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By Charles L. Kimbell

This study is intended to serve three roles. First, it is an extension of the previous works under the same title that have been the overview and summary chapter of the international volume of Minerals Yearbook since the inception of that volume. Following the traditional format of past chapters, the basic statistical presentations herein deal chiefly with 1989, and in some instances with 1988, the latter only because more recent, comprehensive global statistics for 1989 are simply not yet available owing to delayed data collection and processing in some countries and continued governmental suppression of data in others. The second role of this study is to provide an update to the coverage of events impacting on the world's mineral industry that have occurred between the end of 1989 and the preparation of this study. Inclusion of this update is almost essential because of the potential effect of some of these events on global mineral industry activities.

Jan 1, 1992

By D. J. MacDonald

The Bureau of Mines investigated two alternative methods for treating a zirconium-bearing chloride-sulfate strip liquor to obtain reactor-grade Zr02. One method involves neutralization with NH3 and the other hydrothermal precipitation. The strip liquor was derived from zircon sand by a Bureau of Mines method for separating zirconium and hafnium via solvent extraction with a tertiary amine. Neutralization with NH3 to precipitate hydrous zirconium oxide required 0.9 to 1.1 g NH3 per gram of zirconium. The NH3 can be recovered for recycle. Zr02 that met reactor-grade specifications was produced by precipitation with NH3? Hydrothermal precipitation of Zr02 from strip liquor required that the solution be maintained at 2600 C and 680 psi for 10 min and in a non-corrodible pressure vessel. In bench-scale experiments both methods gave-zirconium recoveries greater than 99 pct.

Jan 1, 1984

By Lowell B. Moon

Regardless of how a mineral deposit in first discovered or by whom, any mining enterprise based upon it must pass through a preliminary stage of exploration. The common understanding of ?exploration? among mining engineers is well-expressed by Jackson and Knaebel:3/ Exploration work ranges from that performed by the individual prospector employing only the simplest tool, and equipment to elaborate campaigns involving the expenditure of largo stuns of money end the use of churn- car diamond-drilling equipment, large test-pitting crews, or sometimes a regular mining organization. In any event, the object is to determine as accurately as possible, with the funds available, the size, shape, and other characteristics of the ore bodies and their average value or grade.

Jan 1, 1945

By Rudolf Kudlich

"During the coming winter, it is probable that many householders who have habitually been users of anthracite coal will be obliged to turn to some other fuel for heating purposes, because of the limited supply of anthracite. The next best fuel, from a standpoint of cleanliness and ease of operation, is coke, but here again the supply is inadequate and the householder will have to fall back on bituminous coal. Though bituminous coal has the dis¬advantage of being dirty to handle, requiring more care in firing, and of giving off considerable smoke, it will be more generally available, costs less, and in the better grades which will naturally find their way to the domestic market, is higher in heat value, and contains less ash than anthracite.Choice of CoalThere a variety of bituminous coals are available, the householder should choose a low volatile coal, such as New River, Pocahontas, or some other ""smokeless"" coal, or the British coal now being offered in the markets along the Atlantic seaboard. Though not necessary to have the coal sized, as is the case with anthracite, it will be found cleaner to use coal from which the fine dirt has been screened. If it is found that excessive dust is caused when firing the coal, this can be reduced by slightly wetting the coal at the front of the bin, as it is being used.Method of Firingusing bituminous coal instead of anthracite in the domestic furnace, it will be necessary to use an entirely different method of fir Instead of leveling the fuel bed and putting on fresh coal in an even layer over the entire fire box, the coked and partly burned coal remaining from the previous firing should be pushed as much as possible to one side of the box, and the fresh coal thrown into the empty side so as to leave some burning coal exposed. In this way the green coal is heated slowly, the volatile gases are given off gradually, and are ignited by the burninggoing to waste up the chimney unburned."

Oct 1, 1922

By Rimas Pakalnis, Tom Brady, Lewis Martin

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate weak rock masses (such as are associated with operations in the Carlin Trend in Nevada) into existing design relationships. The original database that led to most of the empirical design relationships presently employed in hard-rock mining was derived from fair-to-good-quality rock. In this study, the relationship between weak rock quality and opening design (non-entry/entry methods) is being investigated. The common factor in all mines is a weak back or wall. This work attempts to provide tools that will enable a mine operator to make economic decisions that will also ensure a safe working environment. Tom Brady (for correspondence - E-mail- thb6@cdc.gov)and Lewis Martin are at the Spokane Research Laboratory, National Institute for Occupational Safety and Health, 315 East Montgomery Avenue, Spokane, WA 99207-2291, USA (E-mail• ljm8@cdcgov); Rimas Pakalnis is at the Mining Department, University of British Columbia, Vancouver, British Columbia, Canada (E-mail: rcp@mining.ubcca).

By R. Hogg

"Agglomeration processes and agglomerate characteristics are largely controlled by the forces of interaction between particles. The nature and typical magnitude of these interaction forces are evaluated relative to the external forces commonly present in agglomeration systems. The specific roles of the interaction forces in the various stages of agglomerate formation and growth and their effects on the integrity and mechanical strength of agglomerates are briefly reviewed. Because the interaction forces affect different aspects of agglomerate development in different ways, conflicting requirements can arise. Examples of such conflicts are given and used to demonstrate the importance of evaluating the effects of interaction forces etc., in the context of the overall agglomeration process and its ultimate objectives.INTRODUCTIONThe term agglomeration is generally used to refer to processes whereby discrete particles are caused, or allowed, to associate into clumps in which the individual particles retain their identity but are held together by relatively weak, usually physical forces. Various other designations are given to these processes, depending on the specific circumstances under which agglomeration occurs. The terms balling and pelletizing are often used to describe agglomeration in dry or semi-dry powders; coagulation and flocculation are used to refer to agglomeration of particles dispersed in fluids. Common to all of these cases is the fact that the formation, growth and integrity of the agglomerates depend primarily on the forces acting on and between particles. The same forces are, of course, responsible for manyaspects of the behavior of colloidal systems and their study and evaluation constitute the,basis for colloid and interface science.FORCES ACTING ON FINE PARTICLES AND AGGLOMERATES It is convenient to classify the forces acting on and between particles into two general types: external forces and interaction forces. It should he recognized, however, that a sharp distinction is not always possible.External Forces Gravity and inertial forces act on all particles and their magnitude is proportional to particle mass, i.e. they vary with the cube of particle size. Such forces are oftensignificant for large agglomerates but may be negligible for individual, fine particles.Hydrodynamic (""drag"") forces are important, for particles suspended in fluids. For very small particles, the drag force is directly proportional to size (Stokes' Law) while for very large particles or agglomerates it varies with approximately the square of size (Newton's Law). A useful procedure for estimating drag forces over a broad range of particle sizes and physical conditions has been given by Concha (1)."

Jan 1, 1989

By John H. Thompson

Recent studies ** at the Pittsburgh Experiment Station of the Bureau of Mines have revealed some interesting facts as to the probable behavior of steamed coke in the blast furnace . The literature on the chemistry of the blast furnace was tho roughly reviewed , and with this information in mind , the probable behavior of the coke sulphur in the blast furnace was deduced . Enough small - scale tests were conducted to furnish a check on most of the important deductions , and the conclusions derived therefrom accord with what is already known in regard to the forms of sulphur in coke , and fit in well with the general opinion concerning blast-furnace reactions .

Aug 1, 1923

By Edward D. Thimons

The Bureau of Mines conducted a state-of-the-art study of techniques currently employed to close large openings in underground mines. A large opening was considered to be any opening over 10 feet high and having a cross section of at least 200 square feet. Five salt mines and one limestone mine were visited to observe various methods of sealing large openings. Because of the variations in conditions from mine to mine, no definite conclusions could be drawn as to which is the best method. In mines where waste material is available, stoppings built by piling waste material are efficient and economical. Where waste material is not available properly constructed brattice cloth stoppings are superior to those built from wood, concrete block, or urethane foams.

Jan 1, 1975

By D. A. Reynolds, A. C. Fieldner, S. H. Katz

"03-01-192403-31-2019RI 2591 - Reports of Investigations - Department of the Interior - Bureau of MinesBureau of MinesPittsburgh Experiment Station American Society of Heating and Ventilating EngineersU.S. Public Health ServicesTucson Experiment Station Introduction.""Carbon monoxide self-rescuers,"" or simply ""self-rescuers,"" are pocketsize gas respirators which protect the wearer from air contaminated with poisonous carbon monoxide gas. On March 6, 1924, the Bureau of Mines approved the ""M.S.A. self-rescuer’ manufactured by the Mine Safety Appliances Co., Pittsburgh, Pa., after the M.S.A- self-rescuer bad passed all the tests and requirements of the Bureau's Schedule 14A4.The purpose of the self-rescuer is to help miners to escape from mines in which fires are burning or explosions have occurred, by providing protection from carbon monoxide for at least one half-hour. The self-rescuer can be used similarly by workers above ground who may through accident become surrounded or entrapped by atmospheres containing carbon monoxide.no hazards threaten the miner, who escapes serious injury by fire or violence in a large mine fire namely, ( 1) asphyxiation by poisonous carbon monoxide gas; and (2) suffocation by insufficient oxygen to support life. In order to save himself, the miner must either erect a barrica4e5 against afterdamp and wait restoration of ventilation and rescue or take a long chance at getting out of the mine through entries not permeated by afterdamp.. The self-rescuer removes the hazard of carbon monoxide poisoning for one half-hour or more, and accordingly greatly increases the miner's chance of saving his life.This paper describes the construction and details of the M.S.A. self-rescuer as approved by the Bureau of Mines, and discusses its performance under test condition"

Mar 1, 1924

By B. J. Dalton

This report gives general expressions for evaluating various thermo-dynamic properties applicable to a two-component system, including liquid-vapor equilibria. In addition, expressions are developed for some of the quantities useful in making thermodynamic consistency checks on phase equilibria data. These formulas were developed from the general principles of thermodynamics and are expressed in terms of the compressibility factor, which is assumed to be an explicit function of the molal density, the absolute thermodynamic temperature, and the composition.

Jan 1, 1968

By Oliver C. Ralston, Foster Fraas

The electrostatic separation of solids utilizes the forces exerted when electrically charged particles of the solids are present in an electric field . The charges may be acquired by various means (5) , and when the acquisition or loss of charge depends on the property of the particle , separation can be obtained between particles having different properties . A property commonly utilized in present - day separators in conductance . Charging also may be accomplished by bringing the particles into intimate contact with various surfaces . This is sometimes described as a " frictional electrical effect. The charge , or specifically the polarity of the charge , in this latter case evidently depends on the property known as the contact potential , as has been explained in the discussion of a paper (7) and in several other papers (10) . Separation by this method is accomplished in two steps - a charging step , in which the particles are brought into intimate contact with an electrification surface , and a separation step , in which the charged particles are separated in an intense electric field . Descriptions of such methods may be found in the literature (2) , (7) , ( 8) . Even as early as 1909 , Blake and Morscher (2) described the charging of particles by intimate contact followed by separation in an electric field . They also state that the polarity of the electrical charge acquired by the particles depends on their composition . O'Brien ( 8) presented several designs of apparatus . He obtained electrification by means of a wiping action , either on inclined plates or in rotating cups , in which a centrifugal force was imparted to the particles .

Nov 1, 1942

By X. Shi, N. S. Dala, V. Vallaythan

"Cellular damage induced by silica dust is known to be associated with increased fragility and destabilization or destruction of the cell membranes. The mechanism by which silica dust effects biological membranes is still unknown. Using the ESR spin-trap methodology, we find that hydroxyl radicals are generated in aqueous suspensions of freshly ground silica. The amount of the radicals generated depends on the extent of grinding and ""freshness"" of the dust. Using linoleic acid as a model lipid, we show that the silica dust causes lipid peroxidation via ·OH, 02-, or linoleic acid related radicals as intermediates. Catalase and superoxide dismutase inhibit the formation of these radicals. The results suggest that free radicals associated with freshly ground silica and the related lipid peroxidation of the memberanes may be the starting point of the silicotic processes.INTRODUCTIONDespite considerable-effort over the years, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrosis are still not fully understood (1,2). It is generally thought, nevertheless, that the interaction of the quartz particles with the cell membranes is the starting point of the silicotic process (3). We felt that the mechanism of the membrane damage by quartz might involve oxygenated free radicals because (a) a suspension of quartz particles in contact with alveolar macrophages has been reported.(4,5) to initiate an enhancement of lipid peroxidation, defined broadly as the ;oxidative deterioration of polyunsaturated components of lipids, and (b) hydroxyl (·OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (6) and initiating lipid peroxidation in lysosomal membranes (7). Moreover it is known that exposure of cell membranes, fatty acids and unsaturated food oils to ionizing radiation, which generates ·OH. radicals, causes rapid peroxidation (6). Earlier studies o~ the aqueous chemistry of quartz suspensions have reported detection of HzOz (8), implicating the formation of ·OH radicals as transient species, but, we are not aware of any report of the detection of ·OH radicals in quartz suspensions and this provided the motivation for the present undertaking. Since it is known that, because of their high reactivity (hence short life time) in aqueous media, the ·OH radicals cannot be detected via electron spin resonance (ESR) directly (9,10), we have used ESR combined with the spin-trap methodology (9) for studying the •OH formation."

Jan 1, 1988

Reduce well construction and operation costs associated with in situ leach mining while increasing mineral recovery. Approach To accommodate the size of centrifugal pumps presently in use, in situ leaching production wells are typically drilled to 6 inches in diameter, while monitor wells are drilled to measure 4 inches in diameter. However, in order to reduce the cost of drilling these larger diameter wells and to increase recovery, the Bureau has developed jet pumps which have smaller diameters than centrifugal pumps of the same capacity. This allows both production and monitor wells to be drilled smaller. Bureau estimates indicate that the cost of drilling a 3-inch-diameter production well at in situ leaching operations would be about 35 percent less than the cost of a 6-inch well. Similarly, the cost of drilling a 2-inch-diameter monitor well would be about 26 percent less than the cost of a 4-inch well. Such significant savings in the cost of drilling these wells would effect a substantial reduction in total capital cost. Use of the new jet pumps can also increase the percentage of recovery because less costly wells allow closer well spacings, improving the distribution of the leach solution. How the System Works After the borehole is cased, the new small-diameter jet pump, along with piping and accessories, is installed and connected to a centrifugal pumping unit on the surface. High-pressure water from the surface pump is forced through a nozzle into the venturi of the jet type pump injector. This jet action lifts the leach and mineral-bearing solution to the surface.

Jan 1, 1984

To develop and design a bit that will rapidly drill smooth and precise instrumentation holes in soft rock. Approach Use a one-piece bit made by combining a drag bit and a diamond bit. Because a smooth-walled borehole with a precise diameter is needed for borehole pressure cells (BPC) and other borehole instruments, a diamond bit is usually used. However, diamond bit drilling is slow, and the bit will tend to bind when squeezing ground is encountered. On the other hand, the drag bit will cut faster, but the walls of the drill hole will be rough and the diameter will not be as precise. The combination will provide a bit which penetrates as rapidly as a drag bit, but retains the smooth-wall and precise borehole diameter of a diamond bit. How It Works A three-foot-length of EW-size drill rod is centered in a diamond bit by welding it to three equally-positioned spacers at each end of the bit. A drag bit is attached to the EW rod with a standard EW-to-drag bit adapter as shown in the diagram. Three equally-spaced diamond inserts are set to the desired hole size and welded to the diamond bit barrel behind the crown. These inserts increase the smoothness and precision of the hole by cut-ting away any hole closure. Three equally-spaced shims are set approximately 0.020-inch under the overall insert diameter size and welded to the rear of the diamond bit barrel. The combination bit should be used on a diamond drill with either water, mist or air as the coolant.

Jan 1, 1982

By Lloyd A. Morley, Robert Stefanko

The most time-consuming research segment was assembling the ref¬erences. These are provided immediately after the conclusions but are divided into two categories. The first is directly applicable publi¬cations, correspondence and personnel communications. The second listing contains those publications that are not directly tied to the research but where a probable application exists. In both listings, all important USBM publications are provided. The reference numbers used in the report apply only to the first reference portion. Further¬more, it should be noted that all entries are not used but are retained to help anyone who wishes to look further into different or allied areas of this research topic. Explosion-proof enclosures have been researched since approxi¬mately 1906. Even so, little is understood about the mechanism by which they are effective. Due to the voluminous literature published, there is a good probability that the assembled list is still incomplete. The literature search took the following directions. Work was first directed to reviewing the several references assembled by the Department of Mineral Engineering - Mining Section prior to the present project year. As a result, some duplications and inapplicabilities were found and eliminated. The primary sources of the previous search were the commonly available and usually superb library listings, such as Engineering Abstracts. Because these sources have enormous content on all subjects, they were cross-checked in the first semiannual period several times by different individuals to make sure all normally avail¬able literature were uncovered.

Jan 1, 1974

By D. Harrington

"In at least three out of every four working faces in metal mines there is no attempt made to cause air circulation other than by use of compressed air, and in at least nine cases out of ten the compressed air is released merely by opening, or partly opening, the valve and allowing the compressed air to escape through open air hose used to convey the compressed air to the drilling machines. Usually no blowers are in use during periods of drilling, as the exhaust from the drill provides cool, comparatively fresh air for the driller; however, in some instances, the compressed-air line is provided with a tea connection, which permits taking air for the drill from one side of the tee, and air for ventilation through a separate hose used as a blower, simultaneously with drilling.Table 1 contains temperature and humidity data as to compressed-air blowers from open end of air hose at 36 working places in eleven metal mines of four States, embracing the mining of gold, silver, copper, lead and zinc ores, and at horizons ranging from 500 feet below the surface to as low as 4900 feet.It is noticed that the ordinary air surrounding the worker at the face gives an average wet bulb temperature of 81.7° F. for the 36 working faces, with 84.7° F. dry bulb and 87.2 per cent relative humidity. The average wet bulb tem¬perature of 36 readings at these working faces of compressed air at the end of the,hose as the air issues from the hose was 67.4° F., or 14.3 degrees lower than the average wet bulb readings of the air of the working places; however, the average dry bulb temperature of the 36 readings of compressed air as it issued from the end of the hose was 79.7° F., or only 5 degrees less than that of the general air (84.7°); the relative humidity was 51.1 per cent as against 87.2 per cent for the surrounding air. Readings were taken in five raises, seven crosscuts, ten drifts and 14 stopes.It will be noted that the velocity or movement of the general atmosphere at each of the entire 36 working faces, was found to be practically imperceptible; this might readily be inferred since compressed air is rarely used on blowers if there is adequate circulation of the general air of the place. Where rook temperatures could be obtained readily, they are shown; it is noticeable that the dry bulb temperature of the air of the working place varies little from the rock temperature, and that the dry bulb temperature of the compressed air as it issues from end of air hose varies only a few degrees from the temperature of the surrounding rock; in some instances the dry bulb temperature of the compressed air as it issued from the end of the air hose was higher than the rock temperature or the dry bulb temperature of the surrounding air."

May 1, 1921

Protect rescue workers fighting fires or mine personnel temporarily working in hot environments from heat stress. Approach A specially designed ice-cooled vest is worn while working in hot environments where cooling the mine air is not possible. How It Works The vest holds a total of 44 individual ice cells in packets that are firmly held near the wearer's skin. These ice cells remove heat from the wearer, reducing heat stress and increasing comfort. The locations of the ice cells and packets are shown in the diagram. The vest is constructed in three layers with the outer layer being aluminzed fiberglass cloth. Its aluminized surface reflects radiated heat, and its fiberglass cloth provides fire resistance and strength.

Jan 1, 1979

By C. P. Mabie

This report summarizes studies by the Bureau of Mines in developing a simple method for estimating the phosphorus pentoxide (P205) content of finely ground sedimentary phosphate ores and beneficiated products. The method used involved leaching, filtration, and precipitation. The Bureau found that measurement of the volume of ammonium phosphomolybdate precipitate obtained from samples containing 16.8 to 37.7 percent P205 and the use of an appropriate calibration curve permitted estimates of percentage of P205 content accurate within ± 1.1 to ± 2.6 percent, respectively, at the 95-percent confidence limits. Incidental to mineral dressing and petrographic investigations of western phosphate ores in 1959, the Bureau of Mines undertook development of a simple process-control method for rapid on-the-spot evaluation of phosphate-mineral recovery. Because of the fine-grained and obscure character of western phosphate ores, chemical, rather than microscopic or petrographic, techniques were investigated. The described method involves acid decomposition of the ore or product, filtration, addition of ammonium molybdate reagent to the filtrate, and centrifuging and measuring the volume of yellow ammonium phosphomolybdate precipitate produced.

Jan 1, 1961

By N. S. Raymon

As part of an interegency agreement with the Energy Research end Development Administration to develop unproved refractory materials for use in coal gasification processes, the Bureau of Mines reviewed the literature to determine the effect of steam, H2, CO, and CH4 as well as the alkali metal oxides K2O and Na2O on refractory materials. Emphasis was given to the performance of high-alumina castable and fired refractories to conditions expected in coal gasification processes. Approximately 85 references were reviewed with 40 cited in the text. The literature was found to contain little data directly applicable to the selection of refractory lining materials suitable for use under the conditions of temperature, pressure, and gas compositions expected in second generation coal gasification reactors.

Jan 1, 1976

By M. K. Larson, J. P. Dunford, E. G. Zahl, T. M. Brady

Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, Spokane, WA, have collaborated with three Western longwall coal mines in an on going effort to develop technologies that will aid in providing safe and stable working areas. The goal of the research described here is to develop a stress monitoring system that will provide immediate information to mine managers for making daily safety decisions as areas of poor ground are mined through. Initial work has focused on answering preliminary questions regarding the reliability and use of stress change patterns. Research is concentrated on monitoring horizontal stress because horizontal stress is transmitted over long distances through stiff strata, thus allowing an extended length of entry to be monitored. This paper presents an explanation of the concept, key results from field tests at two mine sites, and a proposed process for implementing a monitoring system. System design layouts, instrument use, data collection and interpretation methods, and processes to present findings to mine staff are described. Additional validation and correlation with actual failure mechanisms are required before this approach can be recommended at ongoing operations. However, initial results indicate that this approach shows promise in mines prone to bumps and roof falls associated with large stress changes. In particular, analyses of measured changes in horizontal stresses appear useful.