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By Roy L. Wilfong

Infrared reference spectra are presented of compounds of importance in lead sulfide flotation research. Included are the spectra of several short chain alkyl xanthates of lead and zinc, the corresponding dixanthogen compounds, and the common oxidation products of lead sulfide and their sodium analogs. The spectra of several frequently used industrial flotation reagent xanthates are also presented. A thorough, well-documented discussion is given of the various corrections made to correct the as recorded absorption band data to near absolute values.

Jan 1, 1974

By Graham W. Marks, Betsy M. Jones

"Recently4/ it was shown that the total energy method5/ of spectrochemical analysis is suitable for the quantitative estimation of many of the elements of which ores are composed. It was shown how this method can be applied to the determination of germanium, tin, and lead. Continuing this work, the present report deals with analyses for beryllium, zinc, cadmium, and indium.There are three basic problems in these investigations. The first is to study the influence of those elements that make up the greater part of an ore sample on the spectral-line intensities of the elements for which analyses are being made, the latter generally being the minor constituents. The second is to develop proper methods for the preparation of standard spectrographic curves. Finally, we are concerned with improvement in equipment and procedure, so that greater accuracy can be achieved.As discussed previously, it is better to study as groups those elements that belong to the same group in the periodic table because their spectra are similar. Beryllium, zinc, and cadmium are thus related. Indium was included in this work because it is associated with zinc and cadmium in zinc ores.The authors wish to acknowledge the valuable assistance of the staff of the Bureau of Mines Analytical Laboratory who made the chemical analyses and supplied the ore samples used in this work.A brief description of the procedures followed in making the standard curves and analyses is given below; a detailed discussion will be found in an earlier paper.6/Basically, the procedure for determining a standard curve consists of two parts: (1) Choosing a suitable line in the spectrum of the element to be determined and (2) determining the variation in the intensity of this line with the amount of the element burned in the arc."

Nov 1, 1948

By J. W. Horne

The quantitative determination of salt in petroleum ins generally divided into two steps - (1) extraction of salt from the oil and (2) accurate measurement of the extracted salt. This paper presents a method used by the Bureau of Mines for quantitatively extracting the water-soluble chloride salts4/ from petroleum and discusses important details attendant on the success of the method. Among these details are homogeneity in the dispersion of salt crystals, emulsified brine and other impurities in the oil sample, complete solution of the salt, and total extraction and titration of all the aqueous phase. Recently, the chlorides of sodium, calcium, and. magnesium produced with and present in various oils have developed growing problems of salt deposition and corrosion in the petroleum industry. Therefore, a technical study of various emulsions and salts that accompany petroleum is being made by the Bureau of Mines in cooperation with the State of Oklahoma. One report (5)5 reviewing the literature pertinent to the study has been published.

Jan 1, 1940

By M. B. Royer

Sulfur is present in many ores and other raw materials that are used in the production of metals and alloys of industrial importance. Its presence, especially in ferrous-metal products, generally is undesirable because of its detrimental effect during processing and upon various physical properties of the finished metal. Therefore, various methods are resorted to for elimination of the element to some specified maximum final content. Such removal or elimination of sulfur is designated as desulfurization.

Jan 1, 1948

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as 1892, at Point Albino, Canada.4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence urea by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle, the production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is mane of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety end health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide

Jan 1, 1931

By W. H. Young

The thickness of the coal seam is one of the more important items influencing the productivity and general overall efficiency of operation of a coal mine. The average thickness of coal seams mined in the United States has changed very little in the past 40 years. The first measurement of thickness of bituminous coal and lignite seams was made for 1920, when the average thickness was 5.3 feet.2 The average thickness for later years was as follows: 1945, 5.4 feet; 1950, 5.3 feet; 1955, 5.2 feet; 1960, 5.3 feet; and 1965, 5.2 feet.3 Table 1 includes data on number and production of bituminous coal and lignite mines classified by 1-foot intervals of seam thickness mined in 1920, 1945, 1950, 1955, 1960, and 1965. Though bituminous coal and lignite are mined today from seams of exceedingly variable thickness--less than 2 feet to more than 50 feet--a large majority of the production, 62 percent in 1965, came from seams 3 to 6 feet thick. This is not surprising since the coal seam of moderate thickness presents the least mining difficulties.

Jan 1, 1967

By B. W. Haynes

With the national focus on energy, the combustible fraction of urban refuse is being extensively considered as a fuel supplement for coal in the generation of heat and power. The objective of these analytical studies by the Bureau of Mines was to determine the concentration of major, minor, and trace elements in the combustible fractions collected at various locations in the Bureau's urban refuse recycling pilot plant located at College Park, Md. The samples processed through the plant were submitted by various municipalities that are considering resource recovery as an alternative to landfill or other means of disposal. Twenty-five elements were determined in samples from six geographic areas and were compared with element concentrations found in typical coal samples.

Jan 1, 1977

By T. M. Barczak

Many of the support concepts currently used in the United States originated in South Africa. These products include the Hercules Crib1, Propsetter, MX Prop, Rocprop, and Spider Prop. Another recent development has been the introduction of hydraulic prestressing units, such as the Jackpot system, to various U.S. standing support systems. Several other prop-type supports with similarities to systems used in South Africa are in use in U.S. coal mines. Some exciting new developments that improve the installation and yield performance of props are also underway. In addition to prop-type supports, crib-type supports and single-unit systems such as the Can support are also frequently utilized in longwall tailgates in the U.S. The goal in U.S. support development is to enhance roof support capability while alleviating material handling barriers to reduce injuries associated with support handling and installation. Support products are generally full-scale tested at the National Institute for Occupational Safety and Health (NIOSH) in the unique Mine Roof Simulator load frame. The performance testing protocol is designed to simulate the full range of load conditions that occur in underground mining to identify the performance deficiencies and limitations of the support products. Once the products complete the performance evaluation, they are implemented into the NIOSH Support Technology Optimization Program (STOP). STOP is a window’s based software program that was developed by NIOSH for facilitating the design of standing roof support systems. STOP has become an industry standard to compare the performance capabilities and facilitate the application of these support products into various mining conditions. The purpose of this paper is to provide an overview of the support design and application philosophy in the United States.

By M. M. Barr

Rapid expansion of the titanium-metal industry focused attention upon ilmenite as a possible substitute for the more expensive and less abundant rutile in producing titanium tetrachloride. Most of the rutile available for this use is imported. Preliminary studies were undertaken to determine the chlorination characteristics of high-titanium slags produced by electric-arc furnace smelting of alluvial Idaho ilmenite at the Federal Bureau of Mines Northwest Electrodevelopment Experiment Station, Albany, Oreg. Low silicon, calcium, and aluminum contents of the slags enhanced their potential value for chlorination.

Jan 1, 1958

By Peter F. Strong, Robert L. Lagace, Alfred G. Emslie

This paper is concerned with the theoretical study of UHF radio communication in coal mines, with particular reference to the rate of loss of signal strength along a tunnel, and from one tunnel to another around a comer. Of prime interest are the nature of the propagation mechanism and the prediction of the radio frequency that propagates with the smallest loss. Our theoretical results are compared with measurements made by Collins Radio Co. This work was conducted as part of the Pittsburgh Mining and Safety Research Center's investigation of new ways to reach and extend two-way communications to the key individuals that are highly mobile within the sections and haulage ways of coal mines.

Jan 1, 1973

By Wallace W. Roepke

The Bureau of Mines studied the cutting characteristics of point-attack bits to reduce airborne respirable dust and energy during cutting. Linear cutting of two coal types using four bit types at three depths of cut with three space-depth ratios was performed with a modified horizontal milling machine using an optical particle-size monitor for respirable dust sampling. The cutting action of one bit on a rotary hardhead mining machine was mathematically analyzed and compared with the results of the linear cutting test. Airborne respirable dust per unit mass cut (specific dust) was found to be a monotonically increasing function of specific energy. Specific dust and energy decrease with increasing depth of cut. The amount of nonairborne respirable dust was 100 to 1,000 times greater than the airborne dust. The plumb-bob bit produced the most airborne respirable dust and the highest specific energy of the four bits tested. Rotary cutting was a greater dust producer and energy consumer than linear cutting because of the constantly changing depth of cut, space-depth ratio, and attack angle of the bit relative to the horizontal bedding planes. A new cutting technique is proposed to minimize the existing problems of the rotary cutting machines by providing greater production, reduced dust, and minimized methane ignition potential at the face.

Jan 1, 1976

By John T. Aydelotte, Martin J. Gavin

" Oil shale contains little or no oil as such , but it contains an organic material from which oil may be produced by destructive distillation" . This statement , or others conveying the same meaning, appears in many popular and techni cal articles on oil shale . It is based on the belief that the ordinary solvents of petroleum have but little action on the organic substances contained in oil- yielding shales , although on distillation these same shales may yield upwards of 50 gallons of crude shale oil per ton . A 50 - gallon shale thus yields by distillation 18.73 per cent of its weight as oil ( assuming the specific gravity of the oil to be 0.900 ) , although only a relatively small part of this can be recovered by extraction with such solvents as chloroform , carbon tetrachloride , and the like . In the course of certain experiments designed to determine the solubilities of different shales after they had begun to yield oil by distillation , it was found desirable to determine the quantity dissolved from certain unheated shales by various solvents , at or near the boiling points of these solvents . The method used and results obtained are presented below. These experiments were made in connection with the oil - shale investigations being conducted by the U. S. Bureau of Mines , in cooperation with the States of Colorado and Utah .

Jan 1, 1922

By B. R. Mohal, F. F. Aplan, S. Chander

"Dust abatement by water sprays involves the subprocesses of 1) collision between dust particles and water droplets, 2) adhesion of particles to droplets, and 3) engulfment of particles by the droplets. A review of the fundamental aspects of these subprocesses shows that collisions between particles and droplets are determined by aerodynamics and the size and surface charge of the particles and of the droplets. However, the adhesion and engulfment subprocesses depend upon the wetting characteristics of the particles. Although wetting agents (also known as surfactants) have been used as dust suppressants in several investigations, conflicting results are available regarding their effectiveness. In this paper, we show that these results can be explained if the effects of coal rank on surfactant adsorption and wetting characteristics are taken into account.The influence of several nonionic surfactants containing polyethoxy adducts on the wetting behavior of coal is presented. The wetting was determined by a modified Walker Test method, and contact angle measurements. The results show that the wettability of coal depends upon coal rank, structure of the hydrocarbon chain of the surfactant, and the number of ethoxy groups in the molecule.IntroductionDue to the inherent nature of the mining process, a large number of particles are generated, a portion of which becomes airborne to create dust. Dust can be aesthetically and environmentally unacceptable and it can also be explosive. Fine particles in the respirable size range ( < 5 urn) are con-sidered to cause lung diseases, namely, silicosis, pneumoconiosis, etc.(1) Several approaches to reduce dust in mine environments are practiced throughout the mining industry. These include decrease in generation of dust through improvements in mine machinery, ventilation (in which lower dust levels are achieved by dilution of contaminated air with clean air), and dust removal methods. Water sprays are most commonly used to remove dust par-ticles. Recently, scrubbers are reported to have been installed on mining machines to remove dust,(2,3) which also make use of water sprays to reduce dust."

Mar 1, 1989

By Edward P. Barrett

[Iron oxides, when reduced at temperatures below 900° form a dark gray substance, very porous bait otherwise in almost the same form as the original particles. In the temperature ire range of 1,000 to 1,100° the product is pertly sintered but still shows the outlines of the original particles. Those products are known as "sponge iron." At temperatures of 1,100 to 1,2000 the metallic iron begins to flow together and to a semifused, pasty, porous mass called a "bloom," which can he worked under a hammer to form a product similar to wrought iron; it contains slag inclusions and is too low in carbon to make steel. If the temperature is 1,300 to 1,300°, part of the iron will fuse enough to absorb more carbon. The dissolved carbon lowers the melting point and still more carbon is absorbed. The melted portion acts a flux for the unmelted metallic particles until the entire mass becomes a high-carbon fluid known as "cast iron." Sponge iron was probably the form in which the first iron was recovered from the ores. As early as the eighth century the Catlan forge3 developed into a low-shaft furnace known as the "high bloomary," in which iron eras produced in the form of a pasty mass. In 1340 the first blast furnace was built in Belgium. The greater part of the iron was made into wrought-iron blooms by crude puddling processes. Charcoal was used as the fuel until tie latter part of the 17th century when coke was used in England. In 1865 Bessemer built his first converter in. England, and within a few years the Siemen&apos;s regenerative open-hearth furnace was developed, also in England. Enormous expansion in the metallurgy of iron followed. The idea of "direct processes" for the production of iron arid steel has persisted throughout all this time. The production of steel from sponge iron has theoretical advantages over the present-day standard methods, and handreds of so--called "direct processes" have been proposed or tried during the past century.4]

Jan 1, 1929

By L. C. IlsLey

"According to accident statistics, issued from time to time by the Department of the Interior, Bureau of Mines covering fatalities in coal mines, between the years 1870 and 1921 there were 4,897 deaths caused by explosives. The legislatures and safety commissions of the various mining States have Elected and formulated many excellent regulations in regard to the handling and use of explosives in an endeavor to keep this class of accidents as low as possible. An analysis or comparison of the explosive, regulations issued by over thirty States would make a very long paper, however, by subdividing according to phases and issuing several papers it is believed that the material will be more readily available. The first phase was treated in Serial No. 2405 of the Bureau of Mines (""State and Federal Electrical Shot-Firing Regulations,"" issued in October 1922) which gave a compilation of such regulations as apply strictly to electric shot-firing. The second phase under consideration is ""Who may set off blasts in coal mines.""In some States, the person who does the firing must be an ""authorized shotfirer,"" while in other States he must have proved his ability to do this work, and again in other States he is ""any person."" The present paper covers rules and regulations relating to this phase of shotfiring, and those States having similar regulations have been grouped as follows."

Jun 1, 1923

By E. G. King

This paper reports measurements of low-temperature heat capacities and entropies at 298.15° K. of two copper ferrites (CUFe204 and CU0.75Fe2.2504). These substances, which occur in copper-smelting slags, have not been sujected to any previous direct thermodynamic investigation. The two copper ferrites are spinel minerals of the variate class. In previous investigations similar data were obtained for 13 other spinel minerals -7 of the normal class and 6 of the variate class. The entropies at 298.15° K. of these minerals have been compiled and revised as necessary in the light of present knowledge regarding structural randomness; entropy values, recommended for use in thermodynamic calculations, are listed.

Jan 1, 1959

By R. K. Franklin, S. T. Reese, J. J. Forbes

"INTRODUCTION It is a recognized fact that in the coal-mining industry coal dust must be allayed to promote the safety and health of underground workers. The Bureau of Mines has been cognizant of the hazards of coal dust for many years, and the necessity of controlling such dust was acknowledged when the Federal Mine Safety Code was formulated. Accumulations of coal dust increase the explosion hazard in a bituminous-coal mine and facilitate the propagation of an explosion. Some of the coal dust produced in mining is inhaled by the workers and contributes to respiratory infection. Impairment of vision and personal discomfort resulting from working in dense clouds of coal dust reflect unfavorably on the efficiency of workmen. Considerable coal dust, originating at the working face, is carried in the ventilating current and deposited elsewhere in the mine, thereby increasing the explosion hazard. It is apparent, therefore, that if coal dust could be allayed effectively at its points of origin, the dust-explosion hazard in bituminous-coal mines would be reduced greatly.Although dust control is practiced in many bituminous-coal and lignite mines, the extent and effectiveness of control for the, entire industry-is not generally known. The purpose of this circular is to present such information clearly, and to encourage coal-mine operators to install dust- allaying equipment.Factual data on dust-allaying practices at working faces in a large number of the bituminous-coal and lignite mines in the United States were .compiled from reports on recent Federal inspections of these mines, The information is presented in tabular form to permit review of the dust-allaying practices of a substantial part of the industry, by States, and also according to employment, and loading practice."

May 1, 1950

By Robert E. Wood

The compressibility factors, Z, of helium, nitrogen, and helium-nitrogen mixtures in the three-dimensional space of temperature, pressure, and gas composition have been related to the Leiden form of the virial equation of state. The dependency of virial coefficients through the fifth on temperature and gas composition has been established for the temperature range 133.15° to 748.15° K. Compressibility factors, Z, have been computed from the equation of state and tabulated as functions of gas composition, pressure, and temperature. Tabular values of Z are presented for 30.00 through 100.00 percent helium for temperatures from 240° through 700° R for pressures from 14.696 through 3,050 psia and for temperatures from 720° through 1,300° R for pressures from 14.696 through 1,500 psia. Tabular values of Z are presented at increments of 5.00 percent helium and 20° R, and, for pressures greater than 50 psia, at increments of 50 psi.

Jan 1, 1967

By Harold L. Gibbs

The purpose of this paper is to encourage petrographers to prepare thin sections, as the demand for microscopic examination of rocks, ores, and metallurgical products is becoming more general in .the mining metallurgical-fields. This paper has been written with the knowledge that the successful thin-section methods and the several new techniques herein described will be helpful to all engaged in this field of work. Detailed instructions for making thin sections by methods developed at the Salt Lake-City laboratory of the Bureau of&apos; Mines are given in this paper. Several new techniques are described for making thin sections of loose grains and fine sands and for making good thin sections of highly altered and friable rocks. The methods described insure superior bonding of the rock to the glass slide, thus virtually eliminating any failures due to parting of the section from the glass slide, and permit fast mounting, grinding, and finishing, thereby materially lessening the time required to prepare thin sections.

Jan 1, 1950

By R. C. Hickman

Manganiferous breccia formations on three properties were prospected by the Bureau of Mines from January to November 1954 in Johnson County, Tenn. The prospecting consisted of diamond drilling, trenching, shaft sinking, and crosscutting. The results of the exploratory work show the manganiferous material to be low-grade, with little vertical extension. The manuscript on this report was completed February 1955. LOCATION The prospects are in Johnson County, Tenn. (fig. 1), within a radius of 12 miles from Mountain City. The nearest railroad terminal is Damascus, Va., 14 miles from Mountain City.

Jan 1, 1956