the difficulties that may arise in obtaining the entropies of some paramagnetic substances. Also the data and calculations for such substances as CO, H20, and N20 show that the correct entropy is not obtained in all cases by indiscriminate application of the usual

Jan 1, 1936

By Forrest T. Moyer

To keep the mineral and allied industries informed of trends in the causes of accidents and to point, out the need for corrective measures, the Bureau of Mines collects, analyzes, and periodically publishes health and safety statistics. This report includes data for 1962 on injury experience, with related employment statistics, at coal mines in the United States. These data are presented in tabular form under the following: General Injury Experience Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location.

Jan 1, 1964

By O. C. Garst

"The lightness and relatively high strength per unit weight of certain magnesium alloys have interested designing engineers for many years. Ever since the noted investigator Bunsen3/ first produced the element by electrolysis of the fused chloride in 1852, utilization of this light metal has been considered. Magnesium is widely distributed over the earth's surface in high-grade as well as low-grade deposits; it occupies eighth place in the list of elements arranged in order of their decreasing abundance, as there is 2.24 percent magnesium in the earth's lithosphere. Even though the element is distributed widely in the form of relatively insoluble: minerals and also as soluble salts in sea water and spring water, as well as being an indispensable constituent of plants and animals, the technology of magnesium was slow development. This slowness of development was first caused by confusion or the part of the early investigators who thought that magnesia, magnesite, magnetite, and the pyrolusite-type manganese ores were compounds of the same metal. At one time the metal that we now know as manganese was called magnesium, and magnesium was called either magnium or talcium. In addition to this coon, the chemical activity of the metal, especially at high temperatures, created problems that are still difficult to solve.With the advance of science in all branches, .methods for -he production of magnesium were developed. The methods first used for producing the element were: (1) reduction of magnesium salts with alkali metals,4/ (2) electrolysis of aqueous solutions of magnesium salts, and (3) electrolysis of fused magnesiun salts.The first attempts to produce magnesium by the carbothermal reduction of magnesia were failures as sufficient thermodynamic knowledge concerning the reversibility of the reaction between magnesia and carbon was not at hand. As the igneous electrolytic Method for making the element was more easily controlled than the others and. yielded more metal per unit of energy, considerable work was expended on the improvement of this process. The work in this field paralled that on the electroreduction of aluminum and the alkali metals. For several years the entire magnesium industry was dependent on this igneous electrolysis process for its supply of the metal, but as demand for the metal increased and more scientific knowledge was available, other processes were developed. Today magnesium is produced by the electrolysis of molton magnesium chloride electrolytes, the carbothermal reduction of magnesia, in arc furnaces followed by shock cooling of the furnace gases by a coin inert atmosphere, and the silicothermal reduction of calcined dolomite in stainless steel retorts."

Mar 1, 1946

By H. W. Kilau

Thermodynamic calculations indicate that an electrochemical cell might serve as an analytical device for determining the composition of high-purity metals. An equation, readily derived, for the cell voltage, E, is as follows: [E I RT In F NFe unknown sample T of L NFe standard] The cell, however, must come to equilibrium, must be reversible, and must have no thermal effects or complicating side reactions whose magnitude is indeterminable. This Bureau of Mines investigation explores the feasibility of an electrochemical technique for the analysis of high-purity iron. Experiments were conducted using room-temperature aqueous cells and high-temperature molten salt cells. The room-temperature cells proved to be irreversible. The high-temperature cells utilizing FeCl2 and a eutectic mixture of KC1-LiCl were reversible, but did not attain a constant voltage necessary for analytical considerations.

Jan 1, 1963

By C. Melvin Lepper

The Bureau of Mines has developed an improved earth resistivity field system which employs a novel technique for obtaining null measurements. The instrument is designed to operate reliably in high-noise environments such as those found in the vicinity of operating mines. The system consists of a low-frequency transmitter, a sensitive receiver and an external battery pack, each in its own case to provide protection from the elements. The receiver and transmitter units have self-contained recharge-able batteries to supply power to the circuitry and separate built-in battery chargers that operate on standard 115 Vac power. The system is portable and simple to operate. Measurement accuracy, reliability, and dynamic range are superior to most commercially available equipment even though less time and effort is required to make null readings. Unlike some commercial systems, long integration times are not required to enhance signal-to-noise ratio in areas of high background noise.

Jan 1, 1974

By Gregory M. Molinda

The U.S. underground coal miner faces a continuing hazard from the fall of roof. At the root of many injuries and fatalities are weak or defective roof strata. Throughout mining history, millions of miles of entry have provided exposure of every conceivable geologic roof hazard. This report describes the geologic origin, association, and potential danger from the most common hazards. Discussions of weak rock include drawrock, rider coals, head coal, stackrock, and stream valley effects. Discontinuities, or roof defects, are described including, clay veins, slickensides, joints, and paleochannels. A number of examples from U.S. coalfields are used to document geologic structure and associated hazards. Roof fall analysis is a methodology used by NIOSH for hazard recognition and prevention; its application and benefit to the industry are discussed.

Jan 10, 2003

By L. C. IlsLey

Explosives have been fired electrically for several decades. Mountains have been tunneled, deep shafts sunk, extensive coal and metal mine workings excavated and, in times of war, railroads, buildings, bridges, and fortifications have been destroyed by means of electrically fired explosives. Modern engineering depends so much on explosives that their safe and efficient handling and especially their detonation are of prime importance to all those connected with the use of explosive agents. Electric shot-firing is only one method of igniting explosives, but it is rapidly spreading and because of certain inherent safety features should be encouraged. Data collected by the Bureau of Mines indicate that in the United States a large percentage of the blasting in quarries, shafts, and tunnels, and from 15 to 25 per cent of the blasts in mining operations, are set off electrically. The Bureau of Mines is interested in electric shot-firing because of its use in mining, and especially because electric methods, when properly applied, are undoubtedly safer than other methods commonly used.

Jan 1, 1926

By L. C. IlsLey

"There are two general classes of accidents that prevail in and about mines, namely - (1) those that through the nature of mining work can only be lessened, and (2) those that by proper precaution can be eliminated altogether. Explosive accidents that ordinarily take place while explosives are being transported in and about mines belong to the second class, that is, by proper care all such accidents can in general be avoided.The following table gives a brief summary of several accidents and disasters that have occurred in the United States and indicates the need of universal preventive measures as a basic part of all State regulations.ACCIDENTS AND DISASTERS OCCURRING WHILE TRANSPORTING EXPLOSIVES.***"

Sep 1, 1923

By W. E. Miller, Kennedy. R. E., G. W. Jones

"INTRODUCTION Ethyl mercaptan (CH3,CH2SH), a combustible organic liquid of the thioalcohol type, is employed at an odorant in many types of fuel gases and dangerous atmospheres, which in themselves are devoid of characteristic odors, to give warring against leakage of such gases or atmospheres into places where they might constitute health or explosion hazards.Ethyl mercaptan has a penetrating disagreeable odor resembling that of onions, garlic, hydrogen sulfide, or rotting cabbage, that exceedingly low concentrations of it can be detected. The of odorants as a beans of detecting leakage of gases and atmospheres has been investigated extensively by chemists and engineers of the Bureau of Mines, and numerous reports as to its value have been published."

Jun 1, 1942

By C. J. Walker, Ray V. Huff

The feasibility of inert - gas cushions in underground gas storages was studied by the Bureau of Mines in accordance with a continuing program of cooperative research between the natural gas industry -- through the American Gas Association . As mixing of the inert - gas cushion with the stored natural gas is undesirable , the various mechanisms tending to bring about such mixing were the subjects of both theoretical and experimental studies . These studies indicated the practicability of such cushions is dependent upon both reservoir and operating conditions . Equations and tables of illustrative data relating the various reservoir and operating conditions to the expected time required for undesired mixing to occur in ideal reservoirs are presented . This information permits estimating the relationship of such factors in actual storage operations .

Jan 1, 1964

By H. A. Thorne

This paper describing the mining practices at the Chino mines at Santa Rita, Grant County, N. Mex., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The Nevada Consolidated Copper Co., Chino mine's, operates an open-cut copper mine at Santa Rita, Central mining district, Grant County, N. Mex. This mine is located about 16 miles east and slightly north of Silver City, the county seat. The ore is-transported in standard railroad cars by the Atchison, Topeka & Santa Fe Railway Co., approximately 10 miles to Hurley where it is milled. The concentrated are shipped approximately l'70 miles over the same railroad to the smelter of the American Smelting and Refining Co., at El Paso, Tex. (fig. 1)

Jan 1, 1931

By H. E. Peterson, W. L. Anderson

"INTRODUCTION The great demand for tungsten incident to the war has led to the exploration of a large number of low-grade tungsten deposits. To properly evaluate the low-grade deposits it is essential to have available a dependable method of analysis applicable to all types of low-grade tungsten ores. Results reported on the tungsten content of the ores have often varied quite widely and have led to confusion. The Bureau of Mines has been requested by Government lending agencies and by companies interested in the production of tungsten to publish a general method for the determination of tungsten in low-grade ores. To meet this need, the Bureau of Mines is herein submitting two methods for analysis that have been proved on a large number of tungsten-bearing ores various types in the Bureau of Mines laboratory in Salt Lake City. Also, a third method was developed that requires no cinchonine and has proved to be applicable on most tungsten ores. The cinchonine method is the generally accepted for analysis of tungsten ores. Very reliable results can be obtained by this method if certain precautions are taken, as outlined in this report."

May 1, 1943

By L. R. Burdick

This paper presents a review of published investigation dealing with the importance of sulfur compounds in the deterioration of materials or providing some basis for estimating the extent of loss shareable to such air pollution. Materials included are cement, stone, metals, paint, leather, paper, sand cloth. The investigations may be divided into two classes, one of the laboratory type in which the sulfur content and the humidity of the air were controlled and the other dealing with the exposure of materials to atmospheres not under control. The first type of work has shown that cement is subject to deterioration by the action of sulfur dioxide gas. The experiments with stone indicate that although limestone takes up sulfur dioxide, from the air, moist sulfur dioxide-air mixtures alone cannot be used for establishing- the comparative weathering- qualities of the different types of stone by accelerated test methods. Laboratory tests indicate that sulfur compounds in the air accelerate the corrosion of iron, steel, zinc, copper, and nickel at normal air temperatures and at certain relative humidities. It has also been indicated that certain types of paint are, affected by high sulfur dioxide concentrations, and that paper is attacked by sulfur dioxide in the atmosphere. The investigations of the second type show the amount or variation of corrosion in different localities and under different types of exposure. The investigations (10) (18)4/ during which sulfur determinations were made indicate that sulfur dioxide is a main controlling factor in the corrosion of iron and steel but according to Quick (18) may not be for some nonferrous metals. In general, the laboratory tests do not Jive definite data on the loss due to sulfur compounds at the concentrations normally found in the air. The data from atmospheric exposures are not complete from the standpoint of the exact effect of the sulfur compounds. Damage to materials so exposed is affected by factors such as other chemical contaminants, humidity, rainfall, solid deposits, and sunlight. A simple scheme has been devised in Great Britain which is considered to provide a measure of the attack of sulfur compound, on building materials (1). Small cylinders coated

Jan 1, 1939

By Masami Hayashi

Cost evaluations were made for five processes for producing 100,000 tons of electrorefined copper per year from a chalcopyrite concentrate. The processes were (1) conventional smelting with all furnace gases vented to the atmosphere; (2) conventional smelting with converter gases routed to an acid plant and reverberatory gases vented to the atmosphere; (3) conventional smelting with converter gases routed to an acid plant and reverberatory gases to a citrate system plant; (4) conventional smelting with all furnace gases routed to a citrate system plant; and (5) a modified smelting process in which the concentrate is roasted before being charged to the reverberatory furnace, with roaster and converter gases routed to an acid plant. The total fixed capital costs of the plants were estimated as (1) $56.7 million, (2) $77.4 million, (3) $87.2 million, (4) $73.9 million, and (5) $77.0 million, respectively. Total S02 removal from stack gases as sulfuric acid or sulfur for each process was (1) none, (2) 66 percent, (3) 99 percent, (4) 98 percent, and (5) 78 percent. Assuming no credit for byproduct sulfur or sulfuric acid, total operating costs per pound of electro-refined copper produced were estimated as (1) $0.081, (2) $0.103, (3) $0.119, (4) $0.111, and (5) $0.103, respectively.

Jan 1, 1974