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By Masami Hayashi

The Bureau of Mines conducted laboratory studies to investigate methods for desilicating sodium aluminate solution derived from leaching a limestone-anorthosite sinter with 10-pct Na2C03 solution. Desilication tests were made at atmospheric pressure to determine the effects of time and additions of lime and desilication residues. A two-stage, countercurrent desilication procedure was developed to reduce the Si02 content sufficiently to meet specifications for cell-grade A1203. Both stages were conducted at boiling temperatures at atmospheric pressure. Reagent lime was charged as desilication seed to the partially desilicated solution in the second stage, and a product (desilication residue) precipitated by the lime addition was charged to the freshly leached solution in the first stage. Average A1203 loss in the desilication circuit was 5.8 pct, and the product solution contained less than 0.04 g/l Si02. Complete precipitation of A1203 by carbonation resulted in a hydrate containing less than 0.01 pct Si02. Calcination of this hydrate would produce A1203 meeting the 0.015 pct Si02 specification for cell-grade material.

Jan 1, 1982

By I. Liebman

The Bureau of Mines conducted research to develop triggered barrier systems for protection against gas explosions that can occur in underground coal mines during the use of continuous miners. Several extinguishing agents were tested in barriers at a simulated mine face. Water, powered by pressurized nitrogen, was found to be efficient in stopping fully developed gas explosions, but it had little effect against the explosion during its incipient stage. Hybrid combinations of currently known extinguishants, however, were successful against incipient explosions. Three hybrids that were developed and tested consisted of Halon 1301, combined with either an aqueous foam solution, water, or a dry chemical powder. The three hybrids were found to be more efficient than any constituent alone. Results of the tests point to a synergism between the hybrid components, and indicate that the Halon aids in dispersing its constituent and also converts the aqueous foam solution into a stable fine foam and the water into fine drops.

Jan 1, 1978

By Ann C. Kim

This Bureau of Mines report summarizes the methods and results of many of the laboratory studies on spontaneous heating of coal published in the last 50 years. It includes a brief description of experimental methods, indices of combustibility, and important contributing factors. Adiabatic calorimetry, isothermal calorimetry, [0], sorption systems, or temperature differential are the most frequently used experimental methods. Indices of combustibility include various heating rates, crossing point temperature, ignition temperature, and CO index. Factors that affect the spontaneous heating of coal include air flow rate, changes in moisture content, particle size, rank, temperature, pyrite content, geological factors, and mining practice. Experimental conditions and results from 20 papers are summarized in an appendix, and the bibliography contains 45 references.

Jan 1, 1977

By Walter C. Woodmansee

The only reported mineral production in 1977 was small output of alluvial gold, valued at an estimated $54,320.2 In addition, marine shells are gathered for use in lime manufacture, although output was not reported. Proposed development of a bauxite mine and smelter, involving Rennell and Vaghena Islands, was deferred in June. Conzinc Riotinto of Australia Ltd. (CRA), in partnership with Mitsui Mining & Smelting Co. Ltd., and the Solomon Government, with- drew from the project, and Mitsui, which conducted a feasibility study and metallurgical testing of the bauxite, decided to defer further work because of slack demand for aluminum in Japan and difficulties in arranging financing. The Mitsui feasibility studies reportedly indicated that the project could be viable despite technical difficulties and relatively high initial investment costs. The project was to produce 1.5 million tons of bauxite and 600,000 tons of alumina per year from reserves totaling 60 million tans at 45% to 50% A1203.

Jan 1, 1981

By Thomas O. Glover

Cameroon continued to enjoy sustained economic growth that began with its independence in 1960. Growth in the gross domestic product (GDP) averaged 2.8% per year during the 1960's and the first half of the 1970's. Starting in 1976 and for the succeeding 10 years, the GDP accelerated rapidly owing to the coming on-stream of Cameroon's small but domestically significant offshore oil industry. In 1985, the GDP grew by 7.8%, but in 1986, it was only up 5.5%. The country's sustained economic growth in dollar terms of gross national product (GNP) per capita reached $1,075 in 1986. The ranking in GNP per capita by the International Monetary Fund put Cameroon in the middle-income category for developing countries. The sustained economic growth rate up to 1986 was due to the injection of income from oil into the economy, but crude oil price reductions in 1986 brought a slowdown. In 1986, crude oil production grew to 200,000 barrels per day, an increase of 8.2% from that of 1985. Most of the oil came from the Société Nationale Elf Aquitaine (SNEA) wells in the multifield Rio del Rey complex. Additional output came from the Moudi Field operated by Compagnie Française des Pétroles S.A. Proven oil reserves in Cameroon were 540 million barrels. At 1986 production rates, and in the absence of further discoveries, Cameroon will have exhausted its recoverable oil reserves by the year 1995. Owing to worldwide crude price reductions, the country's oil income fell 60% between 1985 and 1986, from $1.82 billion2 to $0.72 billion. Cameroon's refinery operator commenced operating the Sonara refinery in 1981 at Point Limboh. Sonara's capacity of 43,000 barrels per day was small by most standards. In 1986, natural gas reserves, estimated at 100 billion cubic meters, were not produced commercially because there were no domestic users. Proposals for a multibillion-dollar liquefied natural gas plant at Kribi had been submitted; however, work on the plant had not commenced.

Jan 1, 1988

By R. L. Derick

On a regular basis, mine personnel should obtain air samples directly from active underground areas as well as remotely from sealed locations. These samples provide mine officials with data relative to the makeup of the various atmospheres. Should conditions underground change, these results can provide a baseline that can assist officials in determining the extent of change. Relating the concentrations of individual gases to time, applying gases to equations, and examining their change over time are tools that have been successfully used to determine if a heating event exists and, if so, the extent of the emergency. These atmospheric status equations have either been developed for the mining industry or adapted from other industries. They serve as tools to assist personnel in determining the condition of underground mine atmospheres. As long as the problem area continues to be ventilated, certain gases, gas ratios, and equations can be used to determine if a fire exists, what type of material could be burning, and what quantity of coal is burning. Once the mine or the involved section has been temporarily sealed, gases, ratios, and gas-derived equations can assist personnel in determining how conditions within the sealed volume are changing over time. To alleviate potential explosions when fresh air is once again introduced into the sealed volume, equations and a diagram have been developed to predict the likelihood of an explosive atmosphere. Similarly, prior to commencing recovery of a mine or section, equations exist that can assist in determining if the fire will rekindle when air is reintroduced. This paper serves as an overview to remind and/or instruct readers about gas-sampling methodologies and gas analyses to assist in determining the status of underground atmospheres.

By M. E. Tyrrell

To promote greater use of abundant domestic raw materials in the manufacture of synthetic mullite, the Bureau of Mines has undertaken a comprehensive investigation to determine the effects of the impurity oxides TiO2, Fe203, and alkali on physical properties of sintered mullite-forming mixtures. The first part of the report presents the results of work covering a major area within the mullite study; namely, the effect of impurity oxides on volume stability, one of the outstanding characteristics of mullite refractories. The volume stability of 20 compositions in each of 3 alumina- to-silica ratios, which blanket the range commonly found in purchase specifications, has been determined following procedures of Navy Specifications B-15606 A for Grade A high-alumina refractories. Results indicated that so long as 5 percent of impurities are combined approximtely in the proportions of 3 percent Ti02, 1 percent Fe203, and 1 percent alkali, sintered mullite-forming compositions in the almina to silica range tested will be volume stable. A permissible tolerance of one-half per- cent in each impurity oxide provides a range that includes values common in the natural minerals from which sintered mullite may be made. Within the total range of 5-percent impurity mixtures, a greater number of volume-stable compositions were obtained by increasing the alumina-silica ratio.

Jan 1, 1962

By Fred N. Kissell

In This Chapter [Ventilation and methane sampling guidelines for conventional shafts Dealing with restricted spaces where methane can accumulate Ventilation and methane sampling at raise bore drills and Filling shafts at closed coal mines] It is not unusual to encounter methane gas during shaft excavation or shaft-filling operations. Shafts into coalbeds usually produce the most methane, so the information in this chapter applies primarily to shafts at coal mines. Nevertheless, much of the information is relevant for noncoal mines that have methane in the mine or in the overlying strata. METHANE IN SHAFTS EXCAVATED BY CONVENTIONAL MEANS (DRILL, BLAST, MUCK) [ ] Ventilation. Shafts excavated by conventional means are ventilated with a fan on the surface connected to ductwork that extends down into the shaft (Figure 9–1). Shafts into coalbeds should have ventilation systems designed to handle the higher gas flows to be expected as the shaft excavation passes through any over-lying gas-containing strata and nears the coal-bed to be mined. Following are some simple ventilation guidelines for the minimum amount of air required and the selection of the ventilation duct: • Provide enough air to meet the mini-mum OSHA tunnel requirement of 30 ft/min air velocity in the open shaft, as specified in 29 CFR2 1926.800(k)(3). For example, a 20-ft-diam shaft having

Jan 6, 2006

This document is Volume II of a two-volume report on underground and surface coal mine fires occurring between 1950 and 1977. Volume I discusses the methods of data acquisition, data analysis procedures, results and conclusions. This volume contains (1) a master list of all fire incidents obtained from MSHA reports, (2) an annotated bibliography of all MSHA reports, journal articles on selected incidents, and non-reportable fires (appendix), and (3) indexes to be used in accessing incidents in the master list and annotated bibliography. These three types of information provide the reader with a complete summary of coal mine fires during the period from 1950 through 1977 and a convenient means to locate incidents of specific interest. The body of this volume is organized around two tables and a series of indexes. The two tables are master lists of underground and surface fire incidents. They are followed by 14 indexes keyed to the master list and annotated bibliography. The appendix contains three different parts: o The annotated bibliography of MSHA fire reports (one section each for underground and surface mine fires) o The annotated bibliography of journal articles about selected fires from the MSHA bibliography o A listing of non-reportable fires (one section each for underground and surface mine fires) Descriptions of the contents and use of each of the three major components of this volume (i.e., master list, indexes, and appendix) are presented in Section 2.0.

Jan 1, 1979

By M. M. Wong

Beryllium possesses attractive properties for use in the nuclear and space fields. Since fused-salt electrorefining can be employed to produce this metal in high-purity form from low-grade or scrap metals, the Bureau of Mines investigated electrorefining of beryllium in electrolytes composed of a LiC1-KC1 eutectic mixture plus varying amounts of BeC12. Results showed a 99- percent or better reduction of oxygen and magnesium and a substantial reduction of other minor metallic impurities. Extremely pure beryllium metal was produced. Operating variables, including BeCl2 concentration in the bath (3.5 to 16.5 mole-percent), temperature of operation (450° to 550° C.), and cathode current density (45 to 770 a,/sq, ft.), were studied; their effects on the deposition of metal, working condition of the bath, and purity of the refined metal are discussed. The safety precautions used in handling beryllium in the laboratory are also described.

Jan 1, 1962

By Peter de Bakker

The objective of this contract was to develop a simple, reliable, economical, remote-control roof bolting module for installation of mechanical and resin bolts. It was to be capable of placing longer than seam height bolts, up to 10 ft lengths, from a seam height of 36 to 72 in., while keeping the operator under supported roof. The resulting machine, called REM-Bolter, is a low profile unit that utilizes Foster-Miller Flexible Shaft Roof Drill, a Bendix Roof Bolt Inserter and a newly designed. Roof Bolt Lifter/Torquer. Every effort was made to strike a compromise between complete automation and complete manual control. In a controlled laboratory environment the REM-Bolter remotely installed 1000 bolts. Subsequently the machine was tested in an operating coal mine where 500 holes were drilled (and an equal number of bolts were installed) remotely, over a 4 month period. The results of all tests Live shown that the operator of a machine of this kind can quickly, and repeatedly, install rootbolts remotely from his operator compartment some 8 ft away from the drilling/bolting action. The report includes recommendations for improvements to the present REM-Bolter design that would translate the present test bed into a second generation test bed and a potential first generation production unit.

Jan 1, 1983

By Harry W. Campbell

A mineral survey conducted by the U.S. Bureau of Mines in 1983 identified no mineral resources in the Beaver Meadows, Blind Horse Creek, Chute Mountain, Deep Creek/Battle Creek, and North Fork of Sun River Wilderness Study Areas (WSA's). A prospect east of the Beaver Meadows WSA has low potential for lead resources. Sand, gravel, and limestone occurrences are numerous in the WSA's; however, similar or better quality materials outside the areas are abundant and more accessible to potential markets. Impure coal and titaniferous-magnetite occurrences are near the WSA's, but are not known to occur within these areas. In 1983, there were 7,025 acres leased for oil and gas within the five WSA's; no current mining claims were in or near any of the WSA's. Evidence of mining activity was found at only one prospect in the WSA's. It is inside the Deep Creek/Battle Creek WSA; no resources or resource potential were identified at this prospect.

Jan 1, 1984

By Harold L. Rhodes

The Bureau of Mines has developed a quantitative method to determine water vapor in helium in the range of 0.1 to 15 ppm by volume. This method uses the quantitative chemical reaction of H20 with CaH2, which produces 1 mole of hydrogen for each mole of H20 in the sample. A gas chromatograph is then used to determine the concentration of hydrogen in the product. The precision of the H20 analysis is ±0.05 ppm at a concentration of 1 ppm. This method is used to calibrate a commercial platinum-phosphorus pentoxide (Pt-P205) electrolytic water vapor analyzer that has an improved inlet system and digital voltmeter readout.

Jan 1, 1981

By G. W. Jones

As part of its program for the promotion of safety, the Bureau of Mines has investigated various means of mitigating or eliminating the explosion hazards of combustible gases and vapors found in the mining and other industries. Knowledge as to the explosive characteristics of cyclopropane in air, oxygen, and other gaseous mixtures is of both theoretical and practical importance because cyclopropane is now used extensively in anesthesia. As such an agent it has many desirable characteristics, and increased consumption of this gas may be expected if the explosion hazards now attending its use can be minimized or eliminated. The present practice of using mixtures of approximately 20 percent cyclopropane and SO percent oxygen should be discouraged because such mixtures are violently explosive and have led to fatal accidents.

Jan 1, 1940

By G. W. Jones

As part of its program for the promotion of safety, the Bureau of Mines has investigated various means of mitigating or eliminating the explosion hazards of combustible gases and vapors found in the mining and other industries. Knowledge as to the explosive characteristics of cyclopropane in air, oxygen, and other gaseous mixtures is of both theoretical and practical importance because cyclopropane is now used extensively in anesthesia. As such an agent it has many desirable characteristics, and increased consumption of this gas may be expected if the explosion hazards now attending its use can be minimized or eliminated. The present practice of using mixtures of approximately 20 percent cyclopropane and 80 percent oxygen should be discouraged because such mixtures are violently explosive and have led ,to fatal accidents.

Jan 1, 1940

By R. L. Grayson, S. S. Peng

"Research has been conducted during the past year on a study to correlate respirable coal mine dust characteristics with worker positions and coal seams. The first characteristic of respirable coal mine dust which has been addressed in the correlation study is respirable dust mass concentration. In fulfillment of this objective, two mines operating in different coal seams have been selected for respirable dust mass sampling on both longwall panels and continuous mining sections. At present, sampling has been completed on the longwall panel operating in the first mine, and one half of the planned sampling has been accomplished on the continuous mining section.The first mine sampled is operating in the Pittsburgh coal seam. The average mining height is approximately 78"" with an average of 8"" of bottom shale being mined. The mine is primarily a longwall mine, and continuous mining machines are used to support the longwall.Figure 1 shows the layout of the longwall panel which was sampled. Intake air is coursed via the track heading up to the headgate area. The air splits at the headgate. Approximately 20,000-30,000 cubic feet of air per minute (CFM) is used to ventilate the longwall face and about 5,000-10,000 CFM is routed down the belt entry. Substantial leakage across the gob was noted during the sampling period. An average of 1800 CFM per 100 feet of face leaked through the shields into the gob from #1 shield to #112 shield. A substantial amount of leakage also occurred between the #1 shield and the solid rib of the headgate development panel. The path of the air used to ventilate the panel is shown with arrows in Figure 1. Direction of air flow was opposite to the coal moving direction on the armored face conveyor.A double-drum ranging shearer is used on the face to cut a 30-inch web of coal. Normal practice is to cut from the tailgate to headgate with the leading drum raised and the tail drum lowered for cutting bottom. After reaching the headgate, the shearer is reversed and both drums are lowered for a clean-up pass. The last 40 feet of face on the tailgate is cut on the clean-up pass.The shearer is equipped with 2 banks of 4 water sprays each and 2 large sprays on the headgate end and 1 bank of 4 sprays on the tailgate end. Additionally, sprays are located above bits on the cutting drums. Actual cutting speed was approximately 14-18 feet per minute, depending on conditions.The cross sectional area for air flow on the face was approximately 60 square feet before a pass was mined and 80 square feet after a pass was mined but before the shields were advanced. The cross sectional area at the shearer was about 35 square feet.The condition of both the tailgate and headgate of the panel was good with no signs of significant roof problems. The roof conditions along the face during the sampling period were variable. At times, as much as 3 feet of drawslate fell from the roof for a span of as much as 40 shields. Generally, however, relatively local areas of falling roof were encoun-tered, usually limited to a 10-20 shield span when appearing.Ten days were spent gathering respirable dust samples on the longwall panel. Mine Safety Appliance (MSA) sampling units equipped with 10-mm nylon cyclones, pre-weighed MSA PVC filters, and constant-flow DuPont pumps were used to obtain thesamples. The pumps were calibrated at a 2 liters-per-minute flow rate. The 10-mm cyclone was selected for classifying total dust into the desired respirable fraction in order to obtain ""legally defined"" respirable dust samples for detailed physical characterization."

Jan 1, 1988

By G. W. Jones

In a previous report'/ results were given and a method outlined whereby from a knowledge of the composition of the natural gas and of the inflammability limits of the individual constituents composing the natural gas, the limits of inflammability of natural gas and air mixtures could be closely calculated. This method is based on the application of Le Chatelier's law as modified by Coward, Carpenter and Payman,5/ to apply to a mixture of any number of combustible gases. This law must not be used indiscriminately, because many exceptions have been found. For example, when ethylene, acetylene, hydrogen sulphide, or chlorinated hydrocarbons are present the law may not hold. For a discussion of the many exceptions which have been found, reference should be made to a report by Coward and Jones.6/

Jan 1, 1933

By Paul M. Ambrose

Overall the domestic abrasives industry had one of its best years in 1965. Production and value of all commodities increased over that of 1964 which also was a good year. Production of tripoli that was down in the previous year rebounded and production from two new mines was reported. Plant capacities for production of silicon carbide and fused crude aluminum oxide and production from plants in the United States and Canada increased, but demand was high and yearend stocks were less than at the end of 1964. Foreign Trade.-Increases in value of most imports of abrasive materials in 1965 were offset by a decrease in the value of imported industrial diamond. Production of fused aluminum oxide and silicon car-bide in the United States and Canada and imports of these commodities into the United States increased, but combined exports of finished grain of these materials was virtually unchanged from the previous year.

Jan 1, 1966

By Robert B. Worthington

This investigation was undertaken to develop a more efficient copper smelting practice that would help meet the increasingly stringent antipollution standards. Continuous smelting to copper and a 0.8-to 5-percent copper slag using pure oxygen has been demonstrated for several hours at a time in a unique double furnace, which was devised to overcome the heat losses inherent in a laboratory furnace. The use of pure oxygen to effect the smelting and conversion of copper sulfide concentrate in a single unit to produce blister copper and a very high S02 concentration provides a much reduced gas volume for more economical and thorough sulfur recovery. Although the process was successfully demonstrated for several hours at a time, extended test work using longer runs will be required to balance the system and to obtain test data for adequately demonstrating its technical feasibility.

Jan 1, 1973

By Thomas L. Ochs

The stripping of iron-laden solvent with hydrochloric acid in the iron-removal step of the clay-hydrochloric acid process for the extraction of alumina from calcined kaolinitic clay results in a loaded ferric chloride stripping liquor. Treatment of this stripping liquor at boiling with calcined kaolin to form insoluble Fe203(s) and a dilute A1C13 solution was undertaken by the Bureau of Mines to characterize process problems and to aid in sizing of solids-liquid separation equipment. Variables identified as important in the chemical reaction were calcined kaolin particle size, ratio of calcined kaolin to FeC13, and reaction time. These parameters were tested for significance and their interactions investigated. Fine calcined kaolin (-65 mesh) at a greater than 1:1 mole ratio of contained acid-soluble A1203 to Fe203 equivalent of the FeC13 in the stripping liquor required less reaction time than coarser (-16 mesh) material. Solids-liquid separation of the reacted slurries by both settling and filtration requires flocculation.

Jan 1, 2011