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By A. E. Nagel, J. E. Carpetta, M. G. Zabetakis, T. D. Moore

The method of moving averages was found useful in assessing the nature of methane emission in coal mines. Emission rates were influenced markedly by the presence of abandoned oil and gas wells in the vicinity of the mine. Such wells appeared to increase the flow rate of methane into the mine by a factor of 2 to 30 in an active mine in the Pittsburgh coal seam.

Jan 1, 1972

By Donald W. Scott

Chemical thermodynamic properties for the ideal gas state from 0 to 1500 K are tabulated for all of the alkane hydrocarbons through C10. These properties are based on correlations of the extant data for the entropy, vapor heat capacity, and enthalpy of formation of individual alkanes and the equilibrium constants of alkane isomerization reactions.

Jan 1, 1974

By C. E. Jordan

Under its program of advancing minerals technology, the Federal Bureau of Mines has invented a laboratory apparatus for continuous separation of minerals based on differences in dielectric properties. The separator consists of a rotating drum electrode and a wire screen electrode positioned 3 mm apart. A high voltage applied across the electrodes that are immersed in a dielectric fluid produces a high-gradient electric field. The high-dielectric-constant (K) minerals are attracted to and conveyed through the separator by the rotating drum electrode, while the low K minerals settle through the screen electrode. Several design and operating parameters, such as electrode configurations, the dielectric liquid and its dielectric constant, electrical voltage and frequencies, feed rates, and particle sizes were studied. In addition, 28 different mineral mixtures were tested with the dielectric separator. In typical tests, a sample of rutile and quartz gangue containing 10-percent rutile was concentrated to 62-percent rutile with 94-percent rutile recovery. A second-stage dielectric separation of the rutile concentrate produced a 92-percent-rutile concentrate. The overall rutile recovery for the two-stage dielectric separation was 86 percent.

Jan 1, 1980

By D. S. Kingery

This study describes five fatal accidents so unusual in occurrence that the chain of circumstances bringing them about may never be duplicated. The intent of this publication is to illustrate that everyone working underground is subjected, at all times, to definite inherent mining hazards and that safety devices, though provided, often are ineffective or not used. It is hoped that a study of these fatal accidents in bituminous-coal mines will show workers and safety engineers that nothing can be taken for granted. Safety planning with continuous study can prevent these unusual accidents as well as the routine recurring types, which cause the majority of coal-mining injuries. The treacherous, fatalistic philosophy that "it can't happen to me" or that "when my time's up I'll get it regardless of what I do," still prevails among individuals and even safety engineers. The individual or safety man who believes in luck as applied to safety should not read any further, since this study was written for the sincere, safety-minded individual who accepts the prevention of all accidents as a challenge to his knowledge, initiative, persuasiveness, and salesmanship.

Jan 1, 1954

By C. W. Davis

This paper is the second of a series of progress reports on a study of the hydrometallurgy of manganese which is being, conducted in an endeavor to make possible utilization-of the large deposits of low-grade domestic manganese ores that occur in several States. There are at least four processes in which a knowledge of the action of S02 gas on manganese oxides at elevated temperatures may prove of value.

Jan 1, 1930

By Donna L. Anderson

This U.S. Bureau of Mines report discusses the status of a laser-based guidance system to provide position and heading feedback and closed-loop control of tramming maneuvers for a continuous mining machine. The system has been developed and tested at the Bureau, and is now being prepared for underground experiments. The system hardware includes laser scanners, a sensor communication network, and host computer hardware. The system software includes a position and heading computation module and a tram control module. The description of the software includes discussions of laser data acquisition, error compensation methods, position and heading determination, safety checking for continuous miner tramming, and closed-loop tram control. The accuracy of the laser scanner's data, the reliability of the lasers in a dusty environment, and the system's accuracy on tracking the position and heading of the continuous mining machine are shown in the results of experiments performed at the Bureau. Conclusions are stated based on these experimental results, and further work to improve the system performance and prepare for underground testing is discussed.

Jan 1, 1990

By W. J. Johnson

This report presents the Phase I progress in the development of a Radar Coal Thickness Sensor (RCTS) being conducted by Boeing Aerospace and Electronics for the Bureau of Mines. A method is developed for measuring both the dielectric constant and depth of the coal shale interface using a modified UHF network analyzer and antennas in proximity to the surface of the coal. Both bistatic and monostatic systems, are compared. The algorithm technique uses synthetic range gating for clutter rejection and full polarimetric scattering matrix techniques to extract the dielectric constant and depth to sub-wavelength accuracies. Tests were run both in the lab and in a coal mine to build an error budget and demonstrate a validation of the model. The development of a prototype radar suitable for coal mine robotics is specified.

Jan 1, 1990

By F. H. Gibson

In recent years physico-chemical techniques have been applied for rapid analysis of coal and coke ash as replacements for classical wet-chemical methods. Although the classical methods are accurate, they are time consuming because many chemical separations are necessary to complete an analysis, and they require skilled analysts for accurate work (12).4 For the past several years the Bureau of Mines has applied some of the newer physico-chemical techniques in its continued search for new and improved methods at analysis. The methods of analyzing coal and coke ash evolved from this work include spectrophotometric methods far SiO2, A120, , Fe203 , TiO2, and P2O5; chelatometric titration for CaO and MgO; and flame photometry for Na20 and K2O. The methods are rapid and direct, are suitable for analyzing a group of samples at the same time in production work, and dire results with almost the same accuracy as classical procedures. With the new methods, complete analyses in duplicate can be obtained at a rate of 2 to 3 times that of conventional methods.

Jan 1, 1962

By Richard G. Burdick

This Bureau of Hines report describes an interface between a minicomputer and peripheral device, The logic used to develop the device is discussed briefly, after which the device is described in detail; complete construction and operational details are given. The report should aid both in duplicating this device and in designing similar devices for different uses.

Jan 1, 1975

By D. A. Wilson

A laboratory method for processing lead battery scrap has been developed that eliminates virtually all of the S02 emission that normally is produced when a reverberatory or blast furnace is used. The method employs a hydrometallurgical step to convert the PbS04 to PbO and CaS04 by mixing the battery scrap with a slurry of Ca(OH)2. The reaction is exothermic and goes to completion in 2 to 5 minutes at room temperature. The dried product is mixed with a KC1-NaC1 flux and carbon and reduced at 6500 C. A minimum charge ratio of 3 parts of carbon to 100 parts of battery scrap is required for reduction. The process produces lead reductions and recoveries as high as 97.0 and 94.9 percent, respectively. The KCI-NaCl flux is recovered using a standard counter-current water leach followed by evaporation.

Jan 1, 1976

By Jonnie M. Estes

A two-constant equation is presented for helium from 30° = T = 1,473° K. This equation is developed by modifying a generalized equation of state originally presented by Redlich and Kwong (20).3 The modification consists of setting B = 0.06372 Tc/PeT. This modified equation represents the compressibility factors of each of 80 isotherms tested in this temperature range to less than 1 percent average deviation.

Jan 1, 1967

By David R. Flinn

This Bureau of Mines report describes methods to electrodeposit erosion-resistant titanium diboride coatings from molten alkali metal borate baths at 900° C. These coatings have been shown to be highly resistant to material loss during impingement with high-velocity alumina and silicon carbide powders, and they show promise as protective coatings to reduce metal loss in erosive chemical environments, such as coal gasification systems. The most erosion-resistant coatings were prepared on nickel, Inconel, and molybdenum from an electrolyte containing LiBO2, NaBO2, Na2Ti03, and TiO2. The best coatings were deposited at current densities of [~]20 ma/cm2, using titanium or titanium diboride anodes. Erosion-resistant coatings were shown to exhibit (1) a high degree of crystallographic orientation along the (100) or (110) planes, (2) a chromium impurity level of less than 3 pct, and (3) a uniform, smooth, consolidated surface appearance when viewed under a microscope or by scanning electron microscopy. Optical spectroscopic studies of the molten electrolyte suggest that the lower valent (+3) titanium ion predominates in the baths.

Jan 1, 1979

By D. J. Bauer

The Bureau of Mines demonstrated the feasibility of fractionating lanthanide nitrates with a tertiary amine on lanthanum-cerium and thulium-ytterbium pairs. Optimum values were determined for pH, phase concentration, and percent chelation of metal ions in the aqueous phase. Percent extraction is markedly dependent on the concentration of lithium nitrate in the aqueous phase. Selective masking of the heavier element in each extraction system with DTPA or EDTA aqueous-phase chelating agents resulted in lanthanum-cerium separation factors of 8.5 and thulium-ytterbium separation factors of 3.4.

Jan 1, 1966

By D. R. Tesarik, F. M. Jones, J. B. Seymour, L. A. Martin, T. J. Williams

Determining backfill stress is an important part of evaluating mine safety, whether personnel are working in proximity to backfill or in other areas of the mine where backfill is an integral part of regional support. To assist in determining stress in backfill more accurately, researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, Placer Dome, Inc. (Turquoise Ridge Mine), Peabody Energy Co. (Foidel Creek Mine), and Hecla Mining Co. (Lucky Friday Mine) used temperature readings recorded by thermistors to correct for the influence of temperature on stress data. These thermistors were positioned in the stems of earth pressure cells installed in backfill. Corrections were then calculated and compared using four different methods: polynomial equations fit to temperature-versus-stress plots before the pressure cells were loaded by overburden, a factor provided by the manufacturer, a theoretically derived factor, and a linear correction factor based on information collected during periods when no mining was taking place. To evaluate the accuracy of these methods, corrected stresses were calculated using each method and results compared to cumulative stresses caused by blasting at one of the mines. Results indicated that only a small percentage of the temperature effect on stress was corrected using the factor from the manufacturer because that factor accounted for only the pressure transducer and not the entire instrument body. Stresses adjusted with a linear correction factor based on information collected during periods when no mining was taking place were the most accurate. Stresses recorded at two other mines were corrected using the theoretical method and the polynomial equations method; the two methods produced similar results. For some time intervals, the results were identical.

Jan 4, 2006

By Lowell Stroud

Since 1929, the Helium Activity of the Bureau of Mines has operated a helium-extraction plant at Amarillo, Tex. The natural gas that supplies this plant is obtained from the Cliffside geologic structure 12 miles to the northwest and over the years, has become known simply as "Cliffside gas," There is need for published data on the low-temperature phase equilibria of helium-bearing natural gases. To date, little information has been published on the equilibrium phase compositions, solution of helium in condensed natural gas, condensation characteristics, or equilibrium vaporization coefficients for methane, nitrogen, and helium in helium-containing systems. A windowed phase equilibrium apparatus (8)6 was used to obtain 105 equilibrium samples, representing 35 experimental conditions of condensed Cliffside gas at pressures of 100, 200, 300, 400, and 500 p.s.i.a. and temperatures from 0° to -270° F. Data on equilibrium vapor-liquid composition for Cliffside gas are presented in both tabular and graphic form and are discussed in detail to show their relationship to certain criteria that must be met to effect an efficient separation of helium from natural gas by means of low-temperature processes. Facts about condensation characteristics and solution of helium in the liquid phases are included, The important relationship of these two factors in decreasing the percentage of total helium lost by solution in the liquid phase is discussed.

Jan 1, 1961

By W. C. Holliman

This report describes apparatus and procedure used for determining the vapor pressure of aviation gasoline in surveys of commercial aviation-gasoline characteristics made by the Bureau of Mines in cooperation with the Coordinating Fuel and Equipment Committee of the Coordinating Research Council, Inc. (CFR-CRC). The method is a modification of the Reid method, in which a mercury manor is substituted for the Bourdon-type gage of the Reid method. The method was used in earlier surveys made by the National Bureau of Standards in cooperation with the CFR-CRC, and was used in the Bureau of Mines surveys at the request of the cooperating organizations. It is designed for special research problems? particularly in vapor-lock studies, which require a precision greater than obtainable by the Reid vapor pressure method. A repeatability of + 0.01 p.s.i. average deviation from the mean may be obtained by method.

Jan 1, 1950

By Walter K. Utt

The vibration levels of the heavy machines used in surface mining are much greater than for vehicles used on highways. In order to assure the proper functioning of electronic equipment placed on the surface mining vehicles, the U.S. Bureau of Mines has conducted a program of field measurements to define their vibration environment. The information in this report is for a class of vehicle that has a blade for scraping and wheels with rubber tires. The statistical information derived from these measurements can be used as a basis for laboratory testing to qualify equipment for a surface mining vehicle of this class. The envelope that would encompass 99 pct of the vibrations encountered in normal operations is presented for each location on the vehicle. The five locations for which data were recorded are the floor of the cab, the engine, the frame, the drive train (gear, differential, and torque converter), and the axle. Tabulated data are provided for those who wish to use a different probability level. The appropriate test profile for the laboratory testing can be determined from the information presented in this report.

Jan 1, 1993

By G. E. Rennick, F. E. Armstrong, J. Pasini, J. R. Abrams

An oil well penetrating the Pittsburgh bituminous coalbed in northern West Virginia was plugged and safely mined through 3 months later. A sensitive chemical tracer, introduced into the oil reservoir before the test, was not detected in the mine air following the plugging and during mining of the pillar and penetration of the well. Effectiveness of the plugging in preventing reservoir gas from entering the mine through the well hole was verified by continuous monitoring of the mine air for indications of sulfur hexafluoride, an inert gas detectable in amounts as minute as 112 part per billion. Expand- able cement and fly ash-gel-water slurry were utilized to seal the well above and below the coal seam. Three other wells were also plugged using various techniques.

Jul 1, 1972

By L. J. E. Hofer

This Bureau of Mines study, part of a broad program of research in air pollution related to minerals, was conducted to determine the nature and extent of the poisoning of catalysts when used to remove certain air pollutants from exhaust gases. The poisoning examined in this investigation occurs when leaded gasoline is used as a fuel for automotive engines. This research was conducted in cooperation with the Public Health Service. The smog in the Los Angeles area is attributed to the effect of radiant energy on the mixture of hydrocarbons and nitrogen oxides found in the atmosphere there. A large portion of the hydrocarbons is believed to originate in the exhaust gases of automobiles. To prevent the escape of these hydrocarbons into the atmosphere catalytic mufflers have been proposed. In principle, these are simple and nonmechanical, consisting of a vessel charged with a catalyst capable of destroying the exhaust hydrocarbons by catalyzing their oxidation. However, these catalysts are severely affected by the particulate matter, mainly in the form of lead sulfate (PbS04), lead oxysulfate (PbS04.Pb0), and Lead chlorobromide (Pb(Cl,Br)2), contained in the exhaust gas. Deposition of lead on the catalyst as PbS04, PbS04, PbS0, and Pb(Cl,Br)2 restricts catalytic activity. As a result,after 20,000 miles of operation the temperature necessary to achieve 50-percent conversion of isopentane in a mixture of 0.2 percent isopentane, 2 percent carbon monoxide and 4 percent oxygen, and the balance nitrogen at 10,000 hourly space velocity has risen from 400° C. to 500° C. even with a catalyst taken from the exit portion of the catalyst bed. The rest of the catalyst was more severely affected. Therefore, it would appear that operation for 20,000 miles is near the limit for a catalyst.

Jan 1, 1963

By Robert W. Gordon

This report describes the results and conclusions of the further development of a lightweight probe drill for use in anthracite mines. Improvements to the drill previously developed under Contract H0282044 were made and tested at an Eastern Pennsylvania mine. These improvements were: 1. Better hole cleaning due to the development of an air-water mist flushing system. 2. The application of roof drill bits to allow drilling through rock seams and lenses. 3. The development of a quick coupling drill system which reduced total steel change time. 4. Adaptation of a swivel to the drill anchoring system which greatly reduced set-up time between holes. With these improvements the probe drill demonstrated its ability to drill the required 11 holes in one shift. It also gained miner acceptance as a viable underground working tool. The probe drill proved to meet all of the design requirements of portability, low weight drilling controllability, structural integrity and reliability. In addition to its ability to drill the required probe pattern, the probe drill has the capability of drilling long holes. By drilling several holes over 80 feet deep the probe drill has demonstrated a potential for use in robbing pillars and for methane drainage.

Jan 1, 1981