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By J. Roger Loebenstein

Demand for arsenic exceeded supply, and major domestic and foreign producers allocated available supplies to customers for the fourth consecutive year. Major demand for arsenic was about evenly divided between industrial chemicals and agricultural chemicals. Legislation and Government Programs.-Effective April 1, 1981, taxes were collected from companies producing and importing 42 chemicals and petroleum products designated as hazardous, The revenue was used to begin funding of the 5-year, $1.6 billion "superfund" being established under Public Law 96-510, the Comprehensive Environmental Response, Compensation, and Liability Act, designed to help clean up spills of hazardous substances throughout the United States. As hazardous chemicals, arsenic metal and arsenic trioxide were taxed at the rate of $4.45 and $3.41 per short ton, respectively.

Jan 1, 1982

By A. B. Hooler

"A complete list of permissible mine equipment, tested and approved by the Bureau of Mines previous to January 1, 1947, was published as Information Circular 7432. 3/The present list is a supplement thereto that includes all of the equipment approved during the calendar year 1947.The items are numbered to indicate the consecutive order in which each type of machine or device was approved in its particular classification. Thus, Information Circular 7432 showed six air compressors on the active list; two additional compressors, Nos. 7 and 8 in this category, were approved during 1947.Items 2 and 7, unmounted loader and power unit, respectively, under Loading and Conveying Equipment, item 2, rubber-mounted mining machine and item 8, distribution box, appear in Information Circular 7432. They are repeated to show that approvals of these four equipments were extended to cover an additional voltage rating which requires material change in design.Equipment listed in these circulars is approved by the Bureau of Mines only when found upon inspection and test to comply with minimum standards of safety as outlined in schedules prepared on the basis of many years of experience in dealing with safety problems of the coal-mining industry. The use of such equipment in mines known to be gassy, as well as in those that may become so, is earnestly recommended in the interests of safety. This circular is published so that the industry may be kept informed as to the many types of machines, devices, and lamps that are available for reducing explosion and other hazards incidental to coal mining. The present paper, with Information Circular 7432, gives the complete list of permissible mine equipment that is available under the various classifications."

May 1, 1948

By A. W. Maynard

Simple chemical spot tests for the identification of major alloying elements in aluminum-base alloys are described. The tests are suitable for use by nontechnical personnel working outside a laboratory. Tests for zinc, copper, manganese, and magnesium employ electrographic sampling methods and sample papers. Use of electrographic sampling in a test for magnesium in aluminum is made possible by using glass fiber filter paper. Differentiations between magnesium and magnesium-silicon alloys of aluminum and between aluminum-base and magnesium-base alloys are made by direct chemical solution tests. Description of a device for obtaining reliable electrographic samples is included. A sequence of testing for identification by alloy groups is given.

Jan 1, 1971

By Robert G. Yewen, Ronald S. Conti

Underground mines rely on alarm systems, such as stench gas, audible or visual alarms, pager phones, telephones, and messengers to warn miners of a fire or other emergency. These systems are often slow, unreliable, and limited in mine coverage. This report describes the evaluation of a wireless signaling and warning system for underground mines. This system is applicable to both coal and noncoal mines. The work was conducted by the National Institute for Occupational Safety and Health in cooperation with TeleMagnetic Signalling Systems (TSS) under Cooperative3Research and Development Agreement No. BOM-CRDA-6200-0119. A TSS wireless ultra-low-frequency electromagnetic signaling system was installed at the Experimental Mine at Lake Lynn Laboratory near Fairchance, Fayette County, PA. A commercial smoke sensor was interfaced to a remote portable transmitter, and the alarm of the sensor was used to trigger the central evacuation and paging transmitter system during experimental mine fires. The underground/surface receivers flashed cap lamps and activated remote devices, such as strobe lights, within 30 to 40 s after the encoded signal was received. Evaluation results showed full-mine coverage of the electromagnetic field and that the encoded signal was received at the farthest point underground and on the surface perimeter.

Jan 5, 1997

By Robert D. O'Brien

"INTRODUCTION The Miscellaneous Minerals Division of the War Production Board requested the Bureau of Mines to investigate the Gallatin corundum property as a possible source of corundum, which was in short supply due to the war. The Gallatin corundum property, also known as the ""Fuller mine"", the ""Montana Corundum mine"", and as the ""Old Qorundum mine"" was first examined by a Bureau of Mines engineer 2/ in July 1943. Bureau of Mines work on the property started October 11, 1943, was recessed May 5, 1944, and was resumed in October 1944 when the diamond-drilling program started. The project was completed February 7, 1945. The data obtained are given in this report.The Federal Geological Survey made a reconnaissance survey in the spring of 1943 and mapped the area the following autumn. The results of these surveys are contained in a memorandum report prepared in December 1943.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests."

Aug 1, 1947

By J. E. Murphy

The Bureau of Mines developed a hydrometallurgical method for recovering mercury metal from mercury sulfide concentrates. Sulfide flotation concentrate from the McDermitt Mine was leached in a cupric chloride solution at 80° C. The redox potential of the solution was maintained at 850 mV during leaching by chlorine sparging. Mercury extractions exceeded 99 pct in 3 h of leaching. After leaching, the pH of the solu-tion was increased from 1 to 4.5 to precipitate copper as atacamite. The pregnant solution typically containing 100 giL Hg was sent to elec-trolysis to produce high-purity mercury metal and chlorine for recycle. In a 200-A electrolytic cell operated for 24 h, current efficiency was 99 pct and the energy requirement was 0.9 kW·h/lb of mercury produced. Mercury removal from the waste stream was also investigated. Iron or zinc cementation, sulfide precipitation with H2S, and activated carbon adsorption all decreased the mercury concentration from 10 giL to 0.01 mglL, which is less than the Environmental Protection Agency limit on wastewater of 0.02 mg/L.

Jan 1, 1987

By Russell C. Frith, David C. Oyler, Dolinar Dennis R., Christopher Mark

Unusual circumstances may require that a longwall retreat into or through a previously driven room. The operation can be completed successfully, but there have been a number of spectacular failures. To help determine what factors contribute to such failures, a comprehensive international database of 131 case histories has been compiled. The cases include six failures where major rock falls occurred in front of the shields, and seven even more serious failures involving major overburden weighting. The case studies suggest two types of room failure mechanism. The first is a roof fall type failure caused by loading of the immediate roof at the face as the fender or remnant longwall panel narrows. The second is an overburden weighting type failure caused by the inability of the roof to bridge the recovery room and face area, and affecting rockwell above the immediate roof. The data indicate that the roof fall type of failure is less likely when intensive roof reinforcement (bolts, cables and trusses) is employed together with higher-capacity shields. The overburden weighting failures, in contrast, occurred when the roof was weak and little standing support was used. Weighting failures were not greatly affected by the density of roof reinforcement. In one of the overburden weighting cases, in a Pittsburgh coal bed mine, stress cell, convergence, bolt load and extensometer data have been used to analyze the failure in detail. Key words: coal mining, ground control, longwall, recovery room.

By J. Pasini

The Bureau of Mines has investigated novel methods of stimulating petroleum production from reservoirs in the Appalachian Region. An important consideration in applying stimulative production methods is the control and removal of solid precipitates from the boreholes of production wells. Where paraffin-base crude oils are produced, as in the Appalachian Region, the accumulation of paraffin may be particularly troublesome. Paraffin deposition is a major production problem that has confronted the petroleum industry for many years. Although considerable effort has been expended by industry and government, a suitable solution has not been found because of the individuality and complex nature of the deposits. Remedial methods used to prevent or remove paraffin fall generally into four classes: (1) Chemical, (2) physical, (3) operative, and (4) combination. Each class has many subclasses that apply to particular problems in different oil- producing areas. Recently, chemical inhibitors and the sonic pump have assisted operators in preventing and removing paraffin deposits. Because these methods are relatively new, their degree of application has not been completely evaluated.

Jan 1, 1963

By G. M. Potter

During investigation of the occurrence of manganese deposits in the western United States, the Bureau of Mines collected 2-ton samples of 4 ores from 3 properties in northeastern Nevada. Laboratory tests were made to determine the amenability of these ores to ore-dressing methods of concentration. The Caviglia-Vietti property is situated 11 miles southeast of Ely, White Pine County, Nev. The ore deposits are lenticular veins and irregular masses found in limestone fracture zones and along the contact of limestone and underlying shale. Two samples, of the ore were tested: Lot A, from the Vietti shaft, and lot B, from the. Caviglia shaft.

Jan 1, 1954

By W. C. Holliman

Commercial production of synthetic rubber in the United States became a reality in 1931 when E. I. duPont de Nemours, Inc., announced the manufacture of Duprene, a synthetic rubber made by polymerizing r chloroprene. Duprene was later improved and reintroduced as neoprene. Since 1931 other synthetic rubbers and rubberlike materials have been announced and are now produced commercially or are in the pilot-plant stage in the United States. These include Thiokol, Buna S, Perbunan, Koroseal, Vistanex, Flamenol, Ameripol or Hycar, Chemigum, Butyl rubber, and Flexon. None of these is synthetic rubber in the strict chemical meaning of the word synthetic, as none is identical in chemical structure with natural rubber. However, all possess some of the physical properties of natural rubber, and in addition usually have some outstanding property not found in natural rubber that makes them superior for certain uses. Because of these superior qualitites, a considerable demand had arisen for synthetic rubbers before the present emer¬gency, although the price was several times that of natural rubber.

Jan 1, 1943

By H. Kenworthy

The purpose of the study described in this publication is to develop methods for recovering simple master alloys or single metal components from discarded and scrapped S-816 alloy, The Bureau of Mines started this investigation late in 1955 after the need became apparent for a method of reclaiming high-temperature alloys from an ever-increasing accumulation of rejected and wornout jet engine turbine buckets. Laboratory studies showed the following: (1) Pyrometallurgical separations are not selective enough, (2) several methods can be used for effective chemical dissolution of the major constituents of the alloy, (3) a master alloy or complex salts of cobalt and nickel can be separated, (4) chromium, contaminated by several other metals, may be segregated, and (5) more time and effort need to be expended in separating the minor constituents and improving the purity of the major metals removed. Difficult and incomplete chemical separations were attributed to the complexity of alloy composition, as were the long tedious chemical analyses o' products. For determination of several of the metallic components, standard methods of separation and routine analytical procedures had to be considerably modified to achieve satisfactory results. The overall technical problems involved in separating S-816 components do not appear to be insurmountable; however, refinement of several of the methods used in this investigation is desirable.

Jan 1, 1961

By John M. Gomes

A two-phase molten halide-silicate technique for extracting tungstic oxide (WO3) from scheelite (CaW04) and wolframite [(Fe, Mn)W04] was investigated. The halide phase extracted over 99 percent of the was, whereas the lower silicate phase retained about 90 percent of the calcium, iron, or manganese oxides. The most efficient extraction and separation of tungsten from scheelite was accomplished at 1,080° C in a molten system containing, in mole-percent, 9 calcium tungstate (CaW04), 42 sodium chloride (NaCl), 28 sodium fluoride (NaF), 17 sodium metasilicate (Na2SiO3), and 4 alumina (Al2O3). Wolframite was also treated at 1,0800°C; the molten system contained, in mole-percent, 11 (Fe, Mn)W04, 74 NaCl, and 15 Na2 SiO3.

Jan 1, 1968

By Jeanne A. Zimmer, Charles D. Taylor, Edward D. Thimons

On a continuous miner coal face methane concentrations are affected by the quantity of fresh intake air reaching the face. When mining the box cut on a 12.2-m (40-ft) two-pass extended cut face, the continuous miner is always at the point of deepest penetration, and operation of the machine-mounted dust scrubber and water spray system improve the flow of fresh air to the end of the box cut. However, when the continuous miner leaves the box cut to begin cutting the 40-ft slab, little is known about how much ventilation air reaches the end of the box cut. The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health conducted a full-scale study to answer this question. Tests were run to determine how much ventilation air reaches the end of the box cut with the continuous miner at three locations in the 40-fttwo-pass extended cut mining sequence; at the end of the 40-ft box cut, at the start of the 40-ft slab cut, and 6.1 m (20 ft) into the slab cut. During these tests, methane gas was uniformly released at the end of the 40-ft box cut. Methane concentrations measured0.3 m (1 ft) from the roof and face of the box cut were used to estimate face airflow quantities. Fresh air flow rates of 1.89and 4.72 m/sec (4,000 and 10.000 cfm), scrubber flow rates of 0, 4,000 and 10,000 cfm, water spray pressures of 0 and3827 kPa (0 and 120 psi), and a blowing curtain setback position of 15.2m (50 ft) were used during these tests. To improve ventilation to the end of the 40-ft box cut when the continuous miner was starting the 40-ft slab cut and 20 ft into the slab cut, the blowing curtain was advanced from its 50-ft setback to locations 40-ft and then 8.5 m (28 ft) from the face. KEYWORDS: Face ventilation, Extended cut, Methane, Box cut, Continuous miner, Scrubber

By J. M. Stuve

Low-temperature heat capacities of chiolite (Na5Al3F14) were determined by adiabatic calorimetry in the temperature range 5.8 to 300 K. The derived standard entropy (S°, 298.15) was 115.6 ± 0.2 cal/deg-mole. High temperature enthalpies relative to 298.15 K were obtained by precision drop calorimetry up to 1,000 K. Tables of experimental data and related thermodynamic functions are given for the temperature range of experimental observations.

Jan 1, 1980

By A. B. Hooker

Gassy mines require daily inspections with methane detectors to test for the presence of methane. Although in many manes it may be sufficient to know that there is no methane present or that its percentage is below a certain amount, it is desirable and often necessary to determine definitely the percentage of methane at the working faces and in the various air currents. The Bureau of Mines recognizes two general types of portable methane detectors, namely; 1. Methane detectors by which the presence of methane may be detected and its approximate percentage estimated.

Jan 1, 1929

By J. L. Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has continued the research role of the former US Bureau of Mines (USBM) to engineer techniques that will reduce the hazards in the mining workplace associated with coal bumps. Recent research focused on a longwall coal mine in Utah with overburden greater than 750 m (2,500 ft) containing several massive sandstone units. The primary field instrumentation at the site was three-dimensional, full waveform, autonomous microseismic arrays placed underground and on the surface in order to surround the active multi-panel longwall district. The purpose of these arrays was to help investigate the strata mechanics associated with the redistribution of stress and the associated gob formation of the longwall. Specifically, the seismic arrays were used to determine the timing and location of the failure in the strata surrounding the active mining. Overall 13,000 seismic events were detected and located with on-site processing during the five months the panel was being mined, including a magnitude (ML) 4.2 event. Of these, a smaller subset of 5,000 well-located events was selected during post-processing to form a consistent data set for analysis in this paper. From this data set, it was observed that the seismic events generally occurred in advance of the longwall face, both above and below the panel, consistent with failure of the strata in the forward stress abutment zone. Also, the occurrence of the ML 4.2 seismic event within 150-180 m (500-600 ft) of a deep cover longwall face with no associated bump caused a re-evaluation of the nature of the connection between seismic activity and coal bumps.

Jan 1, 2002

By Efrem R. Reeves

Noise-induced hearing loss (NIHL) is the most common occupational illness in the United States, with 30 million workers exposed to excessive noise levels [NIOSH 1996] every day. Of particular concern is the mining industry; which has the highest prevalence of hazardous noise exposure of any major industry sector [Tak et al. 2009] and is second only to the railroad industry in prevalence of work-ers reporting hearing difficulty [Tak and Calvert 2008]. This document is for operators, safety personnel, and mechanics in the mining industry who are not specialists in noise control engineering or acoustics. Evaluations of successful and unsuccessful attempts at controlling noise on several large, underground metal mining machines are detailed to illustrate the basic principles of noise control. Once personnel understand the guidelines and principles of noise control, they will be able to ¦evaluate the extent of a noise problem; ¦determine the best approach to the problem; and ¦apply the most appropriate solution. Because of the insidious nature of NIHL, it can go unnoticed until a considerable loss of hearing has occurred. In some cases, diagnosis is delayed because an exposed individual claims to have become accustomed to the noise. In reality, that person may have already suffered irreversible hearing loss. Humans can hear sounds in the frequency range from about 20 to 20,000 Hertz (Hz). Within this range, NIHL usually begins in the frequency region around 4,000?6,000 Hz, the upper levels of the speech region. The first noticeable symp-toms include difficulty understanding higher pitched voices, such as the voices of females and children, and difficulty understanding certain consonant sounds, which are primarily high frequency in nature. The extent of NIHL varies depending on the level and duration of noise exposure and on an individual?s susceptibility; despite having similar noise exposure, individuals can experience differing degrees of hearing loss, or none at all. NIHL is almost always preventable. To reduce or eliminate the possibility of NIHL, an individual?s noise environment must be analyzed and appropriate action taken to reduce noise exposure.

Dec 1, 2009

By Charles D. Litton

This U.S. Bureau of Mines report describes the results of two large-scale tests conducted to evaluate a prototype nitric oxide (NO)-compensated carbon monoxide (CO) fire sensor, developed by Carnegie Mellon Research Institute (CMRI). In the tests, small coal fires were allowed to develop in the presence of diesel exhaust at relatively low ventilation airflows. These tests compared the response of the CMRI fire sensor with that of other fire sensors, including the Bureau's diesel-discriminating smoke detector. During the tests, CO, NO, and smoke levels were continuously monitored in order to determine the sensor alarm times and gas levels as the fire developed. The data indicated that the NO-compensated CO fire sensor was capable of suppressing the CO produced by a diesel engine and that the sensor responded reliably to the CO produced from the test fires. The tests also showed that the Bureau's diesel-discriminating smoke detector alarmed earlier than the prototype NO-compensated CO fire sensor.

Jan 1, 1993

By Sara Jane Boles

The purpose of this Bureau of Mines investigation was primarily to isolate and examine the effect of liquid content upon the apparent porosity and bulk density of compacts pressed from high-purity, fused aluminum oxide, and, secondarily, to study the actual mechanism by which the liquid content affects the bulk density. No attempt was made to approach the theoretical maximum density of the oxide by introducing additives, particle packings, or similar variables; instead this study is an intercomparison of the bulk densities obtained as functions of the water contents of the compacting mixtures. Water content was varied from 7 percent to 25 percent, on a total-weight basis. The data gathered indicated a well-defined optimum water content for obtaining minimum apparent porosity and maximum bulk density, under the conditions of the experiment. During the course of this study, a number of additional variables in the forming process were discovered and are introduced in this report, although a thorough evaluation was found to be beyond the scope of this present investigation.

Jan 1, 1963

By James S. Browning

Research by the Bureau of Mines demonstrated that organic heavy liquid adhering to or adsorbed on fine mineral particles can be effectively removed by a novel method embracing pulping or displacement washing with hot water alone or in combination with a detergent. Displacement washing with steam alone or in combination with a detergent also was effective for removing the heavy liquid. In tests of sized minus 48-plus 200-mesh mineral charges, both the hot water washing with detergents and detergent steaming effectively reduced the heavy liquid losses on the particles to about 0.2 pound per ton of mineral or less. Centrifuging of the wash solutions permitted an almost complete recovery of heavy liquid from the solution as a pure heavy liquid product.

Jan 1, 1966