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By G. H. Keith

A vanadium-base alloy consisting of the following elements in weight-percent--molybdenum, 20; titanium, 10; carbon, 0.1; silicon, 0.5; and yttrium, 0.5--had exceptionally high strength at temperatures up to 1,200° C. This alloy was capable of fabrication to sheet of ~ 1 mm thickness by a combination of hot swaging and hot and warm rolling. In the warm-rolled condition at ambient temperature, its ultimate tensile strength was 1,205 MN/m2. The strength at 1,200° C was 150 MN/m2. Within the temperature range of 25° to 1,200° C, the ductility of the alloy as measured by elongation increased from 4 to >90 percent. Strengthening was achieved by both solid-solution and dispersed-phase mechanisms. Alloys of 20 percent molybdenum and 10 percent titanium were stronger than the other molybdenum-titanium alloy compositions tested. Strength was increased 15 percent in the temperature range of 25° to 800° C, with no accompanying loss in ductility, by the addition of 0.5 percent silicon. Workability was improved by additions of 0.25 and 0.5 percent yttrium.

Jan 1, 1970

By Seth C. Schaefer

The Bureau of Mines investigated thermodynamic properties of Mn304 (manganomanganic oxide) and Mn203 (manganese sesquioxide). The standard Gibbs energies of formation (?Gf°) of Mn304 and Mn203 from their lower oxides were determined with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, MnO, Mn304//Zr0 2//02(g, 0.0112 atm), Pt, with the overall cell reaction 6Mn0(c) + 02(g, 0.0112 atm) = 2Mn304(c), where- 02 refers to indicated partial pressure of oxygen at the reference electrode. Similar measurements were obtained for the cell Pt, Mn304, Mn203//ZrO2//02(g, 0.0115 atm), Pt, with the overall cell reaction 4Mn304(c) + 02(g, 0.0115 atm) = 6Mn203(c). Equilibrium oxygen pressures for the Mn0-Mn304-02 and Mn304-Mn203-02 systems were measured and may be expressed for the respective systems as [23,400 109 P02 T + 11.91 (764.9 - 1,208.6 K) and log p02 = - 11,957 + 9.66 T (968.6 - 1,208.2 K),] where pressure (p02) is in atmospheres and temperature (T) is in kelvins. Standard thermodynamic properties of Mn304 and Mn203 were derived from these measurements and auxiliary thermodynamic data from the literature.

Jan 1, 1982

By Parviz F. Rad

The Bureau of Mines conducted rock-cutting experiments under constant normal force and constant penetration in an effort to correlate laboratory data with those obtained in the field. Both independent and interacting groove spacing regions were studied, and optimum and critical cutter spacings were determined. For the laboratory work, the effects of specific energy, muck weight, groove depth, cutting coefficient, and size distribution of the muck for both independent and interacting grooves were studied. For field operations, forward thrust, torque, advance rate, and muck size distribution were the parameters studied. Satisfactory correlation is obtained between laboratory cutting results and field performance data.

Jan 1, 1974

By Synthia N. McIntosh

The U.S. Bureau of Mines investigated the feasibility of using ammonium carbamate (NH2CO2NH4) leaching to recover manganese from steel plant slag. This investigation showed that treatment of the slag in hydrogen prior to leaching enhanced manganese extraction. Up to 80 pct of the manganese and 50 pct of the iron could be extracted from a silicon steel slag that had been pretreated in hydrogen at 700° C. Two 4-h leaching stages conducted at ambient temperature with a solution containing ammonia and carbon dioxide dissolved manganese and iron as their carbamate complexes. Heating the pregnant solution to 65° to 85° C decomposed the complexes and precipitated the metals as insoluble carbonate salts. Ammonium carbamate leaching of other slags from several steelmaking plants produced lower manganese extractions, which suggests that the method cannot be applied satisfactorily to all steelmaking slags

Jan 1, 2010

By M. J. Pazuchanics

This U.S. Bureau of Mines report presents results from an ongoing investigation of the use of adaptive signal discriminating methods to distinguish between cutting coal and cutting mine rock. Bit-cutting forces and tool vibration were measured in the laboratory as a linear-cutting apparatus (LCA) made constant-depth cuts in coal, sandstone, and shale test specimens. A portion of the collected data has been analyzed and some preliminary results are given here. The influence of data bandwidth, data window size, number of signal features, and voting among classifiers on classification performance are noted. Results to date, based on ideal-cutting conditions and simple geologic materials, indicate that of the four classifiers tested there appears to be no single best classifier. Usually, classification accuracy showed slight improvement as the number of features considered for classification increased. The highest classification accuracies were achieved when voting was conducted among classifiers followed by voting among force components.

Jan 1, 1991

By C. N. Rosenecker

The power required to circulate a gas-solids suspension was determined using a centrifugal compressor and a closed system. The suspension consisted of 18- to 40-micron glass beads in a mixture of 89 percent N2 and 11 percent CO2 at 20 psig. Solids-to-gas (S/G) ratios w re O to 2.2 lb/lb; gas flow rates were l.2 to 2.5 lb/min. Power requirement was found to follow the relationship hp t = hp(. + l), where hp t = the total power, and hpg = the power required for pure gas.

Jan 1, 1967

By G. R. Smith

This report describes research carried out by the Bureau of Mines to develop new technology for electrorefining metals at much higher current densities than those normally used in commercial practice, preliminary studies using rotating-ring and cylinder electrodes to increase the mass transport of copper are discussed. Following this work, single- and multichannel cells were developed that utilized a high electrolyte flow in the channels formed by the anode-cathode pairs. Using these cells, copper was successfully refined at current densities in the range of 70 to 300 amp/ft2. The effects of flow rate, electrolyte composition, and grain-refining and leveling agents on the morphology and purity of electrodeposited copper were determined.

Jan 1, 1979

By H. G. Iverson

The effects of adding boron and boron plus carbon to electrorefined vanadium were evaluated with respect to mechanical properties at low temperatures and response to heat treatment. Grain size was significantly decreased with the addition of 0.05 percent boron, the decreases ranging from 30 percent at 800° C to 75 percent at 1,100° C. Increasing the boron content resulted in only a small increase in strength at room temperature, but at 77° K, boron contents of 0.005 to 0.076 percent increased the yield strength of vanadium over 50 percent, from 70,000 psi to 110,000 psi. When boron and carbon were present together, the individual grain-refining effects obtained with either element were retained. Approximately a twofold increase in strength was obtained by age-hardening the alloys containing both boron and carbon. Alloys with only boron additions did not age-harden.

Jan 1, 1968

By James P. Bennett

The U.S. Bureau of Mines investigated the role of imported natural flake graphites in dolomite-carbon refractories used in steelmaking processes and evaluated carbon fibers as a potential substitute. Varying quantities (1.5-30 pct) of natural flake graphite and carbon fibers were added to test samples. The effect of the additions on modulus of rupture (75°-2,750° F), deformation under load (2,750° F), and air-slag-metal resistance (3,000° F) was studied. Carbon purity of natural flake graphite additions did not influence hot strength, deformation under load, or air-slag-metal resistance. When the quantity of 90-pct-carbon graphite addition varied between o and 30 wt pct, hot strength was highest, deformation under load lowest, and air-slag-metal wear the least at 10 wt pct. As test temperature increased from 500° to 2,750° F, the hot strength difference became less. Carbon fiber additions were limited to 1.5 pct in dolomite-carbon brick. At this level, physical properties were generally comparable to those obtained with natural flake graphite, but were below values obtained with 10-pet-f1ake graphite additions. Carbon fibers are not considered a satisfactory substitute for natural flake graphite.

Jan 1, 1989

By B. H. Eccleston, R. F. Kendall, D. E. Hirsch, Norman G. Foster

The mass spectra of 23 alkylthiophenes are presented , including 21 that have not been previously reported . Correlations between mass spectra and the structure of the thiophene homologs are discussed . Comparisons with , and corroboration of , earlier workers ' correlations and predictions are made . Several additional correlations are reported to enable the spectroscopist to identify the substituents on alkyl - substituted thiophenes , and the relationship of the mono - substituted and 2,5 - disubstituted alkylthiophenes is discussed in detail .

Jan 1, 1964

By James Paone

This report shows the feasibility of predicting drillability, analytically, by using regression analysis techniques. The approach is new in diamond-drilling research. Further, the study shows that this technique may be of value to drill manufacturers and others in mathematically delineating performance characteristics of new drills in specific rock types. Another application might be the prediction of penetration speeds in extraterrestrial material based on the physical properties of the materials as samples become available. Prediction equations for penetration rates are presented for 9 rocks drilled in the laboratory and for 20 rocks drilled under field conditions. The prediction equations are based on drill operating parameters and on characteristics of the rock penetrated. No single physical property appeared consistently in the best predictor equations, and all the physical properties were found to be highly correlated with each other.

Jan 1, 1966

Roof falls continue to be the greatest single safety hazard faced by underground coal miners. During 1996-99, 44 coal miners lost their lives in rock falls, and nearly 2,400 were injured. In addition, nearly 6,000 noninjury roof collapses were reported. Roof supports are installed to protect the miners, but support system failures contributed to most of these incidents. Reducing the terrible toll taken by ground falls continues to be a major goal of research by the National Institute for Occupational Safety and Health (NIOSH). The purpose of these proceedings is to provide the mining community with a comprehensive survey of coal mine roof supports. Drawing on many years of research undertaken by the NIOSH Pittsburgh and Spokane Research Laboratories, this volume describes what types of support are available, how they work, and when they should be used. The major subjects covered include roof bolts, standing roof supports, cable supports, and longwall shields. Some special topics are also addressed, including an analysis of roof fall accident statistics, techniques for better skin control, material handling considerations, and longwall mining through recovery rooms. This proceedings volume also contains information on several important new technologies, which are described here for the first time: •Guidelines for selecting roof bolt length, pattern, and capacity that were derived from statistical analysis of the roof fall experience at 37 underground mines; •A new design method for longwall tailgate supports; and •A technique for measuring loads developed within cable bolts. The papers in these proceedings were presented at open industry briefings conducted by NIOSH on New Technology for Coal Mine Roof Support. The briefings were held in Norton, VA, Charleston, WV, Evansville, IN, Tuscaloosa, AL, Price, UT, Glenwood Springs, CO, and Washington, PA. The papers were also presented at the Mine Safety and Health Administration (MSHA) Preventative Roof-Rib Outreach Program (PROP) Seminar, which was held at the National Mine Health and Safety Academy near Beckley, WV.

Jan 10, 2000

By E. Morrice, R. D. Smith

Thermal expansion and electrical resistance measurements were made on cerium metal from 4° to 300° K. The apparatus developed , including a specimen holder and a cryostat system , are described along with the experimental techniques used in obtaining the measurements . The total linear thermal expansion Data at of 99.83 weight - percent cerium metal between 4 ° K and room temperature was 4.24 percent . The resistivity at 4° K was 7.0 x 10-6 ohm- centimeter . 4° K indicate a fundamental relationship between residual resistivity and purity of cerium metal . The effects of annealing and repeated thermal cycling on resistivity were determined .

Jan 1, 1964

By J. H. Field

Synthesis of hydrocarbons by the Fischer-Tropsch reaction in a hot-gas- recycle system was demonstrated to be technically feasible. This project was undertaken, by the Bureau of Mines, to determine if the system was operable and to ascertain the optimum conditions for the production of gasoline. Carbon steel turnings packed with a void volume from 88 to 90 pct. were satisfactory catalysts, but steel catalysts with greater void volume, either turnings or steel wool, were not as active. Good temperature control with a pressure drop of less than 0.5 pounds per square inch (p.s,i,) per foot of catalyst bed of turnings was obtained by operating with a recycle to fresh feed ratio of 20 and by splitting the total gas flaw and injecting portions into the reactor at different entry ports.

Jan 1, 1961

By Jack C. White

This U.S. Bureau of Mines report assesses the resource potential of trace metals present in commercial Ti mineral concentrates. Metals of greatest interest: are those defined as "strategic and critical" by the U.S. Congress in 1981. Metals of interest in Ti mineral concentrates are Cb, Cr, Ta, Th, U, V, and Zr. Commercially available Ti mineral concentrates were studied. Characterization and analysis of major and minor constituents were performed by X-ray diffraction, neutron activation, inductively coupled plasma emission, atomic absorption, and classical wet chemical techniques. Of the metals investigated, the Cb, Ta, and V content of some concentrates may be a significant potential resource, depending on their amenability to recovery.

Jan 1, 2010

By G. S. Scott

Safety problems in the mining and allied industries have led the Bureau of Mines to investigate over a period of years; the flammability (explosibility) of many types of combustible atmospheres principally at ordinary pressure; the results of these investigations have been made available as a bulletin. However, more recently, the demand for information on the flammability of gaseous mixtures at high and low pressures has increased greatly. In particular, the rapid development of high-altitude aviation has brought demands for information on the flammable (or explosive) characteristics of certain gases and liquids at low pressures. The present report gives the results of about 900 tests made to determine the flammability of the lighter paraffin hydrocarbons mixed with air and nitrogen at pressures of 400 200, 100 and 70 ram. Hg. The gases tested include natural gas, methane, ethane, propane normal butane and isobutane. The minimum pressures at which these gases are capable of propagating flame whorl individually mixed with air also were investigated.

Jan 1, 1952

By F. E. Block

This investigation was made as part of a larger program to develop basically new methods for preparing yttrium metal in high-purity form. It was performed under a cooperative agreement between the U.S. Atomic Energy Commission (AEC) and the Federal Bureau of Mines. Laboratory-scale tests were made to devise methods for preparing high-purity, anhydrous yttrium trichloride, for reducing the yttrium trichloride with sodium or lithium, and for consolidating the resulting yttrium sponge into ingots.

Jan 1, 1960

By William C. Miller

This report describes investigations by the Bureau of Mines designed to establish the noise level and spectrum of various types of pneumatic rock drills and to furnish information that would be useful in conducting sound measurements in mining environments and in reducing the noise generated in pneumatic drilling. These investigations show that (1) the noise generated by the drills in the frequencies below 100 cps is caused by the impact of the piston and drill steel, in the frequency range between 100 and 2,000 cps by the exhausting of air from the ports, and in the frequencies above 2,000 cps by the resonant frequencies of steel drill parts and of drill steel; (2) satisfactory instruments and instrumentation systems are available for field and laboratory measurements; (3) reliable sound measurements can be made in mining environments; and (4) devices can be developed that will abate the noise.

Jan 1, 1963

By E. Morrice

The Bureau of Mines investigated methods for beneficiating platinum-palladium ores from the Stillwater Complex, Montana. Results of bench-scale and pilot-scale studies employing froth flotation to recover sulfide concentrates containing platinum-palladium values from a serpentinized ore are presented. Best results in the pilot mill were obtained with a sodium isobutyl xanthate-normal dodecyl mercaptan col-lector combination at a natural pH of 8.2. A rougher concentrate con-taining 1.7 oz/ton Pt and 4.7 oz/ton Pd was prepared. Recoveries of platinum and palladium were 96 pet and 86 pet, respectively. Batch cleaner flotation of rougher concentrates yielded concentrates contain-ing 3.7 oz/ton Pt and 9.8 oz/ton Pd.

Jan 1, 1984

By Charles H. Atkinson

The Rio Blanco massive hydraulic fracturing demonstration has been undertaken by the Bureau of Mines, Atomic Energy Commission, and a group of 15 industry participants. CER Geonuclear Corp. has been retained as program manager to evaluate the stimulation effects of very long fractures, suitably propped open in thick sections containing multiple intervals of low-permeability gas-bearing sands. The zone of interest for this demonstration includes Fort Union and Mesaverde sands from about 5,800 to 8,.200 feet deep in Rio Blanco County, Colo., about 1 mile from the site of the May 1973 triple nuclear detonation aimed at stimulating production from the same reservoirs. Drilling the test well and evaluating the reservoir prior to fracturing was funded by Government participants; fracturing and production testing will be funded by industry. The test well has row been completed at a total depth of 8,170 feet, and data obtained from logs, cores, production and drill-stem tests indicate reservoir conditions to be less favorable for gas production than anticipated. Structural position is lower than expected, resulting in higher water saturation than was determined for the same sands at the nuclear fracturing location. The lower sands of the Fort Union sequence appear to have higher shale content than has been encountered in other wells in the area. Despite the likelihood that gas productivity will be undesirably low following stimulation, the industry participants decided to proceed with the stimulation program with the thought that the resulting data would be useful. The success of the stimulation test probably will have to be judged by production increase rather than by production volume.

Jan 1, 1975