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By Leonard J. Prosser, Joseph Cervik, John H. Perry

The Bureau of Mines has developed several techniques for draining methane from coalbeds in advance of mining. Drilling long horizontal holes from an underground location is one such technique, which was successfully demonstrated in the Pittsburgh and Sunnyside Coalbeds. The same technique has now been applied in the Mary Lee Coalbed at Jim Walter Resources, Inc. 's No. 4 Mine, Brookwood, Ala. , where two holes were drilled horizontally--one to a depth of 1,010 feet (308 m) and the other to 540 feet (165 m). The 1,010-foot (3083) hole proved successful in degasifying a portion of the Mary Lee Coalbed. The hole drained methane for 1 year, during which time the initial gas flow of 200,000 ft3/d (5,663 m3/d) declined to 65,000 ft3/d (1,840 m3/d). Total gas production was 40 x lo6 ft3 (1.1 x lo6 m3 ). The gas was of commercial quality, with 98 pct methane and a heat rating of 990 Btu/ft (36.89 Mj/m3). The methane emissions from the faces of the mine section advancing into the degasified zone were reduced by 60 pct. The 540-foot (165-m) hole was terminated prematurely when it became impossible to maintain an open hole. Because of caving, very little gas was drained through this hole.

Jan 1, 1982

By Charles Prasky

The Bureau of Mines investigated the conversion of nonmagnetic iron minerals to magnetic form through reduction Toasting operations. The primary objective was to obtain a concentrate that could be used as a direct shipping material for blast furnace consumption. Crude iron materials from the Steep Rock Lakes, Ontario, area were prepared into a blend of 8 parts siliceous ore, 3 parts pyritic ore, and 1 part tailings. Experimental work included laboratory reduction roasting tests, two continuous 10-day campaigns, and one 12-hour test all in a 34-inch by 36¬-foot rotary kiln. The objective of the project was achieved in producing an iron concentrate containing about 66 percent iron with over 90 percent iron recovery. Desirable operating conditions were developed in the kiln but optimum process variables were not completely established.

Jan 1, 1969

By O. P. Hood, G. St. J. Perott, S. P. Kinney

"FOREWORD (By O. P. Hood, Chief mechanical engineer).During the war certain suggestions concerning power production were made by Mr. Walter E. Trent to the War Inventions Board, and at the request of the War Department facilities for experimental work were provided on the grounds of the. Bureau of Standards.The experiments were along the line of controlling the conditions of combustion in a closed space. In order to reduce slag troubles, experiments were carried out for removing ash from powdered coal. After the war, work along this line was continued, resulting in the Trent Process, which agitates or beats together powdered coal, water and oil.A new technology had previously been given to ore preparation by the use of small quantities of oil in water with froth flotation, and although the methods, results and mixtures of the Trent Process were quite different, yet the same physical phenomena of differential wetting used, and the possibility of there being interesting results in fuel technologic was evident. A cooperative agreement was entered into, whereby the Bureau of Mines was to investigate the underlying physical and chemical facts and make them public, and the Trent Corporation was to pay the cost of the investigation.The several reports as made have been available to any one interested, and are now to be published. While the Bureau of Mines felt justified in investigating the physical phenomena so far as might be done in a laboratory, and so far as public interest might reach, no attempt was made to discover the commercial possibilities which development might bring. The question of commercial possibilities must be left for commercial enterprise to answer."

Jul 1, 1921

By Gerald W. Elger

This report describes development of the fusion-leach crystallization precipitation process for producing a hafnium content feed material for hafnium-zirconium separation plants. Mixtures of zircon, potassium silicofluoride, and potassium carbonate (or potassium chloride) were fused to prepare soluble potassium zirconium hexafluoride-potassium hafnium hexafluoride salts. High extraction of these salts was obtained by countercurrent leaching the fused material in dilute hydrofluoric acid. About one-half of the hafnium was recovered in hafnium-enriched mother liquor by cooling clarified lead: liquor to crystallize most of the zirconium salt. Additional hafnium was recovered from the primary crystals in a multiple dissolution-recrystallization step. Hafnium-enriched oxides having a hafnium-zirconium ratio of more than three times that of zircon were precipitated from the combined mother liquors. The hafnium and zirconium recoveries in the precipitate were 83 and 24 percent, respectively. About 71 percent of the zirconium and the remainder of the hafnium were recovered in potassium zirconium hexafluoride crystals of low-hafnium content.

Jan 1, 1966

By Forest J. Sur

"INTRODUCTION This report describes an exploratory project conducted by the Bureaus of Mines on a fluorite deposit, near Glenwood, N. Mex. Results of wagon drilling, crosscutting, and test pitting are given, together with results of metallurgical tests made upon samples of the ore. Mining and treatment methods are suggested.C. H. Johnson, Bureau of Mines engineer, examined the deposit in August 1942. H. E. Rothrock, of the Federal Geological Survey, completed a preliminary geologic study and mapped the deposit during the fall of 1942. As a result of these brief investigations, it was concluded that the deposit contained substantial inferred ore reserves, and exploratory work was recommended. G. A. ApelI, also of the Bureau of Mines, made a topographic and underground survey and report on the mine in March and April 1944. A wagon drill, air compressor, and other equipment and supplies were delivered to the property on May 19 to 23, 1944. Drilling began under the direction of the author on May 25, 1944, and was completed in October 1944. The results of drilling and. sampling form the basis of this report."

Apr 1, 1947

By K. K. Kershner

The purpose of this research by the Federal Bureau of Mines was to investigate the recovery of tin from mine-run ores and low-grade concentrates. Over 95 percent of the total tin in such materials was volatilized to tin chlorides at temperatures ranging from 520° to 565° C. Gaseous mixtures of hydrogen and hydrogen chloride were used for reducing cassiterite to stannous oxide and for converting this compound to tin chlorides. The chlorides were swept from the reaction zone of an oscillating kiln by a rapid flow of reactant gases and collected in a condensing system. Losses of tin that occur in current metallurgical processing were prevented. Approximately the same time of treatment was required for minus 35-mesh mine-run ores and low-grade concentrates. In a continuous process, the circulating gases would require some enrichment.

Jan 1, 1961

By James R. FitzSimmons

This report describes an instrument developed by the Bureau of Mines as an improved device for examining roof rock in bolt holes. The unit consists of a commercially available fiberoptic unit adapted for use as a flexible stratascope. Field testing in both metal and coal mines has shown the instrument can be easily transported and used by a single operator. The size and flexibility of the instrument eliminate the need for specially drilled holes.

Jan 1, 1979

By R. V. Higgins

The, large volumes of low A. P. I. gravity oil that will remain in many shallow fields of California when such oils no longer can be recovered profitably by pumping are important potential sources of oil when ways and means are found to remove them from the reservoir sands. Estimated ultimate oil recoveries in many of the "low-gravity fields" of the San Joaquin Valley in California indicate that less than 25 percent (on the average) of the original oil will be recovered. These oils have viscosities of 1,000 or more centipoises at reservoir temperatures and, because of their high viscosity and low intensity of the reservoir pressure, the quantities that will be retained in the sands ultimately are so large and their recovery is such a challenge to petroleum engineers that the Bureau of Mines has made the study of their possible recovery one of its major projects. The fact that a slight increase of temperature materially reduces the viscosity of low A. P. I. gravity oils has 'prompted the use of various means for increasing the temperature of the oil in the reservoir sands and hence the rate of flow and Completeness of recovery of the oil. Hot oil, hot water, heated air, and natural gas, steam, super-heated steam, and the products of combustion have been circulated in wells to raise the temperature of the oil it the sands; electric heaters have been installed in wells, and butane and air have been intermittently exploded and the flames propagated through the tubing to the "pay" zones. None of the methods, however, have been entirely satisfactory for the recovery of large quantities of oil.

Jan 1, 1949

By L. B. Pankratz

The heat contents of the sesquioxides of erbium, holmium, thulium, and ytterbium (Er203, Ho203, Tm203, and Yb203) in the cubic crystalline form were measured over the temperature range from 298° to 1,800° K. The erbium and holmium sesquioxides gave regular heat content-temperature curves. Thulium sesquioxide had a minor thermal anomaly near 1,680° K, with a heat absorption of 310 cal/mole; similarly, ytterbium sesquioxide had a minor anomaly near 1,365° K, with a heat absorption of 150 cal/mole. The heat content results are presented in both tabular form (at 100° intervals) and in algebraic form. Entropy increments, corresponding to the tabulated heat content results, also are listed.

Jan 1, 1963

By O. M. Bishop

"SUMMARYAs a result of the increased demand for fluorspar during the war, the Bureau of Mines investigated numerous fluorspar properties in the southern Illinois field, which is centered in Rosiclare. Among these the J. J. Shelby 40-acre tract on the western edge of the district presented favorable factors that caused it to be chosen /or exploration.H. G. Spiller, formen lessee of the property, had explored the Shelby vein by means of an adit level and winze, and showed it to contain goad values in zinc and fluorspar at the depth explored. A diamond-drill hole with which Spiller explored the vein 78 feet southwest of the winze, however, failed to cut ore. After studying the field evidence, the Bureau concluded that the vein merited further exploration, particularly at a depth of about 440 feet, where the Fredonia limestone would form the foot-wall of the vein and the hanging wall would be the competent Cypress sandstone.Between October 17, 1944, and March 26, 1945, three diamond-drill holes were bored for a total inclined depth of 1,592 feet. Holes 1 and spaced approximately 500 feet apart, explored the vein at 440 feet 4 below the surface. The economic mineralization existed in the vein where cut. Hole 3 cut the fault at approximately 300 feet below the outcrop but failed to find any vein matter except stringers of calcite with small amounts of pyrite."

Apr 1, 1947

Provide better ventilation for mines by reducing air leakage around stoppings. Approach Most stoppings are constructed of concrete blocks and trowelled-on mortar and are not very airtight. Bureau of Mines research has shown that brushing on modified mortar containing fiberglass and/or other additives, that enhance strength and adhesion, minimizes air leakage around and through the stoppings. Airtightness is an important factor in building stoppings since an airtight stopping will provide for more efficient ventilation airflow and more cost-efficient use of the mine's ventilation system. How the New Technique Works After broken floor and rib material is removed, the stop-ping faces are covered with one or two coats of modified

Jan 1, 1982

By B. J. Scheiner

As part of the goal to maximize minerals and metals recovery from primary domestic resources, design factors associated with minimizing current leakage in bipolar cell configurations were studied by the Bureau of Mines as a means of improving the efficiency of bipolar e1ectrooxidation cells. Initial studies that were conducted in a small bipolar cell operating at 140 to 145 volts and 15.4 amp indicated how design factors could be employed to minimize cur-rent leakage around adjacent electrodes during cell operation. Based on these results, a 40-electrode, 108-kva prototype of an industrial-sized cell was constructed and tested for extracting metal values from offgrade molybdenite concentrates. The feasibility of recovering molybdenum and rhenium from the oxidized pulp also was determined. Feed to the process sequence consisted of flotation concentrates containing 16 to 35 pet Mo as molybdenite and 6 to 15 pct Cu. E1ectrooxidation in the prototype cell resulted in 84 to 97 pct Mo and Re extraction with a corresponding energy consumption of 9 to 13 kwhr/1b Mo extracted.

Jan 1, 1979

A complete list of permissible mining equipment, rescue apparatus and gas masks tested. Prior to Jan. 1, 1929, w s published in Bureau of mines Information Circular 60972. The present list includes practically all equipment tested and. approved by the Bureau, up to and including July 1, 1929. It covers electric air compressors, coal drills, mining machines, loading machines, conveyors, mine pumps, room hoists,, mine telephones, rock-dusting machines, switches, electric cap lamps, flame safety lamps, electric hand and trip lamps, flash lamps, methane indicators and detectors, blasting units, storage battery locomotives, tandem locomotives, power trucks, concrete mixers, self-contained oxygen breathing apparatus and gas masks. The system under which these devices were tested permits the manufacturer, after his equipment has passed certain tests prescribed by the Bureau of Mines, to mark his equipment with a seal showing hat it has been "approved" by the Bureau. These tests are designs to insure that the equipment has the minimum requirements for safety in use. The only object of the Bureau in making such tests and publishing lists of permissible equipment is to safeguard the lives of workers and to help lessen the hazards of mining.

Jan 1, 1929

By Raymond W. Hiteshue, Sam Friedman, Martin D. Schlesinger

The Bureau of Mines in cooperation with the El Paso Natural Gas Co. investigated the effect of high temperature and pressure at short residence times on the hydrogenation of a New Mexico coal to gaseous and liquid hydrocarbons . The study was made in a bench - scale semicontinuous unit at pressures of 500 to 6,000 psig , 480 ° to 1,000 ° C , and residence times of less than 1 minute to 15 minutes . Ammonium heptamolybdate was impregnated on the coal to furnish 1 percent molybdenum based on maf coal . Coal could be rapidly hydrogenated at elevated temperatures and pressures to yield large quantities of gaseous hydrocarbons and small quantities of lowboiling oils , high in single - ring aromatics . At 800 ° C and 6,000 psig and a residence time of 1 minute , the yield of hydrocarbon gas was 43 percent and of liquid hydrocarbons 9 percent , based on maf coal . With a 15 - minute residence time , the yield of gaseous hydrocarbons increased to 68 percent with a decrease in yield of oil to 6 percent . At higher hydrogen velocities , the yields of oil were much greater but contained large quantities of asphaltene . Low concentrations of molybdenum (0.01 and 0.1 percent ) or a high concentration of iron ( 1 percent ) were ineffective at 800 ° C , 6,000 psig , and short residence time .

Jan 1, 1964

By John R. Shattuck

As a part of the general chromite investigation in California designed to aid In the production of chromite during the recent war emergency, the Bureau of Mines explored the Coggins property in Siskiyou County, Work by the Bureau in cooperation with the Federal Geological Survey began in October 1942 and was concluded in March 1943. This report presents a brief history of the mine, outlines the physical features of the district, describes the deposits) and explains the work completed by the Bureau of Mines, Table 1 shows the analysis of diamond drill-hole samples. The logs of drill holes are in the appendix.

Jan 1, 1949

By Jack O. Jones

The Furnish mine, Caharrus County, W. C., was operated intermittently until 1905 as a gold mine. Scheelite was discovered by A. L. Mash in the mine dumps of the Furniss and Phoenix mines, and he later informed the Bureau of Mines of his discovery. The Bureau of Mines, in two projects at the deposit in 1948 and in drilled 12 holes totaling 1,706.6 feet, examined and sampled the underground workings, excavated by bulldozer and hand, 3,155 linear feet of trenches and collected numerous samples for assay. The best scheelite shown; was found in the underground exposure of the Furniss mine.

Jan 1, 1950

Identify specific sources and the relative levels of contribution of various components of longwall shearer operations to the total airborne respirable dust generated during mining. Approach A research investigation was conducted in two phases by the Bureau of Mines at five mine sites to identify specific dust sources and their relative importance during long-wall shearing operations. During phase I of the project the specific longwall mining elements identified for evaluation were: cutting, sumping, tramming, conveying, and moving roof supports. During phase II of the project, two dust sources were evaluated: clearance ring cutters cutting in six-inch web width increments, and loading operations. Investigation Results As a result of dust measurements, the gage cutters were determined to be the major dust-generating source on the shearer. These cutters, at 6-inch web depth, produce three times as much dust per unit volume as is produced at 30 inches full web depth. The following list of averaged values for the mines tested shows that shearer cutting generated averaged dust levels four times as high as those generated by conveying, and approximately five times as high as those generated in moving roof supports.

Jan 1, 1984

By G. W. Jones

In a previous report results were given and a method outlined whereby from a knowledge of the composition of the natural gas and of the inflammability limits of the individual constituents composing the natural gas, the limits of inflammability of natural gas and air mixtures could be closely calculated. This method is based on the application of Le Chatelier's law as modified by Coward, Carpenter and Payman, to apply to a mixture of any number of combustible gases. This law must not be used indiscriminately, because many exceptions have been found. For example, when ethylene, acetylene, hydrogen sulphide, or chlorinated hydrocarbons are present the law may not hold. For a discussion of the rally exceptions which have been found, reference should be made to a report by Coward and Jones. Before this method can be used the inflammable limits of the individual constituents must be known. Also, the composition of the complex combustible mixture, and representative mixtures besides, must be tested both experimentally and by calculation to prove whether Le Chatelier's law may be applied.

Jan 1, 1933

By R. V. Thurston, Edmund S. Leaver

"During the development of the sulphur dioxide leaching process for the treatment of ""mixed"" copper ores at the Southwest experiment station of the Bureau of Mines*** the pulp from treatment of roasted cupriferous pyrite with sulphur dioxide gases and water showed an unexpected amount of sulphuric acid. After following out several false premises it was found that this was due to iron in the solution, and also that this iron tended to oxidize to the ferric state if the concentration of sulphur dioxide in the roaster gases used did not rise above a certain figure. While the percentage of iron present was email it was enough to cause an entirely different set of conditions from those of the original sulphur dioxide leaching process and to promise a much wider application of the general idea. Sulphurous acid dissolves only certain copper minerals, sulphuric acid solutions certain additional minerals and ferric sulphate solutions certain further additional copper minerals, so this observation was of importance in connection with possibilities in the hydrometallurgy of the so-called ""mixed"" or partly oxidized copper ores.The work has been carried along by a number of experimenters. L. R. Eckman, junior chemist of the Southwest station, contributed largely to the early developments. L. Roberts, W. D. Bonner and C. G. Maier each in turn physical chemists at the Pacific Experiment station, (Berkeley, Calif.) have studied the reactions involved. A complete report of all the work on this process will be prepared later under the direction of O. C. Rolston. The purpose of the present paper is to place a summary of the more practical phases of this seemingly important piece of work before those interested."

Dec 1, 1923

By K. K. Kelley

Despite the wide interest in titanium and its compounds, no heat and free-energy-of-formation values for titanates (that is, compounds formed from titania and other metal oxides) have been available heretofore except for ilmenite (FeTi03). Such data are needed for understanding and developing processes for producing titania and titanium tetrachloride from ores (and possibly slags) and in connection with ceramic usage of titania. This paper reports experimental measurements of the heats of formation at ordinary temperature of 11 titanates-ilmenite, perovskite, barium metatinate, strontium metatitanate, barium-strontium metatitanate, barium orthotitanate, strontium orthotitanate, barium-strontium othotitanate, geikielite, magnesium-titanium spinel, and magnesium dititanate. The experimental method was solution calorimetry. The solution calorimeter was operated at 73.7°C. and used a strong hydrofluoric-hydrochloric acid mixture as the calorimetric fluid and reaction medium.

Jan 1, 1954