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By Donald S. Colby

CARBON-BLACK shipments, which had declined in the latter art of 1953, remained low in 1954 until after settlement of the labor strike that occurred in the rubber industry in July and August. The production of new model automobiles in the last quarter of the year spurred the demand for rubber tires and consequently the demand for carbon black. Total shipments of 1,498 million pounds for the year were 4 percent below 1953.

Jan 1, 1958

By Bernard Porter

The densities of LiF, NaF, and KF, of binary mixtures of these alkali fluorides, and of binary mixtures of UF4, ThF4, YF3, LaF3, and CeF with each of tie alkali fluorides were measured as functions of the melt composition and temperature. Molar volumes at 1,000° C were calculated for all the mixtures. Binary systems containing LiF exhibited molar volume ideality. Binary fluoride systems containing either NaF or KF as the alkali fluoride exhibit positive deviations from molar volume additivity. However, molar volumes in the NaF-KF system are ideal.

Jan 1, 1966

By Rita D. Sylvester

"IntroductionThe Bureau of Mines was established in the public interest to conduct inquiries and scientific and technologic investigations concerning mining and the preparation, treatment, and utilization of mineral substances; to promote health and safety in the mineral industries; to conserve material resources and prevent their waste; to further economic development; to increase efficiency in the mining, metallurgical, quarrying, and other mineral industries; and to inquire into the economic conditions affecting these industries. The organic act of the Bureau, as amended by Congress and approved February 25, 1913, made it the province and duty of the Bureau to ""disseminate information concerning these subjects in such manner as will best carry out the purposes of this Act.""In accordance with this directive, the Bureau reports the findings of its research and investigations in its own series of publications and also in articles that appear in scientific, technical, and trade journals; in proceedings of conventions and seminars; in reference books; and in other non-Bureau publications. The number of these reports, the wide range of subjects they cover, and the variety of mediums in which they appear make the kind of list and index presented in this special publication both necessary and valuable. This issue describes reports and articles published during the period January I, 1965, to December 31, 1969. It supplements the 50-year list of Bureau publications issued from July 1, 1910, to January I, 1960;' the 50-year list of articles by Bureau authors published outside the Bureau from July 1, 1910, to January I, 1960;3 the 5-year list of Bureau publications and articles from January I, 1960, to December 31, 1964.' It includes all the material in the four annual lists of Bureau publications and articles from January 1, 1965, to December 31, 1968, as well as the Bureau publications and articles for 1969."

Jan 1, 1970

By J. P. Walsted

The lack of an iron-smelting industry in the Pacific Northwest places the ferrous metals industries under an economic handicap. No iron-smelting enterprises, now dormant, had been operated successfully. Iron made at both of hoes installations proved to be satisfactory for normal pig-iron uses. Electric power and reductants acre available in the area. Power from the dames now completed and. those being constructed insures present and future needs for basic industries. Subbituminous coal, close to the main supply of iron ore, insures ample reluctant for all smelting requirements.

Jan 1, 1954

By Charles L. Kimbell

While the statistical summary focuses on 1991 data, this update and outlook section draws on information available to the author as of the date of final preparation in early 1993. For all the press notoriety associated with the shift in the Near East crisis from the defensive posture of Desert Shield to the restoration of Kuwaiti sovereignty through Desert Storm, this was not the dominant event governing global economic thinking in 1991 and the first half and more of 1992. From the global perspective, the momentous political changes in the area that was the U.S.S.R. and in the smaller emerging transitional economy states of Eastern Europe will have even greater current and long-lasting effects on world mineral industry activities than the crisis in the Near East.

Jan 1, 1993

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963

By W. D. Mcmillan

Preliminary examination of the north-central Kansas clay deposits was made by the junior author during March 1943. He was accompanied by Norman Plummer, ceramist of the State Geological Survey of Kansas. Three areas Nacre selected for further investigation. Detailed field investigation by the Bureau, consisting of hand auger drilling, trenching, anti. test pitting to obtain representative samples of the clays was carried on from April to June 1943. Field .work was under the direction of Edgar B. Butte and Richard L. Schumacher, former Bureau of Mines engineers. The samples taken were analyzed at the Bureau of Mines laboratory at Rolla, Mo. Factual data obtained from the field investigation and laboratory work are set forth in this report.

Jan 1, 1948

By J. M. Stuve

Standard heats of formation (AH°p) of YbCl3 (c) and TmCl3 (c) were measured by solution calorimetry. Heat of solution data are given for ytterbium and thulium metals and corresponding anhydrous trichlorides in 4.360 molal hydrochloric acid. The derived standard heats of formation of YbCl3 (c) and TmCl3 (c) were -229,370 ±720 and -235,820 ±400 cal/mole, respectively, at 298.15° K. The resulting heats of formation for YbC13 and TmCl3 are about 1 kcal and 6.3 kcal more negative than previously published values.

Jan 1, 1967

By L. B. Pankratz

High-temperature heat-content values of gallium and scandium sesquioxides were measured over the temperature range from 298° to 1,800° K. The results fill gaps in the thermodynamic information for these compounds; no previous similar data existed. The heat-content values were combined with heats and entropies of formation to obtain free energies of formation of gallium and scandium sesquioxides to 2,000° K. The thermodynamic stabilities of the sesquioxides of aluminum, gallium, scandim, and yttrium were compared.

Jan 1, 1963

By Elizabeth G. Baglin

Research was conducted by the Bureau of Mines to determine the feasibility of using electrokinetic densification to dewater Bayer process red mud, magnetic black mud prepared by pressure digestion of red mud in the presence of ferrous sulfate, and magnetic black mud formed by simu-lated Bayer digestion of Jamaican bauxite with added ferrous sulfate. Tests showed that the solids content of presettled muds could be increased from 25 pct to approximately 40 to 48 pct by gravity draining followed by electrodewatering for approximately 48 h. Electrodewatering may not be practical because of increased reagent and processing costs and because the muds must be thoroughly washed prior to electrodewatering to remove dissolved ions and decrease mud conductivities.

Jan 1, 1988

By M. E. Tyrrell

Mixtures of zirconium diboride and iron, cobalt, and nickel were resistance sintered to high-density compacts using modified electric welding equipment. To evaluate the use of iron, cobalt, or nickel as binders for zirconium diboride, the sintered compacts were examined in polished section and tested for crushing strength, hardness, microhardness, oxidation rate, and resistance to mechanical shock. Each of the zirconium diboride-metal mixtures produced brittle cermets, but the hardness was generally satisfactory. The iron- and cobalt-bonded cermets exhibited rather poor oxidation resistance. Cobalt provided the least brittle bond, and nickel, the hardest and most resistant to oxidation. Iron tended to form chalky compacts with low resistance to mechanical shock.

Jan 1, 1963

By D. E. Shanks

As part of its effort to produce cell-grade alumina from clay, the Bureau of Mines investigated the hydrogen chloride gas-sparging crystallization of aluminum chloride hexahydrate (ACH) from aluminum chloride liquor, to provide information for optimizing the crystallization operation. Four parameters important in controlling the crystallization of the aluminum chloride hexahydrate and the concentration of impurities, particularly phosphorus and magnesium, in ACH crystals are (1) aluminum chloride concentration in the feed solution to crystallization, (2) hydrogen chloride gas flow rate, (3) temperature, and (4) concentration of phosphorus and magnesium also in the feed solution. Parameters 1, 2, and 3 affect crystal formation. The combined effects are very important because the phosphorus and magnesium concentrate in the crystals during the early stages of crystal growth. Aluminum chloride hexahydrate of cell-grade purity was crystallized from saturated aluminum chloride solutions containing less than 0.003 wt-pct P205 and 0.010 wt-pct MgO. Crystallization temperatures less than 600 C decreased crystal purity.

Jan 1, 1981

By M. J. Ferrante

Enthalpy and entropy increments above 298.15° K were determined for cop-per sulfate between 298° and 1,000° K and for copper oxysulfate between 2980 and 1,146° K by the method of copper-block drop calorimetry. Enthalpies, entropies, and heat capacities are tabulated for both compounds. In addition, free-energy functions are tabulated for the sulfate. Equations representing the enthalpies are given for each compound.

Jan 1, 1972

By T. Estelle Gardner

Heat-capacity measurements were made over the range 8° to 350° K on beryllium sulfate dihydrate and beryllium sulfate tetrahydrate using an adiabatic calorimeter. No anomalies were noted in the curve for either compound. Smooth values of heat capacity, entropy, enthalpy function, and free-energy function were calculated from the heat-capacity data at 10° K intervals and at 273.15° and 298.15° K. The entropy values calculated at 298.15° K were 39.01 ± 0.12 entropy units (eu) for the dihydrate and 55.68 ± 0.17 eu for the tetrahydrate.

Jan 1, 1967

By Mark I. Copeland

Bureau of Mines researchers investigated the combined effect of copper and tin additions on the mechanical properties of hot-rolled steels. Wrought steels containing 0.2 wt-pct C and up to 0.2 and 1.0 wt-pct Sn and Cu, respectively, were made and evaluated by conducting tensile and impact tests and electron-beam microprobe and electron microscopy examination. Tin additions did not significantly affect the tensile properties of steel at different copper contents in the hot-rolled condition. Tin lowered the copper content at which strengthening by copper precipitation normally starts, 0.8 wt-pct, and decreased the strength of steel aged at 1,022° F (550° C). The most adverse effect of tin was lowering the notch toughness of steels at most copper contents.

Jan 1, 1976

By Leon W. Dupuy

"INTRODUCTION Scheelite occurring in tactite at the Black Rock tungsten mine, near Benton in Mono County, Calif., was investigated by the Bureau of Mines in cooperation with the Geological Survey as part of their search for additional sources of supply of strategic minerals authorized under the Strategic Materials Act. 3/4/The work accomplished by the Bureau, and the assays of samples taken are described in this manuscript. The ore found aided materially in prolonging the operating life of the mine during the recent national emergency, supplying much-needed tungsten for war use. ACKNOWLEDGMENTSIn its program of investigations of mineral deposits, the Bureau of Mines has as its primary objective the more efficient utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, under the direction of Lowell B. Moon, chief, conducts preliminary examinations, performs the actual development work, and prepares the final report. The Metallurgical Division, under the direction of C. C. Ralston, chief, analyzes samples and performs beneficiatibn tests."

Mar 1, 1948

By Renpei Yoda

An investigation was conducted to develop columbium alloys with e1evated-temperature strengths higher than those exhibited by more common commercial columbium alloys, and attention was given to improving the oxidation resistance and ease of fabrication. Additions of carbon, aluminum, and chromium were made to some columbium-base alloys, and their effects on workability, recrystallization, oxidation resistance, and mechanical properties at elevated temperatures were explored. The additions were made to take advantage of (1) solid solution strengthening, and (2) precipitation hardening. Three alloys displayed good high-temperature properties with relatively good oxidation resistance at 1,000° C, and tensile strengths from 26,000 to 32,200 psi at 1,400° C. When the properties of these alloys were compared with those of commercial alloys, B-66 and FS-85 (1),4 the outcome was favor-able for the alloys studied in this investigation.

Jan 1, 1967

By Frank D. Lamb

Four samples of manganese-bearing material from the Aroostook County, Maine, deposits were tested at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., to determine their amenability to beneficiation by ore-dressing methods. The samples represented material from the Maple Mountain-Hovey Mountain deposit, the Dudley farm, and the Burnham farm and contained 11 to 14 percent manganese. None of the tests produced appreciably enriched concentrates suitable for further treatment for the production of ferromanganese. The intimate association of the manganese minerals with iron and siliceous minerals requires extremely fine grinding to liberate the manganese minerals in these ores and prevents efficient concentration by physical means.

Jan 1, 1953

By D. R. Forshey

The recent occurrence of fatal accidents in copper mines, presumably due to premature ignition of loaded holes by the heat from reacting ammonium nitrate-fuel oil (AN-FO) and pyrite-bearing ores, has led to an examination of this reaction. The reactivity of prilled AN-FO mixtures with pyrite-bearing ores and the effects of water, dilute sulfuric acid, and potential inhibitors on reactivity of the mixtures were evaluated. Initiation of an exothermic reaction was observed as low as 150° F with acid in the absence of inhibitors. Low concentrations of urea, calcium carbonate, zinc oxide, and magnesium oxide were effective in inhibiting the reactivity of the mixtures. The temperatures produced during the reaction of mixtures of AN-FO and pyrite-bearing ores, in the absence of inhibitors, always exceeded the temperature at which electric blasting caps are thermally initiated.

Jan 1, 1968

By L. C. IlsLey

Minin,g Qr col-cu.ttint till:I chines are 1?;\i9ng the _m9t wideiy .used de1sses ()f mining equipment.· These 1T:.i:1Chines ,.--re practicaily t-tl\·operc1_ted eiyher_by compressed .iir or by electric. ·motors. According to &.ta• compiled _ from the 122. issue COAL CATALOG\JE. OJMEINED WITH; OOAL "FIELD 'pf!:fC'TOTl1, bf 7,088. mnes from which reports were obttiined there -are 3895 mines that u.se coal-cutting eql;lipmen:ts,, 'f'hi report lists 20,031: r.ct:lchines, 17,&75 being operated by·elct:i.c.m<;>_tors··:r;id :the remtiinder by compressed i.r motors,· ,-. · ', .. . · .. ··, .. _ ,· .,, .. .. . . . . . : ; "'l t:: On tl.Ccou-nt .. of the wide· use of coc:11-cutting -.:i"cliine_- any Stat!;ls have issued regulationa as "to their operation dnd be to safety precautions that.should be observed J especially in gaseous mines.

Oct 1, 1922