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By M. Terry Hoch, George J. Karabin, James M. Kramer

This paper introduces the fracture mechanics approach—a unique way to predict the stability of a coal mine panel. The technique uses analytic equations to calculate the stress, strain, and yield characteristics of coal support systems. It uses fracture mechanics to model almost every type of mine support structure. Another feature is a method that incorporates field-tested knowledge into the analytical analysis. For example, this technique can model the yield characteristics of a coal seam by combining empirical pillar strength equations into the analytic analysis. It may be possible to simulate multiple-seam mining by incorporating subsidence methods into the analysis. The method is simple and quick, which makes it attractive for stress analysis software. It should be more accessible to those in the mining industry who do not have expertise in rock mechanics or numerical modeling. Although the purpose of this research is for modeling coal mines, it should be adaptable to any mine in a tabular deposit.

Jan 1, 1999

By C. Lorimer Colburn, Spencer P. Howell

"Numerous accidents are still being reported that have resulted from the delayed explosions in drill holes. Some of these accidents have boon due to retarded burning of the fuse, causing the charge to explode after the miners had returned to the face, but the majority have been caused by the minors drilling or picking into unexploded explosives, either in unexploded bolas or in broken rock. Although the industry has been cautioned by the Bureau of Mines, manufacturers of explosives, and other agencies regarding the care that is necessary in the handling of explosives, yet reports of these accidents are still being received and many of the accidents are fatal, They occur in spite of the best efforts of the mine officials and men, but many of those that have been reported could have been avoided if the following precautions had been observed:Misfires should not be approached even for the purpose of inspection until three hours have elapsed if fuse was used, and ten minutes if electric detonators or electric igniters were used. These are minimum recommendations. It would be preferable to allow a longer time, for fuses have been known to hang fire for twelve hours."

Aug 1, 1920

By John C. Franklin

Water-based epoxy sealants were examined during a 2-year period to deter-mine their effectiveness as barriers to radon release in uranium mines. Radon emanation rates from uranium ore samples were monitored for extended periods in the laboratory before and after sealant application. Reduction of radon flux due to the coating of laboratory samples was approximately 80 percent. Test chambers in a dormant uranium mine were monitored to determine both short and long-term barrier effectiveness. These field studies of the seal-ants indicated radon flux reductions exceeding 50 percent relatively soon after application and nearly 75 percent about 1 year later. An unexpected complication to early monitoring in the form of a large radon emanation increase, believed due to added moisture, is discussed.

Jan 1, 1977

By Lloyd A. Morley, Robert Stefanko

Before going directly to the analysis, it would be good to summar¬ize explosion-proof container approval methods. Both Magison (52) and Short (84) state that in general practice, the systems are certified for: 1. a rugged enclosure able to withstand an internal explosion but not allow explosively hot gases to escape, and 2. maximum surface temperature, with equipment operating inside, that will not ignite the surrounding atmosphere. Also, testing insures that any material in contact with the container surface will not be ignited by a hot spot. Associated with the first practice, the enclosures are inspected for: 1. a safe flange gap width, 2. a pressure increase during ignition, and 3. an hydrostatic pressure withstand level. The hydrostatic pressure level is almost always determined by a meas¬ured ignition-pressure test and is usually applied to prove the mechan¬ical design to some safety factor. Consequently, explosion-proof enclosure testing includes temper¬ature, permissible flame gap, and pressure. Specifications and prev¬ious research also can be similarly separated even though some interre¬lation exists between the flame gap size and internal enclosure pressure during an explosion. The Schedule 2G Sections applicable to these subjects are: 1. 18.2 Definitions; 2. 18.6 Applications;

Jan 1, 1974

Determine the site specific flow behavior of leachants and groundwater during development, production, and restoration phases of an in situ leaching operation. Approach A computer program has been developed which simulates the hydrologic activity associated with in situ mining. Various user options enable modeling of many of the site specific geologic conditions and well field specifications that affect the hydrology of solution mining. How It Works In situ hydrology is modeled, using a closed-form solution to the three-dimensional, partial differential equation that describes changes in hydraulic head as a result of pumping from leachant Injection and recovery wells. Model capabilities include arbitrary well patterns and pumping schedules, partially penetrating well screens, directionally anisotropic permeability and natural groundwater flow, in either

Jan 1, 1981

By Allan E. Martin, George Glocker, C. E. Wood

"INTRODUCTION As part of a comprehensive investigation of the mechanism of defurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of Mines, in cooperation with the Institute of Technology, University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope.Vogt/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FexCay)S and (MnxCaa)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.Coloration of glass by sulfur also provides indirect information on the nature of sulfur in blast-furnace slags./ There seems to be a general agreement at present among the workers in the field of colored glasses that ferrous sulfide is a strong color producer. Colors that have been attributed to this compound include yellow, orange, brown, blue, and black. Apparently the ferrous sulfide is considered to be dissolved in these glasses. There is no indication that any of them have been examined for a colloidal phase.Lorenz 7/ investigated a single manganese slag in the glassy state and observed a Tyndall beam in an ultramicroscope. His conclusion was that either a manganese compound had precipitated in a finely divided condition or that metallic manganese had volatilized and penetrated into the slag as a vapor and thus formed colloidal particles."

Feb 1, 1941

By A. R. Rule

Laboratory tests were conducted to study removal of magnesium impurities from western phosphate rock concentrates by selective leaching. The systems evaluated included leaching with dilute sulfuric acid, with ammonium sulfate, and in an aqueous medium with sulfur dioxide gas. Set standards for the magnesium impurity level of phosphate rock concentrates are not available, but industrial practice has indicated that magnesium in excess of 0.3 percent MgO causes problems in phosphoric acid manufacture. Removal of magnesium was accomplished with all three systems. With dilute H2S04 the magnesium level was reduced to less than 0.1 percent MgO with an accompanying P205 loss of 6 percent. Magnesium oxide levels from 0.3 to 0.2 percent were obtainable with ammonium sulfate. However, the system requires concentrate roasting at temperatures of 900° C or higher, heated pulps (100° C), and large quantities of ammonium sulfate. Selective leaching was obtained using S02 gas in an aqueous concentrate slurry. Magnesium oxide content was reduced to less than 0.1 percent without loss of phosphate.

Jan 1, 1970

By Ann G. Kim

Methane in coal constitutes a serious hazard during mining. Draining the methane from large blocks of coal in advance of mining is an effective method of improving the safety and efficiency of coal mining. Because of the similarity of the two gases, drained methane can be recovered and added to pipeline supplies of natural gas. To effectively apply advance drainage techniques and recover drained gas, a gross estimate of the methane content of coal is necessary. Using data from previous investigations, the virgin reserves of the Pittsburgh coal in the central and southwestern parts of Washington County, Pa., are estimated at over 1.5 billion tons, with a methane content of 50 to 100 fts/ton. The Pittsburgh bed in this area of approximately 265 mi2 contains over 130 billion ft3 of methane.

Jan 1, 1974

By P. A. Bloom

Arsenic-containing flue dusts are currently being stockpiled by several nonferrous smelters in the United States. These stockpiles are a source of environmental concern since the dusts can be transported by wind and contain water-soluble arsenic. The stockpiles also represent an alternate source of metals. To provide a quality environment, the Bureau of Mines investigated a process to make environmentally acceptable the discard of arsenic obtained from the treatment of arsenical flue dust. The process includes (1) leaching arsenic from a lead smelter copper dross flue dust, (2) fixing arsenic as an insoluble compound, and (3) recovering other metal values. Overall results of acid-leaching tests on lead-smelter flue dusts showed that H2S04 dissolved 80 to 90 percent of the As, Zn, and Cd, and up to 86 percent of the In. Pb, Ag, and Au remain in the residue, which can be recycled to the smelter. Indium was recovered from the strong acid leach solution by solvent extraction; arsenic was fixed in a stable form by precipitation with Fe2(S04)3 and CaO or CaC03.

Jan 1, 1982

By L. A. Johnson

The Bureau of Mines analyzed three cores from the south Seep Ridge area of the P. R. Spring tar sand deposit of northeastern Utah. Four tar sand zones are indicated in the area. The zones range in average thickness from 13 to 24 ft. The total net thickness of the tar sand in the three coreholes ranges from 71 to 112 ft. The tar sand occurs between the depths of 27 and 254 ft. It has good porosity, 25.6 pct of bulk volume; high permeability before and after oil extraction, 819 and 2,218 md, respectively; but a relatively low oil saturation, 36.5 pct of pore volume. Gravity of the oil ranges from 8.20 to 16.5° API.

Jan 1, 1975

By W. J. Fene, H. B. Humphrey, J. J. Forbes

"INTRODUCTION Loss of life from coal-mine explosions in the United States in 1949 was the lowest in any year since before 1870. Although fatality reports from coal nines before 1910 were incomplete,' the explosion fatalities from single disasters or individual States exceeded the 1949 total in each year as far back as 1870, when the records become fragmentary. Since 1890, the only other year in which fewer than 35 were killed was 1946, with a total of 32. Figure 1 shows the total yearly fatalities from explosions in all coal mines and those in anthracite mines alone since 1870. The fatalities in bituminous coal mines were not completely reported before 1910, but enough reports were issued by major coal-producing States to compile reasonably representative figures back to 1885. Any corrections would be additions to these totals.The reason for the moderate total of 46 explosion fatalities in 1948 and the low total of 8 killed in 1949 is thought to be the serious and careful attention devoted to elimination of coal-mine explosion hazards after the disastrous explosions in 1947. The standards now being observed generally with respect to ventilation, rock-dusting, and inspections for gas are better than those found earlier in even the mines having the best reputations for safety. Exceptions are still numerous, but they are fewer, month by month, because of the pressure of Federal and State inspections and a changing conception of the hazards that should not be permitted underground. The prevailing precautions have not eliminated all ignitions of gas or dust, but they have limited propagation to small explosions and have prevented serious loss of life.The number of ignitions (14) reported for the year was less than the average (24) for the 5 years 1944-48 and only half the average for the fiscal years 1929-44. Another favorable factor is that Bureau of Mines representatives were probably in closer contact with both small and large mines in nearly all coal-mining districts. Inspectors now assigned to individual districts are better able to keep informed on the happenings and the progress of safety in their districts. In 1948, one-fourth of the explosions were in mines that employed fewer than 10 men; this condition was duplicated in 1949."

Jul 1, 1950

By Ann G. Kim

Methane in coal constitutes a serious hazard in coal mining. Draining the methane in advance of mining can mitigate this hazard, conserve energy, and offer economic benefits. This Bureau of Mines report evaluates the Pittsburgh coalbed in Greene County, Pa., to determine if advance drainage is feasible. The gas content of virgin reserves in Greene County is estimated at 100 to 200 ft3/ton, a total of over 370 billion ft3 of gas in an area approximately 310 mi2. Because of the similarity to natural gas, drained coalbed gas could be recovered and added to pipeline supplies of natural gas. The value of conserved gas would offset the cost of drainage and extend energy resources.

Jan 1, 1975

By John B. Umhau

[' is ann.tal surve:' gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta l' is ann.tal surve:' gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta ]

Jan 1, 1938

By McHenry Mosier

This paper describes come mechanical raid electrical signal systems in common use in Metal-mine shafts, together with several distinctive systems that indicate or control the origin of the signal. The latter systems remove the hazard of the movement of the cage from one level in response to signals from another. Previous publications of the Bureau of Mines have covered several meritorious installations One of the best signal systems for deep shafts is at the Homestake mine4/. A successful installation of an induction system in the Lake Superior mining region permits signaling as well as telephoning from cages at rest or in motion5/. El Potosi mine uses a variation of the three-wire electric system6/. A mine in Utah has developed a system of the double trolly-wire type, in which the cage attendant may signal from a moving cage7/. At present no system of the sine-shaft signaling employing radio is available.

Jan 1, 1939

By A. W. Henderson

The growing importance of halide metallurgy for preparing high-purity metals has stimulated research to extend halogenation reactions to the direct extraction of metals from low-grade sources. This Bureau of Mines investigation involves a pioneering study of chlorination reactions in the presence of a fluorine donor. Tin slags containing tantalum and columbium and a zircon concentrate containing a relatively high ratio of hafnium to zirconium were studied. Direct chlorination of these materials at 500° C. yields only a 5-percent conversion of tantalum and columbium or zirconium and hafnium to anhydrous chlorides. This investigation showed that small additions of calcium fluoride to the reaction increased the recovery of tantalum and columbium to 95 percent and the recovery of zirconium and hafnium to 27 percent. These results were achieved with ratios of calcium fluoride to mineral or slag of only 0.2. Silica, the major impurity in the materials studied, was found to be converted to silicon tetrafluoride during chlorination in direct proportion to the quantity calcium fluoride added to the charge. However, large additions of calcium fluoride decreased the volatility of the resulting halides of tantalum, zirconium, and hafnium. Smaller amounts of calcium fluoride also favored recovering minor metal constituents in the zircon concentrate (uranium, thorium, and rare earths).

Jan 1, 1962

Maintain good blowing face ventilation while taking deeper cuts with a radio-remote, scrubber-equipped miner. Approach A six week in-mine study of face ventilation effectiveness was made by comparing the existing MSHA-approved blowing curtain setback distance of 25 ft with brattice set back distances of up to 50 ft. Effectiveness was determined by measuring methane levels at the face and in the immediate return. How It Works Blowing ventilation systems are commonly used in mines because the high velocity air stream created by these systems rapidly mixes with and dissipates methane generated during the cutting of coal. A drawback to blowing ventilation is that the work area is placed in return air and this may create dust compliance problems for the shuttle car and mining machine operator. To clean dust from the return a number of mining machine manufacturers supply dust scrubbers built into the machine. Dust-laden air is drawn into ducting at the front of the mining machine's boom and is ducted to a scrubbing unit located on the machine's main frame. The clean air from the scrubber is discharged as a high velocity jet toward the return, generally from the left fender of the mining machine. When taking cuts deeper than 20 to 25 ft with a scrubber-equipped machine, the machine's discharge is in by the mouth of the blowing curtain, creating a concern by mine workers that a loss of air to the face could result. However, Bureau of Mines research found that the push or throw of air toward the return by the scrubber discharge jet allows good face ventilation to be maintained with extended curtain setbacks.

Jan 1, 1984

By Philip C. Tully

This Bureau of Mines report contains experimentally determined vapor-liquid equilibria data for a helium-nitrogen-methane mixture with a nominal composition of 15, 60, and 25 mole-percent, respectively. Measurements of the equilibrium phase compositions were obtained by means of a windowed cell, in conjunction with an automated chromatograph and a special analyzer for low helium concentrations. The data presented include a comprehensive table and eight graphs depicting phase compositions, vaporization ratios, and correlations with a previous study of two helium-nitrogen-methane mixtures of different compositions.

Jan 1, 1976

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional ore-processing methods that will confine and permit controlled disposal of radioactive liquid wastes. Stream and ground water pollution from radio-active nuclides, principally radium 226 and thorium 230, in liquid wastes from uranium mills can be minimized by reusing the waste solution within the mill. Such reuse of waste solution in an acid leach-resin-in-pulp flowsheet was investigated in the laboratory. The process consists of acid leaching for dissolution of the uranium, sand-slime separation and countercurrent decantation washing for recovery of a pregnant slime slurry, and the use of ion-exchange resin for recovery of uranium from the slurry. Reuse of clarified barren effluent for washing in the simulated mill circuit was carried through 55 cycles. Dissolution of uranium from the ore averaged 97.5 percent. Washing efficiency of 99.9 percent was attained when using 4.35 volume tons4 of combined barren effluent and makeup water per ton of ore. Absorption of uranium from the pregnant slime slurry by an ion-exchange resin averaged over 99.9 percent.

Jan 1, 1962

By Jürgen F. Brune, R. Karl Zipf, Kenneth L. Cashdollar

This paper outlines the legal standards and methods for protecting underground coal mines in the United States from explosions of methane gas and coal dust. It will discuss inspection and monitoring of mine atmospheres, dilution of methane through ventilation, methane drainage prior to, during and post-mining, as well as explosion prevention through rock dusting and sealing of mined-out areas. Recent research findings of the National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory on the magnitude of pressures obtained during methane explosions from modeling and full-scale explosion tests at the NIOSH Lake Lynn Experimental Mine will be presented. This work is currently being applied to modeling the structural response of explosion-proof mine seals to pressures from gas explosions. Also, new research will be presented on the inertization of float coal dust in mines through the addition of inert stone dust and on the application of the Coal Dust Explosibility Meter (CDEM), a handheld device developed by NIOSH to directly measure the explosibility of a coal dust - limestone dust mixture based on optical reflectivity.

By E. D. Gradner

During 1924 a number of lives were lost and other men incapacitated by the toxic effects of gases produced in blasting in massive sulphides. In one mine, three men working in a raise were caught by gases from blasting a drift round in massive sulphide on the level. The round in the drift was shot ahead of time and it was necessary for the three men to travel through the gases to the intake air course. Two of the men lost their lives, and the third was injured, apparently for life. Other men at this same mine have been caught in the gases at blasting time and seriously injured. At a second mine, the gases from blasting in sulphides appear to be very dangerous, and it was necessary to send a number of men who were caught in such gases to the hospital. One man who was seriously gassed has not recovered in over a year is time. Another man similarly gassed soon died of influenza.

Jan 1, 1926