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By M. J. Ferrante

Relative enthalpies of V20S from 298.15 to 1,101.0 K were measured at the Bureau of Mines to provide data needed for the advancement of min-eral technology. Enthalpies were measured with a copper-block calorimeter. A sharp melting point was found at 951 K, with [~~ = 15.690 kcal/ mol ] for the standard enthalpy of melting. Tabulated values are given at selected temperature increments between 298.15 and 1,500 K for the standard relative enthalpy [(HO -H~98),] heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)/T]. Standard relative enthal-pies are also given in equation form and combined with data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation.

Jan 1, 1986

By J. W. Town

This report summarizes the results of laboratory investigations conducted by the Federal Bureau of Mines to obtain hydrometallurgical information on the dissolution of mercury sulfides from ores, flotation concentrates, and pure mercuric sulfides. Statistical methods were used to design the experiments and evaluate the resulting data. Studies demonstrated that cinnabar is readily soluble in sodium sulfide, partly soluble in potassium sulfide, and essentially insoluble in ammonium sulfide. Additions of sodium hydroxide or potassium hydroxide to sodium sulfide solutions increased mercury extraction slightly; when either was added to potassium sulfide or ammonium sulfide solutions, mercury extraction was equal to that of sodium sulfide. Tests at the Albany Metallurgy Research Center showed that sodium sulfide would completely dissolve chemically pure mercuric sulfide, more than 95 percent of the cinnabar in 5-percent mercury flotation concentrates, and 60 to 90 percent of the cinnabar in low-grade ores. The double-leach tests showed that potassium sulfide would dissolve over 90 percent of the arsenic in mercury-arsenic products and 1 to 10 percent of the mercury; then sodium sulfide-hydroxide solutions would dissolve 80 to 90 percent of the remaining mercury and 5 to 10 percent of the arsenic.

Jan 1, 1961

On 26 August 1971, the Bureau of Mines, through the Spokane Mining Research Center at Spokane, Washington, approved initiation of the evaluation of oscillatory energy toward enhancing flow of polymer into shale. The effort was an outgrowth of work performed under Bureau of Mines Contract H0210055, "Feasibility Study of Surface Impregnation equipment for the Chemical Stabilization of Coal Mine Structures," wherein feasibility of the impregnation concept was expressed and the detailed design of a machine for impregnation of coal mine roofs with polymer (under static pressure head) accomplished. Under these efforts, the potential enhance¬ment of polymer uptake into the shale thru superposition of oscillatory energy on the static impregnation pressure was suggested. A proposal for investigation of this phenomena entitled "Feasibility Study of the Application of Oscillatory Energy as an Aid to Afford Chemical Stabilization" was presented to the Bureau whereupon a three month program for initiation of investigation was approved.

Jan 1, 1972

From time to time the Bureau of Mines has interpreted and applied certain provisions of the Federal Coal Mine Safety Act and Federal Mine Safety Codes, primarily for the guidance of Federal Coal Mine Inspectors. Although interpretations of the Act have appeared in the Federal Register, the Code interpretations and practical applications have not been published. In response to many requests from representatives of the coal-mining industry, the Bureau is publishing this information to promote better understanding of those provisions that may be misinterpreted or misapplied. INTERPRETATIONS AND APPLICATIONS Two Federal Mine Safety Codes are discussed in this report, namely the Federal Mine Safety Code for Bituminous-Coal and Lignite Mines of the United States, Part 1, and the Federal Mine Safety Code, Anthracite Mines of the United States, Part 1. In this circular the word Codes refers to both directives; Code* refers to the code for bituminous-coal and lignite mines; Code? refers to the one for anthracite mines. Act* refers only to bituminous-coal and lignite mines.

Jan 1, 1963

A prototype EM Location System was fabricated and tested at the Geneva Mine near Dragerton, Utah. This system consisted of six manpack transmitters and six manpack receivers covering the frequency band from 900 Hz to 2900 Hz as well as a six channel receiver designed for use in a helicopter. Tests showed that EM signals from lightweight (314 lb) transmitters could be detected both on the surface and from a helicopter through -2 as much as 1650 ft of relatively high conductivity (2 X 10 mhos/m) over- burden. Furthermore, the resulting field strength profiles could be used to determine source location to within 150 ft of the actual surveyed location in the mine. Modifications were made to a Monitoring, Locating and Communications System being tested at the Bruceton Mine, Pittsburgh, Pennsylvania. These modifications have improved the performance and quality of the paging and voice telephony mode of the system. Subsurface receiver modifications have improved reception of voice downlink signals.

Jan 7, 1973

By Howard W. Kilau

The U.S. Bureau of Mines is investigating surfactants added to water sprays to enhance the control of dust during coal mining operations. The objective of the present work was to establish the general applicability of adding sulfate ion to anionic surfactant solutions in order to improve wetting action. This was pursued through laboratory wettability testing of four anionic surfactants and one nonionic surfactant in combination with various concentrations of sulfate ion. The experimental results demonstrated that the addition of sulfate ion enhanced the wetting characteristics of all the anionic surfactants when applied to hard-to-wet coals, while easy-to-wet coal showed more complex wetting behavior. Sulfate ion in the presence of nonionic surfactant enhanced wetting only slightly or not at all. Surface tension measurements of the dilute aqueous surfactant-sulfate anion solutions indicated this property was not important in coal-wetting phenomena, as long as the value was below the critical value for coal. Sulfate ion helps surfactant reduce surface tension but primarily appears to affect wetting action by altering the adsorption characteristics of surfactant on the coal surface.

Jan 1, 1990

By P. L. Sibrell

Previous research by the U.S. Bureau of Mines has shown that autoclave cyanide leaching of used automobile exhaust catalysts for recovery of platinum-group metals (PGM) is technically feasible. The purpose of this work was to investigate the chemistry of the dissolution of PGM in cyanide solutions in more detail. Where possible, samples of pure, elemental PGM powders or foils were used instead of automobile exhaust catalysts, because of their greater purity. Ultraviolet spectra revealed that Pt and Pd were solubilized as the square planar tetracyanometallate (II) complexes, while Rh was solubilized as the octahedral hexacyanorhodate (III) complex. This explained the poor recovery of Rh from solution by carbon adsorption, solvent extraction, and ion exchange observed in earlier research, because of the higher anionic charge and size of the octahedral complex. Leaching rate studies showed that the rate of solubilization was greatest for Pd, followed by Pt and Rh. Although the rate of chemical reaction was the controlling step for the dissolution of elemental Pt and Rh samples, the rate of pore diffusion was rate limiting for PGM in catalyst samples.

Jan 1, 2010

Determine safe practices for surface mine blasting near pressurized gas, oil, and water transmission pipelines. Background Surface mine blasters regularly have to address the issue of how blasting affects transmission pipelines that run near and sometimes through their permit areas. Regulatory approaches to blasting have ranged from no regulation at all to strict limits intended to prevent cosmetic cracks in plaster interior walls of homes, but they have not directly addressed the impact of blasting on nearby pipelines. Concerned with both productivity and safety, the mining industry and its regulators have requested guidance on safe practices for mining near pipelines. The Pipeline Research Group of the American Gas Association has sponsored studies of the effects of small close-in blasts because of vibration concerns related to the installation of new pipes into existing pipeline right-of-ways. By contrast, the recent study in which the U.S. Bureau of Mines (USBM) took part is the first addressing large-scale mining blasts.

Jan 1, 1995

Viable domestic mineral industries are essential to the economic health of the United States and the well-being of its citizens. The charts in this publication reflect developments significant to the Nation's mineral industries during 1975. Last year was a year of reduced activity for the Nation's mineral industries. Although the value of the country's total mineral output rose, for example, the overall production and use of many minerals fell. At the same time, the industry experienced lower profits and higher debt/equity ratios. These and other adverse effects on many segments of the Nation's mineral industries resulted from the overall decline in domestic and international economic activity.

Jan 1, 1976

By J. M. Stuve

In this Bureau of Mines investigation, the low-temperature heat capacities of polycrystalline phases corresponding to the sulfide compounds CoSO?89' CoS1?33, and CoS2 were measured by adiabatic calorimetry within the nominal temperature range 5 to 300 K. The derived absolute entropies S298 were 10.36±O.02, 12.96±O.03, and 16.31±O.03 cal?mol-1?K-l, respectively, assuming third-law behavior. In addition, the standard enthalpy of formation 8Hf298 of CoSO?89 was determined by bromine solution calorimetry. The derived value of 8Hf298 was -50.63±2.1 kcal?mol-1, based on the 8Hf298 of Co0. This result is considerably more negative than previously published formation values based on high-temperature gas equilibrium studies.

Jan 1, 1985

By W. H. Kerns

The Critchfield manganese deposit, Huntingdon County, Pa., was investigated by the Bureau of Mines in October 1942. Iron ore was mined from an open cut just southeast of the manganese deposit about 80 years ago. The Critchfield Sand & Feldspar Co. was operating (1942) a clay-mining and beneficiation plant northeast of the manganese deposit. The Bureau completed six rotary bucket-drill holes and three hand-auger holes, aggregating 370 feet on the deposit. This report describes the work performed and presents the results obtained.

Jan 1, 1948

By Robert R. Stein

Using an automated drill test fooure, the U.S. Bureau of Mines measured the sound power levels produced by a small, pneumatic, rotary roof drill. A series of tests was conducted to determine (1) the relative effectiveness of several drill muffling schemes and (2) the relationship between drill sound power and pneumatic power supplied to the drill. The influence of rotation rate (i.e., airflow) and feed thrust on the penetration rate of the drill was also noted.

Jan 1, 1989

By Gloria L. Walker

The Bureau of Mines Information and Analysis Directorate collects worldwide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. This data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), to place the collection of mineral statistics on an annual basis. The most recent authority for the Bureau of Mines Information and Analysis activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress), which strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1990

By R. E. Lindstrom

Electrooxidation techniques were investigated on a bench scale by the Bureau of Mines to determine the applicability of the process for extracting molybdenum and rhenium from low-grade molybdenite concentrates. Parameters affecting the extraction, such as pulp density, power consumption, reagent requirements for pH control, and electrolytic cell configuration, were studied. Molybdenum and rhenium extractions of 98 to 99 percent were achieved from several concentrates containing 4.76 to 28.6 percent molybdenum and 180 ppm to 1,000 ppm rhenium. Optimum results were obtained by maintaining pH values between 5.5 and 7.0 during electrolysis and allowing the final pH to rise to about 8.2. Reagent consumption was 4 to 6 pounds of sodium carbonate per pound of molybdenum extracted. The power consumption declined from a range of 12 to 25 kilowatt hours per pound of molybdenum extracted with immersion electrodes to 9.7 kilowatt hours with a bipolar flow-through cell; however, molybdenum extraction was independent of cell configuration.

Jan 1, 1973

By R. G. Nelson

This report covers investigations of the Bureau of Mines for the period of June 15, 1952, to June 15, 1953, on a research project for the Materials Laboratory, Wright Patterson Air Force Base, Dayton, Ohio. The primary purpose of this investigation was to make high-purity chromium-base alloys having room-temperature ductility and high-temperature strength. The Nonferrous Metals Branch of the Bureau of Mines, Albany, Oreg., has, during the past 7 years, developed on a laboratory scale a hydrogen treatment method for making high-purity chromium that can be fabricated into thin sheet and wire. This material can be bent at room temperature. The object of this investigation was to use this material to develop improved chromium-rich alloys for high-temperature uses.

Jan 1, 1955

By H. H. Schrenk

One phase of Bureau of lines work in health and safety is promotion of the use of safe, satisfactory, and reliable respiratory protective devices. To insure that devices embodying these features will be available the Bureau has established schedules of minimum requirements for oxygen breathing apparatus, gas masks4/, supplied-air respirators (hose mask, air-line respirators, and abrasive blasting helmet hoods, or masks)5/, and dispersoid (dust, fume and mist) respirators6/. Approval test, of oxygen¬-breathing apparatus are conducted by the Safety Division; approval tests of other types of respiratory protective equipment are conducted by the Health Division. These divisions comprise the Health and Safety Branch.

Jan 1, 1941

By Edwin B. Cook

This report presents the results of calculations of the equilibrium composition of the products of combustion with air of six different mixtures of octane CgH18, plus PbEt4 and halogen-bearing scavengers at three air-fuel ratios, at pressures of 5 and 30 atm., and at temperatures of 350°, 1,000°, 1,800°, and 2,000° K. The air-fuel weight ratio has the values 12, 15:12, and 18. The concentration of PbEt4, M, in milliliters per gallon of iso-octane, has the value 1 or 3. The word "case" is used to designate the halogen concentration. Three cases have been considered [ ]

Jan 1, 1953

By Wallace W. Roepke

The Bureau of Mines tested new designs of drag bit cutters with sintered diamond inserts instead of standard tungsten carbide tips. The bits were tested for orthogonal cutting forces, primary dust generation, and incendivity, with a standard plumb-bob type conical cutter (600 included tip angle) as the reference. Preliminary wear and impact-failure testing were also done. The results were mixed. Two new designs had forces similar to those of the reference bit, but one new design had about twice the normal force. This same design had almost twice the specific energy during shallow cutting but generated an equal or slightly lower amount of primary dust than did the reference bit. Incendivity was eliminated for two radial designs. One conical design had ignition only after more than 15 impacts, but the other conical design was incendive. Impact failure occurred, but not so quickly as anticipated. Over 7,500 impacts on a sandstone face, with a total cutting distance of more than 1,981.2 m, only scuffed the leading edge of the sintered diamond cutting face but put hairline cracks in the substrate mounting pad. Additional design and testing are needed to develop an optimum cutter, but prospects look good for this material.

Jan 1, 1983

By D. C. Dahlin

The Bureau of Mines conducted laboratory batch beneficiation tests on samples from four potential platinum resources in southeastern Alaska to concentrate platinum and other precious metals. Thin Investigation was done as part of the mission of the Bureau to insure an adequate supply of minerals to meet the Nation's needs. Petrographic studies and beneficiation methods including gravity concentration, froth flotation, and magnetic separation were used to determine mineral association and to attempt to concentrate the platinum values with a primary mineral value such as chromite, copper sulfide, or magnetite. A high-graded sample from the Salt Chuck copper sulfide deposit yielded the platinum-group metal concentrate; the maximum grade attained was 0.04 oz Pt and 1.5 oz Pd per ton of high-grade copper sulfide concentrate. The other samples yielded low-grade primary mineral concentrates with low platinum-group values, and/or the platinum-group metals did not concentrate with the primary mineral value.

Jan 1, 1981

By Margaret R. Egan

The U.S. Bureau of Mines conducted experiments in the intermediate-scale fire tunnel to assess the influence of air velocity on the gas production and smoke characteristics during smoldering and flaming combustion of Pittsburgh seam coal and its impact on the detection of the combustion products. On-line determinations of mass and number of smoke particles, light transmission, and various gas concentrations were made. From these experimental values, generation rates, heat-release rates, production constants, particle sizes, obscuration rates, and optical densities were calculated. Ventilation has a direct effect on fire detection and development. The results indicate that, in general, increased air velocity lengthened the onset of smoke and flaming ignition, increased the fire intensity, but decreased the gas and smoke concentrations. Increased air velocity also lengthened the response times of all the fire sensors tested. Rapid and reliable detector response at this most crucial stage of fire development can increase the possibility that appropriate miner response (fire suppression tactics or evacuation) can be completed before toxic smoke spreads throughout the mine.

Jan 1, 2010