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By Arnold B. Hubbard

This report presents a hydrogenolysis study undertaken to obtain information on the constitution of the kerogen or organic material in Colorado oil shale and to determine some of the properties of the hydrogenolysis products. The high yield of hydrogenolysis products was separated, so far as possible, into type compounds; a number were identified. The results thus obtained were used as a basis for proposing the possible existence of certain structures in kerogen. To the authors' knowledge, few or no hydrogenolysis studies have been made of Colorado oil-shale kerogen by others. However, this method has been used in studying the constitution of coal. In general, the coal studies involved treating pulverized coal at different temperatures and hydrogen pressures with different catalysts. In some instances different solvents were used during the treatments.

Jan 1, 1959

By Harry W. Campbell

During 1983, the U.S. Bureau of Mines conducted a mineral survey of 19,700 acres that included the Fish Creek Mountains WSA (Wilderness Study Area), 15 miles southwest of the Salton Sea. Two United States Gypsum Co. claim groups in the WSA have more than .20 million tons of inferred gypsum reserves. These high-grade, surface and near-surface gypsum deposits are an extension of a gypsum bed that has been mined continuously since 1922. The Waters prospect in the central part of the WSA has large quantities of limestone suitable for many commercial uses. Sand and gravel is plentiful in the WSA in alluvial fan and ancient shore-line deposits. Limestone and alluvial deposits are not economic because similar material is closer to potential markets. No evidence of energy minerals or geothermal resources was identified in the WSA. A portion of the eastern Fish Creek Mountains WSA is leased for oil and gas exploration. United States Gypsum Co. holds eighteen unpatented placer claims in the northwestern part of the WSA. No other mining claims or mineral leases were identified in the study area. No mineral production is known from within the WSA.

Jan 1, 1986

By James P. Ulery, Jon C. Volkwein

The U.S. Bureau of Mines investigated a method of using inert gas to prevent the formation of explosive gas mixtures in auger highwall mining of coal. A combination of gasoline and diesel engine exhaust gases was introduced into the auger drill hole using a short section of pipe located at the collar. Gas samples were taken and analyzed on-site with infrared detectors for oxygen, carbon dioxide, methane, and carbon monoxide. Evacuated bottle samples were also taken and analyzed by gas chromatography in the laboratory. These gas results were analyzed for explosibility. Coal samples from various depths were used to obtain the gas content of the coal using the modified direct method. Personal expo- sure to carbon monoxide was also monitored. The highest methane level observed was 9.55%. The levels of inert gas (carbon dioxide and nitrogen) were sufficiently high to prevent any ignition of the methane. Results showed that for all conditions during mining, gas concentrations were nonexplosive. The gas content of the coal was about 0.30 cm3/g. The maximum personal time-weighted average sample for carbon monoxide was 20 ppm. This system provides a safe, inexpensive, simple method for pre- venting explosions during auger mining.

Jan 1, 1993

By Joe Maher

Adequate mine roof support to insure the safety of men and equipment is essential to successful mining. It is also expensive, amounting to more than one-fifth of the total mining cost at the White Pine mine. Cost effectiveness is therefore a prime consideration in developing optimum roof support. Roof bolt length is an important cost factor. This Phase II work compared uniform four-foot length Resin Bolts with the hitherto standard alternating four-foot and six-foot Resin Bolts, aiming at more cost-effective roof bolting. The data generated under this Phase II show that there is no discernible difference in the roof support given by uniform four-foot, and by alternating four- and six-foot, Resin Bolts in the relatively difficult ground selected for a severe initial test comparison; subsequent data from less difficult ground led to the same conclusion, namely no discernible difference between four-foot and four-six foot bolting.

Jan 1, 1975

By S. L. Gerhard

In the United States the performance characteristics of permissible explosives are controlled by routine tests, which include firing the explosive into a gallery filled with a methane-air mixture. These tests are made by the staff-of the Explosives Division of the Bureau of Mines and are similar, in general, to those employed in other countries. This control has helped to reduce the frequency of accidents involving the ignition of firedamp by explosives but has not clarified the basic causes of the ignition. To advance this control and to minimize potential hazards further, this fundamental knowledge is needed. Some of the results of recent research on the causes of the ignition are described herein. NATURE OF THE PROBLEM When an explosive ignites firedamp in the gallery tests, the source of the ignition must be one or more of the emissions from the steel borehole. It has been accepted generally that these emissions are (1) particles, (2) the shock wave, and (3) hot gases and flames. Photographs show that the shock wave emerges from the borehole first, followed closely by hot gases. At first the velocities of these are high and approximately equal, but the velocity of the gases decreases more rapidly than that of the shock wave, and by the time the reactions causing the flame are complete the shock wave travels in an otherwise undisturbed medium. The particles are originally enveloped in the hot gases but some soon begin to break through and eventually out-distance the shock wave. The approximate geometry of these emissions about 1 millisecond after the shot is fired is illustrated in figure

Jan 1, 1939

By S. L. Gerhard

In the United States the performance characteristics of permissible explosives are controlled by routine tests, which include firing the explosive into a gallery filled with a methane-air mixture. These tests are made by the staff of the Explosives Division of the Bureau of Mines and, are similar, in general, to those employed in other countries. This control has helped to reduce the frequency of accidents involving the ignition of firedamp by explosives but has not clarified the basic causes, of the ignition. To advance this control and to minimize potential hazards further, this fundamental knowledge is needed. Some of the results of recent research on the causes of the ignition are described herein. NATURE OF THE PROBLEM When an explosive ignites firedamp in the gallery tests, the source of the ignition must be one or more of the emissions from the steel borehole. It has been accepted generally that these emissions are (1) particles, (2) the shock wave, and (3) hot gases and flames. Photographs show that the shock wave emerges from the borehole first, followed closely by hot gases. At first the velocities of these are high and approximately equal, but the velocity of the gases decreases more' rapidly than that of the shock wave, and by the time the reactions causing the flame are complete the shock wave travels in an otherwise undisturbed medium. The particles are originally enveloped in the hot gases but some soon begin to break through and eventually out-distance the shock wave. The approximate geometry of these emissions about I millisecond after the shpt is fired is illustrated in figure

Jan 1, 1939

By D. G. Kuehn

Mass spectrographic studies have been conducted on the positive ions and neutral species of glow discharges containing 1.0 pct S02 and 1.0 pct CO in helium. Measurements were conducted for gas pressures from 3.5 to 10.1 torr using both dc and 60-Hz ac excitation. The ion species that were observed included S+, SO+, SO+, 0+, O2+, C+, CO+, and CO2+ with lesser amounts of SO3+, (CO)2+, SCO+, and (SO?CO)+ or CS+2. Interpretation of the functional dependence of the various ionic and neutral species on pressure and applied power showed that CO reacted with the SO formed in the discharges to produce CO2 and sulfur. Deposition of elemental sulfur was observed in the plasma container.

Jan 1, 1973

By Doug Scott

Develop tools that companies can use to comply with 29 CFR 1910.1200.

By Ad. Breyre

For more than 20 years, Belgium, leading all the coal-mining countries, has made increasing use of sheathed explosives, which wore first suggested by the late E. Lemaire, predecessor of the author gas Director of the Institut National des Mines. It appears to the author that it will be valuable to show how the use of sheathed explosives has developed in Belgium, how the various difficulties encountered in their manufacture have been overcome gradually, and the tyros of sheathing that have survived and the reasons for their survival.

Jan 1, 1940

By Fredrick L. Johnson

No mineral resources were delineated during our investigation of the Antelope Wilderness Study Area (WSA). Only a few claims have been located in the area and only four workings were found. There has been, however, considerable exploration and mining activity in and near the south end of the study area. The Morey mining district, just southeast of the WSA, produced silver, and lesser amounts of gold and lead, sporadically from the mid-1860's through the mid-1960's. Long Lac Mineral Exploration (Texas), Inc. is actively exploring a large block of claims for hot-spring type, low-grade, large-tonnage gold deposits. Their claim block extends into the study area. The WSA, located midway between Tonopah and Eureka, encompasses approximately 87,400 acres. It is underlain by Tertiary rhyolitic and latitic volcanic rocks and by Paleozoic sedimentary rocks. At least three areas in the Paleozoic rocks have many of the favorable criterion for hot-spring type gold deposits; they have been faulted, silicified, brecciated, and hydrothermally altered, and have anomalous concentrations of precious metals and pathfinder elements. With additional exploration in the south part of the Antelope WSA, gold resources may be discovered.

Jan 1, 1986

By R. Lincoln

A surplus of vanadium has resulted from the tremendous output of uranium, of which vanadium is a byproduct. More knowledge of the properties and characteristics of vanadium as a pure metal has been needed so that industry can take advantage of its availability and use it according to the best principles of conservation. Besides the problem of utilization, there is the ever present need of finding new materials which will satisfy specific and demanding requirements of science and engineering; vanadium or one of its alloys may possess the latent potential for filling some of these needs. Thus this? research project was undertaken by the Bureau of Mines to determine and examine some of the physical and mechanical properties of pure vanadium. A corallary investigation was the determination of the effect of the interstitial contaminants, oxygen, nitrogen, and carbon, on unalloyed vanadium. The vanadium used for these determinations was principally the product of experimental production of the Bureau. The evaluation of this material, as small quantities became available, provided most of the data that have been obtained.

Jan 1, 1962

By Kenneth M. Earl

In its investigation of deposits of strategic minerals, the Bureau of Mines did same development drilling at the Perkiomen Creek deposits, 5 miles east of Phoenixville, Pa. This area was the center of much copper mining from 1851 to 1858. The most productive vein was the Perkiomen-Ecton mines, owned by the Perkiomen Consolidated Mining CQ. The mines were closed in 1858, and no further production has been recorded. The Perkiomen-Ecton vein ranges in thickness from 2 to 19 feet. The principal mineral of value is chalcopyrite, with minor amounts of galena and sphalerite. No definite record was found as to the grade of ore min d. It was reported that 617 tons of 18-percent copper are obtained by hand sorting 12,200 tons of mine-run ore was shipped in 1851-1852. To cut the vein below the old mine workings, the Bureau of Mines diamond-drilled five holes aggregating 2,216.2 feet. The vein, where intercepted by drilling, carried narrow stringers of copper, lead, and zinc minerals.

Jan 1, 1950

By S. J. Anderson

The Bureau of Mines compared three methods of rock cutting using drag cutters under controlled laboratory conditions. The methods tested were the conventional drag cutting method used on continuous miners, the kerf-core method used on some boring machines, and an experimental method called ripper cutting. All three methods were tested in blocks of Indiana and Kasota limestone. The results of this testing showed ripper cutting to be 30 to 40 pct more energy efficient than both the conventional and the kerf-core methods in Kasota limestone and 35 pct more efficient than the kerf-core method in Indiana limestone. The conventional method was, however, 9 pct more energy efficient than the ripper method in Indiana limestone. These results are considered promising, and more tests are planned with the ripper cutting system.

Jan 1, 1987

By W. H. Goghill

Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with so many "inflection points" and "counterflexures" that they obscure the issue. Some of the investigators have neglected the very essence of the problem, namely the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration. Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.

Jan 1, 1934

By J. J. Demeter

A tube-wall reactor with a Raney nickel catalyst deposited on the outer wall of the tube by flame spraying is effective in the practically complete conversion of 3H2+1CO synthesis gas to a high-Btu gas (methane) at an hourly space velocity of 7,000 volumes of gas (NTP) per hour per volume of annular volume. Partially reacted synthesis gas containing an appreciable amount of methane can also be treated in this reactor to increase the heating value to over 900 Btu per cubic foot. Excellent heat removal through the metal wall to a coolant and temperature control were obtained. The heat transfer co-efficient from the catalyst to the coolant was about 275 Btu per hour per square foot per ° F. Synthesis tests were conducted with tubes 1.2 inches in ad by 6 inches long, and 1.3 inches in od by 36 inches long. When operating at a synthesis gas rate of 100 to 120 scfh per square foot of catalyst-coated tube, catalyst life was long enough to realize a catalyst cost for the raw Raney nickel alloy of about 0.3 cent per 1,000 cubic feet of pipeline gas (900 to 950 Btu per scf). Gas recycling at ratios of 1:1 to 3:1 was effective in increasing conversion and in extending the life of the catalyst to about 16 weeks. In cost and in operating characteristics the tube-wall reactor compares favorably with the fluidized-bed and hot-gas-recycle reactor systems for the synthesis of high-Btu gas from H2+CO.

Jan 1, 1967

By Frank J. Perzak

This report describes a U.S. Bureau of Mines study on the hazards of large-scale conveyor belt fires in underground coal mines, as a function of both air velocity and distance from belt surface to gallery roof. The fire hazards considered were smoke obscuration, toxic effects of carbon monoxide (CO), and elevated air temperatures downstream of the fire. All of these hazards scale with the ratio of fire intensity to ventilation airflow. These hazards were all found to be greater at the lower belt-to-roof distance, owing to the greater fire intensities that resulted. The hazards of smoke obscuration and elevated CO levels were greater at lower air velocities. Smoke obscuration was found to be the earliest hazard, reaching critical levels before the stage of belt flame spread. Critical levels of CO and downstream air temperatures were not reached until the later stages of flame spread. Fire growth rates during rapid flame spread were much greater than rates measured during the early stages of belt burning. Data were analyzed to determine the early-warning capability of fire sensors. Smoke sensors provided the earliest warning, followed closely by CO sensors. Thermal sensors did not exhibit any early warning capability.

Jan 1, 2010

By A. W. Deurbrouck

The Bureau of Mines reviewed available data on the effect of crushing high-sulfur coals for the liberation of impurities in the light of increasingly stringent air pollution regulations. The survey, which provided information on Appalachian region coals only, indicated that such important coal- beds as the Upper and Lower Freeport and the Upper Kittanning show significant sulfur reductions when crushed to 14-mesh top size. For many other coalbeds amenability to sulfur liberation by crushing was indicated, although too few samples were available to draw firm conclusions,

Jan 1, 1966

By G. T. Lineberry, W. J. Wiehagen

A Paradigm Shift As market economists, mine managers are interested in "staying in business" and even "prospering." Bottom-line results are the "order of the day." Concern for bottom-line results invokes questions such as: How much was produced? At what cost? And, was anyone injured? While these questions will always carry everyday emphasis at the mine, they are fundamentally lacking in that they often appear, especially to lower levels of management and to the production worker, as preeminent concerns. Driven by market economics, many organizations have decentralized, outsourced, downsized, restructured, and formed new coalitions. Investments in new technology and concentration on productivity have been part and parcel with these changes, contributing to improvements in both safety and efficiency. A reason for (and, perhaps a result of) these improvements has been the development of a highly experienced and flexible work force. These changes in mining present an interesting opportunity to modify a few paradigms about work life in general, and perhaps a few paradigms about how we invest in the miner, in particular. Studying these issues now might offer some interesting opportunities for the future, as the foundations for the next generation of mine workers are laid. With the average "experienced" U.S. miner five to fifteen years from retirement, perhaps a key determinant of future success in the world market might be how well we make the transition from today's work force to the work force of tomorrow. We can ill afford to wait a few more years to tap into the special knowledge residing within a veteran mining work force. The WCPM work Crew Performance Model, see pp. ) is one approach to defining, capturing, and transferring this expertise.

By L. B. Berger, W. P. Yant, R. R. Sayers

"At the request of the Chesapeake & Ohio Railroad Co. a number of tests were made to determine the temperature, humidity, and composition of the atmosphere in certain tunnels of that railroad between Clifton Forge, Va., and Hinton, W. Va. The purpose of these tests was to determine conditions in the cabs of freight locomotives while pulling trains through these tunnels. Tests were made of two types of locomotives, classified by the railroad company as the H-6 and H-7. Both are of the Mallet type, but the H-6 class has one pair of cylinders operating at boiler pressure and the other pair compound, whereas the H-7 operates all four cylinders at boiler pressure, thereby exhausting steam at a higher temperature than the H-6. It was desired to determine the relation between conditions on the H-6 and H-7 engines under comparable conditions of operation. This information supplements previous tests by the Bureau of Mines, discussed in its Reports of Investigations Serial No. 2624, entitled, ""Temperatures in Cabs of Freight Locomotives Passing Through Tunnels of Chesapeake & Ohio Railroad, 11 by s. H. Katz and E. G. Meiter, July, 1924. Three incidental tests of passenger engines were also made."

Feb 1, 1928

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990